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A novel symmetrical SOFC with thin BZCY electrolyte and PBFNCM-BZCY electrodes for electricity and ethylene co-production through ethane dehydrogenation
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作者 Jun Luo Yan-Dong Ke +6 位作者 Qi-Yue Li Ying-Fa Tian Bing-Hai Dong Dong Yan Jian Li Oi-Lun Li Li-Chao Jia 《Rare Metals》 2025年第9期6175-6184,共10页
Ethylene(C_(2)H_(4))is conventionally produced by a high energy-consumption process based on the steam cracking of ethane(C_(2)H_(6)).In contrast,we presented a novel symmetrical solid oxide fuel cell(SOFC)to coproduc... Ethylene(C_(2)H_(4))is conventionally produced by a high energy-consumption process based on the steam cracking of ethane(C_(2)H_(6)).In contrast,we presented a novel symmetrical solid oxide fuel cell(SOFC)to coproduce electricity and C_(2)H_(4)through C_(2)H_(6)dehydrogenation.The symmetrical cell contains a thin Ba Zr_(0.1)Ce_(0.7)Y_(0.2)O_(3)(BZCY)electrolyte sandwiched between two thicker(PrBa)_(0.95)(Fe_(0.7)Ni_(0.2)Cu_(0.1))_(1.8)Mo_(0.2)O_(6-δ)impregnated BZCY(PBFNCM-BZCY)electrodes.The as-synthesized reduced-PBFNCM(R-PBFNCM)contained Fe-Ni-Cu alloy particles embedded on a double-perovskite matrix uniformly,while the electrode showed high oxygen vacancy concentration,electronic conductivity,redox stability,and activity for C_(2)H_(6)dehydrogenation with improved ethylene selectivity.The symmetrical cell demonstrated a peak power density of 409 mW cm^(-2)using C_(2)H_(6)as fuel,accompanying with a C_(2)H_(6)conversion of 51.2%,a C_(2)H_(4)selectivity of 92.5%,and a C_(2)H_(4)yield of 47.4%at 750℃and 750 mA cm^(-2).Despite carbon deposition occurred slowly in the anode,the deposited carbon was removed by simply switching C_(2)H_(6)and air between electrodes.Consequently,the cell voltage and C_(2)H_(4)yield recover by 91.4%and 98.1%,respectively,after three switches with an interval of 48 h,suggesting that the symmetrical SOFC is a promising solution for long-term continuous electricity and C_(2)H_(4)co-production by C_(2)H_(6)dehydrogenation. 展开更多
关键词 symmetrical solid oxide fuel cells C_(2)H_(6)dehydrogenation (PrBa)_(0.95)(Fe_(0.7)Ni_(0.2)Cu_(0.1))_(1.8)Mo_(0.2)O_(6-δ) BaZr_(0.1)Ce_(0.7)Y_(0.2)O_(3) Power-C_(2)H_(4)co-production
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A 2.4GHz CMOS Quadrature Voltage-Controlled Oscillator Based on Symmetrical Spiral Inductors and Differential Diodes 被引量:2
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作者 池保勇 石秉学 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2002年第2期131-135,共5页
A voltage controlled oscillator (VCO) which can generate 2 4GHz quadrature local oscillating (LO) signals is reported.It combines a LC VCO,realized by on chip symmetrical spiral inductors and differential diodes,an... A voltage controlled oscillator (VCO) which can generate 2 4GHz quadrature local oscillating (LO) signals is reported.It combines a LC VCO,realized by on chip symmetrical spiral inductors and differential diodes,and a two stage ring VCO.The principle of this VCO is demonstrated and further the phase noise is discussed in detail.The fabrication of prototype is demonstrated using 0 25μm single poly five metal N well salicide CMOS digital process.The reports show that the novel VCO is can generate quadrature LO signals with a tuning range of more than 300MHz as well as the phase noise--104 33dBc/Hz at 600KHz offset at 2 41GHz (when measuring only one port of differential outputs).In addition,this VCO can work in low power supply voltage and dissipate low power,thus it can be used in many integrated transceivers. 展开更多
关键词 quadrature VCO symmetrical spiral inductors differential diodes
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ANALYTICAL SOLUTION OF AXIAL SYMMETRICAL WALL TEMPERATURE DISTRIBUTION FOR HOLLOW CYLINDER 被引量:1
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作者 尹华杰 秦建昭 +1 位作者 贾湖 邓胜林 《Transactions of Tianjin University》 EI CAS 2001年第4期268-272,共5页
Using the variable transformation method,the formulae of the axial symmetrical wall temperature distribution during steady heat conduction of a hollow cylinder are derived in this paper.The wall temperature distributi... Using the variable transformation method,the formulae of the axial symmetrical wall temperature distribution during steady heat conduction of a hollow cylinder are derived in this paper.The wall temperature distribution and the wall heat flux distribution in both axial and radial direction can be calculated by the temperature distribution of the liquid medium both inside and outside the cylinder with temperature changing in axial direction.The calculation results are almost consistent with the experience results.The applicative condition of the formulae in this paper consists with most of practice.They can be applied to the engineering calculation of the steady heat conduction.The calculation is simple and accurate. 展开更多
关键词 hollow cylinder shell axial symmetrical problem in space steady heat conduction analytical solution.
