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Thermal Analysis Simulation of Germanium Zone Refining Process Assuming a Constant Radio-Frequency Heating Source
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作者 Mahdi Ezheiyan Hossein Sadeghi Mohammad-Hossein Tavakoli 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第5期123-126,共4页
Three-dimensional thermal a nalysis simulation of a horizontal zone refining system is conducted for germanimn semiconductor materials. The considered geometry includes a g'ral)hite boat filled with germanium placed... Three-dimensional thermal a nalysis simulation of a horizontal zone refining system is conducted for germanimn semiconductor materials. The considered geometry includes a g'ral)hite boat filled with germanium placed in a cylindrical quartz tube. A flow of Ar and H2 gas mixture is purged througll the tube. A narrow section of the, boat is assmned to be exposed to a constant heat rate produced b v an rf coil located outside the quartz tube. The results of this analysis provide essential information about various parameters such as the shape of tile molten zone, required power and temperature gradient in the system. 展开更多
关键词 of on thermal Analysis Simulation of Germanium Zone Refining Process Assuming a constant Radio-Frequency Heating Source in IS for
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“芯-屏-器/气-合”——多功能化聚酰亚胺材料的核心技术突破、性能优化及应用场景探索
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作者 胡锦宏 蔡铭威 +3 位作者 甘一乐 张扬 施海南 闵永刚 《高等学校化学学报》 北大核心 2026年第1期69-86,共18页
聚酰亚胺作为高性能聚合物的关键代表,以其卓越的耐热性、优异的力学性能及突出的介电特性,在集成电路、新能源、航空航天等国家战略新兴领域中扮演着不可替代的角色.然而,面对柔性电子、高效能源转换及“双碳”战略等前沿领域的快速发... 聚酰亚胺作为高性能聚合物的关键代表,以其卓越的耐热性、优异的力学性能及突出的介电特性,在集成电路、新能源、航空航天等国家战略新兴领域中扮演着不可替代的角色.然而,面对柔性电子、高效能源转换及“双碳”战略等前沿领域的快速发展,传统聚酰亚胺材料在介电、柔性、功能集成及热管理等方面仍存在显著瓶颈.基于此,本文综合评述了本课题组围绕“芯-屏-器/气-合”5个关键维度所取得的多功能聚酰亚胺的创新研究成果.在“芯”层面,发展了具有超低介电常数与高强度的材料体系,服务于高端芯片封装;在“屏”层面,研制出高透光、耐折曲的柔性薄膜,满足柔性显示需求;在“器/气”层面,一方面拓展了其在能源器件与航空航天热管理中的应用,另一方面通过结构设计显著提升了气体分离性能,服务于“双碳”目标;在“合”层面,通过构建多维导热网络,实现了复合材料热管理能力的突破.本文不仅展示了聚酰亚胺巨大的功能可塑性,也为解决相关科技领域的关键材料挑战提供了重要的理论与技术支撑. 展开更多
关键词 聚酰亚胺 高频低介电 薄膜 气体分离 热管理
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基于现场实测的电伴热系统能效水平与节能潜力评价
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作者 高盼 《石油石化节能与计量》 2026年第2期61-68,共8页
为评估电伴热系统在油田集输管道中的能效水平与工程适应性,开展了基于现场工况的恒功率与自限温电伴热系统运行性能实测研究。系统分析了该系统在不同环境温度与加热目标条件下的升温响应特性、热稳定性、电能消耗与节能表现,并与传统... 为评估电伴热系统在油田集输管道中的能效水平与工程适应性,开展了基于现场工况的恒功率与自限温电伴热系统运行性能实测研究。系统分析了该系统在不同环境温度与加热目标条件下的升温响应特性、热稳定性、电能消耗与节能表现,并与传统蒸汽伴热系统进行了对比评价。采用多点实时测温与能耗监测,计算了能效比、单位能耗与热损失等关键指标。结果表明,自限温电伴热系统在加热初期具备良好的响应速度,1 h内温升可达25.1℃,稳态运行阶段温度波动控制在±0.4℃以内。典型工况下系统能效比稳定在2.34~2.57,等效能耗相比蒸汽伴热系统降低约25%。在环境温度为5~15℃、加热目标为40~50℃、管道长度为10~30 m的多种工况组合下,节能率维持在15%~30%,展现出良好的适应性与节能弹性。研究明确了两类电伴热的互补性:自限温更适合短距离、复杂结构和安全敏感工况,恒功率更适合长距离、高温及高负荷工况。 展开更多
关键词 油田集输管道 自限温电伴热 恒功率电伴热 热稳定性 能效比
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First-principles investigation of the effects of strain on elastic thermal, and optical properties of CuGaTe2 被引量:2
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作者 薛丽 任一鸣 +1 位作者 何俊荣 徐四六 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第6期324-328,共5页
