Enhancing ecological security for sustainable social,economic,and environmental development is a key focus of current research and a practical necessity for ecological management.However,the integration of retrospecti...Enhancing ecological security for sustainable social,economic,and environmental development is a key focus of current research and a practical necessity for ecological management.However,the integration of retrospective ecological security assessments with future trend predictions and fine-scale targeted regulations remains inadequate,limiting effective ecological governance and sustainable regional development.Guided by Social-Economic-Natural Complex Ecosystems(SENCE)theory,this study proposes an analytical framework that integrates ecological security assessment,prediction,and zoning management.The Daqing River Basin,a typical river basin in the North China Plain,was selected as a case study.The results indicate that overall ecological security in the Daqing River Basin improved from a“Moderate”level to a“Relatively Safe”level between 2000 and 2020;however,spatial heterogeneity persisted,with higher ecological security in northwestern and eastern regions and lower ecological security in the central region.Approximately 62% of the Basin experienced an improvement in ecological security level,except in the major urban areas of Beijing,Tianjin,and Hebei,where ecological security deteriorated.From 2025 to 2040,the overall ecological security of the Daqing River Basin is expected to improve and remain at the“Relatively Safe”level.However,spatial heterogeneity will be further aggravated as the ecological security of major urban areas continues to deteriorate.Ecological security management zones and regulation strategies are proposed at the regional and county scales to emphasize integrated regulation for the entire basin and major urban areas.The proposed analytical framework provides valuable insights for advancing theoretical research on ecological security.The case study offers a practical reference for ecological security enhancement in river basins and other regions facing significant human-land conflicts.展开更多
Against the backdrop of intensifying global water scarcity,reclaimed water reuse has emerged as a critical strategy for ecological replenishment of landscape water bodies.However,its potential ecological risks remain ...Against the backdrop of intensifying global water scarcity,reclaimed water reuse has emerged as a critical strategy for ecological replenishment of landscape water bodies.However,its potential ecological risks remain underexplored.This study aims to establish a multidimensional ecological safety evaluation framework for reclaimed water replenishment systems and propose hierarchical risk prevention strategies.By integrating ecotoxicological assays(algae growth inhibition,Daphnia behavioral anomalies,zebrafish embryo toxicity),multimedia exposure modeling,and Monte Carlo probabilistic simulations,the risk contributions and spatial heterogeneity of typical pollutants are quantitatively analyzed.Results revealed that sulfamethoxazole(RQ=2.3)and diclofenac(RQ=1.8)posed high ecological risks,with their effects nonlinearly correlated with hydraulic retention time(HRT<3 days)and nutrient loading(TN>1.2 mg/L).A three-tier risk prevention system was developed based on the“source-pathway-receptor”framework:ozone-activated carbon pretreatment achieved 85%removal efficiency for pharmaceutical contaminants,ecological floating beds enhanced nitrogen and phosphorus retention by 40%-60%,and hydraulic regulation(flow velocity>0.1 m/s)effectively suppressed pathogen proliferation.The innovation of this study lies in establishing a chemical-biological-hydrological coupled risk quantification model for reclaimed water reuse scenarios.The hierarchical prevention standards have been incorporated into local reclaimed water management regulations,providing a scientific foundation and technical paradigm for sustainable landscape water replenishment.展开更多
Although the southeast Fujian Province has favorable bio-climatic conditions, traditional farming models are limited in effective exploitation of agriculture related resources and have deteriorated the agricultural en...Although the southeast Fujian Province has favorable bio-climatic conditions, traditional farming models are limited in effective exploitation of agriculture related resources and have deteriorated the agricultural environment. After analyzing the conditions at Maping town, we designed a three-dimensional model, special ecological agricultural system (SEAS), at Maping town. The SEAS has been practiced for three years and results show that the SEAS more efficiently utilizes local time and space resources and gains more econo- mic, ecological and social benefits. Thus, the SEAS has been considered as an optimal model for sustainable utilization of agricultural resources.展开更多
