In recent years,due to the increasing demand for portable electronic devices,rechargeable solid-state battery technology has developed rapidly.Lithium-ion batteries are the systems of choice,offering high energy densi...In recent years,due to the increasing demand for portable electronic devices,rechargeable solid-state battery technology has developed rapidly.Lithium-ion batteries are the systems of choice,offering high energy density,flexible and lightweight design,and longer lifespan than comparable battery technologies.Therefore,a better understanding of the relationship between electrochemical mechanism and structural properties from theory and experiment will enable us to accelerate the development of high-performance and security batteries.This review discusses the interplay between theoretical calculation and experiment in the study of lithium ion battery materials.We introduce the application of theoretical calculation method in solid-state batteries through the combination of theory and experiment.We present the concept and assembly technology of solid-state batteries are reviewed.The basic parameters of solid-state electrolytes,especially sulfide-based solid-state electrolytes and their interface mechanisms with high-voltage cathode materials,are analyzed by theoretical methods.We present an overview on the scientific challenges,fundamental mechanisms,and design strategies for solid-state batteries,especially focusing on the issues of stability on solid-state electrolytes and the associated interfaces with both cathode and electrolyte.Owing to the theoretical models,we can not only reveal the unprecedented mechanism from the atomic scale,but also analyze the interface problems in the battery thoroughly,thus effectively designing more promising electrolyte and interface coating materials.It blazed a new trial for engineering an interphase with improved interfacial compatibility for a long-term cyclability.展开更多
Interface is a necessary channel of carrier permeation in sulfide-based all-solid-state lithium battery(ASSLB).Homogeneous and fast lithium-ion(Li^(+))interfacial transport of cathode is the overriding premise for hig...Interface is a necessary channel of carrier permeation in sulfide-based all-solid-state lithium battery(ASSLB).Homogeneous and fast lithium-ion(Li^(+))interfacial transport of cathode is the overriding premise for high capability of ASSLBs.However,the inherent transport heterogeneity of crystalline materials in cathode and the cathode active material(CAM)/sulfide solid electrolyte(SSE)interfacial issues result in high interfacial imped-ance,decreasing the Li^(+)transfer kinetics.In this review,we outline the Li^(+)transport properties of CAMs and SSEs,followed by a discussion of their interfacial electro-chemo-mechanical issues.Commentary is also provided on the solutions to the multiple-scale interfacial Li^(+)transport failure.Furthermore,the underlying interdependent mechanisms between electrodes are summarized and overviewed.Finally,we suggest future paths to better comprehend and promote the interfacial Li^(+)transport in ASSLBs.This review provides an in-depth understanding of cathodal interfacial issues and the proposed improvement strategies will provide guidance for further advancement of high-performance ASSLBs.展开更多
All-solid-state batteries(ASSBs)are pursued due to their potential for better safety and high energy density.However,the energy density of the cathode for ASSBs does not seem to be satisfactory due to the low utilizat...All-solid-state batteries(ASSBs)are pursued due to their potential for better safety and high energy density.However,the energy density of the cathode for ASSBs does not seem to be satisfactory due to the low utilization of active materials(AMs)at high loading.With small amount of solid electrolyte(SE)powder in the cathode,poor electrochemical performance is often observed due to contact loss and non-homogeneous distribution of AMs and SEs,leading to high tortuosity and limitation of lithium and electron transport pathways.Here,we propose a novel cathode design that can achieve high volumetric energy density of 1258 Wh L^(-1)at high AM content of 85 wt%by synergizing the merits of AM@SE core–shell composite particles with conformally coated thin SE shell prepared from mechanofusion process and small SE particles.The core–shell structure with an intimate and thin SE shell guarantees high ionic conduction pathway while unharming the electronic conduction.In addition,small SE particles play the role of a filler that reduces the packing porosity in the cathode composite electrode as well as between the cathode and the SE separator layer.The systematic demonstration of the optimization process may provide understanding and guidance on the design of electrodes for ASSBs with high electrode density,capacity,and ultimately energy density.展开更多
