Understanding the deterioration behaviors and mechanisms of rocks under thermo-hydromechanical(THM)interactions is crucial for mitigating slope instability.In this study,the physicomechanical properties of silty mudst...Understanding the deterioration behaviors and mechanisms of rocks under thermo-hydromechanical(THM)interactions is crucial for mitigating slope instability.In this study,the physicomechanical properties of silty mudstone subjected to THM interactions were investigated by triaxial tests.The underlying micro-mechanisms were revealed using microscopic tests.The triaxial test results indicate that the strength parameters of silty mudstone decrease by 89.50%(deformation modulus),78.15%(peak strength),70.58%(cohesion),and 48.65%(friction angle)under 16 THM cycles,a load of 300 kPa,and alternating between 0℃water immersion and 60℃drying.The SEM test results indicate that the deterioration of silty mudstone strength primarily results from hydrothermal-expansion softening and cracking driven by the TLHM interactions.The specimens manifest shear failure under confining pressure exceeding 140 kPa.Furthermore,a new constitutive model considering hydrothermalexpansion strain and non-linear deformation characteristics was developed.The discrepancy between the experimentally measured peak strength and the damage constitutive model prediction remains below 5%.The proposed model is verified to be in satisfactory agreement with the experimental results.The self-designed THM apparatus overcomes the limitations of traditional investigations,enabling simultaneous consideration of thermal,hydraulic,and mechanical interactions.展开更多
The increase in CO_(2)injectivity and shifting of CO_(2)-absorbing layers in multilayered geological CO_(2)sequestration(GCS)reservoirs in Ordos,China indicate significantpermeability variations in certain layers.To c...The increase in CO_(2)injectivity and shifting of CO_(2)-absorbing layers in multilayered geological CO_(2)sequestration(GCS)reservoirs in Ordos,China indicate significantpermeability variations in certain layers.To capture these system changes,a numerical model incorporating all 21 aquifers and internal aquitards was developed.The monitored pressure was well matched through multiphase and thermalhydraulic-mechanical(THM)coupling numerical simulations by introducing permeability variations.The results revealed that the permeability in the second layer increased on approximately day 13 due to the abrupt pressure buildup and temperature decrease.Even such a low rate of CO_(2)(2.8 kg/s)injected into the low permeability system initiated some fractures and the permeability in the second layer around the wellbore increased by 722 times.The second critical system change occurred on approximately day 386.As demonstrated in the numerical simulation,the substantial injection of cold CO_(2)induced strong thermal stress,leading to rock contraction and the initiation of several cracks.The permeability of the firstlayer around the wellbore unexpectedly increased by 4 orders of magnitude.Since no additional pressure could drive the CO_(2)into the remaining 17 layers,the total storage capability of the multilayered system was reduced.A whole picture of the system variation is fully presented and the underlying mechanisms are analyzed.It is believed that the phenomenon of thermal-hydraulic fracturing observed in this fieldand the simulation procedures will benefitother fluidinjection and production works in various geotechnical settings.展开更多
Disinfection of swimming pool water is critical to ensure the safety of the recreational activity for swimmers.However,swimming pools have a constant loading of organic matter from input water and anthropogenic contam...Disinfection of swimming pool water is critical to ensure the safety of the recreational activity for swimmers.However,swimming pools have a constant loading of organic matter from input water and anthropogenic contamination,leading to elevated levels of disinfection byproducts(DBPs).Epidemiological studies have associated increased risks of adverse health effects with frequent exposure to DBPs in swimming pools.Zhang et al.(2023b)investigated the occurrence of trihalomethanes(THMs),haloacetic acids(HAAs),haloacetonitriles(HANs),and haloacetaldehydes(HALs)in eight swimming pools and the corresponding input water in a city in Eastern China.The concentrations of THMs,HAAs,HANs,and HALs in swimming poolswere 1–2 orders of magnitude higher than those detected in the input water.The total lifetime cancer and non-cancer health risks of swimmers through oral,dermal,inhalation,buccal,and aural exposure pathways were assessed using the United States Environmental Protection Agency’s(USEPA)standard model and Swimmer Exposure Assessment Model(SWIMODEL).The results showed that dermal and inhalation pathways were the most significant for the associated cancer and non-cancer risks.This article provides an overview and perspectives of DBPs in swimming pools,the benefits of swimming,the need to improve the monitoring of DBPs,and the importance of swimmers’hygiene practices to keep swimming pools clean.The benefits of swimming outweigh the risks from DBP exposure for the promotion of public health.展开更多
