Dear Editor,This letter investigates predefined-time optimization problems(OPs) of multi-agent systems(MASs), where the agent of MASs is subject to inequality constraints, and the team objective function accounts for ...Dear Editor,This letter investigates predefined-time optimization problems(OPs) of multi-agent systems(MASs), where the agent of MASs is subject to inequality constraints, and the team objective function accounts for impulse effects. Firstly, to address the inequality constraints,the penalty method is introduced. Then, a novel optimization strategy is developed, which only requires that the team objective function be strongly convex.展开更多
Measuring in-situ stress by using the Kaiser effect in rocks has such advantages as timeefficiency, low cost and little limitation, but the precision of the method is dependent on rock properties and delay time of the...Measuring in-situ stress by using the Kaiser effect in rocks has such advantages as timeefficiency, low cost and little limitation, but the precision of the method is dependent on rock properties and delay time of the measurement. In this paper, experiments on the Kaiser effect in limestones were performed, and it was found that the limestones had good ability to retain a memory of their recent stress history and high time-sensitivity. The longer the experiment was delayed from the extraction of the stone, the larger the Felicity ratio was. As the Felicity ratio approached l, significant Kaiser effect was observed. In-situ stress should be determined by the limestone measurements when the delay time was 40-120 days. Finally, the in-situ stress in a limestone formation could be successfully measured in practice.展开更多
The focus of this study is to investigate the influence of memory effect and the relation of its existence with the dissociation temperature,using gas hydrate formation and dissociation experiments.This is beneficial ...The focus of this study is to investigate the influence of memory effect and the relation of its existence with the dissociation temperature,using gas hydrate formation and dissociation experiments.This is beneficial because memory effect is considered as an effective approach to promote the thermodynamic and dynamic conditions of gas hydrate nucleation.Seven experimental systems （twenty tests in total） were performed in a 1 L pressure cell.Three types of hydrate morphology,namely massive,whiskery and jelly crystals were present in the experiments.The pressures and temperatures at the time when visual hydrate crystals appeared were measured.Furthermore,the influence of memory effect was quantified in terms of pressure-temperature-time （p-T-t） relations.The results revealed that memory effect could promote the thermodynamic conditions and shorten the induction time when the dissociation temperature was not higher than 25℃.In this study,the nucleation superpressure and induction time decrease gradually with time of tests,when the earlier and the later tests are compared.It is assumed that the residual structure of hydrate dissociation,as the source of the memory effect,provides a site for mass transfer between host and vip molecules.Therefore,a driving force is created between the residual structures and its surrounding bulk phase to promote the hydrate nucleation.However,when the dissociation temperature was higher than 25 ℃,the memory effect vanished.These findings provide references for the application of memory effect in hydrate-based technology.展开更多
Presently developed two-phase turbulence models under-predict the gas turbulent fluctuation, because their turbulence modification models cannot fully reflect the effect of particles. In this paper, a two-time-scale d...Presently developed two-phase turbulence models under-predict the gas turbulent fluctuation, because their turbulence modification models cannot fully reflect the effect of particles. In this paper, a two-time-scale dis- sipation model of turbulence modification, developed for the two-phase velocity correlation and for the dissipation rate of gas turbulent kinetic energy, is proposed and used to simulate sudden-expansion and swirling gas-particle flows. The proposed two-time scale model gives better results than the single-time scale model. Besides, a gas tur- bulence augmentation model accounting for the finite-size particle wake effect in the gas Reynolds stress equation is proposed. The proposed turbulence modification models are used to simulate two-phase pipe flows. It can prop- erly predict both turbulence reduction and turbulence enhancement for a certain size of particles observed in ex- periments.展开更多
Presently developed two-phase turbulence models under-predict the gas turbulent fluctuation, because their turbulence modification models cannot fully reflect the effect of particles. In this paper, a two-time-scale d...Presently developed two-phase turbulence models under-predict the gas turbulent fluctuation, because their turbulence modification models cannot fully reflect the effect of particles. In this paper, a two-time-scale dissipation model of turbulence modification, developed for the two-phase velocity correlation and for the dissipation rate of gas turbulent kinetic energy, is proposed and used to simulate sudden-expansion and swirling gas-particle flows. The proposed two-time scale model gives better results than the single-time scale model. Besides, a gas turbulence augmentation model accounting for the f＇mite-size particle wake effect in the gas Reynolds stress equation is proposed. The proposed turbulence modification models are used to simulate two-phase pipe flows. It can properly predict both turbulence reduction and turbulence enhancement for a certain size of particles observed in experiments.展开更多