As natural ecosystems provide the material basis and fundamental support for regional sustainable devel-opment,the sustainability of natural ecosystems is an important prerequisite and a viable approach for the achiev...As natural ecosystems provide the material basis and fundamental support for regional sustainable devel-opment,the sustainability of natural ecosystems is an important prerequisite and a viable approach for the achievement of regional sustainable development.It is also the final criteria to assess whether sustainable development paradigm is successful.Along with the increasing impacts of human activities on natural ecosystems,the evaluation of regional ecological sustainability has become one of the key issues for research on macro ecology and sustainable development.Based on different unit of indicators,this study firstly groups the evaluation frameworks of regional ecological sus-tainability into three major types:comprehensive index evaluation with dimensionless unit,monetary valuation,and biophysical quantity measurement.We then discuss and compare these types in terms of basic principles,scope of ap-plications,advantages and shortcomings.Finally,drawn on the discussion about characteristics of ecological sustain-ability,we outline the current trend and future directions of regional ecological sustainability evaluation,for instance,transition from sustainable development evaluation to sustainability science,integration of goal-oriented and problem-solving approaches,combination of spatial pattern analysis and ecological sustainability evaluation,and en-hancement of ecological sustainability evaluation at landscape scale.展开更多
Two reported three-dimensional covalent organic frameworks(3D-COFs),COF-300 and COF-301,which have hierarchical porous structures and large pore volumes,were synthesized and employed as host materials for lithium-sulf...Two reported three-dimensional covalent organic frameworks(3D-COFs),COF-300 and COF-301,which have hierarchical porous structures and large pore volumes,were synthesized and employed as host materials for lithium-sulfur batteries.Owing to possessing excellent porosities as well as abundant hydroxyl groups in the pore walls,COF-301 can not only trap lithium polysulfides(PSs)via physical adsorption inside the pores,but also capture PSs by chemical interactions to relieve the shuttle effect.Interestingly,it is the first time that 3D-COFs were utilized as host materials for lithium-sulfur batteries as well as hydroxyl groups were introduced into COFs for improving the battery performance.As a result,COF-301@S as cathode material could reserve the capacity of 411.6 mA·h·g^-1 after 500 cycles with only 0.081%fading per cycle at 0.5 C,exhibiting better battery performance compared with COF-300@S.This study not only expands the applications of 3D-COFs but also provides a new route for designing lithium-sulfur batteries.展开更多
The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-cry...The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-crystal diffraction. It belongs to orthorhombic with space group Pccn, a = 20.949(3), b = 17.470(3), c = 20.345(3) Angstrom, V = 7446(2) Angstrom(3), Z = 8, D-c = 1.242 g/cm(3), mu = 1.365 mm(-1), F(000) = 2864, R = 0.0544 and wR = 0.1417. The tin atom is of five-coordination in a trigonal bipyramidal structure by bridging two carboxylate groups in different directions and the resulting structure which contains straight twist large ring channels along the axes of a, b and c is a three-dimensional framework polymer containing two different tin atoms.展开更多
Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully construct...Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24.展开更多
Theoretical frameworks play a vital role in research, spelling out the constructs important in the research area, and the relationships between the constructs. An understanding of the theoretical constructs which unde...Theoretical frameworks play a vital role in research, spelling out the constructs important in the research area, and the relationships between the constructs. An understanding of the theoretical constructs which underpin the research provides researchers with a framework, which enables them to understand when, how and why particular phenomena occur. Depending on the type of research, this either allows them to make reasoned predictions, which can be empirically tested during the research or gives direction for the research if it is open-ended and exploratory. Such frameworks not only guide the questions asked and the design of the research, but also help to interpret the data. If the situation being investigated is very complex, involving numerous interlinked variables, it is often difficult to identify a single theoretical framework that is suitable for a particular study. This article uses the case of human ecological behavioural problems associated with the conservation of biodiversity in the Rwenzori Mountains National Park, to show how a theoretical framework to investigate a complex situation was developed.展开更多
Researchers' understandings of economic, ecological and social benefits of urban green spaces were discussed from many perspectives, connotations of such three major benefits were redefined, existing problems in t...Researchers' understandings of economic, ecological and social benefits of urban green spaces were discussed from many perspectives, connotations of such three major benefits were redefined, existing problems in the present evaluation were analyzed. According to service objects of urban green spaces, 6 relationship fields were classified, specifically, global ecology, regional environment, regional health, basic life, spiritual life and material life, a basic framework for evaluating economic, ecological and social benefits of urban green spaces was proposed.展开更多
