[Objective] The aim was to study on temporal-spatial distribution model of cold chain logistics for vegetables. [Method] Broccoli was taken as an example. Detailedly, time-space distribution model of cold chain logist...[Objective] The aim was to study on temporal-spatial distribution model of cold chain logistics for vegetables. [Method] Broccoli was taken as an example. Detailedly, time-space distribution model of cold chain logistics for broccoli was proposed from standpoints of costs and benefits based on changes of time and space, and a comprehensive evaluation was made on timeliness, efficiency, risks, added- value of products and satisfaction of information in cold-chain logistics. [Result] The efficiency of cold chain logistics for vegetable can be greatly improved by temporal- spatial distribution model of cold chain logistics. [Conclusion] Costs and benefits of vegetables in temporal-apstial distribution could be evaluated by the model.展开更多
Sand-dust storm is a special natural disaster that frequently occurs in deserts and their surrounding areas. With the data published onSurface Meteorological Monthly Bulletin andSurface Chart during 1971–1996, the te...Sand-dust storm is a special natural disaster that frequently occurs in deserts and their surrounding areas. With the data published onSurface Meteorological Monthly Bulletin andSurface Chart during 1971–1996, the temporal-spatial distribution and annual variation of sand-dust storms are analyzed on the basis of the case study of atmospheric processes. Furthermore, the tracks and source areas of sand-dust storms are determined with the aid of GIS. The results show that except some parts of Qinghai Province and Inner Mongolia as well as Beijing, sand-dust storms decrease apparently in time and space in recent decades in China. Sand-dust storms occur most frequently in spring, especially in April. According to their source areas, sand-dust storms are classified into two types, i.e., the inner-source and outer-source sand-dust storms. Most of the outer-source sand-dust storms move along the north and west tracks. The north-track outer-source sand-dust storms always intrude into China across the Sino-Mongolian border from Hami, a city in the eastern part ofXinjiang, to Xilin Gol, a league in Inner Mongolia, while the west-track ones intrude into China from both southern and northern Xinjiang. The source lands of inner-source sand-dust storms concentrate in the Taklimakan Desert and its surrounding areas in southern Xinjiang, southern part of the Junggar Basin in north of Xinjiang, the Hexi Corridor in western Gansu Province, the dry deserts of Inner Mongolia and the Qaidam Basin in Qinghai.展开更多
Heavy metal contamination in soils has been of wide concern in China in the last several decades. The heavy metal contamination was caused by sewage irrigation, mining and inappropriate utilization of various agrochem...Heavy metal contamination in soils has been of wide concern in China in the last several decades. The heavy metal contamination was caused by sewage irrigation, mining and inappropriate utilization of various agrochemicals and pesticides and so on. The Shenyang Zhangshi irrigation area （SZIA） in China is a representative area of heavy metal contamination of soils resulting from sewage irrigation for about 30 years duration. This study investigated the spatial distribution and temporal variation of soil cadmium contamination in the SZIA. The soil samples were collected from the SZIA in 1990 and 2004; Cd of soils was analyzed and then the spatial distribution and temporal variation of Cd in soils was modelled using kriging methods. The kriging map showed that long-term sewage irrigation had caused serious Cd contamination in topsoil and subsoil. In 2004, the Cd mean concentrations were 1.698 and 0.741 mg/kg, and the maxima 10.150 and 7.567 mg/kg in topsoils （0-20 cm） and subsoils （20-40 cm） respectively. These values are markedly more than the Cd levels in the second grade soil standard in China. In 1990, the Cd means were 1.023 and 0.331 mg/kg, and the maxima 9.400 and 3.156 mg/kg, in topsoils and subsoils respectively. The soil area in 1990 with Cd more than 1.5 mg/kg was 2701 and 206.4 hnl2 in topsoils and subsoils respectively; and in 2004, it was 7592 and 1583 hm^2, respectively. Compared with that in 1990, the mean and maximum concentration of Cd, as well as the soil area with Cd more than 1.5 mg/kg had all increased in 2004, both in topsoils and subsoils.展开更多
The Huaihe River basin of Anhui is not only a transitional zone of physical geography, but also a convergent area of many cultures in China. It is one of the sensitive ecotones to global changes and the birthplace of ...The Huaihe River basin of Anhui is not only a transitional zone of physical geography, but also a convergent area of many cultures in China. It is one of the sensitive ecotones to global changes and the birthplace of Chinese civilization. Using the field archaeological data and the sporo-pollens and the age data of the drilling cores, we analysed Neolithic cultural development and environmental evolution in the Huaihe River basin of Anhui. According to the combination of some research results in archaeology with environmental evolution research, this paper discusses the relationship between culture and environment in the Huaihe River basin of Anhui. The Neolithic cultural development was strongly impacted by the environmental change. The primitive culture （Shishanzi） was developed in the beginning of the Holocene Megathermal Period with distinct regional feature of the culture. From 6.5 kaBP to 5.5 kaBP, the climate changed warmer and wetter. The frequent occurrence of flood and waterlog due to such a climate regime and high sea level caused the earth＇s surface environment deteriorated in the Huaihe River basin of Anhui and the interruption of the Neolithic cultural development, hence a lack of archaeological sites. From 5.5 kaBP to 4.0 kaBP, the climate changed from wet to dry, the natural environment was propitious to human survival. Dawenkou Culture and Longshan Culture flourished in this period. The Neolithic cultural development, the number of the sites and their distribution characteristics of the sites in the study area differed apparently from those in Central China and Shandong Province.展开更多
Road silt loading(sL)is an important parameter in the fugitive road dust(FRD)emissions.In this study,the improved Testing Re-entrained Aerosol Kinetic Emissions from Roads(TRAKER)combined with the AP-42 method was fir...Road silt loading(sL)is an important parameter in the fugitive road dust(FRD)emissions.In this study,the improved Testing Re-entrained Aerosol Kinetic Emissions from Roads(TRAKER)combined with the AP-42 method was firstly developed to quickly measure and estimate the sLs of paved roads in Beijing,China.The annual average sLs in Beijing was 0.59±0.31 g/m^(2)in 2020,and decreased by 22.4%compared with that in 2019.The seasonal variations of sLs followed the order of spring>winter>summer>autumn in the two years.The seasonal mean road sLs on the same type road in the four seasons presented a decline trend from^(2)019 to 2020,especially on the Expressway,decreasing 47.4%-72.7%.The road sLs on the different type roads in the same season followed the order of Major arterial∼Minor arterial∼Branch road>Express road,and Township road∼Country highway>Provincial highway∼National highway.The emission intensities of PM10 and PM_(2.5)from FRD in Beijing in 2020 were lower than those in 2019.The PM10 and PM_(2.5)emission intensities at the four planning areas in the two years all presented the order of the capital functional core area>the urban functional expansion area>the urban development new area>the ecological conservation and development area.The annual emissions of PM10 and PM_(2.5)from FRD in Beijing in 2020 were 74,886 ton and 18,118 ton,respectively,decreasing by∼33.3%compared with those in 2019.展开更多