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A 4.8GHz CMOS Fully Integrated LC Balanced Oscillator with Symmetrical Noise Filter Technique and Large Tuning Range
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作者 杨丰林 张钊锋 +1 位作者 李宝骐 闵昊 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第3期448-454,共7页
This paper presents a fully integrated 4 8GHz VCO with an invention——symmetrical noise filter technique.This VCO,with relatively low phase noise and large tuning range of 716MHz,is fabricated with the 0 25μm SMIC... This paper presents a fully integrated 4 8GHz VCO with an invention——symmetrical noise filter technique.This VCO,with relatively low phase noise and large tuning range of 716MHz,is fabricated with the 0 25μm SMIC CMOS process.The oscillator consumes 6mA from 2 5V supply.Another conventional VCO is also designed and simulated without symmetrical noise filter on the same process,which also consumes 6mA current and is with the same tuning.Simulation result describes that the first VCO’ phase noise is 6dBc/Hz better than the latter’s at the same offset frequency from 4 8GHz.Measured phase noise at 1MHz away from the carrier in this 4 8GHz VCO with symmetrical noise filter is -123 66dBc/Hz.This design is suitable for the usage in a phase locked loop and other consumer electronics.It is amenable for future technologies and allows easy porting to different CMOS manufacturing process. 展开更多
关键词 VCO symmetrical noise filter radio frequency INDUCTOR switch capacitor
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Coordinated Rotor-Side Control Strategy for Doubly-FedWind Turbine under Symmetrical and Asymmetrical Grid Faults
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作者 Quanchun Yan Chao Yuan +2 位作者 WenGu Yanan Liu Yiming Tang 《Energy Engineering》 EI 2023年第1期49-68,共20页
In order to solve the problems of rotor overvoltage,overcurrent and DC side voltage rise caused by grid voltage drops,a coordinated control strategy based on symmetrical and asymmetrical low voltage ride through of ro... In order to solve the problems of rotor overvoltage,overcurrent and DC side voltage rise caused by grid voltage drops,a coordinated control strategy based on symmetrical and asymmetrical low voltage ride through of rotor side converter of the doubly-fed generator is proposed.When the power grid voltage drops symmetrically,the generator approximate equation under steady-state conditions is no longer applicable.Considering the dynamic process of stator current excitation,according to the change of stator flux and the depth of voltage drop,the system can dynamically provide reactive power support for parallel nodes and suppress the rise of DC side voltage and rotor over-current.When the grid voltage drops asymmetrically,the positive and negative sequence components are separated in the rotating coordinate system.The doubly fed generator model is established to suppress the rotor positive sequence current and negative sequence current respectively.At the same time,the output voltage limit of the converter is discussed,and the reference value is adjusted within the allowable output voltage range.In order to adapt to the occurrence of different types of power grid faults and complex operating conditions,a fast switching module of fault type detection and rotor control mode is designed to detect the type of power grid faults and voltage drop depth in real time and switch the rotor side control mode dynamically.Finally,the simulation model of the doubly fed wind turbine is constructed in Matlab/Simulink.The simulation results verify that the proposed control strategy can improve the low-voltage ride through performance of the system when dealing with the symmetrical and asymmetric voltage drop of the power grid and identify the power grid fault type and provide the correct control strategy. 展开更多
关键词 Doubly-fed wind turbines symmetrical faults asymmetrical faults low voltage ride through rotor side control fault type detection
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Power Network Asymmetrical Faults Analysis Using Instantaneous Symmetrical Components
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作者 S. LEVA 《Journal of Electromagnetic Analysis and Applications》 2009年第4期205-213,共9页