Anode-free all-solid-state batteries(AF-ASSBs)have received significant attention as a next-generation battery system due to their high energy density and safety.However,this system still faces challenges,such as poor...Anode-free all-solid-state batteries(AF-ASSBs)have received significant attention as a next-generation battery system due to their high energy density and safety.However,this system still faces challenges,such as poor Coulombic efficiency and short-circuiting caused by Li dendrite growth.In this study,the AF-ASSBs are demonstrated with reliable and robust electrochemical properties by employing Cu-Sn nanotube(NT)thin layer(~1μm)on the Cu current collector for regulating Li electrodeposition.Li_(x)Sn phases with high Li-ion diffusivity in the lithiated Cu-Sn NT layer enable facile Li diffusion along with its one-dimensional hollow geometry.The unique structure,in which Li electrodeposition takes place between the Cu-Sn NT layer and the current collector by the Coble creep mechanism,improves cell durability by preventing solid electrolyte(SE)decomposition and Li dendrite growth.Furthermore,the large surface area of the Cu-Sn NT layer ensures close contact with the SE layer,leading to a reduced lithiation overpotential compared to that of a flat Cu-Sn layer.The Cu-Sn NT layer also maintains its structural integrity owing to its high mechanical properties and porous nature,which could further alleviate the mechanical stress.The LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM)|SE|Cu-Sn NT@Cu cell with a practical capacity of 2.9 mAh cm^(−2) exhibits 83.8%cycle retention after 150 cycles and an average Coulombic efficiency of 99.85%at room temperature.It also demonstrates a critical current density 4.5 times higher compared to the NCM|SE|Cu cell.展开更多
All-solid-state lithium batteries(ASSLBs)have advantages of safety and high energy density,and they are expected to become the next generation of energy storage devices.Sulfide-based solid-state electrolytes(SSEs)with...All-solid-state lithium batteries(ASSLBs)have advantages of safety and high energy density,and they are expected to become the next generation of energy storage devices.Sulfide-based solid-state electrolytes(SSEs)with high ionic conduc-tivity and low grain boundary resistance exhibit remarkable practical application.However,the space charge layer(SCL)eff ect and high interfacial resistance caused by a mismatch with the current commercial oxide cathodes restrict the develop-ment of sulfide SSEs and ASSLBs.This review summarizes the research progress on the SCL eff ect of sulfide SSEs and oxide cathodes,including the mechanism and direct evidence from high performance in-situ characterizations,as well as recent progress on the interfacial modification strategies to alleviate the SCL eff ect.This study provides future direction to stabilize the high performance sulfide-based solid electrolyte/oxide cathode interface for state-of-the-art ASSLBs and future all-SSE storage devices.展开更多
Cadmium sulfide(Cd S)-based photocatalysts have attracted extensive attention owing to their strong visible light absorption,suitable band energy levels,and excellent electronic charge transportation properties.This r...Cadmium sulfide(Cd S)-based photocatalysts have attracted extensive attention owing to their strong visible light absorption,suitable band energy levels,and excellent electronic charge transportation properties.This review focuses on the recent progress related to the design,modification,and construction of Cd S-based photocatalysts with excellent photocatalytic H2 evolution performances.First,the basic concepts and mechanisms of photocatalytic H2 evolution are briefly introduced.Thereafter,the fundamental properties,important advancements,and bottlenecks of Cd S in photocatalytic H2 generation are presented in detail to provide an overview of the potential of this material.Subsequently,various modification strategies adopted for Cd S-based photocatalysts to yield solar H2 are discussed,among which the effective approaches aim at generating more charge carriers,promoting efficient charge separation,boosting interfacial charge transfer,accelerating charge utilization,and suppressing charge-induced self-photocorrosion.The critical factors governing the performance of the photocatalyst and the feasibility of each modification strategy toward shaping future research directions are comprehensively discussed with examples.Finally,the prospects and challenges encountered in developing nanostructured Cd S and Cd S-based nanocomposites in photocatalytic H2 evolution are presented.展开更多
基金financial support from the National Natural Science Foundation of China(Nos.52171082 and 51001091)the Program for Innovative Research Team(in Science and Technology)in University of Henan Province(No.21IRTSTHN003)+2 种基金partially supported by the Provincial Scientific Research Program of Henan(No.182102310815)Nuclear Material Technology Innovation Fund for National Defense Technology Industry(No.ICNM-2021-YZ-02)the Science and Technology Project of Henan Province(No.232102241036).