Covalent organic frameworks(COFs) are a class of crystalline porous organic materials with variable structures and fascinating properties. The intrinsic low conductivity impedes their widely application in optoelectro...Covalent organic frameworks(COFs) are a class of crystalline porous organic materials with variable structures and fascinating properties. The intrinsic low conductivity impedes their widely application in optoelectronic. Iodine doping is an effective way to enhance the electrical conductivity of COFs. Here, a novel 3D imine COF with lvt topology is synthesized from two different pentacene derivatives with the same core in the form of structural complementarity. DDHP-COF is a highly crystalline material featuring high surface area of 1679 m^(2)/g and excellent thermal stability up to 490 ℃. Upon doping with iodine, the electrical conductivity can reach as high as 1.5×10^(-2)S/m which is significantly enhanced over 6 orders of magnitude compared with the pristine COF.展开更多
A new heteropolyoxotungstate [（C2H4N2）4（P4Co3W4O28H6）（H2C2O4）]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1...A new heteropolyoxotungstate [（C2H4N2）4（P4Co3W4O28H6）（H2C2O4）]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1006（17）,b = 17.1006（7）,c = 10.7525（5）,V = 3144.2（2）3,Z = 4,Dc = 3.795 g·cm-3,F（000） = 3300,MoKα（λ = 0.71073 ）,μ = 16.460 mm-1,the final R = 0.0335 and wR = 0.0776.In the heteropolyoxotungstate,tungsten-oxygen octahedra are linked by sharing two cis-vertexes into an infinite helical chain extending along the c axis.Cobalt atoms in the octahedral geometry act as the linkers of these chains,forming a three-dimensional framework.The cobalt and phosphorus atoms in the tetrahedral geometry play a role in stabilizing the three-dimensional framework.Ethylenediamine molecules are polymerized into organic chains which locate in the interspaces of the framework in the way of interwinding with the W-O chains.展开更多
Where sustainable development is concerned, there is an urgent need to establish new information systems that integrate economic, social and ecological factors. The emergence of demand for this information makes the d...Where sustainable development is concerned, there is an urgent need to establish new information systems that integrate economic, social and ecological factors. The emergence of demand for this information makes the development of ecological accounting possible. Yet, most current research on ecological accounting focuses on two aspects: (1) the theoretical aspect, including background, concepts and models and (2) specific research on ecological accounting. Some scholars have proposed a conceptual framework, but this is not systematic or thorough enough. Seizing the opportunity of sustainable development in a key strategic location of the world, this paper begins by analyzing the logical evolution of ecological accounting, summarizes the existing ecological accounting theory, and combines the mature theoretical study of resources accounting with environmental accounting. All of these efforts result in this paper forwarding a framework of ecological accounting that aims to provide a guideline for future development.展开更多
The evolution of the society and economy has stimulated the development of Knowledge Service(KS), making it an indispensable solution to address future challenges facing libraries and information institutions. However...The evolution of the society and economy has stimulated the development of Knowledge Service(KS), making it an indispensable solution to address future challenges facing libraries and information institutions. However at present, academic research on knowledge service is falling short and its definition is far from clear and complete. As such,this article proposes the Three-dimensional Framework Knowledge Service(TdFKS) for libraries and information institutions based on the knowledge value chain model. By making reliability analysis and mean value analysis of a questionnaire survey result, the article clarifies the structure of the three-dimensional framework and verifies the rationality of the TdFKS.展开更多
The Critical Discourse Analysis(CDA)is an interdisciplinary tool in various conditions,which aims to provide a better understanding of sociocultural aspects of texts and accounts of the production of internal structur...The Critical Discourse Analysis(CDA)is an interdisciplinary tool in various conditions,which aims to provide a better understanding of sociocultural aspects of texts and accounts of the production of internal structure,and overall organization of texts as well as to provide a critical dimension in its theoretical and descriptive accounts of texts.Since June last year,HK protests or HK violence have been frequently reported by worldwide media.In this paper,the author aims to find out how the HK protesters and the Mainland media describe the same event based on the three-dimensional framework of CDA.At last,the author concludes that the mainland media generally describe the event as violence and riot while the HK protesters define themselves as warriors striving for more freedom,justice and democracy.Besides,on this event,the Mainland media mainly accuses some western countries of interference into HK affairs,which is undoubtedly of China’s internal affairs,and the media give full support to the HK police in safeguarding the peace and stability of Hong Kong.But from the perspective of HK protesters,they firmly believe that they are using their actions to protect all the people of HK,and they are defending their values such as freedom,democracy and justice.These are two totally different systems of language,and the author also gives its potential reasons in the paper so as to offer some viewpoints in this aspect in combination with the CDA theory.展开更多
