A detailed vibrational Raman-lR spectroscopic and diffractional analyses have been performed on basalts from two locations from Tenerife Island： （1） the Arenas Negras volcano which belongs to the historical eruptio...A detailed vibrational Raman-lR spectroscopic and diffractional analyses have been performed on basalts from two locations from Tenerife Island： （1） the Arenas Negras volcano which belongs to the historical eruption not showing visible alteration and （2） Pillow Lavas zone from Anaga Massif which shows a clearly fluid-rock interaction caused by submarine alteration. These places have been extensively studied due to its similarity with the surface of Mars. The analysis is based on the mineral detection of selected samples by a Micro-Raman study of the materials. The complementary techniques have confirmed the mineralogy detected by the Raman measurement. The results show a volcanic environment behavior with primary phases like olivine, pyroxene, and feldsparJplagioclase. Moreover, the presence of accessory minerals or secondary mineralization like phosphate, iron oxides, zeolite or carbonates shows the alteration processes on each outcrop. The variation in the crystallinity and amorphous phases is related to fluid-rock interaction caused by hydrothermal episodes and external weathering processes, which shows several analogies with the ancient volcanic activity from Mars.展开更多
With the development of the hyperspectral remote sensing technique,extensive chemical weathering profiles have been identified on Mars.These weathering sequences,formed through precipitation-driven leaching processes,...With the development of the hyperspectral remote sensing technique,extensive chemical weathering profiles have been identified on Mars.These weathering sequences,formed through precipitation-driven leaching processes,can reflect the paleoenvironments and paleoclimates during pedogenic processes.The specific composition and stratigraphic profiles mirror the mineralogical and chemical trends observed in weathered basalts on Hainan Island in south China.In this study,we investigated the laboratory reflectance spectra of a 53-m-long drilling core of a thick basaltic weathering profile collected from Hainan Island.We established a quantitative spectral model by combining the genetic algorithm and partial least squares regression(GA-PLSR)to predict the chemical properties(SiO2,Al2O3,Fe2O3)and index of laterization(IOL).The entire sample set was divided into a calibration set of 25 samples and a validation set of 12 samples.Specifically,the GA was used to select the spectral subsets for each composition,which were then input into the PLSR model to derive the chemical concentration.The coefficient of determination(R2)values on the validation set for SiO2,Al2O3,Fe2O3,and the IOL were greater than 0.9.In addition,the effects of various spectral preprocessing techniques on the model accuracy were evaluated.We found that the spectral derivative treatment boosted the prediction accuracy of the GA-PLSR model.The improvement achieved with the second derivative was more pronounced than when using the first derivative.The quantitative model developed in this work has the potential to estimate the contents of similar weathering basalt products,and thus infer the degree of alteration and provide insights into paleoclimatic conditions.Moreover,the informative bands selected by the GA can serve as a guideline for designing spectral channels for the next generation of spectrometers.展开更多
Banded iron formations （BIFs） are major rock units having hematite layers intermittent with silica rich layers and formed by sedimentary processes during late Archean to mid Proterozoic time. In terrestrial environm...Banded iron formations （BIFs） are major rock units having hematite layers intermittent with silica rich layers and formed by sedimentary processes during late Archean to mid Proterozoic time. In terrestrial environment, hematite deposits are mainly found associated with banded iron formations. The BIFs in Lake Superior （Canada） and Carajas （Brazil） have been studied by planetary scientists to trace the evolution of hematite deposits on Mars. Hematite deposits are extensively identified in Meridiani region on Mars. Many hypotheses have been proposed to decipher the mechanism for the formation of these deposits. On the basis of geomorphological and mineralogical studies, aqueous environment of deposition is found to be the most supportive mechanism for its secondary iron rich deposits. In the present study, we examined the spectral characteristics of banded iron formations of Joda and Daitari located in Singhbhum craton in eastern India to check its potentiality as an analog to the aqueous/marine environment on Mars. The prominent banding feature of banded iron formations is in the range of few millimeters to few centimeters in thickness. Fe rich bands are darker （gray） in color compared to the light reddish jaspilitic chert bands. Thin quartz veins （〈4 mm） are occasionally observed in the handspecimens of banded iron formations. Spectral investigations have been conducted in VIS/NIR region of electromagnetic spectrum in the laboratory conditions. Optimum absorption bands identified include 0.65, 0.86, 1.4 and 1.9 μm, in which 0.56 and 0.86 μm absorption bands are due to ferric iron and 1.4 and 1,9 μm bands are due to OH/H2O. To validate the mineralogical results obtained from VlS/NIR spectral radiometry, laser Raman and Fourier transform infrared spectroscopic techniques were utilized and the results were found to be similar. Goethite-hematite association in banded iron formation in Singhbhum craton suggests dehydration activity, which has altered the primary iron oxide phases into the secondary iron oxide phases. The optimum bands identified for the minerals using various spectroscopic techniques can be used as reference for similar mineral deposits on any remote area on Earth or on other hydrated planetary surfaces like Mars.展开更多
基金supported by the MICINN with the Project AYA-2008-04529 for the development of the Raman-LIBS combined spectrometer for the ESA-Exo Mars Mission.E.Lalla wish to thank MICINN for the FPI grants(BES-2009-024992)
文摘A detailed vibrational Raman-lR spectroscopic and diffractional analyses have been performed on basalts from two locations from Tenerife Island： （1） the Arenas Negras volcano which belongs to the historical eruption not showing visible alteration and （2） Pillow Lavas zone from Anaga Massif which shows a clearly fluid-rock interaction caused by submarine alteration. These places have been extensively studied due to its similarity with the surface of Mars. The analysis is based on the mineral detection of selected samples by a Micro-Raman study of the materials. The complementary techniques have confirmed the mineralogy detected by the Raman measurement. The results show a volcanic environment behavior with primary phases like olivine, pyroxene, and feldsparJplagioclase. Moreover, the presence of accessory minerals or secondary mineralization like phosphate, iron oxides, zeolite or carbonates shows the alteration processes on each outcrop. The variation in the crystallinity and amorphous phases is related to fluid-rock interaction caused by hydrothermal episodes and external weathering processes, which shows several analogies with the ancient volcanic activity from Mars.
