The Taohuadao, Qingtian and Laoshan granites are three typical late Yanshannian peralkaline granitic plu- tons in the coastal area, eastern China. In this paper, internal structures and chemical compositions of zircon...The Taohuadao, Qingtian and Laoshan granites are three typical late Yanshannian peralkaline granitic plu- tons in the coastal area, eastern China. In this paper, internal structures and chemical compositions of zircon from these A-type granites were investigated by electron microprobe. It is shown that zircon grains are mainly composed of two dis- tinctly separated parts. One is rich in Th (ThO2 >1 wt%, and ThO2/UO2 >2), and attains ThO2 up to 10.1 wt%; such value exceeds the dissolution limit of Th in the zircon structure (ThO2=5.5±2.5 wt%) determined in previous experiment. On the other hand, the other part is poor in Th (ThO2<1 wt%), but contains many thorite micro-inclusions with sieved tex- ture. By comparison, it is also implied that zircon in alumi- nous A-type granites is characterized by low content of ThO2 (<1 wt%), ThO2/UO2 <2 and absence of thorite inclusion. Based on mineralogical features, one is tempted to assume that the Th-rich zircon is formed during the early crystalli- zation of deep-sourced, high-temperature and Th-enriched A-type granitic magma. Such zircon is then subjected to late dissolution owing to accumulation of fluids at the end of magmatic evolution of A-type granite. Recrystallization fi- nally leads to formation of sieved low-Th zircon with thorite micro-inclusions, which may coexist with remnants of Th-rich zircons. The Th-rich zircon may be considered to be one of characteristic accessory minerals of peralkaline A-type granites.展开更多
The lunar magma ocean hypothesis suggests that the primordial KREEP(an acronym of potassium(K),rare earth element(REE),and phosphorus(P))was the final product of fractional crystallization.However,the primordial KREEP...The lunar magma ocean hypothesis suggests that the primordial KREEP(an acronym of potassium(K),rare earth element(REE),and phosphorus(P))was the final product of fractional crystallization.However,the primordial KREEP(a.k.a.urKREEP)has never been identified in previous lunar samples or meteorites.The Moon is the focus of many countries’and agencies’space exploration plans,and with the advancement of technology,crewed missions have been proposed.We propose two candidate landing sites,located respectively in the northwest(9.5°W,0.9°S)and southeast(11.1°W,6.2°S)of Lalande crater(8.6°W,4.5°S),for future crewed missions,with the primary goal of sampling the speculated urKREEP.Both sites are situated on the Th-(a critical marker of KREEP)and silica-rich Lalande ejecta in the Mare Insularum and Mare Nubium,respectively.Their geolocations at the low latitude on the lunar nearside,the flat surface,and the low rock abundance suggest the sites are safe for landing and meet the needs of real-time Earth-Moon communication.The astronauts could perform many extravehicular activities,such as collecting KREEP-rich samples,screening clast samples,and drilling regolith cores,to gather a variety of samples,such as Lalande ejecta,basalts,Copernicus ejecta,and regolith.The returned samples are valuable to explore the speculated urKREEP,to reveal the relationship between heat-producing elements and volcanism,to refine the lunar cratering chronology function,and to investigate volatiles in the regolith.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.40221301,40272036 and 40025209).
文摘The Taohuadao, Qingtian and Laoshan granites are three typical late Yanshannian peralkaline granitic plu- tons in the coastal area, eastern China. In this paper, internal structures and chemical compositions of zircon from these A-type granites were investigated by electron microprobe. It is shown that zircon grains are mainly composed of two dis- tinctly separated parts. One is rich in Th (ThO2 >1 wt%, and ThO2/UO2 >2), and attains ThO2 up to 10.1 wt%; such value exceeds the dissolution limit of Th in the zircon structure (ThO2=5.5±2.5 wt%) determined in previous experiment. On the other hand, the other part is poor in Th (ThO2<1 wt%), but contains many thorite micro-inclusions with sieved tex- ture. By comparison, it is also implied that zircon in alumi- nous A-type granites is characterized by low content of ThO2 (<1 wt%), ThO2/UO2 <2 and absence of thorite inclusion. Based on mineralogical features, one is tempted to assume that the Th-rich zircon is formed during the early crystalli- zation of deep-sourced, high-temperature and Th-enriched A-type granitic magma. Such zircon is then subjected to late dissolution owing to accumulation of fluids at the end of magmatic evolution of A-type granite. Recrystallization fi- nally leads to formation of sieved low-Th zircon with thorite micro-inclusions, which may coexist with remnants of Th-rich zircons. The Th-rich zircon may be considered to be one of characteristic accessory minerals of peralkaline A-type granites.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFF0503104)the National Natural Science Foundation of China(Grant Nos.42241111,62227901,and 42441826)+1 种基金the Macao Young Scholars Program(Grant No.AM201902)the Key Research Program of the Institute of Geology and Geophysics,Chinese Academy of Sciences(Grant No.IGGCAS-202401).
文摘The lunar magma ocean hypothesis suggests that the primordial KREEP(an acronym of potassium(K),rare earth element(REE),and phosphorus(P))was the final product of fractional crystallization.However,the primordial KREEP(a.k.a.urKREEP)has never been identified in previous lunar samples or meteorites.The Moon is the focus of many countries’and agencies’space exploration plans,and with the advancement of technology,crewed missions have been proposed.We propose two candidate landing sites,located respectively in the northwest(9.5°W,0.9°S)and southeast(11.1°W,6.2°S)of Lalande crater(8.6°W,4.5°S),for future crewed missions,with the primary goal of sampling the speculated urKREEP.Both sites are situated on the Th-(a critical marker of KREEP)and silica-rich Lalande ejecta in the Mare Insularum and Mare Nubium,respectively.Their geolocations at the low latitude on the lunar nearside,the flat surface,and the low rock abundance suggest the sites are safe for landing and meet the needs of real-time Earth-Moon communication.The astronauts could perform many extravehicular activities,such as collecting KREEP-rich samples,screening clast samples,and drilling regolith cores,to gather a variety of samples,such as Lalande ejecta,basalts,Copernicus ejecta,and regolith.The returned samples are valuable to explore the speculated urKREEP,to reveal the relationship between heat-producing elements and volcanism,to refine the lunar cratering chronology function,and to investigate volatiles in the regolith.