Land ecological security(LES)is an important part of China’s ecological civilization construction,which plays a vital role in ensuring the sustainable development of its society and economy.Based on the Driving force...Land ecological security(LES)is an important part of China’s ecological civilization construction,which plays a vital role in ensuring the sustainable development of its society and economy.Based on the Driving force-Pressure-State-Impact-Response(DPSIR)framework,this study quantified the spatiotemporal changes of LES in 28 counties of the southern Shaanxi Province from 2009 to 2018.The influencing factors of LES in Yangxian County were explored to clarify the mechanisms that rely on the land ecological advantages to develop organic agriculture and boost poverty alleviation.Results show that the LES of Yangxian always ranked in the top six in 28 counties of the southern Shaanxi region during 2009–2018.The LES in Yangxian increased from 0.385 in 2009 to 0.533 in 2018,and the LES level changed from relatively unsafe to safe.The indicators of rural per capita net income,grain output per unit area of arable land,and grazing intensity could explain 99.8%of the LES variance in Yangxian.Relying on ecological resources,Yangxian increased farmers’income and boosted alleviation of poverty through innovative land policies,developing organic agriculture,and rural tourism.These findings will provide theoretical support and model reference for balancing ecological protection and poverty alleviation in restricted development zones.展开更多
A novel Ni（II） coordination polymer [Ni（dtba）（4,4′-bpy）] （1, H2dtba = 2,2′-dithio- bisbenzoic acid, 4,4′-bpy = 4,4′-bipyridine） has been synthesized by H2dtba and Ni（CH3COO）2·4H2O with exo-bidentate...A novel Ni（II） coordination polymer [Ni（dtba）（4,4′-bpy）] （1, H2dtba = 2,2′-dithio- bisbenzoic acid, 4,4′-bpy = 4,4′-bipyridine） has been synthesized by H2dtba and Ni（CH3COO）2·4H2O with exo-bidentate rigid ligand 4,4′-bpy by using hydrothermal method, and its structure was determined by single-crystal X-ray diffraction. X-ray crystal structure analysis reveals that complex 1 crystallizes in monoclinic, space group Cc with a = 11.7624（9）, b = 18.7933（19）, c = 10.3071（11）, β = 97.6510（10）°, V = 2258.2（4）3, Z = 4, C24H16N2NiO4S2, Mr = 519.22, Dc = 1.527 g/cm3, μ = 1.079 mm-1 and F（000） = 1064. The structure was solved by direct methods and refined to R = 0.0434 and wR = 0.1000 for 3281 observed reflections （I 〉 2σ（I））. The coordination environment of Ni（II） is a distorted octahedron, and a three-dimensional structure was formed with the coordination effect of dtba2- and 4,4′-bpy ligands. The topological analysis reveals that the whole framework of 1 is a 2-nodal net of （52.6）（53.64.72.8） topology. The thermal stability and XRD pattern of 1 were also investigated展开更多
Fenlong Technology has been applied to increase yield by 20%-50%,improve quality by 5%,and retain water by 100%in 40 kinds of crop cultivated land and saline-alkali land in 26 provinces of China.This paper clarified f...Fenlong Technology has been applied to increase yield by 20%-50%,improve quality by 5%,and retain water by 100%in 40 kinds of crop cultivated land and saline-alkali land in 26 provinces of China.This paper clarified for the first time the scientific theory system of Fenlong Technology using three-dimensional space resources"Fenlong Agricultural Nature Theory"and the development of the relative"limits"of agricultural growth,which provides a huge power support and natural force for expanding human living spaces.Through inventing and creating a scientific and technological system of farming tools,farming machinery,farming modes,and magic weapons for cultivation,Fenlong Technology can increase grain,promote ecological development,and greatly expand the living spaces of the Chinese nation and achieve sustainable development.Using Fenlong Technology,China has expanded from the current single"cultivated land agriculture"to the"big pattern agriculture"of Fenlong"cultivated land+saline land+degraded grassland+marginal land+desertified land+river water",flexibly used 147 million ha of"three-dimensional space resources"of land,and the newly increased food,meat,and fish can feed 300 million to 400 million people,increased the water storage by 100 billion m^(3),and reduced the collection of groundwater by 20 million to 60 billion m^(3).展开更多
Responding to the increasingly heated discussion of environmental issues and the mounting concern about ecological degradation, the present thesis is to try formulating a comprehensive and specific theoretical model f...Responding to the increasingly heated discussion of environmental issues and the mounting concern about ecological degradation, the present thesis is to try formulating a comprehensive and specific theoretical model for exploring the ecological ide-ologies revealed in the online Chinese resort profiles. In this model, Fairclough's three-dimensional model draws upon the Subsystem of Appraisal Theory-Attitude as the specific analytical framework and the ecological philosophy in the scope of ecocriticism as the specific explanatory tool for the exploration of ecological ideologies in these texts. Thus, the present thesis finds a point where CDA, Appraisal Theory and Ecocriticism work together to conduct a discourse analysis, which not only broadens the theoretical scope of each, but makes these theories better serve the practical course of environment protection.展开更多
基金supported by the project of the National Natural Science Foundation of China(42330705).
