The kinetics of PTC-Wittig reaction between substituted aromatic aldehydes and 2-butenyl methyldiphenylphosphonium salt has been studied. The low reaction constant (ρ=0. 30) implies that these PTC-Wittig reactions ta...The kinetics of PTC-Wittig reaction between substituted aromatic aldehydes and 2-butenyl methyldiphenylphosphonium salt has been studied. The low reaction constant (ρ=0. 30) implies that these PTC-Wittig reactions take place through low polar intermediate.展开更多
An efficient methodology for the synthesis of 2,3-disubstituted 3H-quinazolin-4-ones is described via one-pot three component reaction from anthranilic acid using T3 P as catalyst. Mild reaction conditions,short react...An efficient methodology for the synthesis of 2,3-disubstituted 3H-quinazolin-4-ones is described via one-pot three component reaction from anthranilic acid using T3 P as catalyst. Mild reaction conditions,short reaction time, broad functional group tolerance, easy isolation of products and good yields are main advantages of this protocol.展开更多
文摘The kinetics of PTC-Wittig reaction between substituted aromatic aldehydes and 2-butenyl methyldiphenylphosphonium salt has been studied. The low reaction constant (ρ=0. 30) implies that these PTC-Wittig reactions take place through low polar intermediate.
基金Financial support from DST-Fast track,New Delhi(No.SERB/F/2013-14)
文摘An efficient methodology for the synthesis of 2,3-disubstituted 3H-quinazolin-4-ones is described via one-pot three component reaction from anthranilic acid using T3 P as catalyst. Mild reaction conditions,short reaction time, broad functional group tolerance, easy isolation of products and good yields are main advantages of this protocol.
