A green synthetic method using mixted solvents of di-methyl formamide(DMF)and acids instead of single DMF to synthesize metalloporphyrins(TRPPMCl)from TRPPH_(2) and MCl_(2) metallization was proposed in this paper.A s...A green synthetic method using mixted solvents of di-methyl formamide(DMF)and acids instead of single DMF to synthesize metalloporphyrins(TRPPMCl)from TRPPH_(2) and MCl_(2) metallization was proposed in this paper.A series of TRPPMCl(M=Fe,Mn,Co)were synthesized through this innovative synthetic method,and these complexes were characterized with various spectroscopic techniques,includingIR and UV-Vis spectroscopy.The results showed that the metallization time was markedly reduced from about 10h to 0.5h in contrast with the conventional synthetic methods.展开更多
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.20776003,20576005)the Key Project of Natural Science Foundation of Beijing(No.2061001).
文摘A green synthetic method using mixted solvents of di-methyl formamide(DMF)and acids instead of single DMF to synthesize metalloporphyrins(TRPPMCl)from TRPPH_(2) and MCl_(2) metallization was proposed in this paper.A series of TRPPMCl(M=Fe,Mn,Co)were synthesized through this innovative synthetic method,and these complexes were characterized with various spectroscopic techniques,includingIR and UV-Vis spectroscopy.The results showed that the metallization time was markedly reduced from about 10h to 0.5h in contrast with the conventional synthetic methods.
