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Laser Ablation Atomic Beam Apparatus with Time-Sliced Velocity Map Imaging for Studying State-to-State Metal Reaction Dynamics
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作者 董常武 刘嘉兴 +1 位作者 李芳芳 王凤燕 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2016年第1期99-104,I0002,共7页
We report a newly constructed laser ablation crossed molecular beam apparatus, equipped with time-sliced velocity map imaging technique, to study state-to-state metal atom reaction dynamics. Supersonic metal atomic be... We report a newly constructed laser ablation crossed molecular beam apparatus, equipped with time-sliced velocity map imaging technique, to study state-to-state metal atom reaction dynamics. Supersonic metal atomic beam is generated by laser vaporization of metal rod, and free expansion design without gas flow channel has been employed to obtain a good quality of metal atomic beam. We have chosen the crossed-beam reaction Al+O2 to test the performance of the new apparatus. Two-rotational-states selected AIO(X^2∑+, v=0, N and N+I4) products can be imaged via P(N) and R(N+14) branches of the Av=l band at the same wavelength, during (1+1) resonance-enhanced multi-photon ionization through the AIO(D2E+) intermediate state. In our experiment at 244.145 nm for simultaneous transitions of P(15) and R(29) branch, two rings in slice image were clearly distinguishable, corresponding to the AiO(v=0, N=IS) and AIO(v=0, N=29) states respectively. The energy difference between the two rotational levels is 403 cm^-1. The success of two states resolved in our apparatus suggests a better collisional energy resolution compared with the recent research study [J. Chem. Phys. 140, 214304 (2014)]. 展开更多
关键词 time-sliced velocity map imaging Crossed beam Laser ablation Metal atom reaction dynamics
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Photodissociation Dynamics of Dichlorodifluoromethane(CF2Cl2) around 235 nm using Time-Sliced Velocity Map Imaging Technology 被引量:1
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作者 Rui Mao Hong Xiao +2 位作者 Yu Hu Qun Zhang Yang Chen 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2019年第4期406-410,I0002,共6页
Photodissociation dynamics of dichlorodifluoromethane (CF2Cl2) around 235 nm has been studied using the time-sliced velocity map imaging technology in combination with the resonance enhanced multi-photon ionization te... Photodissociation dynamics of dichlorodifluoromethane (CF2Cl2) around 235 nm has been studied using the time-sliced velocity map imaging technology in combination with the resonance enhanced multi-photon ionization technology. By measuring the raw images of chlorine atoms which are formed via one-photon dissociation of CF2Cl2, the speed and angular distributions can be directly obtained. The speed distribution of excited-state chlorine atoms consists of high translation energy (ET) and low ET components, which are related to direct dissociation on 3Q0 state and predissociation on the ground state induced by internal conversion, respectively. The speed distribution of ground-state chlorine atoms also consists of high ET and low ET components which are related to predissociation between 3Q0 and 1Q1 states and predissociation on the ground state induced by internal conversion, respectively. Radical dissociation channel is confirmed, nevertheless, secondary dissociation and three-body dissociation channels are excluded. 展开更多
关键词 DICHLORODIFLUOROMETHANE time-sliced velocity map imaging technology Internal conversion
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Photodissociation Dynamics of AlO at 193 nm using Time-Sliced Ion Velocity Imaging
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作者 Fang-fang Li Yu-jie Ma +2 位作者 Jia-xing Liu Guan-jun Wang Feng-yan Wang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2020年第5期649-652,I0079,共5页
The photodissociation dynamics of Al O at 193 nm is studied using time-sliced ion velocity mapping.Two dissociation channels are found through the speed and angular distributions of aluminum ions:one is one-photon dis... The photodissociation dynamics of Al O at 193 nm is studied using time-sliced ion velocity mapping.Two dissociation channels are found through the speed and angular distributions of aluminum ions:one is one-photon dissociation of the neutral AlO to generate Al(2 Pu)+O(3 Pg),and the other is two-photon ionization and then dissociation of AlO^+to generate Al^+(1 Sg)+O(3 Pg).Each dissociation channel includes the contribution of AlO in the vibrational states v=0-2.The anisotropy parameter of the neutral dissociation channel is more dependent on the vibration state of AlO than the ion dissociation channel. 展开更多