A new approach is proposed to analyze the settlement behavior for single pile embedded in layered soils. Firstly, soil layers surrounding pile shaft are simulated by using distributed Voigt model, and finite soil laye...A new approach is proposed to analyze the settlement behavior for single pile embedded in layered soils. Firstly, soil layers surrounding pile shaft are simulated by using distributed Voigt model, and finite soil layers under the pile end are assumed to be virtual soil-pile whose cross-section area is the same as that of the pile shaft. Then, by means of Laplace transform and impedance function transfer method to solve the static equilibrium equation of pile, the analytical solution of the displacement impedance fimction at the pile head is derived. Furthermore, the analytical solution of the settlement at the head of single pile is theoretically derived by virtue of convolution theorem. Based on these solutions, the influences of parameters of soil-pile system on the settlement behavior for single pile are analyzed. Also, comparison of the load-settlement response for two well-instrumented field tests in multilayered soils is given to demonstrate the effectiveness and accuracy of the proposed approach. It can be noted that the presented solution can be used to calculate the settlement of single pile for the preliminary design of pile foundation.展开更多
In this study,a comprehensive parametric analysis was performed on non-uniform excitation of V-shaped topography using the boundary element method in time domain.For this purpose,wave scattering analysis was carried o...In this study,a comprehensive parametric analysis was performed on non-uniform excitation of V-shaped topography using the boundary element method in time domain.For this purpose,wave scattering analysis was carried out on a topography subjected to the SV-wave for different predominant frequencies and shape ratios.Based on the numerical results,new coherence and time delay functions are proposed to generate non-uniform ground motion for topographic irregularities.The efficiency and accuracy of the proposed functions for real engineering problems are indicated by comparison with observations reported in previous literature.展开更多
In order to know about the rheological properties of rock in a long range of the time scale,method of increasing temperature was brought forward to accelerate the rheological process of rock,which could extend the tim...In order to know about the rheological properties of rock in a long range of the time scale,method of increasing temperature was brought forward to accelerate the rheological process of rock,which could extend the time scale of experimental test data.Firstly,based on the generalized linear viscoelastic constitutive equation with temperature variable,the creep behavior of rock was divided into three types according to the different strain dependences of the time,that is,Hookean deformation,Newtonian flow,and retarded elasticity.Then the general equivalence relationship between time parameter and temperature parameter was derived for each type of strain.Finally,the relation between time parameter and temperature parameter in the whole creep was considered and the general theory of time-temperature equivalence effect(TTEE) of rock was established.This research reveals: ①The temperature effect on the instantaneous strain could be modified through vertical shift.②The key point of the TTEE of Newtonian flow depends on whether in the study of linear viscoelastic behavior of rock change of temperature is completely equivalent to a shift of the logarithmic time scale or not.③By plotting the results of a creep experiment performed at different temperatures and comparing the curves obtained,one can decide whether the rock considered have TTEE.④The TTEE of the whole creep should satisfy that the horizontal shift function of Newtonian flow and retarded elasticity is consentaneous.展开更多
With the creep test data of granite taken from Three Gorges,the existence of time-temperature equivalence effect(TTEE) of granite is investigated.Based on the creep test data at different temperatures,which are 20 ℃,...With the creep test data of granite taken from Three Gorges,the existence of time-temperature equivalence effect(TTEE) of granite is investigated.Based on the creep test data at different temperatures,which are 20 ℃,60 ℃,80 ℃,100 ℃,200 ℃,300 ℃,four-component viscoelastic Burgers model is presented to characterize the creep curves.The parameters of elasticity modulus and viscosity coefficient in the constitutive model at different temperatures and their functional dependences on temperature are obtained.Then,according to the basic theory of TTEE presented in research(I),the TTEE of granite is investigated through modifying the compliance curves with vertical shift function and checking the coincidence of the modified curves with horizontal shift functions.It is concluded that:① Burgers model could appropriately characterize the creep property of granite in a short time scale.② Both elastic modulus and viscosity coefficient in the Burgers model decay exponentially with temperature.③ The coincidence of the curves at different temperatures after vertical shift modification and horizontal shift is fine,which indicates the existence of TTEE of granite.④The master curves which reflect the long time scale test data at temperatures 20 ℃,100 ℃,200 ℃ are obtained.展开更多
