An oil-in-water (O/W) solvent evaporation method was used to prepare biodegradable microspheresbased on poly(D,L-lactic acid) (PLA). Nifedipine, a hydrophobic drug, was chosen as a model molecule in the studyof drug e...An oil-in-water (O/W) solvent evaporation method was used to prepare biodegradable microspheresbased on poly(D,L-lactic acid) (PLA). Nifedipine, a hydrophobic drug, was chosen as a model molecule in the studyof drug entrapment and release. Effect of preparation conditions on the size, morphology, drug loading, and releaseprofiles of micropheres was investigated. Based on in vitro release experimental findings, a diffusion/dissolutionmodel was presented for quantitative description of the resulting release behaviors and drug release kinetics fromPLA microspheres analyzed. The mathematical models were used to predict the effect of microstructure on theresulting drug release. It provided an approach to determine the suitable structure parameters for microspheres toachieve desired drug release behaviors.展开更多
A novel quantitative structure-property relationship （QSPR） model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. Th...A novel quantitative structure-property relationship （QSPR） model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. The data set contained non-polar and polar liquids, and saturated and unsaturated compounds. The regression analysis shows that excellent result is obtained with multiple linear regression. The predictive power of the proposed model was discussed using the leave-one-out （LOO） cross-validated （CV） method. The correlation coefficient （R） and the leave-one-out cross-validation correlation coefficient （Rcv） of multiple linear regression model are 0.991 4 and 0.991 3, respectively. The new model gives the average absolute relative deviation of 1.81% for 92 substances. The result demonstrates that novel topological indices based on the equilibrium electro-negativity of atom and the relative bond length are useful model parameters for QSPR analysis of compounds.展开更多
The ring-opening polymerization of heterocyclic monomers and the reversed ring-closing depolymerization of corresponding polymers with neutral thermodynamics are broadly explored to establish a circular economy of nex...The ring-opening polymerization of heterocyclic monomers and the reversed ring-closing depolymerization of corresponding polymers with neutral thermodynamics are broadly explored to establish a circular economy of next-generation plastics.Polythioesters(PTEs),analogues of polyesters,are emerging materials for this purpose due to their high refractive index,high crystallinity,dynamic property and responsiveness.In this work,we synthesize and polymerize a series of D-penicillamine-derivedβ-thiolactones(NRPenTL)with varied side chain alkyl groups,and study the structure-property relationship of the resulting polymers.The obtained PTEs exhibit tunable glass transition temperature in a wide range of 130–50℃,and melting temperature of 90–105℃.In addition,copolymerizations of monomers with different side chains are effective in modulating material properties.The obtained homo and copolymers can be fully depolymerized to recycle monomers.This work provides a robust molecular platform and detailed structure-property relationship of PTEs with potential of achieving sustainable plastics.展开更多
As the scaling down of semiconductor devices, it would be necessary to discover the structure-property relationship of semiconductor nanomaterials at nanometer scale. In this review, the quantitative characterization ...As the scaling down of semiconductor devices, it would be necessary to discover the structure-property relationship of semiconductor nanomaterials at nanometer scale. In this review, the quantitative characterization technique off-axis electron holography is introduced in details, followed by its applications in various semiconductor nanomaterials including group IV, compound and two-dimensional semiconductor nanostructures in static states as well as under various stimuli. The advantages and disadvantages of off-axis electron holography in material analysis are discussed, the challenges facing in-situ electron holographic study of semiconductor devices at working conditions are presented, and all the possible influencing factors need to be considered to achieve the final goal of fulfilling quantitative characterization of the structure-property relationship of semiconductor devices at their working conditions.展开更多