[ Objective] The study aimed to discuss the temporal-spatial distribution and short-range prediction indicators of hail weather in east central Haixi Prefecture of Qinghai Province. [Method] Using hail data of six sta...[ Objective] The study aimed to discuss the temporal-spatial distribution and short-range prediction indicators of hail weather in east central Haixi Prefecture of Qinghai Province. [Method] Using hail data of six stations in east central Haixi Prefecture from 1960 to 2010, the temporal and spatial distribution of hail weather was analyzed firstly. Afterwards, based on the high-altitude factual data of 30 case studies of hail during 2006 -2010, its high-altitude and ground weather situation and physical quantity field were studied to summarize short-term circulation pattern and shod- range prediction characteristics of hail weather. [ Result] In east central Haixi, hail appeared from April to September, and it was most frequently from May to August. Meanwhile, hail was frequent from 14：00 to 20：00. Among the six stations, hail was most frequent in Tianjun but least frequent in Wulan. Moreover, hail disaster mainly occurred in Wulan and Tianjun. In addition, there were three typos of circulation pattern of hail weather at 500 hPa. Hail mainly occurred under the effect of northwest airflow, and it had shortwave trough, cold center or trough, jet stream core or one of the three. Hail appeared frequently under the situation of upper-level divergence and low-level convergence, and abundant water vapor and water vapor flux convergence at low levels were important conditions for hailing. [ Conclusion] The research could provide scientific references for improving the accuracy of hail forecast.展开更多
Based on the official criminal data released by the Tokyo Metropolitan Police Department in 2019,this paper discusses the temporal-spatial distribution of various types of crimes in the special wards of Tokyo.The resu...Based on the official criminal data released by the Tokyo Metropolitan Police Department in 2019,this paper discusses the temporal-spatial distribution of various types of crimes in the special wards of Tokyo.The results show that:(1)The times of high and low incidence of different types of crime differ significantly.Although vicious crime and violent crime present no obvious monthly distribution,property crime clearly differs between the first and second half of a calendar year.(2)The month before the new year sees a surge in most types of crime.(3)Vicious crime peaks in the hours between night and early morning.Violent crime and property crime correlate positively with the frequency of human interaction and peak in the morning and evening commuting hours.(4)The spatial distribution of crime resembles the concentric circles of the three rings of the special wards of Tokyo,with a central high-incidence area,a center-peripheral low-incidence area,and a marginal high-incidence area.In addition,the center sees more personal crime than the periphery,whereas property crimes show the opposite trend.(5)A spatial autocorrelation analysis shows that the special wards of Tokyo may be grouped into the“high-high”and“low-low”agglomeration modes of different types of crime,with marked differences between the various types of crime.The crime can be divided into three types:central agglomeration,double central agglomeration,and decentralized agglomeration.展开更多
The temporal-spatial distribution and seasonal variation of the precipitation acidity in Guangxi Province were statistically analyzed by means of the data from 2003 to 2008 in 10 Stations of Acid Rain Observation in t...The temporal-spatial distribution and seasonal variation of the precipitation acidity in Guangxi Province were statistically analyzed by means of the data from 2003 to 2008 in 10 Stations of Acid Rain Observation in the province and the data from 1996 to 2008 in two Monitoring Spots in Nanning and Baise,respectively.The results showed that annual average pH value of precipitation was <5.6 based on the analysis of the data from 10 Stations of Acid Rain Observation in the province,among which,the data from 5 stations indicated that annual average pH value of precipitation was <4.5.Thus,it can be thought that the serious acid rain had appeared in the province.There was an obvious seasonal variation in the extent of the acidity in precipitation and the acidity of precipitation in spring and winter was heavier than that in summer and autumn.展开更多
[Objective] The rasearch aimed to grasp the spatial and temporal distribution charactedstics of extreme precipitation in Jiangsu Prov- ince. [Methodl Threshold was determined by detrended fluctuation analysis （DFA） ...[Objective] The rasearch aimed to grasp the spatial and temporal distribution charactedstics of extreme precipitation in Jiangsu Prov- ince. [Methodl Threshold was determined by detrended fluctuation analysis （DFA） based on the data of daily precipitation over Jiangsu Province from 1961 to 2010, and the oscillation pedod and mutation were detected by the method of Morlet wavelet analysis and Mann-Kendall test respec- tively. [ Result~ The annual frequency of extreme precipitation in Jiangsu Province demonstrated oscillation characteristics with 8 -10 a, and the mutation mainly happened in 2006, In addition, the oscillation period of extreme precipitation during summer was 8 -10 a, and its mutation hap- pened in 1998. The oscillation periods of extreme precipitation, however, during autumn were 2 -3 and 5 -7 a. Extreme precipitation and total rain- fall had better consistency. They both presented the characteristics of more in the south and less in the north, and big-small-value zone was concentrated. [ Conclusion] The research could provide technical support for making defense policy of the related disaster for relevant departments.展开更多
To discuss response ability of five functional areas to rainstorm flood in Chongqing,by taking 8 districts（ counties） as research object,monthly occurrence times of heavy rain and rainstorm in different functional a...To discuss response ability of five functional areas to rainstorm flood in Chongqing,by taking 8 districts（ counties） as research object,monthly occurrence times of heavy rain and rainstorm in different functional areas over the years and appearance month of the maximum rainfall were conducted statistics. Results showed that frequency distribution of heavy rain in whole year in different functional areas was different,but it was similar in the same functional zone. Temporal-spatial distribution of rainstorm was more independent,and there were different performances in various districts of each functional area. In urban functional core area and urban functional expansion area,rainstorm times was more,and the maximum precipitation was larger. In urban development new district,rainstorm times and the maximum precipitation were relatively smaller in whole Chongqing. In ecological conservation development area of northeast Chongqing,rainstorm duration was longer,and we needed prevention and control during June- September. In ecological protection area of southeast Chongqing,although rainstorm occurrence times was the most in Chongqing,the heavy rainstorm was less.展开更多
[ Objective] The research aimed to analyze temporal-spatial distribution and change trend of the temperature in Beibei District. [ Method] Based on temperature observation data at 6 ground meteorological observatories...[ Objective] The research aimed to analyze temporal-spatial distribution and change trend of the temperature in Beibei District. [ Method] Based on temperature observation data at 6 ground meteorological observatories of Beibei District from 1951 to 2010, EOF and linear trend method were used to analyze temporal-spatial distribution and change characteristics of the temperature in Beibei District in recent 60 years. [ Result] Tem- perature in Beibei District in recent 60 years overall presented rise trend, and average rise velocity was 0.045 ~C/10 a. Temperature rise in autumn was the most obvious, while summer temperature presented decline trend. Average temperature presented gradual rise trend from January to July and gradual decrease trend from August to December. Seen from spatial distribution, temperature in the whole district was higher in the west and lower in the middle. Abnormal spatial distribution of the average temperature in the whole district mainly had consistent higher （lower） type, south- north reverse type and east-west reverse type. [ Condusionl The research provided theoretical basis for effective disaster prevention and reduction in the zone.展开更多