To improve the effect of destroying time-sensitive target （TST）, a method of operational effectiveness evaluation is presented and some influential factors are analyzed based on the combat flow of system for destroy...To improve the effect of destroying time-sensitive target （TST）, a method of operational effectiveness evaluation is presented and some influential factors are analyzed based on the combat flow of system for destroying TST. Considering the possible operation modes of the system, a waved operation mode and a continuous operation mode are put forward at first. At the same time, some relative formulas are modified. In examples, the influential factors and operation modes are analyzed based on the system effectiveness. From simulation results, some design and operation strategies of the system for destroying time sensitive targets are concluded, which benefit to the improvement of the system effectiveness.展开更多
In order to further optimize welding process of Nb-Ti-Mo microalloyed steel, welding thermal cycles on coarse-grained heat-affected zone （CGHAZ） of welded joints were simulated using Gleeble 1500. The microstructure...In order to further optimize welding process of Nb-Ti-Mo microalloyed steel, welding thermal cycles on coarse-grained heat-affected zone （CGHAZ） of welded joints were simulated using Gleeble 1500. The microstructure and low-temperature impact fracture were investigated using a scanning electron microscope and a pendulum impact machine, respectively. Moreover, the relationship between cooling time ts/5 and the microstructure of CGHAZ was discussed, and the effect of microstructure on impact toughness was also studied. As cooling time increased, martensite fraction decreased from 97.8% （3 s） to 3.0% （60 s）. The fraction of martensite/austenite （M/A） constituent increased from 2.2% （3 s） to 39.0% （60 s）, its shape changed from granular to strip, and the maximum length increased from 2.4 μm （3 s） to 7.0 μm （60 s）. As cooling time increased, the prior austenite grain size increased from 34.0 μm （3 s） to 49.0 gm （60 s）, the impact absorption energy reduced from 101.8 J （5 s） to 7.2 J （60 s）, and the fracture mechanism changed from quasi-cleavage fracture to cleavage fracture. The decreased toughness of CGHAZ was due to the reduction of lath martensite-content, coarsening of original austenite grain, and increase and coarsening of M/A constituent. The heat input was controlled under 7 kJ cm-1 during actual welding for these steels.展开更多
LiMnxFe1-xPO_(4) is a promising cathode candidate due to its high security and the availability of a high 4.1 V operating voltage and high energy density.However,the poor electrochemical kinetics and structural instab...LiMnxFe1-xPO_(4) is a promising cathode candidate due to its high security and the availability of a high 4.1 V operating voltage and high energy density.However,the poor electrochemical kinetics and structural instability currently hinder its broader application.Herein,inspired by the hydrogen-bonded cross-linking and steric hindrance effect between short-chain polymer molecules(polyethylene glycol-400,PEG-400),the pomegranate-type LiMn_(0.5)Fe_(0.5)PO_(4)-0.5@C(P-LMFP@C)cathode materials with 3D ion/electron dual-conductive network structure were constructed through ball mill-assisted spray-drying method.The intermolecular effects of PEG-400 promote the spheroidization and uniform PEG coating of LMFP precursor,which prevents agglomeration during sintering.The 3D ion/electron dual-conductive network structure in P-LMFP@C accelerates the Li^(+)transport kinetics,improving the rate performance and cycling stability.As a result,the designed P-LMFP@C has remarkable electrochemical behavior,boasting excellent capacity retention(98%after 100 cycles at the 1C rate)and rate capability(91 mAh·g^(-1)at 20C).Such strategy introduces a novel window for designing high-performance olivine cathodes and offers compatibility with a range of energy storage materials for diverse applications.展开更多
The progress from intelligent interactions requires electronic skin(E-skin)to shift from single-functional perception to multisensory capabilities.However,the intuitive and interference-free reading of multiple sensor...The progress from intelligent interactions requires electronic skin(E-skin)to shift from single-functional perception to multisensory capabilities.However,the intuitive and interference-free reading of multiple sensory signals without involving complex algorithms is a critical challenge.Herein,we propose a flexible multisensory E-skin by developing a highly homogeneous dispersion of BaTiO_(3)nanoparticles in polydimethylsiloxane dielectric layer.The E-skin is sensitive to externally applied pressure as well as temperature and can distinguish dual synergetic stimuli by the time decoupling effect.The pressure and temperature perception was achieved in an individual device,which greatly reduced the structural complexity compared with multifunctional integrated devices.The sensitivity of E-skin for pressure detection is as high as 0.0724 kPa^(−1)and the detection range reaches as wide as 15.625-10 MPa.The sensitivity to temperature detection is as high as−1.34℃^(−1)and the detection range reaches 20-200℃.More importantly,by equipping with a multilayer neural network,the evolution from tactile perception to advanced intelligent tactile cognition is demonstrated.展开更多
The injection to emerging adult workerbees with fluvalinate doses ranging from 1 femtomol to 1 nanomol per individual resulted in a reduction of haemolymph carbohydrate concentrations, particularly at the lowest dose ...The injection to emerging adult workerbees with fluvalinate doses ranging from 1 femtomol to 1 nanomol per individual resulted in a reduction of haemolymph carbohydrate concentrations, particularly at the lowest dose 1 hour after injections. At the same time, a large increase was observed for triacylglycerols and to a much lesser extent for steroids and phospholipids with 0.1 picomol per bee. By contrast, fatty acids, steroids and triacylglycerols exhibited a depress at the higher dose. Most responses were thus biphasic, showing that much attention should be paid to the effects of very low doses of pesticide.展开更多