关键词 time-sliced ion velocity imaging PHOTODISSOCIATION ALO Vibrational state 193 nm
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Crossed-Beam Studies of Aluminum Atom Cooling via Inelastic Collisions with O_(2)Molecules
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作者 Dong Yan Yujie Ma +5 位作者 Ang Xu Fei Song Ti Zhou Zihan Yuan Xiyu Liu Fengyan Wang 《Chinese Journal of Chemical Physics》 2025年第5期575-581,I0147,共8页
The pioneering works have demonstrated that the method of single collisions in crossed molecular beams is an important technique for achieving kinetic cooling of atoms or molecules in specific rotational states.In thi... The pioneering works have demonstrated that the method of single collisions in crossed molecular beams is an important technique for achieving kinetic cooling of atoms or molecules in specific rotational states.In this study,we investigated the elastic and inelastic collisions between Al(^(2)P_(1/2))metal atoms and O_(2)molecules at high collision energies in the range of 6.4-14.8 kcal/mol,utilizing the laser-ablation crossed beams in conjunction with time-sliced ion velocity map imaging technique.We observed kinetic cooling of Al(^(2)P_(1/2))atoms with an upper-limit laboratory-frame root-mean-square velocity of 24±3 m/s,corresponding to a translational temperature of 0.9±0.2 K in the laboratory frame,facilitated by the vibrational excitation of O_(2)(v′=1)in inelastic collisions.The translational cooling of Al atoms in the lab frame enhanced detection probability in the transformation of density-to-flux,as evidenced by the scattering images obtained during the experiments. 展开更多
关键词 Crossed molecular beams time-sliced ion velocity mapping Kinetic cooling Energy transfer
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Characterizing S(^(1)D)Atoms Formed by Exciting D_(2)S Molecules via Intense Rydberg Resonances at Wavelengths~139.1 nm and~129.1 nm
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作者 Zijie Luo Shunyang Zhou +9 位作者 Yucheng Wu Shuaikang Yang Zhenxing Li Yongxin Dong Wei Hua Quan Shuai Li Che Michael N.R.Ashfold Kaijun Yuan Xueming Yang 《Chinese Journal of Chemical Physics》 2025年第6期777-787,I0237,共12页
We report high-resolution velocity map imaging studies of S(^(1)D)atoms formed following excitation on two intense absorption bands of gas phase D_(2)S molecules,centred at wave-lengths~139.1 and~129.1 nm.DS–D bond f... We report high-resolution velocity map imaging studies of S(^(1)D)atoms formed following excitation on two intense absorption bands of gas phase D_(2)S molecules,centred at wave-lengths~139.1 and~129.1 nm.DS–D bond fission is the dominant fragmentation pathway at these wavelengths,yielding SD fragments in both the ground(X)and excited(A)electronic states.Most S(^(1)D)atoms arising via 21A′21A′the rival S atom elimination channel when exciting at~139.1 nm are formed with D_(2)partners,in a wide range of rovibrational levels.The partially resolved structure in the total translational energy distributions,P(ET),derived from the S(^(1)D)atom images,implies two dynamical routes into S(^(1)D)+D_(2)products following non-adiabatic coupling from the photo-excited Rydberg state to the dissociative potential energy surface(PES).Similar D_(2)products are evident in the P(ET)spectra derived from analysis of S(^(1)D)images from D_(2)S photolysis at~129.1 nm,but their contribution is overshadowed by a feature attributable to three-body dissociation to S(^(1)D)+2D fragments.These atomic products are deemed to arise via a natural extension of the dynamics responsible for the previously observed highly rotationally excited SD(A)fragments arising via the rival S–D bond fission pathway:asymmetric bond extension together with a dramatic opening of the interbond angle driven by torques generated after coupling to the highly anisotropic 2^(1)A′PES,leading to a centripetally-driven break-up. 展开更多
关键词 Vacuum ultraviolet photodissociation Rydberg state time-sliced velocity map ion imaging
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Imaging Photodissociation Dynamics of MgO at 193 nm
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作者 Fang-fang Li Yu-jie Ma +3 位作者 Jia-xing Liu Dong Yan Ang Xu Feng-yan Wang 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2022年第2期257-262,I0001,共7页