In recent twenty years,aggregation-induced emission(AIE),due to its excellent application prospect,has aroused widespread interests.The development of novel and easy to make AIE luminogens(AIEgens)is an attractive sub...In recent twenty years,aggregation-induced emission(AIE),due to its excellent application prospect,has aroused widespread interests.The development of novel and easy to make AIE luminogens(AIEgens)is an attractive subject.For this purpose,it is very important to study the structure-property relationship of AIEgens.Because azine derivatives are easy to synthesis and some of them have nice AIE properties,herein,a series of azine derivatives(ADs)were employed as models to study the influence of different functional groups,electronic effects and structures on the AIE properties of azine derivatives.The AIE mechanism were studied by single crystal analysis,density functional theory(DFT)calculations and so on.The results indicated that the o-hydroxyl aryl substituted azine compounds could show good AIE properties.Meanwhile,the AIE properties of o-hydroxyl aryl substituted azine compounds were also influenced by the electronic effects of the aryl groups in the azine compounds.The o-hydroxyl groups could form intramolecular hydrogen bond with imine group,which play key role to restrict the intramolecular rotation of the aryl groups and act as base stone for the AIE process of this kind compounds.The HOMO-LUMO energy gaps of o-hydroxyl substituted azine are smaller than other homologous compounds,which is agree with the proposed AIE mechanism.Finally,thanks to the AIE properties,the o-hydroxy-substituted azines could be used as efficient Al^(3+)and Cu^(2+)fluorescent chemosensors in different conditions.In addition,test strips based on AD10 has been prepared,which can conveniently detect Cu^(2+)in industrial wastewater.This research supplied a way for the design of novel easy to make AIEgens through simple azine derivatives.展开更多
A quantitative structure-property relationship (QSPR) study has been made for the prediction of the surface tension of nonionic surfactants in aqueous solution. The regressed model includes a topological descriptor, ...A quantitative structure-property relationship (QSPR) study has been made for the prediction of the surface tension of nonionic surfactants in aqueous solution. The regressed model includes a topological descriptor, the Kier & Hall index of zero order (KH0) of the hydrophobic segment of surfactant and a quantum chemical one, the heat of formation (fHD) of surfactant molecules. The established general QSPR between the surface tension and the descriptors produces a correlation coefficient of multiple determination, 2r=0.9877, for 30 studied nonionic surfactants.展开更多
X-ray crystal structures of 2,2',3,3'-and 3, 3',4,4'-biphenyltetracarboxylic dianhydride (2,2',3,3'- and 3,3',4,4'-BPDA) were determined. The dianhydride isomers have different symmetr...X-ray crystal structures of 2,2',3,3'-and 3, 3',4,4'-biphenyltetracarboxylic dianhydride (2,2',3,3'- and 3,3',4,4'-BPDA) were determined. The dianhydride isomers have different symmetry caused by difference in two anhydride group positions and the dihedral angles between the two phenyl rings are 62.9°for 2,2',3,3',-BPDA and 0°for 3,3',4,4'-BPDA respectively. The polyimides from 2,2',3,3'-BPDA exhibit enhanced solubility, higher thermal stability, and higher glasstransition temperature (Tg) compared with those from 3,3',4,4'-BPDA.展开更多
Efficient removal of^(137)Cs and^(90)Sr from radioactive waste liquids is challenging due to their strong radioactivity,solubility,and mobility.Herein,the efficient Cs^(+)/Sr^(2+)capture has been achieved by layered t...Efficient removal of^(137)Cs and^(90)Sr from radioactive waste liquids is challenging due to their strong radioactivity,solubility,and mobility.Herein,the efficient Cs^(+)/Sr^(2+)capture has been achieved by layered thioniobates and thiotantalate with radiation resistance,namely K_(0.36)NbS_(2)·0.54H_(2)O(K-NbS_(2)),Rb_(0.36)NbS_(2)·0.54H_(2)O(Rb-NbS_(2)),and K_(0.33)TaS_(2)·0.75H_2O(K-TaS_(2)).In particular,K-NbS_(2)exhibits high adsorption capacities,fast kinetics,and fantastic p H durability.K-NbS_(2)is an unprecedented scavenger for selective Sr^(2+)capture in acidic solutions containing excess Na^(+)/Mg^(2+)ions.They show successful cleanup for acidic^(90)Sr-liquid-waste generated during industrial production.Importantly,the removal mechanism is revealed as the ion exchange between Cs^(+)/Sr^(2+)and interlayer K^(+)in thioniobates and thiotantalate due to their appropriate interlayer distances,flexible and adjustable frameworks,and strong affinity of soft basic S^(2-)for Cs^(+)/Sr^(2+).Further,the structure-property relationship study indicates that there is an inverted U-curve rule for the relationship between interlayer distances of layered metal sulfides and ion exchange performance.The rule combined with the factors affecting interlayer distance can be used to direct the structural design and predict properties for the specific recognition and separation of radionuclides.This is a pioneering work on the development of thioniobates/thiotantalate ion exchangers with a deep insight into structure-property relationship for radionuclide remediation.展开更多