The time-varying periodic variations in Global Navigation Satellite System(GNSS)stations affect the reliable time series analysis and appropriate geophysical interpretation.In this study,we apply the singular spectrum...The time-varying periodic variations in Global Navigation Satellite System(GNSS)stations affect the reliable time series analysis and appropriate geophysical interpretation.In this study,we apply the singular spectrum analysis(SSA)method to characterize and interpret the periodic patterns of GNSS deformations in China using multiple geodetic datasets.These include 23-year observations from the Crustal Movement Observation Network of China(CMONOC),displacements inferred from the Gravity Recovery and Climate Experiment(GRACE),and loadings derived from Geophysical models(GM).The results reveal that all CMONOC time series exhibit seasonal signals characterized by amplitude and phase modulations,and the SSA method outperforms the traditional least squares fitting(LSF)method in extracting and interpreting the time-varying seasonal signals from the original time series.The decrease in the root mean square(RMS)correlates well with the annual cycle variance estimated by the SSA method,and the average reduction in noise amplitudes is nearly twice as much for SSA filtered results compared with those from the LSF method.With SSA analysis,the time-varying seasonal signals for all the selected stations can be identified in the reconstructed components corresponding to the first ten eigenvalues.Moreover,both RMS reduction and correlation analysis imply the advantages of GRACE solutions in explaining the GNSS periodic variations,and the geophysical effects can account for 71%of the GNSS annual amplitudes,and the average RMS reduction is 15%.The SSA method has proved to be useful for investigating the GNSS timevarying seasonal signals.It could be applicable as an auxiliary tool in the improvement of nonlinear variations investigations.展开更多
To describe the shielding ability of materials accurately and comprehensively,the frequency-domain and time-domain shielding effectiveness(SE) of material is investigated.The relevance between them was analyzed based ...To describe the shielding ability of materials accurately and comprehensively,the frequency-domain and time-domain shielding effectiveness(SE) of material is investigated.The relevance between them was analyzed based on the minimum phase method,and the time-domain SE can be derived from frequency-domain SE.The SE of an energy selective surface(ESS) made of a novel material is investigated,and the relationship between SE and radiation field intensity are analyzed.The results show that not only material,but also the intensity of radiation electric field shows influence on SE in its frequency; for some materials,the dependence of SE on radiation electric field intensity needs to be considered.Therefore,it is necessary to research on the SE of shielding material in high-intensity electromagnetic environment.展开更多
The photo-dissociation dynamics of LiF is investigated with newly constructed accurate ab initio potential energy curves （PECs） using the time-dependent quantum wave packet method. The oscillations and decay of the ...The photo-dissociation dynamics of LiF is investigated with newly constructed accurate ab initio potential energy curves （PECs） using the time-dependent quantum wave packet method. The oscillations and decay of the wave packet on the adiabats as a function of time are given, which can be compared with the femtosecond transition-state （FTS） spectroscopy. The photo-absorption spectra and the kinetic-energy distribution of the dissociation fragments, which can exhibit the vibration-level structure and the dispersion of the wave packet, respectively, are also obtained. The investigation shows a blue shift of the band center for the photo-absorption spectrum and multiple peaks in the kinetic-energy spectrum with increasing laser intensity, which can be attributed to external field effects. By analyzing the oscillations of the wave packet evolving on the upper adiabat, an approximate inversion scheme is devised to roughly deduce its shape.展开更多
A series of“half-sandwich”bis(imino)pyridyl iron complexes with a substituted 8-(p-Xphenyl)naphthylamine(X=OMe,Me,CF3)was designed and synthesized by combining weakπ-πinteraction with steric and electronic tunings...A series of“half-sandwich”bis(imino)pyridyl iron complexes with a substituted 8-(p-Xphenyl)naphthylamine(X=OMe,Me,CF3)was designed and synthesized by combining weakπ-πinteraction with steric and electronic tunings.The weak noncovalentπ-πinteraction as well as the steric and electronic effects of bis(imino)pyridyl iron complexes were identified by experimental analyses and calculations.The roles of weakπ-πinteraction,steric bulk,and electronic tuning on the ethylene polymerization performance of bis(imino)pyridyl iron catalysts were studied in detail.The combination ofπ-πinteraction with steric and electronic tunings can access to thermally stable bis(imino)pyridyl iron at 130°C.展开更多
基金supported in part by the National Natural Science Foundation of China(62276119)the Natural Science Foundation of Jiangsu Province(BK20241764)the Postgraduate Research & Practice Innovation Program of Jiangsu Province(KYCX22_2860)
文摘Dear Editor,This letter investigates predefined-time optimization problems(OPs) of multi-agent systems(MASs), where the agent of MASs is subject to inequality constraints, and the team objective function accounts for impulse effects. Firstly, to address the inequality constraints,the penalty method is introduced. Then, a novel optimization strategy is developed, which only requires that the team objective function be strongly convex.