Although the application of Symmetrical Components to time-dependent variables was introduced by Lyon in 1954, for many years its application was essentially restricted to electric machines. Recently, thanks to its ad... Although the application of Symmetrical Components to time-dependent variables was introduced by Lyon in 1954, for many years its application was essentially restricted to electric machines. Recently, thanks to its advantages, the Lyon transformation is also applied to power network calculation. In this paper, time-dependent symmetrical components are used to study the dynamic analysis of asymmetrical faults in a power system. The Lyon approach allows the calculation of the maximum values of overvoltages and overcurrents under transient conditions and to study network under non-sinusoidal conditions. Finally, some examples with longitudinal asymmetrical faults are illustrated. 展开更多
关键词 POWER System FAULT Analysis Asymmetrical FAULTS symmetrical COMPONENTS Lyon TRANSFORMATION
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Vehicle detection based on information fusion of vehicle symmetrical contour and license plate position 被引量:1
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作者 连捷 赵池航 +2 位作者 张百灵 何杰 党倩 《Journal of Southeast University(English Edition)》 EI CAS 2012年第2期240-244,共5页
An efficient vehicle detection approach is proposed for traffic surveillance images, which is based on information fusion of vehicle symmetrical contour and license plate position. The vertical symmetry axis of the ve... An efficient vehicle detection approach is proposed for traffic surveillance images, which is based on information fusion of vehicle symmetrical contour and license plate position. The vertical symmetry axis of the vehicle contour in an image is. first detected, and then the vertical and the horizontal symmetry axes of the license plate are detected using the symmetry axis of the vehicle contour as a reference. The vehicle location in an image is determined using license plate symmetry axes and the vertical and the horizontal projection maps of the vehicle edge image. A dataset consisting of 450 images (15 classes of vehicles) is used to test the proposed method. The experimental results indicate that compared with the vehicle contour-based, the license plate location-based, the vehicle texture-based and the Gabor feature-based methods, the proposed method is the best with a detection accuracy of 90.7% and an elapsed time of 125 ms. 展开更多
关键词 vehicle detection symmetrical contour license plate position information fusion
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Ni doped La_(0.6)Sr_(0.4)FeO_(3-δ) symmetrical electrode for solid oxide fuel cells 被引量:1
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作者 马朝晖 孙春文 +3 位作者 马超 吴昊 占忠亮 陈立泉 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2016年第8期1347-1353,共7页
The conventional Ni cermet anode suffers from severe carbon deposition and sulfur poisoning when fossil fuels are used. Alternative anode materials are desired for high performance hydrocarbon fuel solid oxide fuel ce... The conventional Ni cermet anode suffers from severe carbon deposition and sulfur poisoning when fossil fuels are used. Alternative anode materials are desired for high performance hydrocarbon fuel solid oxide fuel cells (SOFCs). We report the rational design of a very active Ni doped La0.6Sr0.4FeO3‐δ(LSFN) electrode for hydrocarbon fuel SOFCs. Homogeneously dispersed Ni‐Fe alloy nanoparticles were in situ extruded onto the surface of the LSFN particles during the operation of the cell. Sym‐metric SOFC single cells were prepared by impregnating a LSFN precursor solution onto a YSZ (yt‐tria stabilized zirconia) monolithic cell with a subsequent heat treatment. The open circuit voltage of the LSFN symmetric cell reached 1.18 and 1.0 V in humidified C3H8 and CH4 at 750??, respective‐ly. The peak power densities of the cells were 400 and 230 mW/cm2 in humidified C3H8 and CH4, respectively. The electrode showed good stability in long term testing, which revealed LSFN has good catalytic activity for hydrocarbon fuel oxidation. 展开更多
关键词 Solid oxide fuel cells Ni dopedLa0.6Sr0.4FeO3-δ symmetrical electrode Hydrocarbon fuels
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Prediction of Symmetrical and Asymmetrical of Diurnal Global Solar Irradiance Distribution—New Approach
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作者 M. K. El-Adawi 《Optics and Photonics Journal》 2019年第2期15-24,共10页