Based on the density functional theory, the influences of strain on structural, elastic, thermal and optical properties of CuGaTe2 are discussed in detail. It is found that the tensile strain on CuGaTe2 is beneficial ... Based on the density functional theory, the influences of strain on structural, elastic, thermal and optical properties of CuGaTe2 are discussed in detail. It is found that the tensile strain on CuGaTe2 is beneficial to the decrease of lattice thermal conductivity by reducing the mean sound velocity and Debye temperature. Moreover, all strained and unstrained CuGaTe2 exhibit rather similar optical characters. But the tensile strain improves the ability to absorb sunlight in the visible range.These research findings can give hints for designing thermoelectric and photovoltaic devices. 展开更多
关键词 elastic constants thermal properties optical properties FIRST-PRINCIPLES
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汽车LED照明系统的驱动电路设计与光效提升研究
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作者 史聪聪 徐赞扬 《汽车电器》 2026年第1期105-107,共3页
本文围绕汽车LED照明系统的工程化实现,聚焦两条核心主线:驱动电路的可落地设计与光效提升的系统路径。在驱动电路设计方面,明确了车规输入级、防反接电路与滤波网络在台架上可复现的边界条件;针对恒流与反馈环节,提出包含采样电阻开尔... 本文围绕汽车LED照明系统的工程化实现,聚焦两条核心主线:驱动电路的可落地设计与光效提升的系统路径。在驱动电路设计方面,明确了车规输入级、防反接电路与滤波网络在台架上可复现的边界条件;针对恒流与反馈环节,提出包含采样电阻开尔文走线、补偿网络迭代调试及基于非易失性存储器(Non-Volatile Memory,NVM)的出厂标定在内的完整流程;在EMC与诊断一体化设计上,制定了印刷电路板(Printed Circuit Board,PCB)叠层分区、单点接地与源头抑制的优化顺序。光效提升部分直接靶向光学路径衰减、热-电协同损耗及光谱色度稳定性三类核心损耗源,细化了材料选型、装配洁净控制、光学衍射元件(Diffractive Optical Element,DOE)微调、热接口压缩率验证、热管固定件耐久性测试及短波截止涂层抽检等关键工程动作。 展开更多
关键词 LED 驱动电路 恒流控制 光效提升 热-电协同
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The patterns of high-degree thermal free convection and its features in a spherical shell 被引量:1
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作者 朱涛 冯锐 《Acta Seismologica Sinica(English Edition)》 EI CSCD 2005年第1期12-26,共15页
A high-degree (degree l = 6 and order m = 0, 1, 2, [midline ellipsis] , l. High-order model for short) and steady thermal free convective motion of an infinite Prandtl number and Boussinesq fluid in a spherical shell ... A high-degree (degree l = 6 and order m = 0, 1, 2, [midline ellipsis] , l. High-order model for short) and steady thermal free convective motion of an infinite Prandtl number and Boussinesq fluid in a spherical shell is calculated by a Galerkin method. Convection is driven by an imposed temperature drop across top rigid and bottom stress-free isothermal boundaries only heated from below of the shell. In this paper, the scalar poloidal and fluctuating temperature fields are expanded into associated Legendre polynomials with degree l = 6 and order m = 0, 1, 2, [midline ellipsis] , l. Compared with zero-order model (degree l = 6 and order m = 0), from which 2-D longitudinal (r-θ) profiles can be obtained, high-order model can provide a series of southerly (r-θ), easterly (r-φ) and radial (θ-φ) velocity profiles, which probably reveal more detail features of mass motion in the mantle. It is found that Rayleigh number has great effects on the patterns and velocities of thermal free convection and controls the relative ratio of hot and cold plume in the shell. Probably, the present results mainly reveal the mass motion in the lower mantle, while the striking differences of convection patterns from velocities at different positions have important geodynamical significances. 展开更多
