High catalytic efficiency is a fundamental prerequisite for the industrial adoption of catalytic transformations.However,reactions achieving turnover numbers(TONs)exceeding 10,000 remain rare in photocatalytic areas,w...High catalytic efficiency is a fundamental prerequisite for the industrial adoption of catalytic transformations.However,reactions achieving turnover numbers(TONs)exceeding 10,000 remain rare in photocatalytic areas,which is primarily attributed to insufficient photostability and light-absorption capacity of photocatalysts.Metalloporphyrins,featured by extendedπ-conjugation systems,exhibit distinct advantages including high molar extinction coefficients,long-lived triplet excited states,and exceptional photostability,alongside distinctive Soret and Q absorption bands.展开更多
基金the Natural Science Foundation of China(Nos.22261019,22001101,22401116)the Science Foundation of Jiangxi Province(Nos.20224BAB213007,20224BAB203014,20212BAB203009,20212BAB213027,and 20212BAB213014)support from Jiangxi Provincial Key Laboratory of OrganicF unctional Molecules(No.2024SSY05141).
文摘High catalytic efficiency is a fundamental prerequisite for the industrial adoption of catalytic transformations.However,reactions achieving turnover numbers(TONs)exceeding 10,000 remain rare in photocatalytic areas,which is primarily attributed to insufficient photostability and light-absorption capacity of photocatalysts.Metalloporphyrins,featured by extendedπ-conjugation systems,exhibit distinct advantages including high molar extinction coefficients,long-lived triplet excited states,and exceptional photostability,alongside distinctive Soret and Q absorption bands.
