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Coal petrology,sedimentology and depositional environment of the Parvadeh coais in the Upper Triassic,Tabas Block of Central-East Iran 被引量:1
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作者 Ziba Zamani Hossain Rahimpour-Bonab Ralf Littke 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第3期58-77,共20页
Peat forming environment strongly influences the economic value of any coal seam and coal-bearing strata.Hence,pal-aeoenvironmental studies provide important information for coal resource exploration.In this context,d... Peat forming environment strongly influences the economic value of any coal seam and coal-bearing strata.Hence,pal-aeoenvironmental studies provide important information for coal resource exploration.In this context,detailed studies on selected coals from the Parvadeh Area,Iran,were conducted using sedimentology,coal petrology,X-ray diffraction(XRD),scanning electron microscopy-energy dispersive X-ray analyzer(SEM-EDX),and proximate analysis.The sedi-mentary facies above and below the coal seams are mainly marine or marine-influenced facies,supporting that the coal-forming mires in the Parvadeh Area developed in a paralic environment,where the base level must be closely related to sea level.Sulfur contents are moderate to high and mark the influence of brackish/marine water,especially during transgres-sion after peat growth in a lower delta plain environment.The peat-forming mires extended on coastal/delta plain lobes.The lower delta plain/coastal plain coals are characterized by lateral continuity and substantial thickness,whereas few coals possibly representing the upper delta plain are thin and more discontinuous.The detrital nature and composition of the numerous partings and the overall high ash yield in the coal seams indicate an active tectonic area with high rates of creation of accommodation space over peat growth.Coal petrology and coal facies analysis exhibits a permanently high water table within a forest swamp and mostly rheotrophic conditions,sometimes with connection to the seawater.Accord-ing to paleoenvironmental reconstructions,it seems that coal layers may be thicker,with less sulfur(pyrite),but more clastic minerals and partings toward the western part of the area.Although these coal seams presently have low economic potential for the mining operation,partly due to great depth,this humic,high-volatile to medium-volatile bituminous coal may be suitable for exploration of coal bed methane resources. 展开更多
关键词 Coal petrology SEDIMENTOLOGY Coal facies analysis Upper Triassic Nayband Formation tabas Block
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Neotectonics of Tabas Area, Central Iran by Index of Active Tectonics (IAT) 被引量:1
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作者 Elahe Javadi Mosavi Mehran Arian +1 位作者 Manochehr Ghorshi Mohammad Nazemi 《Open Journal of Geology》 2015年第4期209-223,共15页