This study was conducted following research on metallogenesis in the Zhangjiajie-Xuanhua and East Hebei mantle branch structure zones. The Fuping mantle branch structure zone is one where Au, Cu and Ag poly-metallic o...This study was conducted following research on metallogenesis in the Zhangjiajie-Xuanhua and East Hebei mantle branch structure zones. The Fuping mantle branch structure zone is one where Au, Cu and Ag poly-metallic ore resources are concentrated in North Hebei. However, there has existed a long-standing controversy on the temporal-spatial distribution of ore resources and their ore-forming material sources. In terms of age dating and the comprehensive analysis of S, Pb, O, C and Si isotopes, it is considered that the temporal-spatial distribution of ore resources in this mantle branch structure zone is obviously controlled by the Fuping mantle branch structure. In space there is developed such a metallogenic pattern as to be Ag, Pb and Zn polymetallic ore deposits with gold appearing inside and copper appearing outside. Metallogenesis is dated mainly at Yanshanian, the ore-forming materials were derived predominantly from the deep interior of the Earth, and ore-forming fluids were derived largely from Yanshanian magmatism.展开更多
Themassive integration of high-proportioned distributed photovoltaics into distribution networks poses significant challenges to the flexible regulation capabilities of distribution stations.To accurately assess the f...Themassive integration of high-proportioned distributed photovoltaics into distribution networks poses significant challenges to the flexible regulation capabilities of distribution stations.To accurately assess the flexible regulation capabilities of distribution stations,amulti-temporal and spatial scale regulation capability assessment technique is proposed for distribution station areas with distributed photovoltaics,considering different geographical locations,coverage areas,and response capabilities.Firstly,the multi-temporal scale regulation characteristics and response capabilities of different regulation resources in distribution station areas are analyzed,and a resource regulation capability model is established to quantify the adjustable range of different regulation resources.On this basis,considering the limitations of line transmission capacity,a regulation capability assessment index for distribution stations is proposed to evaluate their regulation capabilities.Secondly,considering different geographical locations and coverage areas,a comprehensive performance index based on electrical distance modularity and active power balance is established,and a cluster division method based on genetic algorithms is proposed to fully leverage the coordination and complementarity among nodes and improve the active power matching degree within clusters.Simultaneously,an economic optimization model with the objective of minimizing the economic cost of the distribution station is established,comprehensively considering the safety constraints of the distribution network and the regulation constraints of resources.This model can provide scientific guidance for the economic dispatch of the distribution station area.Finally,case studies demonstrate that the proposed assessment and optimization methods effectively evaluate the regulation capabilities of distribution stations,facilitate the consumption of distributed photovoltaics,and enhance the economic efficiency of the distribution station area.展开更多
The vast majority of in vitro studies have demonstrated that PINK1 phosphorylates Parkin to work together in mitophagy to protect against neuronal degeneration.However,it remains largely unclear how PINK1 and Parkin a...The vast majority of in vitro studies have demonstrated that PINK1 phosphorylates Parkin to work together in mitophagy to protect against neuronal degeneration.However,it remains largely unclear how PINK1 and Parkin are expressed in mammalian brains.This has been difficult to address because of the intrinsically low levels of PINK1 and undetectable levels of phosphorylated Parkin in small animals.Understanding this issue is critical for elucidating the in vivo roles of PINK1 and Parkin.Recently,we showed that the PINK1 kinase is selectively expressed as a truncated form(PINK1–55)in the primate brain.In the present study,we used multiple antibodies,including our recently developed monoclonal anti-PINK1,to validate the selective expression of PINK1 in the primate brain.We found that PINK1 was stably expressed in the monkey brain at postnatal and adulthood stages,which is consistent with the findings that depleting PINK1 can cause neuronal loss in developing and adult monkey brains.PINK1 was enriched in the membrane-bound fractionations,whereas Parkin was soluble with a distinguishable distribution.Immunofluorescent double staining experiments showed that PINK1 and Parkin did not colocalize under physiological conditions in cultured monkey astrocytes,though they did colocalize on mitochondria when the cells were exposed to mitochondrial stress.These findings suggest that PINK1 and Parkin may have distinct roles beyond their well-known function in mitophagy during mitochondrial damage.展开更多
The electrochemical corrosion of ductile pipes(DPs)in drinking water distribution systems(DWDS)has a crucial impact on cement-mortar lining(CML)failure and metal release,potentially leading to drinking water quality d...The electrochemical corrosion of ductile pipes(DPs)in drinking water distribution systems(DWDS)has a crucial impact on cement-mortar lining(CML)failure and metal release,potentially leading to drinking water quality deterioration and posing a risk to public health.An in-situ scanning vibrating electrode technique(SVET)with micron-scale resolution,microscopic scale detection and water quality analysis were used to investigate the corrosion behavior and metal release from DPs throughout the whole CML failure process.Metal pollutants release occurred at three different stages of CML failure process,and there are potential risks of water quality deterioration exceeding the maximum allowable levels set by national standards in the partial failure stage and lining peeling stage.Furthermore,the effects of water chemistry(Cl^(−),SO_(4)^(2−),NO_(3)−,and Ca^(2+))on corrosion scale growth and iron release activity,were investigated during the CML partial failure stage.Results showed that the CML failure process in DPs was accelerated by the autocatalysis of localized corrosion.Cl^(−)was found to damage the uncorroded metal surface,while SO_(4)^(2−)mainly dissolved the corrosion scale surface,increasing iron release.Both the oxidation of NO_(3)−and selective sedimentation of Ca2+were found to enhance the stability of corrosion scales and inhibit iron release.展开更多