The utilization of coalbed methane(CBM)cannot only alleviate the energy crisis,but also reduce greenhouse gas emissions.Gas injection is an effective method to enhance CBM recovery.Compared to single-gas injection,the...The utilization of coalbed methane(CBM)cannot only alleviate the energy crisis,but also reduce greenhouse gas emissions.Gas injection is an effective method to enhance CBM recovery.Compared to single-gas injection,the injection of CO_(2)/N_(2) mixtures can balance the sharp decline in permeability caused by pure CO_(2) and the premature breakthrough by pure N_(2).In this study,a more comprehensive thermo-hydro-mechanical(THM)coupled mathematical model was developed,incorporating processes such as ternary gas non-isothermal adsorption,gas dissolution in water,gas-water two-phase flow,energy exchange,and coal deformation.After experimental validation,the model was applied to simulate the entire process of gas mixtures for enhanced CBM recovery(GM-ECBM).Results indicate that the permeability near the production well(Pw)initially decreases due to increased effective stress,then increases as a result of CH_(4) desorption.Near the injection well(Iw),the permeability first increases due to reduced effective stress and later stabilizes under the combined effects of effective stress and CO_(2)/N_(2) adsorption.The initial CH_(4) pressure and coal seam permeability have the most significant impact on CH_(4) production,while the coal seam permeability and temperature significantly affect CO_(2)/N_(2) injection.As the coal seam permeability increases,the optimal CO_(2)/N_(2) ratio also increases accordingly.These findings provide important theoretical guidance for improving GM-ECBM efficiency in coal seams with varying permeabilities.展开更多
This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening aft...This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening after peak strength, anisotropy of stiffness and strength, as well as permeability variation due to damage. In addition, the mechanical properties are coupled with thermal phenomena and accumulated plastic strains. The adopted nonlocal and viscoplastic approaches enhance numerical efficiency and provide the possibility to simulate localization phenomena. The model is validated against experimental data from laboratory tests conducted on Callovo-Oxfordian (COx) claystone samples that are initially unsaturated and under suction. The tests include a thermal phase where the COx specimens are subjected to different temperature increases. A good agreement with experimental data is obtained. In addition, parametric analyses are carried out to investigate the influence of the hydraulic boundary conditions (B.C.) and post-failure behavior models on the THM behavior evolution. It is shown that different drainage conditions affect the thermally induced pore pressures that, in turn, influence the onset of softening. The constitutive model presented constitutes a promising approach for simulating the most important features of the THM behavior of clay rocks. It is a tool with a high potential for application to several relevant case studies, such as thermal fracturing analysis of nuclear waste disposal systems.展开更多
基金supported by“the National Natural Science Foundation of China(52378440,52078067,52078066,42477143,52408458)the Key Science and Technology Program in the Transportation Industry(2022-MS1-032,2022-MS5-125)+4 种基金the Natural Science Foundation of Hunan Province(2023JJ10045)the Outstanding Innovative Youth Training Program of Changsha City(kq2305023)Scientific Research Foundation of Hunan Provincial Education Department(24B0292)Water Resources Science and Technology Project of Hunan Province(XSKJ2023059-41)the Guangxi Key Research and Development Program(AB23075184)。
文摘Understanding the deterioration behaviors and mechanisms of rocks under thermo-hydromechanical(THM)interactions is crucial for mitigating slope instability.In this study,the physicomechanical properties of silty mudstone subjected to THM interactions were investigated by triaxial tests.The underlying micro-mechanisms were revealed using microscopic tests.The triaxial test results indicate that the strength parameters of silty mudstone decrease by 89.50%(deformation modulus),78.15%(peak strength),70.58%(cohesion),and 48.65%(friction angle)under 16 THM cycles,a load of 300 kPa,and alternating between 0℃water immersion and 60℃drying.The SEM test results indicate that the deterioration of silty mudstone strength primarily results from hydrothermal-expansion softening and cracking driven by the TLHM interactions.The specimens manifest shear failure under confining pressure exceeding 140 kPa.Furthermore,a new constitutive model considering hydrothermalexpansion strain and non-linear deformation characteristics was developed.The discrepancy between the experimentally measured peak strength and the damage constitutive model prediction remains below 5%.The proposed model is verified to be in satisfactory agreement with the experimental results.The self-designed THM apparatus overcomes the limitations of traditional investigations,enabling simultaneous consideration of thermal,hydraulic,and mechanical interactions.
基金supports from the National Natural Science Foundation of China(Grant Nos.52179095,52378323,and 42407216)are gratefully acknowledged.
文摘The increase in CO_(2)injectivity and shifting of CO_(2)-absorbing layers in multilayered geological CO_(2)sequestration(GCS)reservoirs in Ordos,China indicate significantpermeability variations in certain layers.To capture these system changes,a numerical model incorporating all 21 aquifers and internal aquitards was developed.The monitored pressure was well matched through multiphase and thermalhydraulic-mechanical(THM)coupling numerical simulations by introducing permeability variations.The results revealed that the permeability in the second layer increased on approximately day 13 due to the abrupt pressure buildup and temperature decrease.Even such a low rate of CO_(2)(2.8 kg/s)injected into the low permeability system initiated some fractures and the permeability in the second layer around the wellbore increased by 722 times.The second critical system change occurred on approximately day 386.As demonstrated in the numerical simulation,the substantial injection of cold CO_(2)induced strong thermal stress,leading to rock contraction and the initiation of several cracks.The permeability of the firstlayer around the wellbore unexpectedly increased by 4 orders of magnitude.Since no additional pressure could drive the CO_(2)into the remaining 17 layers,the total storage capability of the multilayered system was reduced.A whole picture of the system variation is fully presented and the underlying mechanisms are analyzed.It is believed that the phenomenon of thermal-hydraulic fracturing observed in this fieldand the simulation procedures will benefitother fluidinjection and production works in various geotechnical settings.