In this work,we used time-sliced ion velocity imaging to study the photodissociation dynamics of Mg O at 193 nm.Three dissociation pathways are found through the speed and angular distributions of magnesium.One pathwa... In this work,we used time-sliced ion velocity imaging to study the photodissociation dynamics of Mg O at 193 nm.Three dissociation pathways are found through the speed and angular distributions of magnesium.One pathway is the one-photon excitation of Mg O(X^(1)∑^(+))to Mg O(G^(1)Π)followed by spin-orbit coupling between the G^(1)Π,3^(3)Πand ^(1^(5))Πstates,and finally dissociated to the Mg(^(3)Pu)+O(^(3)Pg)along the 1^(5)Πsurface.The other two pathways are one-photon absorption of Mg O(A^(1)Π)state to Mg O(G^(1)Π)and Mg O(4^(1)Π)state to dissociate into Mg(^(3)P_(u))+O(^(3)P_(g))and Mg(^(1)S_(g))+O(^(1)S_(g)),respectively.The anisotropy parameters of the dissociation pathways are related to the lifetime of the vibrational energy levels and the coupling of rotational and vibronic spin-orbit states.The total kinetic energy analysis gives D0(Mg-O)=21645±50 cm^(-1). 展开更多
关键词 time-sliced ion velocity imaging PHOTODISSOCIATION MGO Vibrational state Excited state 193 nm
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Imaging Reaction Dynamics of Y+SO2
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作者 Dong Yan Yu-jie Ma +3 位作者 Fang-fang Li Jia-xing Liu Guan-jun Wang Feng-yan Wang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2020年第2期239-242,I0003,共5页
The reaction dynamics of yttrium atoms with sulfur dioxide molecules at a high collision energy of 36 kcal/mol was studied using time-sliced velocity map ion imaging,crossed molecular beam and laser-ablation method.Th... The reaction dynamics of yttrium atoms with sulfur dioxide molecules at a high collision energy of 36 kcal/mol was studied using time-sliced velocity map ion imaging,crossed molecular beam and laser-ablation method.The product YO was detected via multiphoton ionization at various wavelengths in the region of 482-615 nm.The slice images of YO show a broad velocity distribution and forward-backward peaking angular distribution.The forward scattering signal is stronger than its backward distribution.This indicates that the reaction proceeds via an intermediate complex and the lifetime of the intermediate state is less than one rotational period.The formation of complex suggests that electron transfer occurs in the oxidation reaction. 展开更多
关键词 time-sliced velocity map imaging CROSSED-BEAM Laser ablation Metal atom reaction dynamics SO2
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Advanced Techniques for Quantum-State Specific Reaction Dynamics of Gas Phase Metal Atoms
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作者 Ang Xu Yu-jie Ma +3 位作者 Dong Yan Fang-fang Li Jia-xing Liu Feng-yan Wang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2021年第1期61-70,I0011,共11页
One of the themes of modern molecular reac tion dynamics is to charac terize elementary chemical reactions from“quan tum state to quan tum stat e”,and the study of molecular reaction dynamics in excited states can h... One of the themes of modern molecular reac tion dynamics is to charac terize elementary chemical reactions from“quan tum state to quan tum stat e”,and the study of molecular reaction dynamics in excited states can help test the validi ty of modern chemical t heories and provide met hods to cont rol chemical reactions.The subject of this review is to describe the recent experimental techniques used to study the reaction dynamics of metal atoms in the gas phase.Through these techniques,information such as the internal energy distribution and angular distribution of the nascent products or the three-dimensional stereodynamic reactivity can be obtained.In addition,by preparing metal at oms wi th specific exci ted elec tronic states or orbi tal arrangemen ts,information about the reactivity of the electronic states enriches the relevant understanding of the electron transfer mechanism in metal reaction dynamics. 展开更多
关键词 time-sliced ion velocity map imaging Crossed molecular beams Laser ablation Metal atom reaction dynamics STEREODYNAMICS
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Photodissociation Dynamics of CS_(2) Near 204 nm: The S(^(3)PJ)+CS(X^(1)∑^(+)) Channels
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作者 Min Zhao Zhen-xing Li +8 位作者 Ting Xie Yao Chang Fu-yan Wu Qin Wang Wen-tao Chen Tao Wang Xing-an Wang Kai-jun Yuan Xue-ming Yang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2021年第1期95-101,I0012,共8页