文摘In recent years,due to the increasing demand for portable electronic devices,rechargeable solid-state battery technology has developed rapidly.Lithium-ion batteries are the systems of choice,offering high energy density,flexible and lightweight design,and longer lifespan than comparable battery technologies.Therefore,a better understanding of the relationship between electrochemical mechanism and structural properties from theory and experiment will enable us to accelerate the development of high-performance and security batteries.This review discusses the interplay between theoretical calculation and experiment in the study of lithium ion battery materials.We introduce the application of theoretical calculation method in solid-state batteries through the combination of theory and experiment.We present the concept and assembly technology of solid-state batteries are reviewed.The basic parameters of solid-state electrolytes,especially sulfide-based solid-state electrolytes and their interface mechanisms with high-voltage cathode materials,are analyzed by theoretical methods.We present an overview on the scientific challenges,fundamental mechanisms,and design strategies for solid-state batteries,especially focusing on the issues of stability on solid-state electrolytes and the associated interfaces with both cathode and electrolyte.Owing to the theoretical models,we can not only reveal the unprecedented mechanism from the atomic scale,but also analyze the interface problems in the battery thoroughly,thus effectively designing more promising electrolyte and interface coating materials.It blazed a new trial for engineering an interphase with improved interfacial compatibility for a long-term cyclability.
基金supported by the National Natural Science Foundation of China(Nos.22379155,52037006)the Postdoctoral Fellowship Program of CPSF(No.GZC20241810)+5 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA22010600)the Youth Innovation Promotion Association of CAS(No.2021210)the Key Scientific and Technological Innovation Project of Shandong(Nos.2022CXGC020301,2023CXGC010302)the Emerging Industry Cultivation Plan of Qingdao Future Industry Culti-vation Project(No.24-1-4-xxgg-7-gx)the Qingdao New Energy Shan-dong Laboratory(No.QIBEBT/SEI/QNESLS202304)the Taishan Scholars Program(Nos.ts201511063,tsqn202306308).
文摘Interface is a necessary channel of carrier permeation in sulfide-based all-solid-state lithium battery(ASSLB).Homogeneous and fast lithium-ion(Li^(+))interfacial transport of cathode is the overriding premise for high capability of ASSLBs.However,the inherent transport heterogeneity of crystalline materials in cathode and the cathode active material(CAM)/sulfide solid electrolyte(SSE)interfacial issues result in high interfacial imped-ance,decreasing the Li^(+)transfer kinetics.In this review,we outline the Li^(+)transport properties of CAMs and SSEs,followed by a discussion of their interfacial electro-chemo-mechanical issues.Commentary is also provided on the solutions to the multiple-scale interfacial Li^(+)transport failure.Furthermore,the underlying interdependent mechanisms between electrodes are summarized and overviewed.Finally,we suggest future paths to better comprehend and promote the interfacial Li^(+)transport in ASSLBs.This review provides an in-depth understanding of cathodal interfacial issues and the proposed improvement strategies will provide guidance for further advancement of high-performance ASSLBs.
基金supported by the Technology Innovation Program(Grant no.20009985,Grant no.20026752)funded By the Ministry of Trade,Industry&Energy(MOTIE,Korea)。
文摘All-solid-state batteries(ASSBs)are pursued due to their potential for better safety and high energy density.However,the energy density of the cathode for ASSBs does not seem to be satisfactory due to the low utilization of active materials(AMs)at high loading.With small amount of solid electrolyte(SE)powder in the cathode,poor electrochemical performance is often observed due to contact loss and non-homogeneous distribution of AMs and SEs,leading to high tortuosity and limitation of lithium and electron transport pathways.Here,we propose a novel cathode design that can achieve high volumetric energy density of 1258 Wh L^(-1)at high AM content of 85 wt%by synergizing the merits of AM@SE core–shell composite particles with conformally coated thin SE shell prepared from mechanofusion process and small SE particles.The core–shell structure with an intimate and thin SE shell guarantees high ionic conduction pathway while unharming the electronic conduction.In addition,small SE particles play the role of a filler that reduces the packing porosity in the cathode composite electrode as well as between the cathode and the SE separator layer.The systematic demonstration of the optimization process may provide understanding and guidance on the design of electrodes for ASSBs with high electrode density,capacity,and ultimately energy density.