The dominated contradiction in optimizing the performance of magnesium-air battery anode lies in the difficulty of achieving a good balance between activation and passivation during discharge process.To further reconci...The dominated contradiction in optimizing the performance of magnesium-air battery anode lies in the difficulty of achieving a good balance between activation and passivation during discharge process.To further reconcile this contradiction,two Mg-0.1Sc-0.1Y-0.1Ag anodes with different residual strain distribution through extrusion with/without annealing are fabricated.The results indicate that annealing can significantly lessen the“pseudo-anode”regions,thereby changing the dissolution mode of the matrix and achieving an effective dissolution during discharge.Additionally,p-type semiconductor characteristic of discharge productfilm could suppress the self-corrosion reaction without reducing the polarization of anode.The magnesium-air battery utilizing annealed Mg-0.1Sc-0.1Y-0.1Ag as anode achieves a synergistic improvement in specific capacity(1388.89 mA h g^(-1))and energy density(1960.42 mW h g^(-1)).This anode modification method accelerates the advancement of high efficiency and long lifespan magnesium-air batteries,offering renewable and cost-effective energy solutions for electronics and emergency equipment.展开更多
Severe ground-level ozone(O_(3))pollution over major Chinese cities has become one of the most challenging problems,which have deleterious effects on human health and the sustainability of society.This study explored ...Severe ground-level ozone(O_(3))pollution over major Chinese cities has become one of the most challenging problems,which have deleterious effects on human health and the sustainability of society.This study explored the spatiotemporal distribution characteristics of ground-level O_(3) and its precursors based on conventional pollutant and meteorological monitoring data in Zhejiang Province from 2016 to 2021.Then,a high-performance convolutional neural network(CNN)model was established by expanding the moment and the concentration variations to general factors.Finally,the response mechanism of O_(3) to the variation with crucial influencing factors is explored by controlling variables and interpolating target variables.The results indicated that the annual average MDA8-90th concentrations in Zhejiang Province are higher in the northern and lower in the southern.When the wind direction(WD)ranges from east to southwest and the wind speed(WS)ranges between 2 and 3 m/sec,higher O_(3) concentration prone to occur.At different temperatures(T),the O_(3) concentration showed a trend of first increasing and subsequently decreasing with increasing NO_(2) concentration,peaks at the NO_(2) concentration around 0.02mg/m^(3).The sensitivity of NO_(2) to O_(3) formation is not easily affected by temperature,barometric pressure and dew point temperature.Additionally,there is a minimum IRNO_(2) at each temperature when the NO_(2) concentration is 0.03 mg/m^(3),and this minimum IRNO_(2) decreases with increasing temperature.The study explores the response mechanism of O_(3) with the change of driving variables,which can provide a scientific foundation and methodological support for the targeted management of O_(3) pollution.展开更多
As a significant city in the Yangtze River Delta regions,Hefei has experienced rapid changes in the sources of air pollution due to its high-speed economic development and urban expansion.However,there has been limite...As a significant city in the Yangtze River Delta regions,Hefei has experienced rapid changes in the sources of air pollution due to its high-speed economic development and urban expansion.However,there has been limited research in recent years on the spatial-temporal distribution and emission of its atmospheric pollutants.To address this,this study conducted mobile observations of urban roads using the Mobile-DOAS instrument from June 2021 to May 2022.The monitoring results exhibit a favourable consistent with TROPOMI satellite data and ground monitoring station data.Temporally,there were pronounced seasonal variations in air pollutants.Spatially,high concentration of HCHO and NO_(2)were closely associated with traffic congestion on roadways,while heightened SO_(2)levels were attributed to winter heating and industrial emissions.The study also revealed that with the implementation of road policies,the average vehicle speed increased by 95.4%,while the NO concentration decreased by 54.4%.In the estimation of urban NO_(x)emission flux,it was observed that in temporal terms,compared with inventory data,the emissions calculated viamobile measurements exhibitedmore distinct seasonal patterns,with the highest emission rate of 349 g/sec in winter and the lowest of 142 g/sec in summer.In spatial terms,the significant difference in emissions between the inner and outer ring roads also suggests the presence of the city’s primary NO_(x)emission sources in the area between these two rings.This study offers data support for formulating the next phase of air pollution control measures in urban areas.展开更多
Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization proces...Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization processes lead to different order of crystallization dynamics within the perovskite thin film,resulting in the differences of additive distribution.We then tailor-designed an additive molecule named 1,3-bis(4-methoxyphenyl)thiourea to obtain films with fewer defects and holes at the buried interface,and prepared perovskite solar cells with a certified efficiency of 23.75%.Furthermore,this work also demonstrates an efficiency of 20.18%for the large-area perovskite solar module(PSM)with an aperture area of 60.84 cm^(2).The PSM possesses remarkable continuous operation stability for maximum power point tracking of T_(90)>1000 h in ambient air.展开更多
Coking industry is a potential source of heavy metals(HMs)pollution.However,its impacts to the groundwater of surrounding residential areas have not been well understood.This study investigated the pollution character...Coking industry is a potential source of heavy metals(HMs)pollution.However,its impacts to the groundwater of surrounding residential areas have not been well understood.This study investigated the pollution characteristics and health risks of HMs in groundwater nearby a typical coking plant.Nine HMs including Fe,Zn,Mo,As,Cu,Ni,Cr,Pb and Cd were analyzed.The average concentration of total HMswas higher in the nearby area(244.27μg/L)than that of remote area away the coking plant(89.15μg/L).The spatial distribution of pollution indices including heavy metal pollution index(HPI),Nemerow index(NI)and contamination degree(CD),all demonstrated higher values at the nearby residential areas,suggesting coking activity could significantly impact the HMs distribution characteristics.Four sources of HMs were identified by Positive Matrix Factorization(PMF)model,which indicated coal washing and coking emission were the dominant sources,accounted for 40.4%,and 31.0%,respectively.Oral ingestionwas found to be the dominant exposure pathway with higher exposure dose to children than adults.Hazard quotient(HQ)values were below 1.0,suggesting negligible non-carcinogenic health risks,while potential carcinogenic risks were from Pb and Ni with cancer risk(CR)values>10−6.Monte Carlo simulation matched well with the calculated results with HMs concentrations to be the most sensitive parameters.This study provides insights into understanding how the industrial coking activities can impact the HMs pollution characteristics in groundwater,thus facilitating the implement of HMs regulation in coking industries.展开更多
基金Supported by Tianjin Science and Technology Development Project (060YFGNC1900)National Key Technology R&D Program in the 11th Five-year Plan of China(2012BAD38B01)~~
文摘[Objective] The aim was to study on temporal-spatial distribution model of cold chain logistics for vegetables. [Method] Broccoli was taken as an example. Detailedly, time-space distribution model of cold chain logistics for broccoli was proposed from standpoints of costs and benefits based on changes of time and space, and a comprehensive evaluation was made on timeliness, efficiency, risks, added- value of products and satisfaction of information in cold-chain logistics. [Result] The efficiency of cold chain logistics for vegetable can be greatly improved by temporal- spatial distribution model of cold chain logistics. [Conclusion] Costs and benefits of vegetables in temporal-apstial distribution could be evaluated by the model.