关键词 nonlinear thermal free convection constant viscosity Galerkin method
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Dynamic thermal modeling and parameter identification for a monolithic laser diode module
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作者 李金义 杜振辉 +1 位作者 马艺闻 徐可欣 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第3期317-322,共6页
We improved the thermal equivalent-circuit model of the laser diode module(LDM) to evaluate its thermal dynamic properties and calculate the junction temperature of the laser diode with a high accuracy.The thermal p... We improved the thermal equivalent-circuit model of the laser diode module(LDM) to evaluate its thermal dynamic properties and calculate the junction temperature of the laser diode with a high accuracy.The thermal parameters and the transient junction temperature of the LDM are modeled and obtained according to the temperature of the thermistor integrated in the module.Our improved thermal model is verified indirectly by monitoring the emission wavelength of the laser diode against gas absorption lines,and several thermal parameters are obtained with the temperature uncertainty of 0.01 K in the thermal dynamic process. 展开更多
关键词 laser diode module dynamic thermal modeling thermal time constant tunable diode laser absorption spectroscopy(TDLAS)
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Effects on the thermal expansion coefficient and dielectric properties of CLST/PTFE filled with modified glass fiber as microwave material 被引量:3
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作者 Liu Zheng Jing Zhou +2 位作者 Jie Shen Yanyuan Qi Wen Chen 《Chinese Chemical Letters》 SCIE CAS CSCD 2019年第5期1111-1114,共4页
Ceramic and polytetrafluoroethylene composites as dielectric materials have a low dielectric loss at high frequency and play an important role in the modern communication field.However,room temperature phase transform... Ceramic and polytetrafluoroethylene composites as dielectric materials have a low dielectric loss at high frequency and play an important role in the modern communication field.However,room temperature phase transformation of PTFE resins,which is accompanied by a large volume change(>400 ppm/℃),seriously affects the dimensional stability and performance stability of materials.The LD125 modified glass fiber(GF)was introduced to the CaO-Li2 O-Sm2O3-TiO2(CLST)/PTFE composite,to reduce the thermal expansion coefficient(CTE)of the composites.The tri-phase composites(CLST/PTFE/GF)show the low dielectric loss and excellent machine-ability.The effect of GF content on the dielectric properties and CTE was also investigated.The CLST/PTFE filled with 5%GF exhibits the best overall performance,which is a promising microwave dielectric material for microwave communication. 展开更多