A simple formula to predict the received global solar irradiance q(t), W/m2 for clear days is suggested on pure theoretical basis. It is expressed in terms of the length of the local day time td which is well defined ... A simple formula to predict the received global solar irradiance q(t), W/m2 for clear days is suggested on pure theoretical basis. It is expressed in terms of the length of the local day time td which is well defined in literatures on meteorological basis. The introduced distribution is also a function of the maximum value of the daily received irradiance qmax. which in turn is expressed in term of the solar constant. This renders the trial to be a closed system. Thus the obtained distribution is not a semi empirical one. Both cases of symmetrical and asymmetrical distributions for q(t) are considered. For its simplicity it can be easily integrated along the length of the day to get the daily totals of solar energy received by unit horizontal area. This is important for practical applications. Comparison between computed according to the present model and published experimental meteorological data in Barcelona (Spain), Hong Kong (China), Jeddah and Makkah (Saudi Arabia) is given as illustrative examples. Better fitting relative to the published trials for the same locations are obtained. The introduced model itself gives good fitting for the intermediate intervals points of the local day time which is the more effective region. The estimated relative error is 12% for Hong Kong, and it is 7% for Barcelona, Jeddah and Makah. 展开更多
关键词 GLOBAL SOLAR IRRADIANCE symmetrical and Asymmetrical Distributions PREDICTION Formula SOLAR Constant Comparative Study
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Simulation on Residual Stress of Shot Peening Based on a Symmetrical Cell Model 被引量:12
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作者 Cheng WANG Jiacheng HU +2 位作者 Zhenbiao GU Yangjian XU Xiaogui WANG 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2017年第2期344-351,共8页
The symmetrical cell model is widely used to study the residual stress induced by shot peening. However, the correlation between the predicted residual stresses and the shot peening coverage, which is a big challenge ... The symmetrical cell model is widely used to study the residual stress induced by shot peening. However, the correlation between the predicted residual stresses and the shot peening coverage, which is a big challenge for the researchers of the symmetrical cell model, is still not established. Based on the dynamic stresses and the residual stresses outputted from the symmetrical cell model, the residual stresses corresponding to full coverage are evalu- ated by normal distribution analysis. The predicted nodal dynamic stresses with respect to four corner points indicate that the equi-biaxial stress state exists only for the first shot impact. Along with the increase of shot number, the interactions of multiple shot impacts make the fluctuation of the nodal dynamic stresses about an almost identical value more and more obvious. The mean values and standard deviations of the residual stresses gradually tend to be stable with the increase of the number of shot peening series. The mean values at each corner point are almost the same after the third peening series, which means that an equi-biaxial stress state corresponding to the full coverage of shot peening is achieved. Therefore, the mean values of the nodal residual stresses with respect to a specific transverse cross-section below the peened surface can be used to correlate the measured data by X-ray. The predicted residual stress profile agrees with the experimental results very well under 200% peening coverage. An effective correlation method is proposed for the nodal residual stresses predicted by the symmetrical cell model and the shot peening coverage. 展开更多
关键词 Residual stress symmetrical cell model Equi·biaxial stress state Shot peening coverage Dynamic stress
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Feature Extraction of Symmetrical Triangular LFMCW Signal Using Wigner-Hough Transform 被引量:12
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作者 刘锋 徐会法 +2 位作者 孙大鹏 陶然 王越 《Journal of Beijing Institute of Technology》 EI CAS 2009年第4期478-483,共6页
Feature extraction of symmetrical triangular linear frequency modulation continuous wave (LFM- CW) signal is studied. Combined with its peculiar charaeteristics, a novel algorithm based on Wigner-Hough transform (... Feature extraction of symmetrical triangular linear frequency modulation continuous wave (LFM- CW) signal is studied. Combined with its peculiar charaeteristics, a novel algorithm based on Wigner-Hough transform (WHT) is presented for the deteetion and parameter estimation of this type of waveform. The initial frequency and chirp rate of each segment of this wave are estimated, and the peak-value searching steps in the parameter spaee is given. Compared with Wigner-Ville distribution (WVD), Pseudo-Wigner-Ville distri- bution (PWD) and Smoothed-Peseudo-Wigner-Ville distribution (SPWD), WHT has proven itself to be the best method for feature extraetion of symmetrical triangular LFMCW signal. In the end, Monte-Carlo simulations under different SNRs are earried out, with validating results on this method. 展开更多