文摘Enhancing ecological security for sustainable social,economic,and environmental development is a key focus of current research and a practical necessity for ecological management.However,the integration of retrospective ecological security assessments with future trend predictions and fine-scale targeted regulations remains inadequate,limiting effective ecological governance and sustainable regional development.Guided by Social-Economic-Natural Complex Ecosystems(SENCE)theory,this study proposes an analytical framework that integrates ecological security assessment,prediction,and zoning management.The Daqing River Basin,a typical river basin in the North China Plain,was selected as a case study.The results indicate that overall ecological security in the Daqing River Basin improved from a“Moderate”level to a“Relatively Safe”level between 2000 and 2020;however,spatial heterogeneity persisted,with higher ecological security in northwestern and eastern regions and lower ecological security in the central region.Approximately 62% of the Basin experienced an improvement in ecological security level,except in the major urban areas of Beijing,Tianjin,and Hebei,where ecological security deteriorated.From 2025 to 2040,the overall ecological security of the Daqing River Basin is expected to improve and remain at the“Relatively Safe”level.However,spatial heterogeneity will be further aggravated as the ecological security of major urban areas continues to deteriorate.Ecological security management zones and regulation strategies are proposed at the regional and county scales to emphasize integrated regulation for the entire basin and major urban areas.The proposed analytical framework provides valuable insights for advancing theoretical research on ecological security.The case study offers a practical reference for ecological security enhancement in river basins and other regions facing significant human-land conflicts.
文摘Against the backdrop of intensifying global water scarcity,reclaimed water reuse has emerged as a critical strategy for ecological replenishment of landscape water bodies.However,its potential ecological risks remain underexplored.This study aims to establish a multidimensional ecological safety evaluation framework for reclaimed water replenishment systems and propose hierarchical risk prevention strategies.By integrating ecotoxicological assays(algae growth inhibition,Daphnia behavioral anomalies,zebrafish embryo toxicity),multimedia exposure modeling,and Monte Carlo probabilistic simulations,the risk contributions and spatial heterogeneity of typical pollutants are quantitatively analyzed.Results revealed that sulfamethoxazole(RQ=2.3)and diclofenac(RQ=1.8)posed high ecological risks,with their effects nonlinearly correlated with hydraulic retention time(HRT<3 days)and nutrient loading(TN>1.2 mg/L).A three-tier risk prevention system was developed based on the“source-pathway-receptor”framework:ozone-activated carbon pretreatment achieved 85%removal efficiency for pharmaceutical contaminants,ecological floating beds enhanced nitrogen and phosphorus retention by 40%-60%,and hydraulic regulation(flow velocity>0.1 m/s)effectively suppressed pathogen proliferation.The innovation of this study lies in establishing a chemical-biological-hydrological coupled risk quantification model for reclaimed water reuse scenarios.The hierarchical prevention standards have been incorporated into local reclaimed water management regulations,providing a scientific foundation and technical paradigm for sustainable landscape water replenishment.
文摘Although the southeast Fujian Province has favorable bio-climatic conditions, traditional farming models are limited in effective exploitation of agriculture related resources and have deteriorated the agricultural environment. After analyzing the conditions at Maping town, we designed a three-dimensional model, special ecological agricultural system (SEAS), at Maping town. The SEAS has been practiced for three years and results show that the SEAS more efficiently utilizes local time and space resources and gains more econo- mic, ecological and social benefits. Thus, the SEAS has been considered as an optimal model for sustainable utilization of agricultural resources.