关键词 MICROWAVE communication thermal expansion COEFFICIENT CLST PTFE DIELECTRIC loss DIELECTRIC constant
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Calculation of thermal physical parameters of dissociated air by the dissociation degree method
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作者 Yaopeng ZHAO Wei CAO 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2018年第7期1045-1056,共12页
The high temperature gas occurs behind shock or near the wall surface of vehicle in the hypersonic flight. As the temperature exceeds 2 000 K, 4 000 K, respectively, O2 and N2 molecules are successively dissociated. B... The high temperature gas occurs behind shock or near the wall surface of vehicle in the hypersonic flight. As the temperature exceeds 2 000 K, 4 000 K, respectively, O2 and N2 molecules are successively dissociated. Because of variable components at dif- ferent temperatures and pressures, the dissociated air is no longer a perfect gas, In this paper, a new method is developed to calculate accurate thermal physical parameters with the dissociation degree providing the thermochemical equilibrium procedure. Based on the dissociation degree, it is concluded that few numbers of equations and the solutions are easily obtained. In addition, a set of formulas relating the parameter to the dissociation degree are set up four-species, O2 molecule The thermodynamic properties of dissociated air containing and N2 molecule, O atom and N atom, are studied with the new method, and the results are consistent with those with the traditional equilibrium constant method. It is shown that this method is reliable for solving thermal physical parameters easily and directly. 展开更多
关键词 dissociated air thermal physical parameter equilibrium constant dissociation degree
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Determination of Catalytic Rate Constants towards Polymeric Conversion to Synthetic Oils: Bridging the Gap between Kinetics and Thermodynamics
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作者 Zharama M. Llarena 《Journal of Materials Science and Chemical Engineering》 2017年第8期1-11,共11页
Coal fly ash is being utilized as a recycling material for catalysis due to its aluminosilicate content. Catalytic conversion of polymeric wastes into synthetic gasoline and diesel through pyrolysis requires applicati... Coal fly ash is being utilized as a recycling material for catalysis due to its aluminosilicate content. Catalytic conversion of polymeric wastes into synthetic gasoline and diesel through pyrolysis requires application of kinetic and thermodynamic principles. This study aimed to identify the catalytic rate constant necessary for rate law involved in reaction mechanisms and activation energy reduction needed for heat transfer rate. Stoichiometric application for balanced total series of elementary reactions is solved for the concentration determination of reactants and products. Unsteady-state in three dimensional directions of thermodynamics is derived for the determination of heat transfer rate, temperatures at any position in a sphere using Gurney and Lurie chart and center temperature in a sphere by Heisler chart. Application principles of rate law and Arrhenius equation can result to thermal conductivity as a function of activation energy leading to synthetic fuel production. 展开更多