基金National Key Developing Program for Basic Sciences, No. G1999043505
文摘Sand-dust storm is a special natural disaster that frequently occurs in deserts and their surrounding areas. With the data published onSurface Meteorological Monthly Bulletin andSurface Chart during 1971–1996, the temporal-spatial distribution and annual variation of sand-dust storms are analyzed on the basis of the case study of atmospheric processes. Furthermore, the tracks and source areas of sand-dust storms are determined with the aid of GIS. The results show that except some parts of Qinghai Province and Inner Mongolia as well as Beijing, sand-dust storms decrease apparently in time and space in recent decades in China. Sand-dust storms occur most frequently in spring, especially in April. According to their source areas, sand-dust storms are classified into two types, i.e., the inner-source and outer-source sand-dust storms. Most of the outer-source sand-dust storms move along the north and west tracks. The north-track outer-source sand-dust storms always intrude into China across the Sino-Mongolian border from Hami, a city in the eastern part ofXinjiang, to Xilin Gol, a league in Inner Mongolia, while the west-track ones intrude into China from both southern and northern Xinjiang. The source lands of inner-source sand-dust storms concentrate in the Taklimakan Desert and its surrounding areas in southern Xinjiang, southern part of the Junggar Basin in north of Xinjiang, the Hexi Corridor in western Gansu Province, the dry deserts of Inner Mongolia and the Qaidam Basin in Qinghai.
基金The National Natural Science Foundation of China (No. 20477029)the National Basic Research Program (973) of China (No.2004CB418506)the Basic Research Program of Educational Department of Liaoning Government (No. 05L262)
文摘Heavy metal contamination in soils has been of wide concern in China in the last several decades. The heavy metal contamination was caused by sewage irrigation, mining and inappropriate utilization of various agrochemicals and pesticides and so on. The Shenyang Zhangshi irrigation area （SZIA） in China is a representative area of heavy metal contamination of soils resulting from sewage irrigation for about 30 years duration. This study investigated the spatial distribution and temporal variation of soil cadmium contamination in the SZIA. The soil samples were collected from the SZIA in 1990 and 2004; Cd of soils was analyzed and then the spatial distribution and temporal variation of Cd in soils was modelled using kriging methods. The kriging map showed that long-term sewage irrigation had caused serious Cd contamination in topsoil and subsoil. In 2004, the Cd mean concentrations were 1.698 and 0.741 mg/kg, and the maxima 10.150 and 7.567 mg/kg in topsoils （0-20 cm） and subsoils （20-40 cm） respectively. These values are markedly more than the Cd levels in the second grade soil standard in China. In 1990, the Cd means were 1.023 and 0.331 mg/kg, and the maxima 9.400 and 3.156 mg/kg, in topsoils and subsoils respectively. The soil area in 1990 with Cd more than 1.5 mg/kg was 2701 and 206.4 hnl2 in topsoils and subsoils respectively; and in 2004, it was 7592 and 1583 hm^2, respectively. Compared with that in 1990, the mean and maximum concentration of Cd, as well as the soil area with Cd more than 1.5 mg/kg had all increased in 2004, both in topsoils and subsoils.
基金National Natural Science Foundation of China, No.40271103 Natural Science Foundation of Anhui Provincial Education Department, No.2005KJ202/021
文摘The Huaihe River basin of Anhui is not only a transitional zone of physical geography, but also a convergent area of many cultures in China. It is one of the sensitive ecotones to global changes and the birthplace of Chinese civilization. Using the field archaeological data and the sporo-pollens and the age data of the drilling cores, we analysed Neolithic cultural development and environmental evolution in the Huaihe River basin of Anhui. According to the combination of some research results in archaeology with environmental evolution research, this paper discusses the relationship between culture and environment in the Huaihe River basin of Anhui. The Neolithic cultural development was strongly impacted by the environmental change. The primitive culture （Shishanzi） was developed in the beginning of the Holocene Megathermal Period with distinct regional feature of the culture. From 6.5 kaBP to 5.5 kaBP, the climate changed warmer and wetter. The frequent occurrence of flood and waterlog due to such a climate regime and high sea level caused the earth＇s surface environment deteriorated in the Huaihe River basin of Anhui and the interruption of the Neolithic cultural development, hence a lack of archaeological sites. From 5.5 kaBP to 4.0 kaBP, the climate changed from wet to dry, the natural environment was propitious to human survival. Dawenkou Culture and Longshan Culture flourished in this period. The Neolithic cultural development, the number of the sites and their distribution characteristics of the sites in the study area differed apparently from those in Central China and Shandong Province.
基金This research was funded by the Development and Demonstration of Road Dust Monitoring and Management System(No.Z191100009119011)the National Research Program for Key Issues in Air Pollution Control China(No.DQGG0201)the National Key Research and Development program of China(No.2018YFC0213203).
文摘Road silt loading(sL)is an important parameter in the fugitive road dust(FRD)emissions.In this study,the improved Testing Re-entrained Aerosol Kinetic Emissions from Roads(TRAKER)combined with the AP-42 method was firstly developed to quickly measure and estimate the sLs of paved roads in Beijing,China.The annual average sLs in Beijing was 0.59±0.31 g/m^(2)in 2020,and decreased by 22.4%compared with that in 2019.The seasonal variations of sLs followed the order of spring>winter>summer>autumn in the two years.The seasonal mean road sLs on the same type road in the four seasons presented a decline trend from^(2)019 to 2020,especially on the Expressway,decreasing 47.4%-72.7%.The road sLs on the different type roads in the same season followed the order of Major arterial∼Minor arterial∼Branch road>Express road,and Township road∼Country highway>Provincial highway∼National highway.The emission intensities of PM10 and PM_(2.5)from FRD in Beijing in 2020 were lower than those in 2019.The PM10 and PM_(2.5)emission intensities at the four planning areas in the two years all presented the order of the capital functional core area>the urban functional expansion area>the urban development new area>the ecological conservation and development area.The annual emissions of PM10 and PM_(2.5)from FRD in Beijing in 2020 were 74,886 ton and 18,118 ton,respectively,decreasing by∼33.3%compared with those in 2019.