关键词 symmetrical triangular LFMCW signal signal detection Wigner-Hough transform (WHT) parameter estimation
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Lie symmetrical perturbation and adiabatic invariants of generalized Hojman type for Lagrange systems 被引量:8
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作者 罗绍凯 陈向炜 郭永新 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第11期3176-3181,共6页
Based on the invariance of differential equations under infinitesimal transformations of group, Lie symmetries, exact invariants, perturbation to the symmetries and adiabatic invariants in form of non-Noether for a La... Based on the invariance of differential equations under infinitesimal transformations of group, Lie symmetries, exact invariants, perturbation to the symmetries and adiabatic invariants in form of non-Noether for a Lagrange system are presented. Firstly, the exact invariants of generalized Hojman type led directly by Lie symmetries for a Lagrange system without perturbations are given. Then, on the basis of the concepts of Lie symmetries and higher order adiabatic invariants of a mechanical system, the perturbation of Lie symmetries for the system with the action of small disturbance is investigated, the adiabatic invariants of generalized Hojman type for the system are directly obtained, the conditions for existence of the adiabatic invariants and their forms are proved. Finally an example is presented to illustrate these results. 展开更多
关键词 Lagrange system Lie symmetrical perturbation exact invariant adiabatic invariant of generalized Hojman type
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Amplitude modulation measurement of symmetrical microwave power sensor
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作者 王德波 廖小平 田涛 《Journal of Southeast University(English Edition)》 EI CAS 2010年第1期68-72,共5页
In order to reduce the mismatch error, a direct current (DC) calibration method is introduced when the modulated microwave signal is measured. The microwave power is input to the left section of the power sensor, an... In order to reduce the mismatch error, a direct current (DC) calibration method is introduced when the modulated microwave signal is measured. The microwave power is input to the left section of the power sensor, and the DC power is input to the right of the power sensor. Due to the existence of parasitic loss and electromagnetic coupling, the microwave power results in a mismatch error. However, the DC power does not have the mismatch error. So the DC power applied in the right section can calibrate the mismatch error of the microwave power in the left section. The calibration factor is measured at different modulation rates and modulation depths.The measurement results show that the carrier frequency is the major factor influencing the measurement results. After calibration, the carrier frequency and the modulation rate have little effect on the output voltage. The frequency response becomes relatively flat in the frequency range up to 20 GHz, and the sensitivity on average is enhanced by about 0.12 mV/dBm. Therefore, the DC calibration method has a certain reference value for the terminal-type microwave power sensor. 展开更多
关键词 amplitude modulation symmetrical power sensor direct current (DC) calibration
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Megascopic Symmetrical Metazoans from the Ediacaran Doushantuo Formation in the Northeastern Guizhou,South China 被引量:7
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作者 王约 王训练 黄禹铭 《Journal of China University of Geosciences》 SCIE CSCD 2008年第3期200-206,共7页
In South China, various megascopic symmetrical metazoan fossils were found in the upper Doushantuo (陡山沱) Formation of the Neoproterozoic Ediacaran. The worm-like fossil is characterized by modern taxological anne... In South China, various megascopic symmetrical metazoan fossils were found in the upper Doushantuo (陡山沱) Formation of the Neoproterozoic Ediacaran. The worm-like fossil is characterized by modern taxological annelid, for many metameres, parapodia, one possible tentale, an alimentary canal, and a dorsal vessel. The triradiate discoidal fossils belong to Trilobozoa, and the octaradiate discoidal fossil might be Ctenophora. All these fossils indicate that the megascopic metazoans have appeared in the Doushantuoian of Eidacaran and imply that the symmetrical metazoans must have originated at least 550 Ma ago. 展开更多
关键词 symmetrical metazoan Doushantuo Formation Neoproterozoic Ediacaran South China.