关键词 Catalyst Coal FLY ASH RATE Law RATE constant thermal Conductivity
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Study of Thermally Induced Vibration of Non-Homogeneous Trapezoidal Plate with Parabolically Thickness Variation in Both Directions
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作者 Kavita Satish Kumar Pragati Sharma 《Applied Mathematics》 2016年第12期1283-1296,共14页
The present analysis demonstrates the thermal effect on vibrations of a symmetric, non-homoge- neous trapezoidal plate with parabolically varying thickness in both directions. The variation in Young’s modulus and mas... The present analysis demonstrates the thermal effect on vibrations of a symmetric, non-homoge- neous trapezoidal plate with parabolically varying thickness in both directions. The variation in Young’s modulus and mass density is the main cause for the occurrence of non-homogeneity in plate’s material. In this consideration, density varies linearly in one direction. The governing differential equations have been derived by Rayleigh-Ritz method in order to attain fundamental frequencies. With C-S-C-S boundary condition, a two term deflection function has been considered. The effect of structural parameters such as taper constants, thermal gradient, aspect ratio and non-homogeneity constant has been investigated for first two modes of vibration. The obtained numerical results have been presented in tabular and graphical form. 展开更多
关键词 VIBRATION Trapezoidal Plate Taper constants thermal Gradient Aspect Ratio Non-Homogeneity Parabolically Thickness Linearly Density
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Study of Temperature Behaviour on Thermally Induced Vibration of Non-Homogeneous Trapezoidal Plate with Bi-Linearly Varying Thickness
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作者 Kavita Satish Kumar Pragati Sharma 《Journal of Applied Mathematics and Physics》 2016年第10期1936-1948,共14页
The main aim of the present work is to study the linear temperature behaviour of a non-homogeneous trapezoidal plate whose thickness varies linearly in both directions. The temperature behaviour considered linear alon... The main aim of the present work is to study the linear temperature behaviour of a non-homogeneous trapezoidal plate whose thickness varies linearly in both directions. The temperature behaviour considered linear along the length of the plate. Non-homogeneity in plate arises due to variation in density along the length of the plate. The two-term deflection function with clamped-simply supported-clamped-simply supported boundary condition is taken into consideration. The effect of structural parameters such as taper constants, thermal gradient, non-homogeneity constant and aspect ratio has been studied. Rayleigh-Ritz method is used to solve the governing differential equations and to obtain the fundamental frequencies for the first two modes of vibration. Results are presented in graphical form. 展开更多