文摘[ Objective] The study aimed to discuss the temporal-spatial distribution and short-range prediction indicators of hail weather in east central Haixi Prefecture of Qinghai Province. [Method] Using hail data of six stations in east central Haixi Prefecture from 1960 to 2010, the temporal and spatial distribution of hail weather was analyzed firstly. Afterwards, based on the high-altitude factual data of 30 case studies of hail during 2006 -2010, its high-altitude and ground weather situation and physical quantity field were studied to summarize short-term circulation pattern and shod- range prediction characteristics of hail weather. [ Result] In east central Haixi, hail appeared from April to September, and it was most frequently from May to August. Meanwhile, hail was frequent from 14：00 to 20：00. Among the six stations, hail was most frequent in Tianjun but least frequent in Wulan. Moreover, hail disaster mainly occurred in Wulan and Tianjun. In addition, there were three typos of circulation pattern of hail weather at 500 hPa. Hail mainly occurred under the effect of northwest airflow, and it had shortwave trough, cold center or trough, jet stream core or one of the three. Hail appeared frequently under the situation of upper-level divergence and low-level convergence, and abundant water vapor and water vapor flux convergence at low levels were important conditions for hailing. [ Conclusion] The research could provide scientific references for improving the accuracy of hail forecast.
基金National Natural Science Foundation of China(No.U1811464)。
文摘Based on the official criminal data released by the Tokyo Metropolitan Police Department in 2019,this paper discusses the temporal-spatial distribution of various types of crimes in the special wards of Tokyo.The results show that:(1)The times of high and low incidence of different types of crime differ significantly.Although vicious crime and violent crime present no obvious monthly distribution,property crime clearly differs between the first and second half of a calendar year.(2)The month before the new year sees a surge in most types of crime.(3)Vicious crime peaks in the hours between night and early morning.Violent crime and property crime correlate positively with the frequency of human interaction and peak in the morning and evening commuting hours.(4)The spatial distribution of crime resembles the concentric circles of the three rings of the special wards of Tokyo,with a central high-incidence area,a center-peripheral low-incidence area,and a marginal high-incidence area.In addition,the center sees more personal crime than the periphery,whereas property crimes show the opposite trend.(5)A spatial autocorrelation analysis shows that the special wards of Tokyo may be grouped into the“high-high”and“low-low”agglomeration modes of different types of crime,with marked differences between the various types of crime.The crime can be divided into three types:central agglomeration,double central agglomeration,and decentralized agglomeration.
文摘The temporal-spatial distribution and seasonal variation of the precipitation acidity in Guangxi Province were statistically analyzed by means of the data from 2003 to 2008 in 10 Stations of Acid Rain Observation in the province and the data from 1996 to 2008 in two Monitoring Spots in Nanning and Baise,respectively.The results showed that annual average pH value of precipitation was <5.6 based on the analysis of the data from 10 Stations of Acid Rain Observation in the province,among which,the data from 5 stations indicated that annual average pH value of precipitation was <4.5.Thus,it can be thought that the serious acid rain had appeared in the province.There was an obvious seasonal variation in the extent of the acidity in precipitation and the acidity of precipitation in spring and winter was heavier than that in summer and autumn.
基金Supported by Natural Science Foundation of Jiangsu Province,China(BK2009412)Special Project of Science Research in Public WelfareSector(Meteorology),China(GYHY200906021)Construction Project of Advantage Discipline in University of Jiangsu,China
文摘[Objective] The rasearch aimed to grasp the spatial and temporal distribution charactedstics of extreme precipitation in Jiangsu Prov- ince. [Methodl Threshold was determined by detrended fluctuation analysis （DFA） based on the data of daily precipitation over Jiangsu Province from 1961 to 2010, and the oscillation pedod and mutation were detected by the method of Morlet wavelet analysis and Mann-Kendall test respec- tively. [ Result~ The annual frequency of extreme precipitation in Jiangsu Province demonstrated oscillation characteristics with 8 -10 a, and the mutation mainly happened in 2006, In addition, the oscillation period of extreme precipitation during summer was 8 -10 a, and its mutation hap- pened in 1998. The oscillation periods of extreme precipitation, however, during autumn were 2 -3 and 5 -7 a. Extreme precipitation and total rain- fall had better consistency. They both presented the characteristics of more in the south and less in the north, and big-small-value zone was concentrated. [ Conclusion] The research could provide technical support for making defense policy of the related disaster for relevant departments.
基金Supported by Chongqing Municipal Frontiers and Application Base Research Program,China(cstc2014jcyjA 20002)Chongqing Municipal Key Laboratory of Institutions of Higher Education,China(WEPKL2013MS-10)+1 种基金Wanzhou District Soft Science Project,China(201404009)Innovation Planning Project for University Students of Chongqing Three Gorges University,China(2014-55)
文摘To discuss response ability of five functional areas to rainstorm flood in Chongqing,by taking 8 districts（ counties） as research object,monthly occurrence times of heavy rain and rainstorm in different functional areas over the years and appearance month of the maximum rainfall were conducted statistics. Results showed that frequency distribution of heavy rain in whole year in different functional areas was different,but it was similar in the same functional zone. Temporal-spatial distribution of rainstorm was more independent,and there were different performances in various districts of each functional area. In urban functional core area and urban functional expansion area,rainstorm times was more,and the maximum precipitation was larger. In urban development new district,rainstorm times and the maximum precipitation were relatively smaller in whole Chongqing. In ecological conservation development area of northeast Chongqing,rainstorm duration was longer,and we needed prevention and control during June- September. In ecological protection area of southeast Chongqing,although rainstorm occurrence times was the most in Chongqing,the heavy rainstorm was less.
文摘[ Objective] The research aimed to analyze temporal-spatial distribution and change trend of the temperature in Beibei District. [ Method] Based on temperature observation data at 6 ground meteorological observatories of Beibei District from 1951 to 2010, EOF and linear trend method were used to analyze temporal-spatial distribution and change characteristics of the temperature in Beibei District in recent 60 years. [ Result] Tem- perature in Beibei District in recent 60 years overall presented rise trend, and average rise velocity was 0.045 ~C/10 a. Temperature rise in autumn was the most obvious, while summer temperature presented decline trend. Average temperature presented gradual rise trend from January to July and gradual decrease trend from August to December. Seen from spatial distribution, temperature in the whole district was higher in the west and lower in the middle. Abnormal spatial distribution of the average temperature in the whole district mainly had consistent higher （lower） type, south- north reverse type and east-west reverse type. [ Condusionl The research provided theoretical basis for effective disaster prevention and reduction in the zone.