文摘Measuring in-situ stress by using the Kaiser effect in rocks has such advantages as timeefficiency, low cost and little limitation, but the precision of the method is dependent on rock properties and delay time of the measurement. In this paper, experiments on the Kaiser effect in limestones were performed, and it was found that the limestones had good ability to retain a memory of their recent stress history and high time-sensitivity. The longer the experiment was delayed from the extraction of the stone, the larger the Felicity ratio was. As the Felicity ratio approached l, significant Kaiser effect was observed. In-situ stress should be determined by the limestone measurements when the delay time was 40-120 days. Finally, the in-situ stress in a limestone formation could be successfully measured in practice.
基金supported by the National Natural Science Foundation(No.50874040,No.50904026)Heilongjiang Provincial Natural Science Foundation(No.B2007-10)Harbin Innovation Talent of Science and Technology Foundation(No.2007RFXXS050,No.2008RFQXG111)
文摘The focus of this study is to investigate the influence of memory effect and the relation of its existence with the dissociation temperature,using gas hydrate formation and dissociation experiments.This is beneficial because memory effect is considered as an effective approach to promote the thermodynamic and dynamic conditions of gas hydrate nucleation.Seven experimental systems （twenty tests in total） were performed in a 1 L pressure cell.Three types of hydrate morphology,namely massive,whiskery and jelly crystals were present in the experiments.The pressures and temperatures at the time when visual hydrate crystals appeared were measured.Furthermore,the influence of memory effect was quantified in terms of pressure-temperature-time （p-T-t） relations.The results revealed that memory effect could promote the thermodynamic conditions and shorten the induction time when the dissociation temperature was not higher than 25℃.In this study,the nucleation superpressure and induction time decrease gradually with time of tests,when the earlier and the later tests are compared.It is assumed that the residual structure of hydrate dissociation,as the source of the memory effect,provides a site for mass transfer between host and vip molecules.Therefore,a driving force is created between the residual structures and its surrounding bulk phase to promote the hydrate nucleation.However,when the dissociation temperature was higher than 25 ℃,the memory effect vanished.These findings provide references for the application of memory effect in hydrate-based technology.
基金State Key Development Program for Basic Research of China (No.2006CB200305), the National Natural Sci-ence Foundation of China (No.50376004), and Ph.D. Program Foundation of Ministry of Education of China (No.20030007028).
文摘Presently developed two-phase turbulence models under-predict the gas turbulent fluctuation, because their turbulence modification models cannot fully reflect the effect of particles. In this paper, a two-time-scale dis- sipation model of turbulence modification, developed for the two-phase velocity correlation and for the dissipation rate of gas turbulent kinetic energy, is proposed and used to simulate sudden-expansion and swirling gas-particle flows. The proposed two-time scale model gives better results than the single-time scale model. Besides, a gas tur- bulence augmentation model accounting for the finite-size particle wake effect in the gas Reynolds stress equation is proposed. The proposed turbulence modification models are used to simulate two-phase pipe flows. It can prop- erly predict both turbulence reduction and turbulence enhancement for a certain size of particles observed in ex- periments.
基金Supported by the State Key Development Program for Basic Research of China （No.2006CB200305）, the National Natural Science Foundation of China （No.50376004）, and Ph.D. Program Foundation of Ministry of Education of China （No.20030007028）.
文摘Presently developed two-phase turbulence models under-predict the gas turbulent fluctuation, because their turbulence modification models cannot fully reflect the effect of particles. In this paper, a two-time-scale dissipation model of turbulence modification, developed for the two-phase velocity correlation and for the dissipation rate of gas turbulent kinetic energy, is proposed and used to simulate sudden-expansion and swirling gas-particle flows. The proposed two-time scale model gives better results than the single-time scale model. Besides, a gas turbulence augmentation model accounting for the f＇mite-size particle wake effect in the gas Reynolds stress equation is proposed. The proposed turbulence modification models are used to simulate two-phase pipe flows. It can properly predict both turbulence reduction and turbulence enhancement for a certain size of particles observed in experiments.
基金Project(50879077) supported by the National Natural Science Foundation of China
文摘A new approach is proposed to analyze the settlement behavior for single pile embedded in layered soils. Firstly, soil layers surrounding pile shaft are simulated by using distributed Voigt model, and finite soil layers under the pile end are assumed to be virtual soil-pile whose cross-section area is the same as that of the pile shaft. Then, by means of Laplace transform and impedance function transfer method to solve the static equilibrium equation of pile, the analytical solution of the displacement impedance fimction at the pile head is derived. Furthermore, the analytical solution of the settlement at the head of single pile is theoretically derived by virtue of convolution theorem. Based on these solutions, the influences of parameters of soil-pile system on the settlement behavior for single pile are analyzed. Also, comparison of the load-settlement response for two well-instrumented field tests in multilayered soils is given to demonstrate the effectiveness and accuracy of the proposed approach. It can be noted that the presented solution can be used to calculate the settlement of single pile for the preliminary design of pile foundation.