基金Under the auspices of National Natural Science Foundation of China (No.40635028,40801066)State Key Laboratory of Earth Surface Processes and Resource Ecology of China (No.2008-KF-04)
文摘As natural ecosystems provide the material basis and fundamental support for regional sustainable devel-opment,the sustainability of natural ecosystems is an important prerequisite and a viable approach for the achievement of regional sustainable development.It is also the final criteria to assess whether sustainable development paradigm is successful.Along with the increasing impacts of human activities on natural ecosystems,the evaluation of regional ecological sustainability has become one of the key issues for research on macro ecology and sustainable development.Based on different unit of indicators,this study firstly groups the evaluation frameworks of regional ecological sus-tainability into three major types:comprehensive index evaluation with dimensionless unit,monetary valuation,and biophysical quantity measurement.We then discuss and compare these types in terms of basic principles,scope of ap-plications,advantages and shortcomings.Finally,drawn on the discussion about characteristics of ecological sustain-ability,we outline the current trend and future directions of regional ecological sustainability evaluation,for instance,transition from sustainable development evaluation to sustainability science,integration of goal-oriented and problem-solving approaches,combination of spatial pattern analysis and ecological sustainability evaluation,and en-hancement of ecological sustainability evaluation at landscape scale.
基金supported by the National Natural Science Foundation of China(Nos.21674026,21574032,51573125,51573147,51803149,51973155,and 51633007(the State Key Program))the Sino-German Center for Research Promotion(No.GZ1286)the Chinese Academy of Sciences(No.121D11KYSB20170031).
文摘Two reported three-dimensional covalent organic frameworks(3D-COFs),COF-300 and COF-301,which have hierarchical porous structures and large pore volumes,were synthesized and employed as host materials for lithium-sulfur batteries.Owing to possessing excellent porosities as well as abundant hydroxyl groups in the pore walls,COF-301 can not only trap lithium polysulfides(PSs)via physical adsorption inside the pores,but also capture PSs by chemical interactions to relieve the shuttle effect.Interestingly,it is the first time that 3D-COFs were utilized as host materials for lithium-sulfur batteries as well as hydroxyl groups were introduced into COFs for improving the battery performance.As a result,COF-301@S as cathode material could reserve the capacity of 411.6 mA·h·g^-1 after 500 cycles with only 0.081%fading per cycle at 0.5 C,exhibiting better battery performance compared with COF-300@S.This study not only expands the applications of 3D-COFs but also provides a new route for designing lithium-sulfur batteries.
基金the National Natural Science Foundation of China (No. 20271025)the Natural Science Foundation of Shandong province (No. Z2001B02)the State Key Laboratory of Crystal Materials,Shandong University
文摘The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-crystal diffraction. It belongs to orthorhombic with space group Pccn, a = 20.949(3), b = 17.470(3), c = 20.345(3) Angstrom, V = 7446(2) Angstrom(3), Z = 8, D-c = 1.242 g/cm(3), mu = 1.365 mm(-1), F(000) = 2864, R = 0.0544 and wR = 0.1417. The tin atom is of five-coordination in a trigonal bipyramidal structure by bridging two carboxylate groups in different directions and the resulting structure which contains straight twist large ring channels along the axes of a, b and c is a three-dimensional framework polymer containing two different tin atoms.
文摘Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24.
文摘Theoretical frameworks play a vital role in research, spelling out the constructs important in the research area, and the relationships between the constructs. An understanding of the theoretical constructs which underpin the research provides researchers with a framework, which enables them to understand when, how and why particular phenomena occur. Depending on the type of research, this either allows them to make reasoned predictions, which can be empirically tested during the research or gives direction for the research if it is open-ended and exploratory. Such frameworks not only guide the questions asked and the design of the research, but also help to interpret the data. If the situation being investigated is very complex, involving numerous interlinked variables, it is often difficult to identify a single theoretical framework that is suitable for a particular study. This article uses the case of human ecological behavioural problems associated with the conservation of biodiversity in the Rwenzori Mountains National Park, to show how a theoretical framework to investigate a complex situation was developed.
文摘Researchers' understandings of economic, ecological and social benefits of urban green spaces were discussed from many perspectives, connotations of such three major benefits were redefined, existing problems in the present evaluation were analyzed. According to service objects of urban green spaces, 6 relationship fields were classified, specifically, global ecology, regional environment, regional health, basic life, spiritual life and material life, a basic framework for evaluating economic, ecological and social benefits of urban green spaces was proposed.