关键词 VIBRATION Trapezoidal Plate Taper constants thermal Gradient Aspect Ratio Non-Homogeneity Thickness Density Frequencies
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Effect of trace calcium on melting behavior of Ag-Cu-Zn brazing alloy by thermal analysis kinetics 被引量:1
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作者 鲍丽 龙伟民 +3 位作者 何鹏 吴铭方 顾小龙 马佳 《China Welding》 EI CAS 2015年第4期15-20,共6页
The purity of the brazing alloys applied is necessary to be improved with the increasing cleanness of steel. Calcium is easily brought into the widely ased brazing alloy, Ag-Cu-Zn, during the producing process. This p... The purity of the brazing alloys applied is necessary to be improved with the increasing cleanness of steel. Calcium is easily brought into the widely ased brazing alloy, Ag-Cu-Zn, during the producing process. This paper aims at revealing the effect of calcium on the melting behavior of the brazing alloy. The thermal analysis kinetics of silver alloy with trace calcium was studied by using differential scanning calorimetry ( DSC ) , and the enthalpy peaks were analyzed by differential methods. The rate constant of phase transformation in the probable brazing temperature range goes up with increasing calcium content, according to the values of the apparent activation energy, E, and the frequeney constant, A. It is concluded that the calcium addition could improve the melting performance of Ag-Cu-Zn brazing alloy. 展开更多
关键词 silver brazing alloy thermal analysis kinetics melting behavior apparent activation energy frequency constant
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基于热-时换算的发电机反时限保护曲线修正方法
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作者 李振兴 徐昆 +3 位作者 安喆 朱益 李振华 翁汉琍 《三峡大学学报(自然科学版)》 北大核心 2025年第5期80-88,共9页
受负序抑制策略的影响,线路重合闸期间存在负序电流动态变化的特殊工况,发电机传统反时限保护面临温度曲线严重偏离实际温度曲线的问题,对此提出一种基于热-时换算的发电机反时限保护曲线修正方法.首先构建转子温度变化曲线并分析曲线... 受负序抑制策略的影响,线路重合闸期间存在负序电流动态变化的特殊工况,发电机传统反时限保护面临温度曲线严重偏离实际温度曲线的问题,对此提出一种基于热-时换算的发电机反时限保护曲线修正方法.首先构建转子温度变化曲线并分析曲线参数对保护的影响,分别针对负序电流与稳态温度不匹配问题及转子复杂传热对时间常数影响问题进行参数修正.然后结合热量传导关系,提出热-时换算模型并计算保护剩余时间.最后采用多种抑制程度及时刻变化场景进行算例仿真并测试误差结果,所提保护方案能保证转子不超过极限温度,与实际误差波动不超过1.9%.相较于传统方案较大程度地贴合转子实际温度曲线,结果验证了方案在特殊工况下的适用性及准确性. 展开更多
关键词 反时限 负序电流 热平衡 时间常数 稳态温度 热-时换算
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低压直流断路器热脱扣器温度场分析
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作者 苏秀苹 王东跃 +1 位作者 贾彦庆 王林林 《现代电子技术》 北大核心 2025年第20期120-126,共7页
低压直流断路器的热脱扣器主要通过热双金属片受热弯曲完成过载保护动作。为分析服役时热双金属片的温度分布,在有限元软件COMSOL中建立实际工况的低压直流断路器电-热-流体耦合模型,得到热脱扣器部分的温升曲线,并通过实验验证仿真结... 低压直流断路器的热脱扣器主要通过热双金属片受热弯曲完成过载保护动作。为分析服役时热双金属片的温度分布,在有限元软件COMSOL中建立实际工况的低压直流断路器电-热-流体耦合模型,得到热脱扣器部分的温升曲线,并通过实验验证仿真结果的正确性。仿真与实验结果表明,间接加热式的热双金属片以及加热元件都呈现出中间温度高、两端温度低的分布特点。通过分析断路器内部的热传导、热对流以及热辐射,对热双金属片和加热元件的传热方式进行研究,得出间接加热式热双金属片主要通过热对流进行加热,在温度较高时热辐射也不能忽略。同时利用Levenberg-Marquardt最小二乘法对热双金属片的非线性温度进行拟合,对其热时间常数进行修正,修正后的热时间常数能够反映断路器的实际工作状况,可为热脱扣器的退化研究与优化设计提供参考。 展开更多