In this research, Tabas area, which is located in central Iran, was selected as the study area and three geomorphic indices were calculated for its structural fronts. Through averaging these three indices, we obtained... In this research, Tabas area, which is located in central Iran, was selected as the study area and three geomorphic indices were calculated for its structural fronts. Through averaging these three indices, we obtained index of active tectonics (IAT). The values of the index were divided into classes to define the degree of active tectonics. Therefore, relative tectonic activity was calculated and their values were classified and analyzed in two groups. Regions were identified as high and moderate levels. In analyzing data and combining them with tectonic setting, the results were often associated and justified with regional geology. Our results show that the highest value is located along Shoutori fault, which shows 2 class of relative tectonic activity (high level). Also, moderate values are located along Ereshk, Ezmeighan and Jamal faults (moderate level). According to these results, Shoutori fault is the most active fault in the study area and this situation is compatible with its position as a mountain front fault. 展开更多
关键词 ACTIVE TECTONICS INDEX tabas CENTRAL Iran
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Wildfire events at the Triassic-Jurassic boundary of the Tabas Basin,Central Iran
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作者 Majid Alipour Bahram Alizadeh +1 位作者 AmirAbbas Jahangard AhmadReza GandomiSani 《International Journal of Coal Science & Technology》 EI CAS CSCD 2021年第5期897-907,共11页
This paper presents organic geochemical evidence pointing to the occurrence of wildfire events at the Triassic-Jurassic boundary in Central Iran.The studied outcrop section(the Kamarmacheh Kuh section)is comprised of ... This paper presents organic geochemical evidence pointing to the occurrence of wildfire events at the Triassic-Jurassic boundary in Central Iran.The studied outcrop section(the Kamarmacheh Kuh section)is comprised of the Upper Triassic Nayband Formation which passes conformably into the Lower Jurassic Ab-e-Haji Formation with no sharp boundary.Organic petrographical studies reveal a higher concentration of semi-fusinite macerals and microscopic charcoal at the boundary between studied formations.This observation can be an evidence for widespread wildfire events at the Triassic-Jurassic boundary of the studied area.Following these fires,vast areas of land were exposed for erosion and large volumes of clastic sediments were provided due to increased run-off.This agrees well with previous sedimentological and stratigraphical studies suggesting a major change in the depositional conditions from marine to non-marine at the Triassic-Jurassic boundary of the Tabas Basin.These findings can have important implications about paleo-depositional settings of the studied formations and the nature of the associated organic matter. 展开更多
关键词 Wildfire events Triassic-Jurassic boundary Nayband and Ab-e-Haji formations tabas Basin Central Iran