基金Korea Institute of Energy Technology Evaluation and Planning,Grant/Award Number:20214000000520Ministry of Trade,Industry and Energy,Grant/Award Number:20009985。
文摘Anode-free all-solid-state batteries(AF-ASSBs)have received significant attention as a next-generation battery system due to their high energy density and safety.However,this system still faces challenges,such as poor Coulombic efficiency and short-circuiting caused by Li dendrite growth.In this study,the AF-ASSBs are demonstrated with reliable and robust electrochemical properties by employing Cu-Sn nanotube(NT)thin layer(~1μm)on the Cu current collector for regulating Li electrodeposition.Li_(x)Sn phases with high Li-ion diffusivity in the lithiated Cu-Sn NT layer enable facile Li diffusion along with its one-dimensional hollow geometry.The unique structure,in which Li electrodeposition takes place between the Cu-Sn NT layer and the current collector by the Coble creep mechanism,improves cell durability by preventing solid electrolyte(SE)decomposition and Li dendrite growth.Furthermore,the large surface area of the Cu-Sn NT layer ensures close contact with the SE layer,leading to a reduced lithiation overpotential compared to that of a flat Cu-Sn layer.The Cu-Sn NT layer also maintains its structural integrity owing to its high mechanical properties and porous nature,which could further alleviate the mechanical stress.The LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM)|SE|Cu-Sn NT@Cu cell with a practical capacity of 2.9 mAh cm^(−2) exhibits 83.8%cycle retention after 150 cycles and an average Coulombic efficiency of 99.85%at room temperature.It also demonstrates a critical current density 4.5 times higher compared to the NCM|SE|Cu cell.
基金financially supported by National Natural Science Foundation of China(Nos.21575015,21203008,21975025,and 51772030)the Beijing Nature Science Foundation(No.2172051),the National Key Research and Develop-ment Program of China(No.2016YFB0100204)+1 种基金Beijing Outstand-ing Young Scientists Program(No.BJJWZYJH01201910007023)funded by State Key Laboratory for Modification of Chemi-cal Fibers and Polymer Materials,Donghua University.
文摘All-solid-state lithium batteries(ASSLBs)have advantages of safety and high energy density,and they are expected to become the next generation of energy storage devices.Sulfide-based solid-state electrolytes(SSEs)with high ionic conduc-tivity and low grain boundary resistance exhibit remarkable practical application.However,the space charge layer(SCL)eff ect and high interfacial resistance caused by a mismatch with the current commercial oxide cathodes restrict the develop-ment of sulfide SSEs and ASSLBs.This review summarizes the research progress on the SCL eff ect of sulfide SSEs and oxide cathodes,including the mechanism and direct evidence from high performance in-situ characterizations,as well as recent progress on the interfacial modification strategies to alleviate the SCL eff ect.This study provides future direction to stabilize the high performance sulfide-based solid electrolyte/oxide cathode interface for state-of-the-art ASSLBs and future all-SSE storage devices.
基金the National Natural Science Foundation of China(21975084 and 51672089)the Ding Ying Talent Project of South China Agricultural University for their support+1 种基金the Hong Kong Research Grant Council(RGC)General Research Fund GRF1305419 for financial supportthe National Natural Science Foundation of China(51972287 and 51502269)。
文摘Cadmium sulfide(Cd S)-based photocatalysts have attracted extensive attention owing to their strong visible light absorption,suitable band energy levels,and excellent electronic charge transportation properties.This review focuses on the recent progress related to the design,modification,and construction of Cd S-based photocatalysts with excellent photocatalytic H2 evolution performances.First,the basic concepts and mechanisms of photocatalytic H2 evolution are briefly introduced.Thereafter,the fundamental properties,important advancements,and bottlenecks of Cd S in photocatalytic H2 generation are presented in detail to provide an overview of the potential of this material.Subsequently,various modification strategies adopted for Cd S-based photocatalysts to yield solar H2 are discussed,among which the effective approaches aim at generating more charge carriers,promoting efficient charge separation,boosting interfacial charge transfer,accelerating charge utilization,and suppressing charge-induced self-photocorrosion.The critical factors governing the performance of the photocatalyst and the feasibility of each modification strategy toward shaping future research directions are comprehensively discussed with examples.Finally,the prospects and challenges encountered in developing nanostructured Cd S and Cd S-based nanocomposites in photocatalytic H2 evolution are presented.