文摘In this study,a comprehensive parametric analysis was performed on non-uniform excitation of V-shaped topography using the boundary element method in time domain.For this purpose,wave scattering analysis was carried out on a topography subjected to the SV-wave for different predominant frequencies and shape ratios.Based on the numerical results,new coherence and time delay functions are proposed to generate non-uniform ground motion for topographic irregularities.The efficiency and accuracy of the proposed functions for real engineering problems are indicated by comparison with observations reported in previous literature.
基金Supported by the Long-term evolution of stability and permeability of high-level radioactive waste repository surrounding rock under THMC coupling process
文摘In order to know about the rheological properties of rock in a long range of the time scale,method of increasing temperature was brought forward to accelerate the rheological process of rock,which could extend the time scale of experimental test data.Firstly,based on the generalized linear viscoelastic constitutive equation with temperature variable,the creep behavior of rock was divided into three types according to the different strain dependences of the time,that is,Hookean deformation,Newtonian flow,and retarded elasticity.Then the general equivalence relationship between time parameter and temperature parameter was derived for each type of strain.Finally,the relation between time parameter and temperature parameter in the whole creep was considered and the general theory of time-temperature equivalence effect(TTEE) of rock was established.This research reveals: ①The temperature effect on the instantaneous strain could be modified through vertical shift.②The key point of the TTEE of Newtonian flow depends on whether in the study of linear viscoelastic behavior of rock change of temperature is completely equivalent to a shift of the logarithmic time scale or not.③By plotting the results of a creep experiment performed at different temperatures and comparing the curves obtained,one can decide whether the rock considered have TTEE.④The TTEE of the whole creep should satisfy that the horizontal shift function of Newtonian flow and retarded elasticity is consentaneous.
基金Long-term evolution of stability and permeability of high-level radioactive waste repository surrounding rock under THMC coupling process
文摘With the creep test data of granite taken from Three Gorges,the existence of time-temperature equivalence effect(TTEE) of granite is investigated.Based on the creep test data at different temperatures,which are 20 ℃,60 ℃,80 ℃,100 ℃,200 ℃,300 ℃,four-component viscoelastic Burgers model is presented to characterize the creep curves.The parameters of elasticity modulus and viscosity coefficient in the constitutive model at different temperatures and their functional dependences on temperature are obtained.Then,according to the basic theory of TTEE presented in research(I),the TTEE of granite is investigated through modifying the compliance curves with vertical shift function and checking the coincidence of the modified curves with horizontal shift functions.It is concluded that:① Burgers model could appropriately characterize the creep property of granite in a short time scale.② Both elastic modulus and viscosity coefficient in the Burgers model decay exponentially with temperature.③ The coincidence of the curves at different temperatures after vertical shift modification and horizontal shift is fine,which indicates the existence of TTEE of granite.④The master curves which reflect the long time scale test data at temperatures 20 ℃,100 ℃,200 ℃ are obtained.
基金supported by the National Natural Science Foundation of China (60774064)the Aerospace Science Foundation (05D53022)the Youth for NPU Teachers Scientific and Technological Innovation Foundation (W016210)
文摘To improve the effect of destroying time-sensitive target （TST）, a method of operational effectiveness evaluation is presented and some influential factors are analyzed based on the combat flow of system for destroying TST. Considering the possible operation modes of the system, a waved operation mode and a continuous operation mode are put forward at first. At the same time, some relative formulas are modified. In examples, the influential factors and operation modes are analyzed based on the system effectiveness. From simulation results, some design and operation strategies of the system for destroying time sensitive targets are concluded, which benefit to the improvement of the system effectiveness.
基金This work was financially supported by the National Natural Science Foundation of China （No. 51775102）, Open Research Fund from the State Key Laboratory of Roiling and Automation, Northeastern University （No. 2016005） and Project Funded by China Postdoctoral Science Foundation （No. 2016M601877）.
