The chemically induced dynamic electron polarization (CIDEP) of photolyzed benzophenone radicals in the microheterogeneous phase systems has been made by using the time-resolved electron spin resonance (TRESR) spectro...The chemically induced dynamic electron polarization (CIDEP) of photolyzed benzophenone radicals in the microheterogeneous phase systems has been made by using the time-resolved electron spin resonance (TRESR) spectrometer. In the AEO9/isoproanol/H2O/C8H18 liquid crystal system, the TRESR sptrtrum of Ph2COH shows an unusual CIDEP of spin correlation radical pair (SCRP). The SCRP formation in these systems resulting from the character microenvironment and the related physical chemistry property are discussed.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 29373110)the Key Laboratory of Photographic Chemistry, Chinese Academy of Sciences
文摘The chemically induced dynamic electron polarization (CIDEP) of photolyzed benzophenone radicals in the microheterogeneous phase systems has been made by using the time-resolved electron spin resonance (TRESR) spectrometer. In the AEO9/isoproanol/H2O/C8H18 liquid crystal system, the TRESR sptrtrum of Ph2COH shows an unusual CIDEP of spin correlation radical pair (SCRP). The SCRP formation in these systems resulting from the character microenvironment and the related physical chemistry property are discussed.
