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高氮化合物4,4′,6,6′-四叠氮基偶氮-1,3,5-三嗪的合成研究 被引量:6
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作者 李小童 庞思平 +1 位作者 于永忠 罗运军 《含能材料》 EI CAS CSCD 2007年第5期485-489,共5页
以2,4,6-三氯-1,3,5-三嗪和水合肼为起始原料,经偶联、肼解、重氮化、氧化等反应合成4,4,′6,6′-四叠氮基偶氮-1,3,5-三嗪(TAAT)。采用DSC、IR、NMR、元素分析等对TAAT和中间产物进行了分析和表征,确定了它们的结构。DSC分析发现TAAT在... 以2,4,6-三氯-1,3,5-三嗪和水合肼为起始原料,经偶联、肼解、重氮化、氧化等反应合成4,4,′6,6′-四叠氮基偶氮-1,3,5-三嗪(TAAT)。采用DSC、IR、NMR、元素分析等对TAAT和中间产物进行了分析和表征,确定了它们的结构。DSC分析发现TAAT在198℃分解。研究表明采用氯气作氧化剂,在两相条件下进行反应可以94%的收率得到TAAT。而N-溴代丁二酰亚胺(NBS)作氧化剂收率仅为84%。提出了氧化反应的反应机理并推测了具体的反应历程。 展开更多
关键词 有机化学 高氮化合物 4 4 ′6 6′-四叠氮基偶氮-1 3 5-三嗪(taat) 反应机理
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以4,4′,6,6′-四叠氮基偶氮-1,3,5-三嗪为前体热解制备氮化碳纳米材料
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作者 马巧丽 于艺 +1 位作者 张雪娇 庞思平 《火炸药学报》 EI CAS CSCD 北大核心 2012年第1期46-51,共6页
通过改进的合成方法制备4,4′,6,6′-四叠氮基偶氮-1,3,5-三嗪(TAAT),总产率为82.1%。采用DSC、IR、NMR、元素分析等对TAAT和中间产物进行了表征,并对其单晶结构进行了分析。以TAAT为前体,采用热解法制备出碳氮比非常接近理论值的C2N3和... 通过改进的合成方法制备4,4′,6,6′-四叠氮基偶氮-1,3,5-三嗪(TAAT),总产率为82.1%。采用DSC、IR、NMR、元素分析等对TAAT和中间产物进行了表征,并对其单晶结构进行了分析。以TAAT为前体,采用热解法制备出碳氮比非常接近理论值的C2N3和C3N5氮化碳纳米材料。推测出TAAT可能的热解过程及C2N3、C3N5氮化碳纳米材料的生成机理。 展开更多
关键词 材料科学 4 4′ 6 6′-四叠氮基偶氮-1 3 5-三嗪(taat) 热解法 氮化碳 合成
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Numerical Simulation of the Tip Aerodynamics and Acoustics Test
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作者 F Tejero E P Doerffer +1 位作者 O Szulc J L Cross 《Journal of Thermal Science》 SCIE EI CAS CSCD 2016年第2期153-160,共8页
The application of an efficient flow control system on helicopter rotor blades may lead to improved aerodynamic performance. Recently, our invention of Rod Vortex Generators(RVGs) has been analyzed for helicopter roto... The application of an efficient flow control system on helicopter rotor blades may lead to improved aerodynamic performance. Recently, our invention of Rod Vortex Generators(RVGs) has been analyzed for helicopter rotor blades in hover with success. As a step forward, the study has been extended to forward flight conditions. For this reason, a validation of the numerical modelling for a reference helicopter rotor(without flow control) is needed. The article presents a study of the flow-field of the AH-1G helicopter rotor in low-, medium- and high-speed forward flight. The CFD code FLOWer from DLR has proven to be a suitable tool for the aerodynamic analysis of the two-bladed rotor without any artificial wake modelling. It solves the URANS equations with LEA(Linear Explicit Algebraic stress) k-ω model using the chimera overlapping grids technique. Validation of the numerical model uses comparison with the detailed flight test data gathered by Cross J. L. and Watts M. E. during the Tip Aerodynamics and Acoustics Test(TAAT) conducted at NASA in 1981. Satisfactory agreements for all speed regimes and a presence of significant flow separation in high-speed forward flight suggest a possible benefit from the future implementation of RVGs. The numerical results based on the URANS approach are presented not only for a popular, low-speed case commonly used in rotorcraft community for CFD codes validation but preferably for medium- and high-speed test conditions that have not been published to date. 展开更多
关键词 AH-1G taat helicopter rotor forward flight chimera overlapping grid
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