文摘In order to further optimize welding process of Nb-Ti-Mo microalloyed steel, welding thermal cycles on coarse-grained heat-affected zone （CGHAZ） of welded joints were simulated using Gleeble 1500. The microstructure and low-temperature impact fracture were investigated using a scanning electron microscope and a pendulum impact machine, respectively. Moreover, the relationship between cooling time ts/5 and the microstructure of CGHAZ was discussed, and the effect of microstructure on impact toughness was also studied. As cooling time increased, martensite fraction decreased from 97.8% （3 s） to 3.0% （60 s）. The fraction of martensite/austenite （M/A） constituent increased from 2.2% （3 s） to 39.0% （60 s）, its shape changed from granular to strip, and the maximum length increased from 2.4 μm （3 s） to 7.0 μm （60 s）. As cooling time increased, the prior austenite grain size increased from 34.0 μm （3 s） to 49.0 gm （60 s）, the impact absorption energy reduced from 101.8 J （5 s） to 7.2 J （60 s）, and the fracture mechanism changed from quasi-cleavage fracture to cleavage fracture. The decreased toughness of CGHAZ was due to the reduction of lath martensite-content, coarsening of original austenite grain, and increase and coarsening of M/A constituent. The heat input was controlled under 7 kJ cm-1 during actual welding for these steels.
基金supported by the Key Technologies R&D Program of Xiamen(No.3502Z20231057)Industry Leading Key Projects of Fujian Province(No.2022H0057)+2 种基金the National Natural Science Foundation of China(No.21975212)High-Level Talent Start-Up Foundation of Xiamen Institute of Technology for financial support(No.YKJ23017R)Graduate Science and Technology Innovation Program of Xiamen University of Technology(No.YKJCX2023194).
文摘LiMnxFe1-xPO_(4) is a promising cathode candidate due to its high security and the availability of a high 4.1 V operating voltage and high energy density.However,the poor electrochemical kinetics and structural instability currently hinder its broader application.Herein,inspired by the hydrogen-bonded cross-linking and steric hindrance effect between short-chain polymer molecules(polyethylene glycol-400,PEG-400),the pomegranate-type LiMn_(0.5)Fe_(0.5)PO_(4)-0.5@C(P-LMFP@C)cathode materials with 3D ion/electron dual-conductive network structure were constructed through ball mill-assisted spray-drying method.The intermolecular effects of PEG-400 promote the spheroidization and uniform PEG coating of LMFP precursor,which prevents agglomeration during sintering.The 3D ion/electron dual-conductive network structure in P-LMFP@C accelerates the Li^(+)transport kinetics,improving the rate performance and cycling stability.As a result,the designed P-LMFP@C has remarkable electrochemical behavior,boasting excellent capacity retention(98%after 100 cycles at the 1C rate)and rate capability(91 mAh·g^(-1)at 20C).Such strategy introduces a novel window for designing high-performance olivine cathodes and offers compatibility with a range of energy storage materials for diverse applications.
基金Ningbo Scientific and Technological Innovation 2025 Major Project,Grant/Award Number:2020Z022German Research Foundation(DFG)grants,Grant/Award Numbers:MA 5144/13-1,MA 5144/28-1+6 种基金the National Natural Science Foundation of China,Grant/Award Numbers:62204246,51931011,51971233,52127803,62174165the External Cooperation Program of Chinese Academy of Sciences,Grant/Award Numbers:174433KYSB20190038,174433KYSB20200013the Instrument Developing Project of the Chinese Academy of Sciences,Grant/Award Number:YJKYYQ20200030K.C.Wong Education Foundation,Grant/Award Number:GJTD-2020-11Chinese Academy of Sciences Youth Innovation Promotion Association,Grant/Award Number:2018334Zhejiang Provincial Key R&D Program,Grant/Award Numbers:2021C01183,2022C01032the National Natural Science Foundation of Zhejiang Province of China,Grant/Award Number:LQ23F040004.
文摘The progress from intelligent interactions requires electronic skin(E-skin)to shift from single-functional perception to multisensory capabilities.However,the intuitive and interference-free reading of multiple sensory signals without involving complex algorithms is a critical challenge.Herein,we propose a flexible multisensory E-skin by developing a highly homogeneous dispersion of BaTiO_(3)nanoparticles in polydimethylsiloxane dielectric layer.The E-skin is sensitive to externally applied pressure as well as temperature and can distinguish dual synergetic stimuli by the time decoupling effect.The pressure and temperature perception was achieved in an individual device,which greatly reduced the structural complexity compared with multifunctional integrated devices.The sensitivity of E-skin for pressure detection is as high as 0.0724 kPa^(−1)and the detection range reaches as wide as 15.625-10 MPa.The sensitivity to temperature detection is as high as−1.34℃^(−1)and the detection range reaches 20-200℃.More importantly,by equipping with a multilayer neural network,the evolution from tactile perception to advanced intelligent tactile cognition is demonstrated.
文摘The injection to emerging adult workerbees with fluvalinate doses ranging from 1 femtomol to 1 nanomol per individual resulted in a reduction of haemolymph carbohydrate concentrations, particularly at the lowest dose 1 hour after injections. At the same time, a large increase was observed for triacylglycerols and to a much lesser extent for steroids and phospholipids with 0.1 picomol per bee. By contrast, fatty acids, steroids and triacylglycerols exhibited a depress at the higher dose. Most responses were thus biphasic, showing that much attention should be paid to the effects of very low doses of pesticide.
