A novel high gravity multi-concentric cylinder electrodes-rotating bed(MCCE-RB) was developed for the electrocatalytic degradation of phenol wastewater in order to enhance the mass transfer with the self-made RuO_2-Ir...A novel high gravity multi-concentric cylinder electrodes-rotating bed(MCCE-RB) was developed for the electrocatalytic degradation of phenol wastewater in order to enhance the mass transfer with the self-made RuO_2-IrO_2-SnO_2/Ti anodes. The influences of electric current density, inlet liquid circulation flowrate, high gravity factor, sodium chloride concentration,and initial pH value on phenol degradation efficiency were investigated, with the optimal operating conditions determined. The results showed that under the optimal operating conditions covering a current density of 35 mA/cm^2, an inlet liquid circulation flowrate of 48 L/h, a high gravity factor of 20, a sodium chloride concentration of 8.5 g/L, an initial pH value of 6.5, a reaction time of 100 min, and an initial phenol concentration of 500 mg/L, the efficiency for removal of phenol reached 99.7%, which was improved by 10.4% as compared to that achieved in the normal gravity field. The tendency regarding the change in efficiency for removal of phenol, total organic carbon(TOC), and chemical oxygen demand(COD)over time was studied. The intermediates and degradation pathway of phenol were deduced by high performance liquid chromatography(HPLC).展开更多
The electrochemical characteristics of Ta2O5-IrO2 electrodes prepared from different chemical compositions and coating methods were observed by using cyclic voltammetry, potentiostatic polarization, galvanostatic pola...The electrochemical characteristics of Ta2O5-IrO2 electrodes prepared from different chemical compositions and coating methods were observed by using cyclic voltammetry, potentiostatic polarization, galvanostatic polarization and scanning electron microscopy. The efficiency for chloride oxidation and oxygen evolution processes was not only influenced by the chemical composition but also by the surface morphology of the oxide electrode which was susceptible to the ratio of the two components and the coating method. Ta2O5(50)-IrO2(50) electrodes revealed the highest catalytic activity for the chloride ion oxidation and oxygen evolution reaction because they had the largest effective surface area. The durability of the oxide electrodes in the accelerated life tests was improved as the thickness of the oxide layer increased and the ratio of [IrO2] to [Ta2O5] approached 80/20.展开更多
The electrochemical treatment of COD contained in biologically pretreated coking wastewater treated by a three-dimensional electrode system with modified coke as the particle electrode was investigated. And the electr...The electrochemical treatment of COD contained in biologically pretreated coking wastewater treated by a three-dimensional electrode system with modified coke as the particle electrode was investigated. And the electrochemical perromance of the coke modified with various active components was studied. The results show that the coke modified with Fe（NO3）2 has the lowest energy consumption and higher COD removal rate under the same condition, and the modified coke has better surface characteristics for the purpose of this study. In addition, the kinetic constant was also calculated. The study shows that the three-dimensional electrode system with Fe （NO3）z-modified coke can give a satisfactory solution in biologically pretreated coking wastewater.展开更多
In the work,we successfully explore a two-step hydrothermal method for scalable synthesis of the hybrid sodium titanate(NaTi8O13/NaTiO2) nanoribbons well in-situ formed on the multi-layered MXene Ti3C2(designed as NTO...In the work,we successfully explore a two-step hydrothermal method for scalable synthesis of the hybrid sodium titanate(NaTi8O13/NaTiO2) nanoribbons well in-situ formed on the multi-layered MXene Ti3C2(designed as NTO/Ti3C2).Benefiting from the inherent structural and componential superiorities,the resulted NTO/Ti3C2 composite exhibits long-duration cycling stability and superior rate behaviors when evaluated as a hybrid anode for advanced SIBs,which delivers a reversible and stable capacity of^82 mAh/g even after 1900 cycles at 2000 mA/g for SIBs.展开更多
Both Ti foil and porous Ti were anodized in 0.5%HF and in ethylene glycol electrolyte containing 0.5%NH4F(mass fraction) separately. The results show that TiO2 nanotubes can be formed on Ti foil by both processes, whe...Both Ti foil and porous Ti were anodized in 0.5%HF and in ethylene glycol electrolyte containing 0.5%NH4F(mass fraction) separately. The results show that TiO2 nanotubes can be formed on Ti foil by both processes, whereas TiO2 nanotubes can be formed on porous Ti only in the second process. The overhigh current density led to the failure of the formation nanotubes on porous Ti in 0.5%HF electrolyte. TiO2 nanotubes were characterized by SEM and XRD. TiO2 nanotubes on porous Ti were thinner than those on Ti foil. Anatase was formed when TiO2 nanotubes were annealed at 400 °C and fully turned into rutile at 700 °C. To obtain good photodegradation, the optimal heat treatment temperature of TiO2 nanotubes was 450 °C. The porosity of the substrates influenced photodegradation properties. TiO2 nanotubes on porous Ti with 60% porosity had the best photodegradation.展开更多
