采用溶胶-凝胶法制备Ti/Sn O_2-F电极,进行全氟辛酸(PFOA)电氧化降解的研究,实验考察了F替代Sb掺杂、电流密度、初始pH值和支持电解质对PFOA降解效率的影响。结果表明,当F替代Sb掺杂Sn O_2,电流密度为20 m A/cm^2,初始pH值3.7,支持电解...采用溶胶-凝胶法制备Ti/Sn O_2-F电极,进行全氟辛酸(PFOA)电氧化降解的研究,实验考察了F替代Sb掺杂、电流密度、初始pH值和支持电解质对PFOA降解效率的影响。结果表明,当F替代Sb掺杂Sn O_2,电流密度为20 m A/cm^2,初始pH值3.7,支持电解质为NaClO_4时,电解30 min后PFOA的降解率达98%。采用液相色谱-质谱联用(HPLC-MS/MS)和离子色谱(IC)对PFOA降解产物进行分析,解析了PFOA电氧化降解的反应机理。展开更多
The low cell voltage during electrolytic Mn from the MnCl_(2) system can effectively reduce the power consumption.In this work,the Ti/Sn−Ru−Co−Zr modified anodes were obtained by using thermal decomposition oxidation....The low cell voltage during electrolytic Mn from the MnCl_(2) system can effectively reduce the power consumption.In this work,the Ti/Sn−Ru−Co−Zr modified anodes were obtained by using thermal decomposition oxidation.The physical parameters of coatings were observed by SEM(scanning electron microscope).Based on the electrochemical performance and SEM/XRD(X-ray diffraction)of the coatings,the influence of Zr on electrode performance was studied and analyzed.When the mole ratio of Sn−Ru−Co−Zr is 6:1:0.8:0.3,the cracks on the surface of coatings were the smallest,and the compactness was the best due to the excellent filling effect of ZrO_(2)nanoparticles.Moreover,the electrode prepared under this condition had the lowest mass transfer resistance and high chloride evolution activity in the 1mol%NH_(4)Cl and 1.5mol%HCl system.The service life of 3102 h was achieved according to the empirical formula of accelerated-life-test of the new type anode.展开更多
TiO2-SnO2-SiO2 nanocomposite photocatalysts were prepared with Na2SiO3·9H2O, SnCl4·5H2O and TiCl4 as precursors by chemistry coating processes and supercritical fluid drying (SCFD) method. Characterizations ...TiO2-SnO2-SiO2 nanocomposite photocatalysts were prepared with Na2SiO3·9H2O, SnCl4·5H2O and TiCl4 as precursors by chemistry coating processes and supercritical fluid drying (SCFD) method. Characterizations with XRD, TEM, NMR and FTIR showed that in addition to anatase type TiO2, a new active phase(Ti,Sn)O2 was also formed in the range of the studied doping concentration, The catalytic activity was evaluated by photocatalytic degradation of phenol as model reaction. SiO2 remained amphorous at all samples. It could prevent from growth of the size of nanopaticle and transformation from anatase to rutile. Compared with pure TiO2, or TiO2-SnO2 catalyst prepared by Sol-gel method, Nano-composite photo-catalyst showed significant improvement in catalytic activity, the photo-catalytic degradation rate of phenol in 7 h reached 88.7%. Application of the composite catalysts for the photocatalytic decomposition of phenol not only gave the same activity relative to pure ultrafine TiO2, but also reduced cost. The experimental results also proved that the thermal stability of TiO2 was greatly enhanced after mixing with small amount of SiO2. The optimized doping of SiO2 was 20.3%. The photo-catalyst prepared by SCFD combination technology was characterized with smaller particle size, larger surface area and higher activity.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 51564029, 51504111, 52064028, and 22002054)the China Postdoctoral Science Foundation (No. 2018M633418)+1 种基金the Technology Innovation Talents Project of Yunnan Province (No. 2019HB111)Analysis and Testing Foundation of Kunming University of Science and Technology (Nos. 2019 M20182202013, 2020M20192202035, and 2020M2019 2202099)
文摘The low cell voltage during electrolytic Mn from the MnCl_(2) system can effectively reduce the power consumption.In this work,the Ti/Sn−Ru−Co−Zr modified anodes were obtained by using thermal decomposition oxidation.The physical parameters of coatings were observed by SEM(scanning electron microscope).Based on the electrochemical performance and SEM/XRD(X-ray diffraction)of the coatings,the influence of Zr on electrode performance was studied and analyzed.When the mole ratio of Sn−Ru−Co−Zr is 6:1:0.8:0.3,the cracks on the surface of coatings were the smallest,and the compactness was the best due to the excellent filling effect of ZrO_(2)nanoparticles.Moreover,the electrode prepared under this condition had the lowest mass transfer resistance and high chloride evolution activity in the 1mol%NH_(4)Cl and 1.5mol%HCl system.The service life of 3102 h was achieved according to the empirical formula of accelerated-life-test of the new type anode.
文摘TiO2-SnO2-SiO2 nanocomposite photocatalysts were prepared with Na2SiO3·9H2O, SnCl4·5H2O and TiCl4 as precursors by chemistry coating processes and supercritical fluid drying (SCFD) method. Characterizations with XRD, TEM, NMR and FTIR showed that in addition to anatase type TiO2, a new active phase(Ti,Sn)O2 was also formed in the range of the studied doping concentration, The catalytic activity was evaluated by photocatalytic degradation of phenol as model reaction. SiO2 remained amphorous at all samples. It could prevent from growth of the size of nanopaticle and transformation from anatase to rutile. Compared with pure TiO2, or TiO2-SnO2 catalyst prepared by Sol-gel method, Nano-composite photo-catalyst showed significant improvement in catalytic activity, the photo-catalytic degradation rate of phenol in 7 h reached 88.7%. Application of the composite catalysts for the photocatalytic decomposition of phenol not only gave the same activity relative to pure ultrafine TiO2, but also reduced cost. The experimental results also proved that the thermal stability of TiO2 was greatly enhanced after mixing with small amount of SiO2. The optimized doping of SiO2 was 20.3%. The photo-catalyst prepared by SCFD combination technology was characterized with smaller particle size, larger surface area and higher activity.
