针对装配式钢筋模板一体化(Integration of reinforcement and framework,IRF)体系采用硫铝酸盐水泥存在成本高、性能调控难度大等问题,基于最紧密堆积理论设计了满足装配式IRF体系性能要求的P·Ⅱ水泥砂浆配合比,研究了该砂浆在不...针对装配式钢筋模板一体化(Integration of reinforcement and framework,IRF)体系采用硫铝酸盐水泥存在成本高、性能调控难度大等问题,基于最紧密堆积理论设计了满足装配式IRF体系性能要求的P·Ⅱ水泥砂浆配合比,研究了该砂浆在不同CO_(2)养护温度(40℃、60℃)和养护压强(0.3、0.5、0.8 MPa)下的力学性能、水化热、水化产物和孔结构的变化规律,并与60℃、常压蒸汽养护组进行了对比。结果表明:60℃下,与蒸汽养护相比,CO_(2)养护有效促进了砂浆早期抗压强度发展,建议CO_(2)养护压强为0.5 MPa;CO_(2)养护延长了胶凝材料的水化诱导期,降低了水化放热速率峰值和24 h水化放热量;养护压强对胶凝材料水化动力学的影响不显著;用适量辅助胶凝材料替代水泥细化了硬化水泥浆体的孔结构,且碳减排效果显著。展开更多
A highly efficient and environmentally benign protocol for the synthesis of 2-amino-5,7-dimethoxy-4- aryl/alkyl-4H-chromene-3-carbonitrile derivatives by one-pot three-component coupling reacting of aromatic aldehydes...A highly efficient and environmentally benign protocol for the synthesis of 2-amino-5,7-dimethoxy-4- aryl/alkyl-4H-chromene-3-carbonitrile derivatives by one-pot three-component coupling reacting of aromatic aldehydes, malononitrile and 3,5-dimethoxy phenol under reflux condition has been developed in aqueous EtOH media using Na2O-Al2O3-P2O5 glass-ceramic system.展开更多
文摘针对装配式钢筋模板一体化(Integration of reinforcement and framework,IRF)体系采用硫铝酸盐水泥存在成本高、性能调控难度大等问题,基于最紧密堆积理论设计了满足装配式IRF体系性能要求的P·Ⅱ水泥砂浆配合比,研究了该砂浆在不同CO_(2)养护温度(40℃、60℃)和养护压强(0.3、0.5、0.8 MPa)下的力学性能、水化热、水化产物和孔结构的变化规律,并与60℃、常压蒸汽养护组进行了对比。结果表明:60℃下,与蒸汽养护相比,CO_(2)养护有效促进了砂浆早期抗压强度发展,建议CO_(2)养护压强为0.5 MPa;CO_(2)养护延长了胶凝材料的水化诱导期,降低了水化放热速率峰值和24 h水化放热量;养护压强对胶凝材料水化动力学的影响不显著;用适量辅助胶凝材料替代水泥细化了硬化水泥浆体的孔结构,且碳减排效果显著。
基金the Najafabad Branch,Islamic Azad University for financial support of this research
文摘A highly efficient and environmentally benign protocol for the synthesis of 2-amino-5,7-dimethoxy-4- aryl/alkyl-4H-chromene-3-carbonitrile derivatives by one-pot three-component coupling reacting of aromatic aldehydes, malononitrile and 3,5-dimethoxy phenol under reflux condition has been developed in aqueous EtOH media using Na2O-Al2O3-P2O5 glass-ceramic system.