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Earthquake Disaster Risk Reduction in Iran:Lessons and "Lessons Learned" from Three Large Earthquake Disasters——Tabas 1978,Rudbar 1990,and Bam 2003 被引量:2
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作者 Michaela Ibrion Mohammad Mokhtari Farrokh Nadim 《International Journal of Disaster Risk Science》 SCIE CSCD 2015年第4期415-427,共13页
This article addresses three large earthquake disasters in Iran: Tabas in 1978, Rudbar in 1990, and Bam in 2003. Lessons and 'Lessons Learned' from these three earthquake disasters were investigated together w... This article addresses three large earthquake disasters in Iran: Tabas in 1978, Rudbar in 1990, and Bam in 2003. Lessons and 'Lessons Learned' from these three earthquake disasters were investigated together with their contributions over time towards earthquake disaster risk reduction in Iran. Many lessons from 1978 Tabas, 1990 Rudbar, and 2003 Bam did not become 'Lessons Learned' and they were identified again within the dramatic context of other earthquake disasters in various places of Iran. Both lessons and 'Lessons Learned' from Tabas, Rudbar, Bam,and other earthquake disasters in Iran require a sustainable long-term framework—an earthquake culture. 展开更多
关键词 BAM Earthquake disaster risk reduction LESSONS Lessons learned Rudbar tabas
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评判性思维教学法在护理技能训练中的应用 被引量:9
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作者 李冬莉 孔静 +2 位作者 王永红 姚志翠 纪敬敏 《中国医药导报》 CAS 2014年第19期127-130,共4页
目的探讨评判性思维教学法在护理本科生护理技能训练中的作用。方法将河北中医学院2010级护理本科生118名分为两组,在实习前1个月开设护理技能训练课程,实验组(60名)运用Taba教学法和反思日记法,对照组(58名)则采用传统的教学方法,技能... 目的探讨评判性思维教学法在护理本科生护理技能训练中的作用。方法将河北中医学院2010级护理本科生118名分为两组,在实习前1个月开设护理技能训练课程,实验组(60名)运用Taba教学法和反思日记法,对照组(58名)则采用传统的教学方法,技能训练结束后,比较两组学生的评判性思维能力和技能训练成绩。结果实验组护生护理技能训练[(92.21±4.27)分]以及评判性思维的寻求真相[(39.88±2.76)分]、分析能力[(44.30±2.28)分]、自信心[(43.32±6.18)分]、求知欲[(46.47±4.01)分]、总分[(298.03±10.52)分]与对照组[护生护理技能训练平均(90.11±5.21)分以及评判性思维的寻求真相(38.07±3.23)分、分析能力(42.79±2.61)分、自信心(39.91±2.42)分、求知欲(44.83±4.57)分、总分(288.02±10.59)分]比较,差异均有统计学意义(P<0.05)。结论评判性思维教学法有助于提高护理本科生护理技能训练效果。 展开更多
关键词 评判性思维 Taba教学法 反思日记法 护理本科生 护理技能训练
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航天测控设备状态配置和管理方法 被引量:6
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作者 党琦 苟茹君 +1 位作者 吴涛 董广然 《电讯技术》 北大核心 2017年第1期106-110,共5页
针对我国航天测控网设备状态配置和管理方法现状,分析了测控设备任务准备和历史任务恢复节点的现实需要,提出了航天测控设备历史状态宏迁移、设备参数共享以及设备状态集中管理3种方法。通过分析比较,给出了设备状态集中管理和可扩展标... 针对我国航天测控网设备状态配置和管理方法现状,分析了测控设备任务准备和历史任务恢复节点的现实需要,提出了航天测控设备历史状态宏迁移、设备参数共享以及设备状态集中管理3种方法。通过分析比较,给出了设备状态集中管理和可扩展标记语言(XML)格式设备状态共享方法相结合的实现途径。该方法能够实现设备参数的快速设置和检查以及不同设备之间状态的共享,有利于提高整个测控网的自动化程度和运行效率。 展开更多
关键词 航天测控网 测控设备 状态管理 任务参数宏 数据库迁移
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应用多主体系统预测和分析城市用地变化 被引量:9
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作者 李新延 李德仁 《武汉大学学报(工学版)》 CAS CSCD 北大核心 2005年第5期109-113,共5页
城市用地变化是世界各国特别是发展中国家城市研究中的一个焦点问题.利用多主体系统(MAS)技术,从城市用地演变机制出发,研究建模思路和方法,利用RePast软件和GIS空间数据库,初步构造了一个模拟城市用地演变的模型.
关键词 多主体系统 复杂适应系统理论 城市用地RePast软件 空间数据库
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Taba教学法培养临床低年资护士评判性思维能力的效果评价 被引量:5