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Anti-Overturning Fully Symmetrical Triboelectric Nanogenerator Based on an Elliptic Cylindrical Structure for All-Weather Blue Energy Harvesting 被引量:5
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作者 Dujuan Tan Qixuan Zeng +6 位作者 Xue Wang Songlei Yuan Yanlin Luo Xiaofang Zhang Liming Tan Chenguo Hu Guanlin Liu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第7期342-353,共12页
Triboelectric nanogenerators(TENGs) have shown promising potential for large-scale blue energy harvesting. However, the lack of reasonable designs has largely hindered TENG from harvesting energy from both rough and t... Triboelectric nanogenerators(TENGs) have shown promising potential for large-scale blue energy harvesting. However, the lack of reasonable designs has largely hindered TENG from harvesting energy from both rough and tranquil seas. Herein, a fully symmetrical triboelectric nanogenerator based on an elliptical cylindrical structure(EC-TENG) is proposed for all-weather blue energy harvesting. The novel elliptical cylindrical shell provides a unique selfstability, high sensitivity to wave triggering, and most importantly, an anti-overturning capability for the EC-TENG. Moreover, benefiting from its internal symmetrical design, the EC-TENG can produce energy normally, even if it was overturned under a rude oscillation in the rough seas, which distinguishes this work from previous reported TENGs. The working mechanism and output performance are systematically studied. The as-fabricated EC-TENG is capable of lighting 400 light-emitting diodes and driving small electronics. More than that, an automatic monitoring system powered by the EC-TENG can also monitor the water level in real-time and provide an alarm if necessary. This work presents an innovative and reliable approach toward all-weather wave energy harvesting in actual marine environments. 展开更多
关键词 ANTI-OVERTURNING Fully symmetrical Elliptic cylindrical Triboelectric nanogenerator Wave energy
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Recent advances and influencing parameters in developing electrode materials for symmetrical solid oxide fuel cells 被引量:5
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作者 Wan Nor Anasuhah Wan Yusoff Nurul Akidah Baharuddin +3 位作者 Mahendra Rao Somalu Andanastuti Muchtar Nigel P.Brandon Huiqing Fan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第10期1933-1956,共24页
This article delivers a robust overview of potential electrode materials for use in symmetrical solid oxide fuel cells(S-SOFCs),a relatively new SOFC technology.To this end,this article provides a comprehensive review... This article delivers a robust overview of potential electrode materials for use in symmetrical solid oxide fuel cells(S-SOFCs),a relatively new SOFC technology.To this end,this article provides a comprehensive review of recent advances and progress in electrode materials for S-SOFC,discussing both the selection of materials and the challenges that come with making that choice.This article discussed the relevant factors involved in developing electrodes with nano/microstructure.Nanocomposites,e.g.,non-cobalt and lithiated materials,are only a few of the electrode types now being researched.Furthermore,the phase structure and microstructure of the produced materials are heavily influenced by the synthesis procedure.Insights into the possibilities and difficulties of the material are discussed.To achieve the desired microstructural features,this article focuses on a synthesis technique that is either the most recent or a better iteration of an existing process.The portion of this analysis that addresses the risks associated with manufacturing and the challenges posed by materials when fabricating S-SOFCs is the most critical.This article also provides important and useful recommendations for the strategic design of electrode materials researchers. 展开更多
关键词 nano composites ELECTRODE microstructure tailoring OXIDATION symmetrical solid oxide fuel cell
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Cerium and ruthenium co-doped La_(0.7)Sr_(0.3)FeO_(3-δ) as a high-efficiency electrode for symmetrical solid oxide fuel cell 被引量:4
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作者 Junkai Wang Lei Fu +3 位作者 Jiaming Yang Ke Wu Jun Zhou Kai Wu 《Journal of Rare Earths》 SCIE EI CAS CSCD 2021年第9期1095-1099,共5页