基金National Key Research and Development Project(Grant No.2019YFE0123300)National Natural Science Foundation of China(Grant Nos.42072337,42241111,and 42241129)+1 种基金Pandeng Program of National Space Science Center,Chinese Academy of Sciences.Xing Wu also acknowledges support from the Young Elite Scientists Sponsorship Program by the China Association for Science and Technology(Grant No.2022QNRC001)China Postdoctoral Science Foundation(Grant No.2021M700149).
文摘With the development of the hyperspectral remote sensing technique,extensive chemical weathering profiles have been identified on Mars.These weathering sequences,formed through precipitation-driven leaching processes,can reflect the paleoenvironments and paleoclimates during pedogenic processes.The specific composition and stratigraphic profiles mirror the mineralogical and chemical trends observed in weathered basalts on Hainan Island in south China.In this study,we investigated the laboratory reflectance spectra of a 53-m-long drilling core of a thick basaltic weathering profile collected from Hainan Island.We established a quantitative spectral model by combining the genetic algorithm and partial least squares regression(GA-PLSR)to predict the chemical properties(SiO2,Al2O3,Fe2O3)and index of laterization(IOL).The entire sample set was divided into a calibration set of 25 samples and a validation set of 12 samples.Specifically,the GA was used to select the spectral subsets for each composition,which were then input into the PLSR model to derive the chemical concentration.The coefficient of determination(R2)values on the validation set for SiO2,Al2O3,Fe2O3,and the IOL were greater than 0.9.In addition,the effects of various spectral preprocessing techniques on the model accuracy were evaluated.We found that the spectral derivative treatment boosted the prediction accuracy of the GA-PLSR model.The improvement achieved with the second derivative was more pronounced than when using the first derivative.The quantitative model developed in this work has the potential to estimate the contents of similar weathering basalt products,and thus infer the degree of alteration and provide insights into paleoclimatic conditions.Moreover,the informative bands selected by the GA can serve as a guideline for designing spectral channels for the next generation of spectrometers.
基金financially supported by Indian Institute of Space Science and Technology(IIST),Thiruvananthapuram
文摘Banded iron formations （BIFs） are major rock units having hematite layers intermittent with silica rich layers and formed by sedimentary processes during late Archean to mid Proterozoic time. In terrestrial environment, hematite deposits are mainly found associated with banded iron formations. The BIFs in Lake Superior （Canada） and Carajas （Brazil） have been studied by planetary scientists to trace the evolution of hematite deposits on Mars. Hematite deposits are extensively identified in Meridiani region on Mars. Many hypotheses have been proposed to decipher the mechanism for the formation of these deposits. On the basis of geomorphological and mineralogical studies, aqueous environment of deposition is found to be the most supportive mechanism for its secondary iron rich deposits. In the present study, we examined the spectral characteristics of banded iron formations of Joda and Daitari located in Singhbhum craton in eastern India to check its potentiality as an analog to the aqueous/marine environment on Mars. The prominent banding feature of banded iron formations is in the range of few millimeters to few centimeters in thickness. Fe rich bands are darker （gray） in color compared to the light reddish jaspilitic chert bands. Thin quartz veins （〈4 mm） are occasionally observed in the handspecimens of banded iron formations. Spectral investigations have been conducted in VIS/NIR region of electromagnetic spectrum in the laboratory conditions. Optimum absorption bands identified include 0.65, 0.86, 1.4 and 1.9 μm, in which 0.56 and 0.86 μm absorption bands are due to ferric iron and 1.4 and 1,9 μm bands are due to OH/H2O. To validate the mineralogical results obtained from VlS/NIR spectral radiometry, laser Raman and Fourier transform infrared spectroscopic techniques were utilized and the results were found to be similar. Goethite-hematite association in banded iron formation in Singhbhum craton suggests dehydration activity, which has altered the primary iron oxide phases into the secondary iron oxide phases. The optimum bands identified for the minerals using various spectroscopic techniques can be used as reference for similar mineral deposits on any remote area on Earth or on other hydrated planetary surfaces like Mars.