基金financially supported by the Nature Science Foundation of China (Grant No.U1610106)the Nature Science Foundation of China (Grant No.21703208)
文摘A novel high gravity multi-concentric cylinder electrodes-rotating bed(MCCE-RB) was developed for the electrocatalytic degradation of phenol wastewater in order to enhance the mass transfer with the self-made RuO_2-IrO_2-SnO_2/Ti anodes. The influences of electric current density, inlet liquid circulation flowrate, high gravity factor, sodium chloride concentration,and initial pH value on phenol degradation efficiency were investigated, with the optimal operating conditions determined. The results showed that under the optimal operating conditions covering a current density of 35 mA/cm^2, an inlet liquid circulation flowrate of 48 L/h, a high gravity factor of 20, a sodium chloride concentration of 8.5 g/L, an initial pH value of 6.5, a reaction time of 100 min, and an initial phenol concentration of 500 mg/L, the efficiency for removal of phenol reached 99.7%, which was improved by 10.4% as compared to that achieved in the normal gravity field. The tendency regarding the change in efficiency for removal of phenol, total organic carbon(TOC), and chemical oxygen demand(COD)over time was studied. The intermediates and degradation pathway of phenol were deduced by high performance liquid chromatography(HPLC).
文摘The electrochemical characteristics of Ta2O5-IrO2 electrodes prepared from different chemical compositions and coating methods were observed by using cyclic voltammetry, potentiostatic polarization, galvanostatic polarization and scanning electron microscopy. The efficiency for chloride oxidation and oxygen evolution processes was not only influenced by the chemical composition but also by the surface morphology of the oxide electrode which was susceptible to the ratio of the two components and the coating method. Ta2O5(50)-IrO2(50) electrodes revealed the highest catalytic activity for the chloride ion oxidation and oxygen evolution reaction because they had the largest effective surface area. The durability of the oxide electrodes in the accelerated life tests was improved as the thickness of the oxide layer increased and the ratio of [IrO2] to [Ta2O5] approached 80/20.
文摘The electrochemical treatment of COD contained in biologically pretreated coking wastewater treated by a three-dimensional electrode system with modified coke as the particle electrode was investigated. And the electrochemical perromance of the coke modified with various active components was studied. The results show that the coke modified with Fe（NO3）2 has the lowest energy consumption and higher COD removal rate under the same condition, and the modified coke has better surface characteristics for the purpose of this study. In addition, the kinetic constant was also calculated. The study shows that the three-dimensional electrode system with Fe （NO3）z-modified coke can give a satisfactory solution in biologically pretreated coking wastewater.
基金financial support from National Natural Science Foundation of China(Nos.51772127and 51772131)Taishan Scholars(No.ts201712050)+1 种基金Major Program of Shandong Province Natural Science Foundation(No.ZR2018ZB0317)Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong。
文摘In the work,we successfully explore a two-step hydrothermal method for scalable synthesis of the hybrid sodium titanate(NaTi8O13/NaTiO2) nanoribbons well in-situ formed on the multi-layered MXene Ti3C2(designed as NTO/Ti3C2).Benefiting from the inherent structural and componential superiorities,the resulted NTO/Ti3C2 composite exhibits long-duration cycling stability and superior rate behaviors when evaluated as a hybrid anode for advanced SIBs,which delivers a reversible and stable capacity of^82 mAh/g even after 1900 cycles at 2000 mA/g for SIBs.
基金Project(1254G024)supported by the Young Core Instructor Foundation from Heilongjiang Educational Committee,ChinaProject(2012RFQXS113)supported by Scientific and Technological Innovation Talents of Harbin,China
文摘Both Ti foil and porous Ti were anodized in 0.5%HF and in ethylene glycol electrolyte containing 0.5%NH4F(mass fraction) separately. The results show that TiO2 nanotubes can be formed on Ti foil by both processes, whereas TiO2 nanotubes can be formed on porous Ti only in the second process. The overhigh current density led to the failure of the formation nanotubes on porous Ti in 0.5%HF electrolyte. TiO2 nanotubes were characterized by SEM and XRD. TiO2 nanotubes on porous Ti were thinner than those on Ti foil. Anatase was formed when TiO2 nanotubes were annealed at 400 °C and fully turned into rutile at 700 °C. To obtain good photodegradation, the optimal heat treatment temperature of TiO2 nanotubes was 450 °C. The porosity of the substrates influenced photodegradation properties. TiO2 nanotubes on porous Ti with 60% porosity had the best photodegradation.