Symmetrical solid oxide fuel cells(SSOFCs)could be alternative energy conversion devices due to their simple fabrication process and low cost.Herein,perovskite La_(0.6)Ce_(0.1)Sr_(0.3)Fe_(0.95)Ru_(0.05O3-δ)(LCSFR)was... Symmetrical solid oxide fuel cells(SSOFCs)could be alternative energy conversion devices due to their simple fabrication process and low cost.Herein,perovskite La_(0.6)Ce_(0.1)Sr_(0.3)Fe_(0.95)Ru_(0.05O3-δ)(LCSFR)was synthesized and evaluated as a high-performance electrode for SSOFCs based on the electrolyte of La_(0.9)Sr_(0.1)Ga_(0.8)Mg_(0.2)O_(3-δ)(LSGM).LCSFR retains their stable perovskite crystal structure in both reducing and oxidizing atmospheres,though a minor amount of LaSrFeO4 phase is present under reducing conditions.Morphology investigation shows that homogeneously dispersed Ru metallic nanoparticles are exsolved on the surface of LCSFR after being reduced.The polarization resistance(Rp)of LCSFR-CGO(Ce_(0.9)Gd_(0.1O2-δ))is about 0.11Ω·cm^(2)at 800℃in air,while the value of Rp for LCSFR-CGO in wet H_(2)(3%H_(2)O)increases up to 0.32Ω·cm^(2).The symmetrical LCSFR-CGOILSGMILCSFR-CGO cell demonstrates a performance with an open circuit potential(OCV)of 1.07 V and a maximum peak power density of 904 mW/cm^(2)at 800℃using wet H2 as the fuel.This high performance indicates that LCSFR is a candidate electrode for SSOFCs. 展开更多
关键词 symmetrical electrode SSOFCs EXSOLUTION Nanoparticle catalysts Rare earths
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Serum matrix metalloproteinase 3 in detecting remitting seronegative symmetrical synovitis with pitting edema syndrome: A case report 被引量:4
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作者 Tsuneaki Kenzaka Ken Goda 《World Journal of Clinical Cases》 SCIE 2018年第5期84-87,共4页
We report a case of remitting seronegative symmetrical synovitis with pitting edema(RS3 PE) syndrome in a 71-year-old woman. She referred to our hospital with finger stiffness, edema of both hands and feet, pain of bi... We report a case of remitting seronegative symmetrical synovitis with pitting edema(RS3 PE) syndrome in a 71-year-old woman. She referred to our hospital with finger stiffness, edema of both hands and feet, pain of bilateral shoulder, wrist, metacarpophalangeal, proximal interphalangeal, and ankle joints. Rheumatoid factor was negative, human leukocyte antigen-B7 antigen was positive. Moreover, matrix metalloproteinase 3(MMP-3) was high. She was diagnosed with RS3 PE syndrome, and treatment with prednisolone(15 mg/d) was started. One week after prednisolone treatment initiation, CRP decreased to negative, and joint pain was almost completely resolved. However, hand stiffness persisted, and MMP-3 level was still high. Thus, prednisolone dose was increased to 20 mg/d, and the stiffness resolved. Twenty days after treatment initiation, MMP-3 was normalized. MMP-3 was more indicative of RS3 PE syndrome symptoms than CRP. Thus, MMP-3 seems to be more sensitive to RS3 PE syndrome symptoms. 展开更多
关键词 SERUM matrix metalloproteinase 3 Remitting SERONEGATIVE symmetrical SYNOVITIS with PITTING EDEMA syndrome
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Lie Symmetrical Perturbation and Adiabatic Invariants of Generalized Hojman Type for Relativistic Birkhoffian Systems 被引量:4
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作者 LUO Shao-Kai GUO Yong-Xin 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第1期25-30,共6页
For a relativistic Birkhoffian system, the Lie symmetrical perturbation and adiabatic invariants of generalized Bojman type are studied under general infinitesimal transformations. On the basis of the invariance of re... For a relativistic Birkhoffian system, the Lie symmetrical perturbation and adiabatic invariants of generalized Bojman type are studied under general infinitesimal transformations. On the basis of the invariance of relativistic Birkhotfian equations under general infinitesimal transformations,Lie symmetrical transformations of the system are constructed, which only depend on the Birkhoffian variables. The exact invariants in the form of generalized Hojman conserved quantities led by the Lie symmetries of relativistic Birkhoffian system without perturbations are given. Based on the definition of higher-order adiabatic invariants of a mechanical system, the perturbation of Lie symmetries for relativistic Birkhoffian system with the action of small disturbance is investigated, and a new type of adiabatic invariants of the system is obtained. In the end of the paper, an example is given to illustrate the application of the results. 展开更多
关键词 relativity BirkhofIian system Lie symmetrical perturbation exact invariant adiabatic invariant of generalized Hojman type
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Synthesis of Symmetrical Biaryls via Rhodium Catalyzed Dimerization of Arylmercurials and Mechanism of the Dimerization 被引量:2
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作者 WANG Yulan WU Yangjie 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2000年第2期131-135,共5页
A series of symmetrical biaryls was synthesized from arylmercuric chlorides and biarylmercurials in the presence of [ClRh(CO) 2] 2 in hexamethylphosphoramide(HMPA). The mechanism of the [ClRh(CO) 2] 2 catalyzed d... A series of symmetrical biaryls was synthesized from arylmercuric chlorides and biarylmercurials in the presence of [ClRh(CO) 2] 2 in hexamethylphosphoramide(HMPA). The mechanism of the [ClRh(CO) 2] 2 catalyzed dimerization of biarylmercurials was studied, and shown to be mainly intermolecular reaction. 展开更多
关键词 symmetrical biaryls Synthesis Arylmercurials Intermolecular reaction
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