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作者 刘琬椿 苏霖 +1 位作者 汪爱茹 汪淼芹 《实用医院临床杂志》 2015年第3期117-119,共3页
目的探讨Taba教学法在临床低年资护士评判性思维能力培养中的应用与效果。方法从我院内科片区临床科室中随机选择10个科室的低年资护士,其中5个科室护士为观察组(n=53),5个科室护士为对照组(n=50)。两组均遵循医院一般护理培训,观察组... 目的探讨Taba教学法在临床低年资护士评判性思维能力培养中的应用与效果。方法从我院内科片区临床科室中随机选择10个科室的低年资护士,其中5个科室护士为观察组(n=53),5个科室护士为对照组(n=50)。两组均遵循医院一般护理培训,观察组在此基础上实施Taba教学法。6个月后比较两组评判性思维意向问卷(CCTDI)得分并分析观察组Taba教学评价结果。结果 CCTDI量表测试结果显示观察组开放思想、分析能力、系统能力、自信心、求知欲5个维度和总得分均高于对照组,差异有统计学意义(P<0.05);83.02%的观察组护士认为Taba教学法能够提高临床决策能力,81.13%认为能够增强交流沟通能力,94.33%的护士认为能够适应Taba教学法,92.45%认为该法值得推广。结论 Taba教学法运用于临床低年资护士培训有助于提高护士的评判性思维能力。 展开更多
关键词 Taba教学法 低年资护士 评判性思维 效果评价
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4-(2,4,6-三硝基苯胺基)苯甲酸(TABA)及铅、铜盐合成与表征 被引量:2
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作者 常佩 黄新萍 +4 位作者 郑晓东 王伯周 李普瑞 唐望 姜俊 《含能材料》 EI CAS CSCD 北大核心 2011年第4期380-383,共4页
以2,4,6-三硝基氯苯(苦基氯)及对氨基苯甲酸为原料,在50%乙醇水溶液中经过缩合反应脱去氯化氢得到中间体4-(2,4,6-三硝基苯氨基)苯甲酸(TABA),收率94.0%,产品纯度98.9%,利用红外、核磁及元素分析等鉴定产物的结构;探讨了缩合反应机理及... 以2,4,6-三硝基氯苯(苦基氯)及对氨基苯甲酸为原料,在50%乙醇水溶液中经过缩合反应脱去氯化氢得到中间体4-(2,4,6-三硝基苯氨基)苯甲酸(TABA),收率94.0%,产品纯度98.9%,利用红外、核磁及元素分析等鉴定产物的结构;探讨了缩合反应机理及影响反应的主要因素,确定了适宜的合成条件为反应温度70℃,反应时间5 h,最佳物料摩尔比为n(2,4,6-三硝基氯苯)∶n(与对氨基苯甲酸)=1∶1。制备出TABA的铅盐及铜盐,其摩擦感度分别为100%与72%(表压3.92 MPa,摆角90°),特性落高H50分别为15.5,28.2 cm;DSC分析测试了TABA铅、铜盐的热稳定性,其分别在270.82,282.25℃放热分解,二次放热分解峰温度为322.98,331.91℃。 展开更多
关键词 有机化学 4-(2 4 6-三硝基苯氨基)苯甲酸(TABA) 铅、铜盐 合成与表征
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Prediction of roadheaders' performance using artificial neural network approaches (MLP and KOSFM) 被引量:12
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作者 Arash Ebrahimabadi Mohammad Azimipour Ali Bahreini 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2015年第5期573-583,共11页
A pplication o f m echanical excavators is one o f th e m o st com m only used excavation m eth o d s because itcan bring th e p ro ject m ore productivity, accuracy and safety. A m ong th e m echanical excavators, ro... A pplication o f m echanical excavators is one o f th e m o st com m only used excavation m eth o d s because itcan bring th e p ro ject m ore productivity, accuracy and safety. A m ong th e m echanical excavators, roadhead ers are m echanical m iners w h ich have b een extensively u se d in tu n n elin g , m ining an d civil indu stries. Perform ance pred ictio n is an im p o rta n t issue for successful ro a d h e a d e r application andgenerally deals w ith m achine selection, p ro d u ctio n rate an d b it consu m p tio n . The m ain aim o f thisresearch is to investigate th e c u ttin g p erfo rm an ce (in stan tan eo u s c u ttin g rates (ICRs)) o f m ed iu m -d u tyro ad h ead ers by using artificial neural n etw o rk (ANN) approach. T here are d ifferent categories forANNs, b u t based o n train in g alg o rith m th e re are tw o m ain k in d s: supervised and u n su p erv ised . Them u lti-lay er p ercep tro n (MLP) an d K ohonen self-organizing feature m ap (KSOFM) are th e m o st w idelyused neu ral netw o rk s for supervised an d u n su p erv ised ones, respectively. For gaining this goal, ad atab ase w as prim arily