基金supported by the National Natural Science Foundation of China (Grant No. 40872137)Natural Science Foundation of Hebei Province (GrantNo.D2007000751)
文摘This study was conducted following research on metallogenesis in the Zhangjiajie-Xuanhua and East Hebei mantle branch structure zones. The Fuping mantle branch structure zone is one where Au, Cu and Ag poly-metallic ore resources are concentrated in North Hebei. However, there has existed a long-standing controversy on the temporal-spatial distribution of ore resources and their ore-forming material sources. In terms of age dating and the comprehensive analysis of S, Pb, O, C and Si isotopes, it is considered that the temporal-spatial distribution of ore resources in this mantle branch structure zone is obviously controlled by the Fuping mantle branch structure. In space there is developed such a metallogenic pattern as to be Ag, Pb and Zn polymetallic ore deposits with gold appearing inside and copper appearing outside. Metallogenesis is dated mainly at Yanshanian, the ore-forming materials were derived predominantly from the deep interior of the Earth, and ore-forming fluids were derived largely from Yanshanian magmatism.
基金funded by the“Research and Application Project of Collaborative Optimization Control Technology for Distribution Station Area for High Proportion Distributed PV Consumption(4000-202318079A-1-1-ZN)”of the Headquarters of the State Grid Corporation.
文摘Themassive integration of high-proportioned distributed photovoltaics into distribution networks poses significant challenges to the flexible regulation capabilities of distribution stations.To accurately assess the flexible regulation capabilities of distribution stations,amulti-temporal and spatial scale regulation capability assessment technique is proposed for distribution station areas with distributed photovoltaics,considering different geographical locations,coverage areas,and response capabilities.Firstly,the multi-temporal scale regulation characteristics and response capabilities of different regulation resources in distribution station areas are analyzed,and a resource regulation capability model is established to quantify the adjustable range of different regulation resources.On this basis,considering the limitations of line transmission capacity,a regulation capability assessment index for distribution stations is proposed to evaluate their regulation capabilities.Secondly,considering different geographical locations and coverage areas,a comprehensive performance index based on electrical distance modularity and active power balance is established,and a cluster division method based on genetic algorithms is proposed to fully leverage the coordination and complementarity among nodes and improve the active power matching degree within clusters.Simultaneously,an economic optimization model with the objective of minimizing the economic cost of the distribution station is established,comprehensively considering the safety constraints of the distribution network and the regulation constraints of resources.This model can provide scientific guidance for the economic dispatch of the distribution station area.Finally,case studies demonstrate that the proposed assessment and optimization methods effectively evaluate the regulation capabilities of distribution stations,facilitate the consumption of distributed photovoltaics,and enhance the economic efficiency of the distribution station area.
基金supported by the National Natural Science Foundation of China,Nos.32070534(to WY),32370567(to WY),82371874(to XL),81830032(to XL),82071421(to SL)Key Field Research and Development Program of Guangdong Province,No.2018B030337001(to XL)+2 种基金Guangzhou Key Research Program on Brain Science,No.202007030008(to XL)Department of Science and Technology of Guangdong Province,Nos.2021ZT09Y007,2020B121201006(to XL)Guangdong Basic and Applied Basic Research Foundation,Nos.2022A1515012301(to WY),2023B1515020031(to WY).
文摘The vast majority of in vitro studies have demonstrated that PINK1 phosphorylates Parkin to work together in mitophagy to protect against neuronal degeneration.However,it remains largely unclear how PINK1 and Parkin are expressed in mammalian brains.This has been difficult to address because of the intrinsically low levels of PINK1 and undetectable levels of phosphorylated Parkin in small animals.Understanding this issue is critical for elucidating the in vivo roles of PINK1 and Parkin.Recently,we showed that the PINK1 kinase is selectively expressed as a truncated form(PINK1–55)in the primate brain.In the present study,we used multiple antibodies,including our recently developed monoclonal anti-PINK1,to validate the selective expression of PINK1 in the primate brain.We found that PINK1 was stably expressed in the monkey brain at postnatal and adulthood stages,which is consistent with the findings that depleting PINK1 can cause neuronal loss in developing and adult monkey brains.PINK1 was enriched in the membrane-bound fractionations,whereas Parkin was soluble with a distinguishable distribution.Immunofluorescent double staining experiments showed that PINK1 and Parkin did not colocalize under physiological conditions in cultured monkey astrocytes,though they did colocalize on mitochondria when the cells were exposed to mitochondrial stress.These findings suggest that PINK1 and Parkin may have distinct roles beyond their well-known function in mitophagy during mitochondrial damage.
基金supported by the National Natural Science Foundation of China(Nos.51808158,52170101,and 52200116)Tianjin Natural Science Foundation(No.23JCYBJC00640).
文摘The electrochemical corrosion of ductile pipes(DPs)in drinking water distribution systems(DWDS)has a crucial impact on cement-mortar lining(CML)failure and metal release,potentially leading to drinking water quality deterioration and posing a risk to public health.An in-situ scanning vibrating electrode technique(SVET)with micron-scale resolution,microscopic scale detection and water quality analysis were used to investigate the corrosion behavior and metal release from DPs throughout the whole CML failure process.Metal pollutants release occurred at three different stages of CML failure process,and there are potential risks of water quality deterioration exceeding the maximum allowable levels set by national standards in the partial failure stage and lining peeling stage.Furthermore,the effects of water chemistry(Cl^(−),SO_(4)^(2−),NO_(3)−,and Ca^(2+))on corrosion scale growth and iron release activity,were investigated during the CML partial failure stage.Results showed that the CML failure process in DPs was accelerated by the autocatalysis of localized corrosion.Cl^(−)was found to damage the uncorroded metal surface,while SO_(4)^(2−)mainly dissolved the corrosion scale surface,increasing iron release.Both the oxidation of NO_(3)−and selective sedimentation of Ca2+were found to enhance the stability of corrosion scales and inhibit iron release.
基金the National Natural Science:Foundation of China(52375370)the Open Project of Salt Lake Chemical Engineering Research Complex,Qinghai University(2023-DXSSKF-Z02)+2 种基金the Nat-ural Science Foundation of Shanxi(202103021224049)GDAS Projects of International cooperation platform of Sci-ence and Technology(2022GDASZH-2022010203-003)Guangdong province Science and Technology Plan Projects(2023B1212060045).