文摘Disinfection of swimming pool water is critical to ensure the safety of the recreational activity for swimmers.However,swimming pools have a constant loading of organic matter from input water and anthropogenic contamination,leading to elevated levels of disinfection byproducts(DBPs).Epidemiological studies have associated increased risks of adverse health effects with frequent exposure to DBPs in swimming pools.Zhang et al.(2023b)investigated the occurrence of trihalomethanes(THMs),haloacetic acids(HAAs),haloacetonitriles(HANs),and haloacetaldehydes(HALs)in eight swimming pools and the corresponding input water in a city in Eastern China.The concentrations of THMs,HAAs,HANs,and HALs in swimming poolswere 1–2 orders of magnitude higher than those detected in the input water.The total lifetime cancer and non-cancer health risks of swimmers through oral,dermal,inhalation,buccal,and aural exposure pathways were assessed using the United States Environmental Protection Agency’s(USEPA)standard model and Swimmer Exposure Assessment Model(SWIMODEL).The results showed that dermal and inhalation pathways were the most significant for the associated cancer and non-cancer risks.This article provides an overview and perspectives of DBPs in swimming pools,the benefits of swimming,the need to improve the monitoring of DBPs,and the importance of swimmers’hygiene practices to keep swimming pools clean.The benefits of swimming outweigh the risks from DBP exposure for the promotion of public health.
基金supported by the National Natural Science Foundation of China(Grant No.52174117)the Universitylocal Government Scientific and Technical Cooperation Cultivation Project of Ordos Institute-LNTU(Grant No.YJY-XD-2024-A-009)+2 种基金the Basic Scientific Research Project of Liaoning Provincial Department of Education(Grant No.JYTZD2023073)the Liaoning Revitalization Talents Program(XLYC2203139)the Liaoning Provincial Natural Science Foundation Program(Excellent Youth Fund)(Grant No.2024JH3/10200043).
文摘The utilization of coalbed methane(CBM)cannot only alleviate the energy crisis,but also reduce greenhouse gas emissions.Gas injection is an effective method to enhance CBM recovery.Compared to single-gas injection,the injection of CO_(2)/N_(2) mixtures can balance the sharp decline in permeability caused by pure CO_(2) and the premature breakthrough by pure N_(2).In this study,a more comprehensive thermo-hydro-mechanical(THM)coupled mathematical model was developed,incorporating processes such as ternary gas non-isothermal adsorption,gas dissolution in water,gas-water two-phase flow,energy exchange,and coal deformation.After experimental validation,the model was applied to simulate the entire process of gas mixtures for enhanced CBM recovery(GM-ECBM).Results indicate that the permeability near the production well(Pw)initially decreases due to increased effective stress,then increases as a result of CH_(4) desorption.Near the injection well(Iw),the permeability first increases due to reduced effective stress and later stabilizes under the combined effects of effective stress and CO_(2)/N_(2) adsorption.The initial CH_(4) pressure and coal seam permeability have the most significant impact on CH_(4) production,while the coal seam permeability and temperature significantly affect CO_(2)/N_(2) injection.As the coal seam permeability increases,the optimal CO_(2)/N_(2) ratio also increases accordingly.These findings provide important theoretical guidance for improving GM-ECBM efficiency in coal seams with varying permeabilities.
基金funded by the European Union's Horizon 2020 research and innovation programme under a grant agreement (Grant No.847593)partially supported by the Fundamental Research Funds for the Central Universities (Grant No.22120240029).
文摘This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening after peak strength, anisotropy of stiffness and strength, as well as permeability variation due to damage. In addition, the mechanical properties are coupled with thermal phenomena and accumulated plastic strains. The adopted nonlocal and viscoplastic approaches enhance numerical efficiency and provide the possibility to simulate localization phenomena. The model is validated against experimental data from laboratory tests conducted on Callovo-Oxfordian (COx) claystone samples that are initially unsaturated and under suction. The tests include a thermal phase where the COx specimens are subjected to different temperature increases. A good agreement with experimental data is obtained. In addition, parametric analyses are carried out to investigate the influence of the hydraulic boundary conditions (B.C.) and post-failure behavior models on the THM behavior evolution. It is shown that different drainage conditions affect the thermally induced pore pressures that, in turn, influence the onset of softening. The constitutive model presented constitutes a promising approach for simulating the most important features of the THM behavior of clay rocks. It is a tool with a high potential for application to several relevant case studies, such as thermal fracturing analysis of nuclear waste disposal systems.