基金supported by the National Natural Science Foundation of China(NO.42104028,42174030 and 42004017)the Open Fund of Hubei Luojia Laboratory(No.220100048 and 230100021)the Scientific Research Project of Hubei Provincial Department of Education,and Research Foundation of the Department of Natural Resources of Hunan Province(No.20230104CH)。
文摘The time-varying periodic variations in Global Navigation Satellite System(GNSS)stations affect the reliable time series analysis and appropriate geophysical interpretation.In this study,we apply the singular spectrum analysis(SSA)method to characterize and interpret the periodic patterns of GNSS deformations in China using multiple geodetic datasets.These include 23-year observations from the Crustal Movement Observation Network of China(CMONOC),displacements inferred from the Gravity Recovery and Climate Experiment(GRACE),and loadings derived from Geophysical models(GM).The results reveal that all CMONOC time series exhibit seasonal signals characterized by amplitude and phase modulations,and the SSA method outperforms the traditional least squares fitting(LSF)method in extracting and interpreting the time-varying seasonal signals from the original time series.The decrease in the root mean square(RMS)correlates well with the annual cycle variance estimated by the SSA method,and the average reduction in noise amplitudes is nearly twice as much for SSA filtered results compared with those from the LSF method.With SSA analysis,the time-varying seasonal signals for all the selected stations can be identified in the reconstructed components corresponding to the first ten eigenvalues.Moreover,both RMS reduction and correlation analysis imply the advantages of GRACE solutions in explaining the GNSS periodic variations,and the geophysical effects can account for 71%of the GNSS annual amplitudes,and the average RMS reduction is 15%.The SSA method has proved to be useful for investigating the GNSS timevarying seasonal signals.It could be applicable as an auxiliary tool in the improvement of nonlinear variations investigations.
基金Project supported by National Basic Research Program of China（973 Program） （6131380301） National Natural Science Foundation of China （61001050）.
文摘To describe the shielding ability of materials accurately and comprehensively,the frequency-domain and time-domain shielding effectiveness(SE) of material is investigated.The relevance between them was analyzed based on the minimum phase method,and the time-domain SE can be derived from frequency-domain SE.The SE of an energy selective surface(ESS) made of a novel material is investigated,and the relationship between SE and radiation field intensity are analyzed.The results show that not only material,but also the intensity of radiation electric field shows influence on SE in its frequency; for some materials,the dependence of SE on radiation electric field intensity needs to be considered.Therefore,it is necessary to research on the SE of shielding material in high-intensity electromagnetic environment.
基金the International Cooperation Program for Excellent Lectures of 2008 by Shandong Provincial Education Department,Chinathe National Natural Science Foundation of China(Grant No.11074151)Fundao para a Ciência e a Tecnologia,Portugal
文摘The photo-dissociation dynamics of LiF is investigated with newly constructed accurate ab initio potential energy curves （PECs） using the time-dependent quantum wave packet method. The oscillations and decay of the wave packet on the adiabats as a function of time are given, which can be compared with the femtosecond transition-state （FTS） spectroscopy. The photo-absorption spectra and the kinetic-energy distribution of the dissociation fragments, which can exhibit the vibration-level structure and the dispersion of the wave packet, respectively, are also obtained. The investigation shows a blue shift of the band center for the photo-absorption spectrum and multiple peaks in the kinetic-energy spectrum with increasing laser intensity, which can be attributed to external field effects. By analyzing the oscillations of the wave packet evolving on the upper adiabat, an approximate inversion scheme is devised to roughly deduce its shape.
基金supported by the State Key Research Development Program of China(No.2021YFB3800701)National Natural Science Foundation of China(NSFC,No.52173016)+2 种基金Guangdong Basic and Applied Basic Research Foundation(Nos.2024A1515012784,2024A1515011102,and 2023A1515110549)Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.24qnpy047)PetroChina Scientific and Technological Projects(No.2022DJ6308).
文摘A series of“half-sandwich”bis(imino)pyridyl iron complexes with a substituted 8-(p-Xphenyl)naphthylamine(X=OMe,Me,CF3)was designed and synthesized by combining weakπ-πinteraction with steric and electronic tunings.The weak noncovalentπ-πinteraction as well as the steric and electronic effects of bis(imino)pyridyl iron complexes were identified by experimental analyses and calculations.The roles of weakπ-πinteraction,steric bulk,and electronic tuning on the ethylene polymerization performance of bis(imino)pyridyl iron catalysts were studied in detail.The combination ofπ-πinteraction with steric and electronic tunings can access to thermally stable bis(imino)pyridyl iron at 130°C.