provided from ro ad h e a d e rs' p erfo rm an ce an d geom echanical characteristics o frock form ations in tu n n els and d rift galleries in Tabas coal m ine, th e larg est an d th e only fullymech an ized coal m ine in Iran. T hen th e datab ase w as analyzed in o rd e r to yield th e m ost im p o rtan tfactor for ICR by using relatively im p o rta n t factor in w hich G arson eq u atio n w as utilized. The MLPn etw o rk w as train ed by 3 in p u t p ara m e te rs including rock m ass pro p erties, rock quality d esignation(RQD), in tact rock p ro p erties such as uniaxial com pressive stre n g th (UCS) an d Brazilian ten sile stren g th(BTS), and o n e o u tp u t p a ra m e te r (ICR). In o rd e r to have m ore v alidation o n MLP o u tp u ts, KSOFM visualizationw as applied. The m ean square e rro r (MSE) an d regression coefficient (R ) o f MLP w e re found tobe 5.49 an d 0.97, respectively. M oreover, KSOFM n etw o rk has a m ap size o f 8 x 5 and final qu an tizatio nan d topographic erro rs w e re 0.383 an d 0.032, respectively. The results show th a t MLP neural n etw orkshave a strong capability to p red ict an d ev alu ate th e perfo rm an ce o f m ed iu m -d u ty ro ad h ead ers in coalm easu re rocks. Furtherm ore, it is concluded th a t KSOFM neural n etw o rk is an efficient w ay for u n d e rstand in g system beh av io r an d know ledge extraction. Finally, it is indicated th a t UCS has m ore influenceo n ICR b y applying th e b e st train ed MLP n etw o rk w eig h ts in G arson eq u atio n w h ich is also confirm ed byKSOFM. 展开更多
关键词 Artificial neural network(ANN) Performance prediction ROADHEADER Instantaneous cutting rate(ICR) tabas coal mine project
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多分散细水雾遮蔽热辐射的高效计算方法 被引量:1
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作者 杜永成 杨立 +1 位作者 谢志辉 孙丰瑞 《红外与毫米波学报》 SCIE EI CAS CSCD 北大核心 2014年第4期436-441,共6页
建立了多分散细水雾0.8~20μm辐射特性参数数据库和谱带-灰体模型,并提出了采用数据库调用获取辐射特性参数、采用谱带-灰体模型处理细水雾非灰特性相结合的方法.通过将该方法计算的无量纲辐射热流与采用Mie理论和窄谱带模型计算的结果... 建立了多分散细水雾0.8~20μm辐射特性参数数据库和谱带-灰体模型,并提出了采用数据库调用获取辐射特性参数、采用谱带-灰体模型处理细水雾非灰特性相结合的方法.通过将该方法计算的无量纲辐射热流与采用Mie理论和窄谱带模型计算的结果作对比,证明该方法准确可靠.通过精度分析和效率分析,证明所提方法既可保证精度在可接受的水平,又能使计算时间大幅缩减. 展开更多
关键词 多分散细水雾 热遮蔽 辐射特性参数 谱带-灰体模型 数据库
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A new model to predict roadheader performance using rock mass properties 被引量:7
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作者 Yazdani-Chamzini ABDOLREZA SIAMAK Haji Yakhchali 《Journal of Coal Science & Engineering(China)》 2013年第1期51-56,共6页
Prediction of roadheader performance plays a significant role in the plan of tunnel construction, which is influenced by different key parameters, including rock strength, discontinuity in rock mass, type and specific... Prediction of roadheader performance plays a significant role in the plan of tunnel construction, which is influenced by different key parameters, including rock strength, discontinuity in rock mass, type and specifications of roadheader machine, and brittleness. The main aim of this study is to build a robust