The electrochemistry of (TPP)Co in the presence of pyridine was investigated in dichloroethane solution by cyclic voltammetry. With the addition of pyridine to the solution, the reduction peaks of the axial complex co...The electrochemistry of (TPP)Co in the presence of pyridine was investigated in dichloroethane solution by cyclic voltammetry. With the addition of pyridine to the solution, the reduction peaks of the axial complex compounds, (TPP)Co(III)(Py) and (TPP)Co(III)(Py)(2) were observed. It was found that the reduction peak of Co(II)/Co(I) shifted to about -1.20V (SCE) with the increase of added pyridine. The new reduction peak may be attributed to the direct reduction of the axially complex (TPP)Co(II)(Py).展开更多
The 18th APEC Economic Leaders’ Meeting was held in Yokohama,Japan in November 2010.In the outcome document Pathways to a Free Trade Area of the Asia-Pacific,Trans-Pacific Partnership(TPP) was officially cited as a p...The 18th APEC Economic Leaders’ Meeting was held in Yokohama,Japan in November 2010.In the outcome document Pathways to a Free Trade Area of the Asia-Pacific,Trans-Pacific Partnership(TPP) was officially cited as a pathway to implement the concept of the free trade area of the Asia-Pacific(FTAAP).Only展开更多
文摘The electrochemistry of (TPP)Co in the presence of pyridine was investigated in dichloroethane solution by cyclic voltammetry. With the addition of pyridine to the solution, the reduction peaks of the axial complex compounds, (TPP)Co(III)(Py) and (TPP)Co(III)(Py)(2) were observed. It was found that the reduction peak of Co(II)/Co(I) shifted to about -1.20V (SCE) with the increase of added pyridine. The new reduction peak may be attributed to the direct reduction of the axially complex (TPP)Co(II)(Py).
文摘The 18th APEC Economic Leaders’ Meeting was held in Yokohama,Japan in November 2010.In the outcome document Pathways to a Free Trade Area of the Asia-Pacific,Trans-Pacific Partnership(TPP) was officially cited as a pathway to implement the concept of the free trade area of the Asia-Pacific(FTAAP).Only