基金financially supported by the National Natural Science Foundation of China (Nos. 51973153, 22001191)。
文摘Covalent organic frameworks(COFs) are a class of crystalline porous organic materials with variable structures and fascinating properties. The intrinsic low conductivity impedes their widely application in optoelectronic. Iodine doping is an effective way to enhance the electrical conductivity of COFs. Here, a novel 3D imine COF with lvt topology is synthesized from two different pentacene derivatives with the same core in the form of structural complementarity. DDHP-COF is a highly crystalline material featuring high surface area of 1679 m^(2)/g and excellent thermal stability up to 490 ℃. Upon doping with iodine, the electrical conductivity can reach as high as 1.5×10^(-2)S/m which is significantly enhanced over 6 orders of magnitude compared with the pristine COF.
基金supported by the Analysis and Testing Foundation of Northeast Normal University
文摘A new heteropolyoxotungstate [（C2H4N2）4（P4Co3W4O28H6）（H2C2O4）]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1006（17）,b = 17.1006（7）,c = 10.7525（5）,V = 3144.2（2）3,Z = 4,Dc = 3.795 g·cm-3,F（000） = 3300,MoKα（λ = 0.71073 ）,μ = 16.460 mm-1,the final R = 0.0335 and wR = 0.0776.In the heteropolyoxotungstate,tungsten-oxygen octahedra are linked by sharing two cis-vertexes into an infinite helical chain extending along the c axis.Cobalt atoms in the octahedral geometry act as the linkers of these chains,forming a three-dimensional framework.The cobalt and phosphorus atoms in the tetrahedral geometry play a role in stabilizing the three-dimensional framework.Ethylenediamine molecules are polymerized into organic chains which locate in the interspaces of the framework in the way of interwinding with the W-O chains.
文摘Where sustainable development is concerned, there is an urgent need to establish new information systems that integrate economic, social and ecological factors. The emergence of demand for this information makes the development of ecological accounting possible. Yet, most current research on ecological accounting focuses on two aspects: (1) the theoretical aspect, including background, concepts and models and (2) specific research on ecological accounting. Some scholars have proposed a conceptual framework, but this is not systematic or thorough enough. Seizing the opportunity of sustainable development in a key strategic location of the world, this paper begins by analyzing the logical evolution of ecological accounting, summarizes the existing ecological accounting theory, and combines the mature theoretical study of resources accounting with environmental accounting. All of these efforts result in this paper forwarding a framework of ecological accounting that aims to provide a guideline for future development.
基金supported by the National Planning Office of Philosophy and Social Science(Grant No.06BTQ027)
文摘The evolution of the society and economy has stimulated the development of Knowledge Service(KS), making it an indispensable solution to address future challenges facing libraries and information institutions. However at present, academic research on knowledge service is falling short and its definition is far from clear and complete. As such,this article proposes the Three-dimensional Framework Knowledge Service(TdFKS) for libraries and information institutions based on the knowledge value chain model. By making reliability analysis and mean value analysis of a questionnaire survey result, the article clarifies the structure of the three-dimensional framework and verifies the rationality of the TdFKS.
文摘The Critical Discourse Analysis(CDA)is an interdisciplinary tool in various conditions,which aims to provide a better understanding of sociocultural aspects of texts and accounts of the production of internal structure,and overall organization of texts as well as to provide a critical dimension in its theoretical and descriptive accounts of texts.Since June last year,HK protests or HK violence have been frequently reported by worldwide media.In this paper,the author aims to find out how the HK protesters and the Mainland media describe the same event based on the three-dimensional framework of CDA.At last,the author concludes that the mainland media generally describe the event as violence and riot while the HK protesters define themselves as warriors striving for more freedom,justice and democracy.Besides,on this event,the Mainland media mainly accuses some western countries of interference into HK affairs,which is undoubtedly of China’s internal affairs,and the media give full support to the HK police in safeguarding the peace and stability of Hong Kong.But from the perspective of HK protesters,they firmly believe that they are using their actions to protect all the people of HK,and they are defending their values such as freedom,democracy and justice.These are two totally different systems of language,and the author also gives its potential reasons in the paper so as to offer some viewpoints in this aspect in combination with the CDA theory.