关键词 低压直流断路器 热脱扣器 热双金属片 温度场 多物理场耦合 有限元分析 热时间常数
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固封极柱环氧树脂的电热绝缘老化特性分析
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作者 张晨 刘润田 +2 位作者 符晨涛 黄影 张玉泽 《塑料》 北大核心 2025年第5期106-110,115,共6页
固封极柱由于具有较好的绝缘特性与紧凑型结构,被广泛应用于柜式气体绝缘金属封闭开关(C-GIS)。环氧树脂作为其主要绝缘材料在长时间使用的情况下,受到电、热环境的综合影响。结合环氧树脂在电、热应力作用下,产生的绝缘劣化问题,进行... 固封极柱由于具有较好的绝缘特性与紧凑型结构,被广泛应用于柜式气体绝缘金属封闭开关(C-GIS)。环氧树脂作为其主要绝缘材料在长时间使用的情况下,受到电、热环境的综合影响。结合环氧树脂在电、热应力作用下,产生的绝缘劣化问题,进行环氧树脂电热联合老化试验。结果表明,随着电热联合老化试验时间的增加,局部放电量由2.70 pC增大至37.46 pC;介质损耗角正切值由0.012增大至0.057;介电常数、泄漏电流与绝缘电阻呈现阶段性的变化趋势,分别由4.45、0.104、5.027变化为4.96、0.301、0.012;SEM结果表明,表面老化处理后,环氧树脂材料微观形貌为颗粒物质逐渐增多,分子间形成较大的沟壑与裂缝,揭示了环氧树脂绝缘材料电热联合老化机制。 展开更多
关键词 环氧树脂 电热老化 介电常数 固封极柱 电场仿真
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高导热无溶剂覆铜板的制备与性能研究
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作者 汪伟 《科学技术创新》 2025年第18期1-4,共4页
本文以环氧树脂和不饱和聚酯为基体树脂,微米球形氧化铝为导热粉体,制备层压板,进行性能研究。随着球形氧化铝含量的提高,EP-UPR层压板的导热系数逐渐提高。随着球形氧化铝含量的增加,力学性能呈现先增加后减小的趋势;在球形氧化铝添加... 本文以环氧树脂和不饱和聚酯为基体树脂,微米球形氧化铝为导热粉体,制备层压板,进行性能研究。随着球形氧化铝含量的提高,EP-UPR层压板的导热系数逐渐提高。随着球形氧化铝含量的增加,力学性能呈现先增加后减小的趋势;在球形氧化铝添加量为50 wt.%时,试样整体电学性能最好。 展开更多
关键词 覆铜板 热导率 介电常数
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关于我国锅炉热工性能试验标准中SO_(2)和NO平均比定压热容缺失问题的探讨
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作者 齐国利 张松松 刘超 《中国特种设备安全》 2025年第8期8-11,37,共5页
我国锅炉性能试验标准中普遍没有提供SO_(2)和NO平均比定压热容的计算方法,本文基于《API技术数据手册》和沈维道《工程热力学》(第4版)的SO_(2)瞬时比定压热容计算方法,分别给出了使用积分方法和算术平均值方法SO_(2)平均比定压热容计... 我国锅炉性能试验标准中普遍没有提供SO_(2)和NO平均比定压热容的计算方法,本文基于《API技术数据手册》和沈维道《工程热力学》(第4版)的SO_(2)瞬时比定压热容计算方法,分别给出了使用积分方法和算术平均值方法SO_(2)平均比定压热容计算方法,通过计算发现2种方法的差距很小,如果是工程应用2种方法都可以选取;基于Fundamentals of Thermodynamics(第10版)的NO瞬时比定压热容计算方法,提出了使用积分方法的NO平均比定压热容计算方法,解决了我国锅炉性能试验标准中SO_(2)和NO平均比定压热容缺少计算方法的问题。 展开更多
关键词 比定压热容 热工性能试验 锅炉 理想气体
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银川某地源热泵工程岩土热响应试验研究
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作者 扈志勇 《洁净与空调技术》 2025年第4期27-29,共3页
以银川某地埋管地源热泵工程为例,采用恒定热流法对双U型地埋管进行现场岩土热响应试验,获取地层热物性参数。结果表明,该处地层平均热传导系数为2.27W/m·K,夏季工况下地层每延米换热量为62.4W/m。
关键词 热响应试验 恒定热流法 岩土热物性
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共沉淀法对yYCr_(x)Mn_(1-x)O_(3)-(1-y)Y_(2)O_(3)体系特征值的影响 被引量:1
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作者 王典 谢光远 +1 位作者 吕俊涛 李湾湾 《中国粉体技术》 2025年第2期105-111,共7页
【目的】通过调控Cr、Mn原子的掺杂比(x)和YCr_(x)Mn_(1-x)O_(3)相的物质的量比(y),研究共沉淀法对yYCr_(x)Mn_(1-x)O_(3)-(1-y)Y_(2)O_(3)体系产物特征值的影响。【方法】采用固相法制备8组不同x、y配比的稀土钙钛矿负温度系数(negativ... 【目的】通过调控Cr、Mn原子的掺杂比(x)和YCr_(x)Mn_(1-x)O_(3)相的物质的量比(y),研究共沉淀法对yYCr_(x)Mn_(1-x)O_(3)-(1-y)Y_(2)O_(3)体系产物特征值的影响。【方法】采用固相法制备8组不同x、y配比的稀土钙钛矿负温度系数(negative temperature coefficient,NTC)热敏电阻,通过X射线衍射(X-ray diffraction,XRD)和电性能分析粗选出性能较优异组(x=0.3,y=0.6),在此基础上,对yYCr_(0.3)Mn_(0.7)O_(3)-(1-y)Y_(2)O_(3)体系用化学共沉淀法制备4组不同y值的粒径更小、均匀性更高的粉体,通过煅烧压片得到NTC陶瓷,探讨共沉淀法对产物性能的影响。【结果】在共沉淀法制备的yYCr_(0.3)Mn_(0.7)O_(3)-(1-y)Y_(2)O_(3)体系中,当y≥0.6时,热敏常数B25/85≥2180 K,活化能为Ea≥0.19 eV;通过增加Mn4+的质量分数,降低Y_(2)O_(3)的质量分数,可以增加YCr_(0.3)Mn_(0.7)O_(3)相,提高电阻对温度改变的敏感度,即热敏常数B。【结论】在共沉淀法制备的yYCr_(0.3)Mn_(0.7)O_(3)-(1-y)Y_(2)O_(3)体系中,通过调控x和y,可以降低材料的电阻率。 展开更多
关键词 化学共沉淀法 热敏常数 固相法 热敏陶瓷 钙钛矿
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