empirical equation based on rock mass properties for the roadheader performance prediction. For achieving the aim, a dataset composed of roadheader performance rate and rock properties is established using the dataset compiled from an underground coal mine located in a remote rugged desert environment some 85 km south of Tabas City in mid east Iran. By using gathered data, the statistical analyses are conducted between rock mass properties and roadheader performance to find whether there is a significant relationship between input variables and roadheader performance. The results show that rock mass properties have a considerable impact on the rate of the roadheader performance. It is demonstrated that the proposed model can accurately predict the roadheader performance as a function of rock mass properties. 展开更多
关键词 roadheader performance tabas Coal Mine rock mass property alpha angle prediction
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基于web的专家评价信息服务平台构建研究 被引量:10
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作者 杜晖 《重庆大学学报(社会科学版)》 CSSCI 北大核心 2014年第2期99-104,共6页
搭建基于web的领域专家评价信息服务平台,实现基于国内外学术数据库的信息采集、整理、分析与挖掘的自动化处理,能够按照多种指定条件筛选指定领域专家,基于文献计量、统计分析、社会网络分析等方法,通过分析专家的各项评价指标数据,构... 搭建基于web的领域专家评价信息服务平台,实现基于国内外学术数据库的信息采集、整理、分析与挖掘的自动化处理,能够按照多种指定条件筛选指定领域专家,基于文献计量、统计分析、社会网络分析等方法,通过分析专家的各项评价指标数据,构建各领域的专家库,形成社会化的专家网络,并提供分析结果的多途径导出和可视化展示,能够为科研工作者和科研管理部门提供相应的信息服务和决策支持。 展开更多
关键词 专家评价 网络信息服务 文献分析与挖掘 专家库 专家地图 社会网络
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Taba教学法在护理学实践教学中的应用 被引量:6
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作者 左慧敏 杨艳玲 +1 位作者 张勇 李联祥 《卫生职业教育》 2011年第1期56-57,共2页
评判性思维,也译为批判性思维,由20世纪30年代德国法兰克福学派学者提出[1]。1989年美国护理联盟(National League for Nursing)在护理本科的认证指南中将评判性思维能力作为衡量护理教育水平的一项重要指标。评判性思维是要求学生运... 评判性思维,也译为批判性思维,由20世纪30年代德国法兰克福学派学者提出[1]。1989年美国护理联盟(National League for Nursing)在护理本科的认证指南中将评判性思维能力作为衡量护理教育水平的一项重要指标。评判性思维是要求学生运用已学知识和经验选择问题的解决方法。从护理角度看,评判性思维是指对临床复杂护理问题所进行的有目的、 展开更多
关键词 护理学 实践教学 Taba教学法 评判性思维
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网络学术信息资源知识产权保护 被引量:6
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作者 田梅 《中华医学图书情报杂志》 CAS 2014年第2期20-23,共4页
通过分析自建数据库、开放存取文库、在线图书这三类新型信息资源的类别、获取方式及可能涉及的知识产权问题,探讨了网络信息资源的知识产权保护,提出了加强网络版权法建设、引入技术手段等增强知识产权保护的建议。
关键词 知识产权 合理使用 数字图书馆 自建数据库 开放存取 在线图书
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论类案智能推送的优化路径 被引量:8
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作者 朱福勇 杨梦男 《科技与法律(中英文)》 CSSCI 2022年第4期37-45,共9页
科技与司法审判叠加使类案智能推送绘出公正与高效双飞的新图景。然而,实践中,类案要素的判断标准模糊、类案推送的精准度不高,以及数据库的非圆满性等,一定程度上抑制其运行实效。事实上,大数据挖掘、光学字符识别等智能技术,审判三段... 科技与司法审判叠加使类案智能推送绘出公正与高效双飞的新图景。然而,实践中,类案要素的判断标准模糊、类案推送的精准度不高,以及数据库的非圆满性等,一定程度上抑制其运行实效。事实上,大数据挖掘、光学字符识别等智能技术,审判三段论的法律推理,以及要素式审判思维,为类案智能推送奠定了坚实基础。未来,通过句化案件基本事实,改变文本相似度对比策略,完善类案对比算法;通过整合法律规范数据、收录非正式法律渊源及指导性案例数据等手段完善规范数据库,进而构建让民众可接受、具有世界领先水平的中国特色的类案智能推送模式和运行机制。 展开更多
关键词 类案智能判别 类案智能对比 类案规范库 类案智能推送
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人工智能技术在美国文档领域的应用及启示——基于专利数据的分析 被引量:2
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作者 朱伶杰 贺圆圆 《档案管理》 北大核心 2024年第6期124-128,共5页