基金Strategic Priority Research Program of the Chinese Academy of Sciences,No.XDA23070301Key Program of the National Natural Science Foundation of China,No.41931293。
文摘Land ecological security(LES)is an important part of China’s ecological civilization construction,which plays a vital role in ensuring the sustainable development of its society and economy.Based on the Driving force-Pressure-State-Impact-Response(DPSIR)framework,this study quantified the spatiotemporal changes of LES in 28 counties of the southern Shaanxi Province from 2009 to 2018.The influencing factors of LES in Yangxian County were explored to clarify the mechanisms that rely on the land ecological advantages to develop organic agriculture and boost poverty alleviation.Results show that the LES of Yangxian always ranked in the top six in 28 counties of the southern Shaanxi region during 2009–2018.The LES in Yangxian increased from 0.385 in 2009 to 0.533 in 2018,and the LES level changed from relatively unsafe to safe.The indicators of rural per capita net income,grain output per unit area of arable land,and grazing intensity could explain 99.8%of the LES variance in Yangxian.Relying on ecological resources,Yangxian increased farmers’income and boosted alleviation of poverty through innovative land policies,developing organic agriculture,and rural tourism.These findings will provide theoretical support and model reference for balancing ecological protection and poverty alleviation in restricted development zones.
基金the National Natural Science Foundation of China (No. 20771006, 20901004 and 20801025)
文摘A novel Ni（II） coordination polymer [Ni（dtba）（4,4′-bpy）] （1, H2dtba = 2,2′-dithio- bisbenzoic acid, 4,4′-bpy = 4,4′-bipyridine） has been synthesized by H2dtba and Ni（CH3COO）2·4H2O with exo-bidentate rigid ligand 4,4′-bpy by using hydrothermal method, and its structure was determined by single-crystal X-ray diffraction. X-ray crystal structure analysis reveals that complex 1 crystallizes in monoclinic, space group Cc with a = 11.7624（9）, b = 18.7933（19）, c = 10.3071（11）, β = 97.6510（10）°, V = 2258.2（4）3, Z = 4, C24H16N2NiO4S2, Mr = 519.22, Dc = 1.527 g/cm3, μ = 1.079 mm-1 and F（000） = 1064. The structure was solved by direct methods and refined to R = 0.0434 and wR = 0.1000 for 3281 observed reflections （I 〉 2σ（I））. The coordination environment of Ni（II） is a distorted octahedron, and a three-dimensional structure was formed with the coordination effect of dtba2- and 4,4′-bpy ligands. The topological analysis reveals that the whole framework of 1 is a 2-nodal net of （52.6）（53.64.72.8） topology. The thermal stability and XRD pattern of 1 were also investigated
基金Special Fund Project for Innovation Driven Development of Guangxi(Gui Ke AA17204037)Key Science and Technology Project of Guangxi(Gui Ke AA16380017)Team Project of Guangxi Academy of Agricultural Sciences(2015YT60).
文摘Fenlong Technology has been applied to increase yield by 20%-50%,improve quality by 5%,and retain water by 100%in 40 kinds of crop cultivated land and saline-alkali land in 26 provinces of China.This paper clarified for the first time the scientific theory system of Fenlong Technology using three-dimensional space resources"Fenlong Agricultural Nature Theory"and the development of the relative"limits"of agricultural growth,which provides a huge power support and natural force for expanding human living spaces.Through inventing and creating a scientific and technological system of farming tools,farming machinery,farming modes,and magic weapons for cultivation,Fenlong Technology can increase grain,promote ecological development,and greatly expand the living spaces of the Chinese nation and achieve sustainable development.Using Fenlong Technology,China has expanded from the current single"cultivated land agriculture"to the"big pattern agriculture"of Fenlong"cultivated land+saline land+degraded grassland+marginal land+desertified land+river water",flexibly used 147 million ha of"three-dimensional space resources"of land,and the newly increased food,meat,and fish can feed 300 million to 400 million people,increased the water storage by 100 billion m^(3),and reduced the collection of groundwater by 20 million to 60 billion m^(3).
文摘Responding to the increasingly heated discussion of environmental issues and the mounting concern about ecological degradation, the present thesis is to try formulating a comprehensive and specific theoretical model for exploring the ecological ide-ologies revealed in the online Chinese resort profiles. In this model, Fairclough's three-dimensional model draws upon the Subsystem of Appraisal Theory-Attitude as the specific analytical framework and the ecological philosophy in the scope of ecocriticism as the specific explanatory tool for the exploration of ecological ideologies in these texts. Thus, the present thesis finds a point where CDA, Appraisal Theory and Ecocriticism work together to conduct a discourse analysis, which not only broadens the theoretical scope of each, but makes these theories better serve the practical course of environment protection.