We study the phot odissociation dynamics of CS2 in the ultraviolet region using the time-sliced velocity map ion imaging technique.The S(3 Pj)+CS(X1E+)product channels were observed and identified at four wavelengths ... We study the phot odissociation dynamics of CS2 in the ultraviolet region using the time-sliced velocity map ion imaging technique.The S(3 Pj)+CS(X1E+)product channels were observed and identified at four wavelengths of 201.36,203.10,204.85 and 206.61 nm.In the measured images of S(3Pj=2,1,0),the vibrational states of the CS(X1E+)co-products were partially resolved and the vibrational state distributions were determined.Moreover,the product total kinetic energy releases and the anisotropic parameters were derived.The relatively small anisotropic parameter values indicate that the S(3Pj=2丄0)+CS(X1E+)channels are very likely formed via the indirect predissociation process of CS2.The study of the S(3Pj=2,1;0)+CS(X1E+)channels,which come from the spin-orbit coupling dissociation process of CS2,shows that nonadiabatic process plays a role in the ultraviolet photodissociation of CS2. 展开更多
关键词 Carbon disulfide time-sliced velocity map ion imaging PHOTODISSOCIATION
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Imaging photodissociation dynamics of excited SiO molecules at 193 nm with laser ablation supersonic beam
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作者 Yujie Ma Fangfang Li +4 位作者 Dong Yan Ang Xu Ti Zhou Jiaxing Liu Fengyan Wang 《Chinese Journal of Chemical Physics》 CSCD 2024年第6期807-813,I0042,共8页
SiO is a wide-spread molecule found in interstellar space.Previous research has primarily focused on its spectroscopy,while its photodissociation dynamics is elusive to study due to high dissociation energy.Using time... SiO is a wide-spread molecule found in interstellar space.Previous research has primarily focused on its spectroscopy,while its photodissociation dynamics is elusive to study due to high dissociation energy.Using time-sliced ion velocity imaging technique,we observed the Si(^(3)P)+O(^(3)P)photodissociation process resulting from the excitation of highly vibrationally excited SiO(X^(1)Σ^(+),υ=13-18)molecules to the SiO(A^(1)Π,E^(1)Σ^(+))states at 193 nm.The vibrationally excited SiO molecules were generated via laser ablation of silicon rod with the collision of the oxygen molecular beam acting as carrier gas and reaction gas.The bond dissociation energy D_(e)(Si-O)is determined to be 67253±110 cm^(-1)(8.34±0.01 eV)based on the kinetic energy distribution spectrum.The SiO photodissociation study has deepened our understanding of the mechanisms of silicon chemistry for silica-rich rocky meteors as they burn in the Earth's atmosphere,and the dissociation of SiO from ablation of meteoroids following ultraviolet photon absorption. 展开更多
关键词 PHOTODISSOCIATION SIO Vibrational excitation Laser ablation time-sliced ion velocity imaging
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Scheduling optimization for upstream dataflows in edge computing
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作者 Haohao Wang Mengmeng Sun +3 位作者 Lianming Zhang Pingping Dong Yehua Wei Jing Mei 《Digital Communications and Networks》 SCIE CSCD 2023年第6期1448-1457,共10页
Edge computing can alleviate the problem of insufficient computational resources for the user equipment,improve the network processing environment,and promote the user experience.Edge computing is well known as a pros... Edge computing can alleviate the problem of insufficient computational resources for the user equipment,improve the network processing environment,and promote the user experience.Edge computing is well known as a prospective method for the development of the Internet of Things(IoT).However,with the development of smart terminals,much more time is required for scheduling the terminal high-intensity upstream dataflow in the edge server than for scheduling that in the downstream dataflow.In this paper,we study the scheduling strategy for upstream dataflows in edge computing networks and introduce a three-tier edge computing network architecture.We propose a Time-Slicing Self-Adaptive Scheduling(TSAS)algorithm based on the hierarchical queue,which can reduce the queuing delay of the dataflow,improve the timeliness of dataflow processing and achieve an efficient and reasonable performance of dataflow scheduling.The experimental results show that the TSAS algorithm can reduce latency,minimize energy consumption,and increase system throughput. 展开更多
关键词 Edge computing time-slicing Dataflow scheduling Dynamic analysis
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