人工智能技术与文档领域的结合是顺应时代发展、优化管理流程的必然选择。基于美国人工智能技术发展优势,采用专利分析方法对其文档领域人工智能技术的应用进行深度挖掘,发现美国注重人工智能基础层布局、技术领域涉及广泛、能及时把握... 人工智能技术与文档领域的结合是顺应时代发展、优化管理流程的必然选择。基于美国人工智能技术发展优势,采用专利分析方法对其文档领域人工智能技术的应用进行深度挖掘,发现美国注重人工智能基础层布局、技术领域涉及广泛、能及时把握人工智能政策动态、持续强化人工智能公私合作伙伴关系,这为我国文档领域人工智能技术的进一步发展提供了重要经验参考。 展开更多
关键词 人工智能 专利分析 档案 专利数据库 技术应用
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A fuzzy logic model to predict the out-of-seam dilution in longwall mining 被引量:2
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作者 Ali Bahri Najafi Mohammad Ali Ebrahimi Farsangi Golam Reza Saeedi 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2015年第1期91-98,共8页
The longwall mining method is often affected by the out-of-seam dilution (OSD). Therefore, predicting and controlling of dilution are important factors for reducing mining costs. In this study, the fuzzy set theory ... The longwall mining method is often affected by the out-of-seam dilution (OSD). Therefore, predicting and controlling of dilution are important factors for reducing mining costs. In this study, the fuzzy set theory and multiple regression models with parameters, including variation in seam thickness, dip of seam, seam thickness, depth of seam, and hydraulic radius as inputs to the models were applied to pre- dict the OSD in the longwall coal panels. Field data obtained from Kerman and Tabas coal mines, lran were used to develop and validate the models. Three indices including coefficient of determination (R2), root mean square error (RMSE) and variance account for (VAF) were used to evaluate the perfor- mance of the models. With 10 randomly selected datasets, for the linear, polynomial, power, exponential, and fuzzy logic models, R2, RSME and VAF are equal to (0.85, 4.4, 84.4), (0.61, 7.5, 59.6), (0.84, 4.5, 72.7), (0.80, 4.1, 79.6), and (0.97, 2.1, 95.7), respectively. The obtained results indicate that the fuzzy logic model predictor with R2 = 0.97, RMSE = 2.1, and VAF = 95.7 performs better than the other models. 展开更多
关键词 Out-of-seam dilutionLongwall coal miningRegression modelingFuzzy set theoryKerman and tabas coal mines
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4-(2,4,6-三硝基苯胺基)苯甲酸(TABA)的新型铅配合物:制备、晶体结构及热分解性质
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作者 唐望 常佩 +5 位作者 郑晓东 李洪丽 秦明娜 姜俊 黄晓川 邱少君 《含能材料》 EI CAS CSCD 北大核心 2016年第5期444-450,共7页
以4-(2,4,6-三硝基苯胺基)苯甲酸(TABA)为配体,采用溶剂挥发法合成出了一种新型铅配合物:{[PbL2(DMF)H2O]·2(DMF)H2O}n(1)(L=4-(2,4,6-三硝基苯胺基)苯甲酸根,DMF=N,N-二甲基甲酰胺)。用X-射线单晶衍射仪测定了它的单晶结构。用TG-... 以4-(2,4,6-三硝基苯胺基)苯甲酸(TABA)为配体,采用溶剂挥发法合成出了一种新型铅配合物:{[PbL2(DMF)H2O]·2(DMF)H2O}n(1)(L=4-(2,4,6-三硝基苯胺基)苯甲酸根,DMF=N,N-二甲基甲酰胺)。用X-射线单晶衍射仪测定了它的单晶结构。用TG-DSC测定了其热分解过程。在不同升温速率下测试了配合物1与RDX(质量比1∶1)混合物的DSC曲线。计算了该混合物热分解反应的动力学参数。结果表明,该配合物属于单斜晶系,P2(1)/c空间群,晶体参数为:a=6.900(2),b=19.162(6),c=34.866(11),β=94.261(4)°,V=4597(3)~3,Z=4。以Pb(Ⅱ)为桥联离子与4-(2,4,6-三硝基苯胺基)苯甲酸根配位形成一维配位聚合物链。配合物1的热分解主要经历四个阶段。第一阶段发生在58~84℃,主要失去结晶态、配位态水分子及部分结晶状态的DMF。第二阶段为84~231℃,主要是剩余DMF分子的失去。231~320℃和320~415℃为第三和第四阶段,主要是有机含能配体TABA^(2-)的放热分解,在296℃及335℃出现放热峰。配合物1可促进了RDX的热分解。 展开更多
关键词 配合物 燃烧催化剂 X-射线单晶衍射 4-(2 4 6-三硝基苯胺基)苯甲酸(TABA) 热分析
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