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^(90)Sr在SuperLig~620固相萃取颗粒上的吸附性能研究 被引量:4
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作者 宋志君 张生栋 +1 位作者 丁有钱 张积桥 《原子能科学技术》 EI CAS CSCD 北大核心 2016年第10期1741-1747,共7页
为了建立SuperLig~620分离水中^(90)Sr的方法,研究了接触时间、硝酸酸度、柠檬酸铵浓度、干扰核素等对^(90)Sr在SuperLig~620固相萃取颗粒上分配系数K_d的影响。在0.1mol/L HNO_3介质中,接触时间大于30 min时,K_d大于1 000 mL/g。在c(H^... 为了建立SuperLig~620分离水中^(90)Sr的方法,研究了接触时间、硝酸酸度、柠檬酸铵浓度、干扰核素等对^(90)Sr在SuperLig~620固相萃取颗粒上分配系数K_d的影响。在0.1mol/L HNO_3介质中,接触时间大于30 min时,K_d大于1 000 mL/g。在c(H^+)>1 mmol/L时,SuperLig~620不吸附^(137) Cs、^(239)Pu、^(90) Y,但可吸附^(133)Ba。通过调节解吸时柠檬酸铵的浓度,可排除^(133)Ba对^(90) Sr分离的干扰。研究了SuperLig~620色层柱分离水中^(90)Sr的方法,将样品调节至0.1mol/L HNO_3上柱,首先用10V_c(柱体积V_c=0.1mL)0.1mol/L HNO_3洗涤杂质,然后依次用9V_c0.1mol/L柠檬酸铵、13V_c1.8mol/L柠檬酸铵解吸^(90)Sr、^(133)Ba。该流程对^(90)Sr的回收率大于99%,对主要干扰核素的去污因子大于3×10~3,适用于环境水中^(90)Sr的分析。 展开更多
关键词 superlig620固相萃取颗粒 90Sr 吸附性能
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SuperLig^®620用于水中^(90)Sr含量的监测方法研究 被引量:2
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作者 宋志君 张生栋 +1 位作者 丁有钱 马鹏 《原子能科学技术》 EI CAS CSCD 北大核心 2016年第12期2124-2129,共6页
为实现水中^(90)Sr的连续监测,利用SuperLig~?620固相萃取颗粒从水中选择性分离和富集^(90)Sr,并通过塑料闪烁体测量SuperLig~?620色层柱上^(90)Sr的含量。研究了0.2mg/L Sr-0.01mol/L HNO_3介质下,^(90)Sr在SuperLig~?620色层柱上的动... 为实现水中^(90)Sr的连续监测,利用SuperLig~?620固相萃取颗粒从水中选择性分离和富集^(90)Sr,并通过塑料闪烁体测量SuperLig~?620色层柱上^(90)Sr的含量。研究了0.2mg/L Sr-0.01mol/L HNO_3介质下,^(90)Sr在SuperLig~?620色层柱上的动态平衡。结果表明,吸附平衡时^(90)Sr在两相间的浓度呈正比,因此通过测量柱上^(90)Sr的含量可得到水中^(90)Sr的浓度。所建立的方法对^(90)Sr的探测效率和最小可探测活度分别为21.3%和2.6Bq/L,对某低放废水中^(90)Sr的分析误差小于20%。 展开更多
关键词 ^(90)Sr superlig^®620固相萃取颗粒 塑料闪烁体
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Metal separations of interest to the Chinese metallurgical industry 被引量:3
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作者 S.R.Izatt N.E.Izatt R.L.Bruening 《Journal of Rare Earths》 SCIE EI CAS CSCD 2010年第S1期22-29,共8页
IBC Advanced Technologies’ Molecular Recognition Technology(MRT) SuperLig products selectively and rapidly bind with target species enabling their selective removal from solutions.The MRT process can produce a high p... IBC Advanced Technologies’ Molecular Recognition Technology(MRT) SuperLig products selectively and rapidly bind with target species enabling their selective removal from solutions.The MRT process can produce a high purity separation product of maximum added value at a competitive cost.SuperLig products have high selectivity for many target species which can include metal ions,anions,and neutral molecules.In operation,the SuperLig product is first placed in a packed column.A solution containing a mixture of the target species and other chemical species is then passed through the column.The target species is removed selectively by the SuperLig product,the column is washed to remove residual feed solution,and the target species is recovered by a minimal quantity of eluent.The result is a pure and concentrated species that can be kept for its value or disposed of safely.The process is environmentally and ecologically friendly with no organic solvents being used.This paper provides a review of some examples of applications of MRT to separations of interest to the Chinese metallurgical industry.Included are several applications of MRT,including Pd separations from Pt metal refinery streams and low-grade spent catalyst wastes,Rh recovery from spent auto catalyst and other feeds,Re removal from selected impurity ions,Cd removal from Co electrolyte,Bi removal from Cu electrolyte,In and Ge separations from difficult matrices,and removal of bivalent first transition series and other metal ions from acid mine drainage(Berkeley Pit,Montana).Finally,the potential application of MRT to separations involving the recovery of rare earth metals and Li from low-level waste solutions and end-of-life products is discussed. 展开更多
关键词 selective and environmentally friendly metal separations molecular recognition technology superlig platinum group metals minor metals transition series metals RHENIUM cadmium indium germanium BISMUTH rare earth metals lithium
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