文摘The dominated contradiction in optimizing the performance of magnesium-air battery anode lies in the difficulty of achieving a good balance between activation and passivation during discharge process.To further reconcile this contradiction,two Mg-0.1Sc-0.1Y-0.1Ag anodes with different residual strain distribution through extrusion with/without annealing are fabricated.The results indicate that annealing can significantly lessen the“pseudo-anode”regions,thereby changing the dissolution mode of the matrix and achieving an effective dissolution during discharge.Additionally,p-type semiconductor characteristic of discharge productfilm could suppress the self-corrosion reaction without reducing the polarization of anode.The magnesium-air battery utilizing annealed Mg-0.1Sc-0.1Y-0.1Ag as anode achieves a synergistic improvement in specific capacity(1388.89 mA h g^(-1))and energy density(1960.42 mW h g^(-1)).This anode modification method accelerates the advancement of high efficiency and long lifespan magnesium-air batteries,offering renewable and cost-effective energy solutions for electronics and emergency equipment.
基金supported by the National Key Research and Development Program of China (Nos.2022YFC3702000 and 2022YFC3703500)the Key R&D Project of Zhejiang Province (No.2022C03146).
文摘Severe ground-level ozone(O_(3))pollution over major Chinese cities has become one of the most challenging problems,which have deleterious effects on human health and the sustainability of society.This study explored the spatiotemporal distribution characteristics of ground-level O_(3) and its precursors based on conventional pollutant and meteorological monitoring data in Zhejiang Province from 2016 to 2021.Then,a high-performance convolutional neural network(CNN)model was established by expanding the moment and the concentration variations to general factors.Finally,the response mechanism of O_(3) to the variation with crucial influencing factors is explored by controlling variables and interpolating target variables.The results indicated that the annual average MDA8-90th concentrations in Zhejiang Province are higher in the northern and lower in the southern.When the wind direction(WD)ranges from east to southwest and the wind speed(WS)ranges between 2 and 3 m/sec,higher O_(3) concentration prone to occur.At different temperatures(T),the O_(3) concentration showed a trend of first increasing and subsequently decreasing with increasing NO_(2) concentration,peaks at the NO_(2) concentration around 0.02mg/m^(3).The sensitivity of NO_(2) to O_(3) formation is not easily affected by temperature,barometric pressure and dew point temperature.Additionally,there is a minimum IRNO_(2) at each temperature when the NO_(2) concentration is 0.03 mg/m^(3),and this minimum IRNO_(2) decreases with increasing temperature.The study explores the response mechanism of O_(3) with the change of driving variables,which can provide a scientific foundation and methodological support for the targeted management of O_(3) pollution.
基金supported by the National Natural Science Foundation of China(Nos.U19A2044,42105132,42030609,41975037,and 42105133)the National Key Research and Development Program of China(No.2022YFC3703502)+1 种基金the Plan for Anhui Major Provincial Science&Technology Project(No.202203a07020003)Hefei Ecological Environment Bureau Project(No.2020BFFFD01804).
文摘As a significant city in the Yangtze River Delta regions,Hefei has experienced rapid changes in the sources of air pollution due to its high-speed economic development and urban expansion.However,there has been limited research in recent years on the spatial-temporal distribution and emission of its atmospheric pollutants.To address this,this study conducted mobile observations of urban roads using the Mobile-DOAS instrument from June 2021 to May 2022.The monitoring results exhibit a favourable consistent with TROPOMI satellite data and ground monitoring station data.Temporally,there were pronounced seasonal variations in air pollutants.Spatially,high concentration of HCHO and NO_(2)were closely associated with traffic congestion on roadways,while heightened SO_(2)levels were attributed to winter heating and industrial emissions.The study also revealed that with the implementation of road policies,the average vehicle speed increased by 95.4%,while the NO concentration decreased by 54.4%.In the estimation of urban NO_(x)emission flux,it was observed that in temporal terms,compared with inventory data,the emissions calculated viamobile measurements exhibitedmore distinct seasonal patterns,with the highest emission rate of 349 g/sec in winter and the lowest of 142 g/sec in summer.In spatial terms,the significant difference in emissions between the inner and outer ring roads also suggests the presence of the city’s primary NO_(x)emission sources in the area between these two rings.This study offers data support for formulating the next phase of air pollution control measures in urban areas.
基金supported by National Natural Science Foundation of China(62104082)Guangdong Basic and Applied Basic Research Foundation(2022A1515010746,2022A1515011228,and 2022B1515120006)the Science and Technology Program of Guangzhou(202201010458).
文摘Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization processes lead to different order of crystallization dynamics within the perovskite thin film,resulting in the differences of additive distribution.We then tailor-designed an additive molecule named 1,3-bis(4-methoxyphenyl)thiourea to obtain films with fewer defects and holes at the buried interface,and prepared perovskite solar cells with a certified efficiency of 23.75%.Furthermore,this work also demonstrates an efficiency of 20.18%for the large-area perovskite solar module(PSM)with an aperture area of 60.84 cm^(2).The PSM possesses remarkable continuous operation stability for maximum power point tracking of T_(90)>1000 h in ambient air.
基金supported by the National Key Research and Development Program of China(No.2019YFC1804501)the National Natural Science Foundation of China(Nos.42122056 and U1901210)+2 种基金Guangdong Basic and Applied Basic Research Foundation(No.2021B1515020063)the Key Research and Development Program of Guangdong Province(No.2021B1111380003)the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01Z032).
文摘Coking industry is a potential source of heavy metals(HMs)pollution.However,its impacts to the groundwater of surrounding residential areas have not been well understood.This study investigated the pollution characteristics and health risks of HMs in groundwater nearby a typical coking plant.Nine HMs including Fe,Zn,Mo,As,Cu,Ni,Cr,Pb and Cd were analyzed.The average concentration of total HMswas higher in the nearby area(244.27μg/L)than that of remote area away the coking plant(89.15μg/L).The spatial distribution of pollution indices including heavy metal pollution index(HPI),Nemerow index(NI)and contamination degree(CD),all demonstrated higher values at the nearby residential areas,suggesting coking activity could significantly impact the HMs distribution characteristics.Four sources of HMs were identified by Positive Matrix Factorization(PMF)model,which indicated coal washing and coking emission were the dominant sources,accounted for 40.4%,and 31.0%,respectively.Oral ingestionwas found to be the dominant exposure pathway with higher exposure dose to children than adults.Hazard quotient(HQ)values were below 1.0,suggesting negligible non-carcinogenic health risks,while potential carcinogenic risks were from Pb and Ni with cancer risk(CR)values>10−6.Monte Carlo simulation matched well with the calculated results with HMs concentrations to be the most sensitive parameters.This study provides insights into understanding how the industrial coking activities can impact the HMs pollution characteristics in groundwater,thus facilitating the implement of HMs regulation in coking industries.