Spinels have been widely concerned as a promising class of electrocatalysts due to their appealing catalytic properties and the tunability of their compositions and structures.Ligand field theory(LFT),which describes ...Spinels have been widely concerned as a promising class of electrocatalysts due to their appealing catalytic properties and the tunability of their compositions and structures.Ligand field theory(LFT),which describes the origins and the consequences of metal-ligand interactions,offers crucial insights for the design of spinel-type electrocatalysts.In this review,we timely summarize the research progress of spinel electrocatalysts that leverage LFT for structure-property insights,providing a pioneering perspective in this field.This review explores how LFT plays a pivotal role in optimizing the electrocatalytic properties of spinels.It covers important aspects such as identifying the origin of the catalytic properties,tuning the number of active sites,manipulating the eg-filling and the spin state of metal cations,and modulating the 2p band of ligands.We anticipate that this review will provide valuable theoretical guidance and inspire creative spinel designs that excel in electrocatalytic applications.展开更多
Since antiquity,humans have been involved in designing materials through alloying strategies to meet the ever-growing technological demands.In 2004,this endeavor witnessed a significant breakthrough with the discovery...Since antiquity,humans have been involved in designing materials through alloying strategies to meet the ever-growing technological demands.In 2004,this endeavor witnessed a significant breakthrough with the discovery of high-entropy alloys(HEAs)comprising multi-principal elements.Owing to the four“core-effects”,these alloys exhibit exceptional properties including better structural stability,high strength and ductility,improved fatigue/fracture toughness,high corrosion and oxidation resistance,superconductiv-ity,magnetic properties,and good thermal properties.Different synthesis routes have been designed and used to meet the properties of interest for particular applications with varying dimensions.How-ever,HEAs are providing new opportunities and challenges for computational modelling of the complex structure-property correlations and in predictions of phase stability necessary for optimum performance of the alloy.Several attempts have been made to understand these alloys by empirical and computa-tional models,and data-driven approaches to accelerate the materials discovery with a desired set of properties.The present review discusses advances and inferences from simulations and models spanning multiple length and time scales explaining a comprehensive set of structure-properties relations.Addi-tionally,the role of machine learning approaches is also reviewed,underscoring the transformative role of computational modelling in unravelling the multifaceted properties and applications of HEAs,and the scope for future efforts in this direction.展开更多
During Donald Trump’s first term,the“Trump Shock”brought world politics into an era of uncertainties and pulled the transatlantic alliance down to its lowest point in history.The Trump 2.0 tsunami brewed by the 202...During Donald Trump’s first term,the“Trump Shock”brought world politics into an era of uncertainties and pulled the transatlantic alliance down to its lowest point in history.The Trump 2.0 tsunami brewed by the 2024 presidential election of the United States has plunged the U.S.-Europe relations into more gloomy waters,ushering in a more complex and turbulent period of adjustment.展开更多
I am delighted to join my Thai and Chinese friends in celebrating the 50th anniversary of the establishment of diplomatic relations between our two great nations.It is the“Golden Jubilee”of Thailand-China friendship...I am delighted to join my Thai and Chinese friends in celebrating the 50th anniversary of the establishment of diplomatic relations between our two great nations.It is the“Golden Jubilee”of Thailand-China friendship.Half a century ago when Thailand’s then Prime Minister M.R.Kukrit Pramoj and China’s Premier Zhou Enlai signed a Joint Communique on the Establishment of Diplomatic Relations on July 1,1975,the foundation for a profound and mutually beneficial partnership was laid,fostering enduring friendship,cooperation,and understanding between our two nations.This bond has stood the test of time amidst the ever-changing international landscape and been further enhanced by both countries’commitment to advancing the Comprehensive Strategic Cooperative Partnership and building a Thailand-China community with a shared future for enhanced stability,prosperity,and sustainability through a forwardlooking and people-centered vision.展开更多
The year 2025 marks the 50th anniversary of diplomatic relations between China and the Philippines.Over the past half century,despite ups and downs,China-Philippines relations have maintained a steady momentum of deve...The year 2025 marks the 50th anniversary of diplomatic relations between China and the Philippines.Over the past half century,despite ups and downs,China-Philippines relations have maintained a steady momentum of development with continuous progress in political,economic,and cultural exchanges.Since the second half of 2023,the Philippines’freguent provocations in the South China Sea have negatively impacted bilateral relations.展开更多
If there were any doubts about the Trump administration’s inherent obsession with decoupling,polarization and jolting of global trade,they can be laid to rest.A series of statements and measures have been made by the...If there were any doubts about the Trump administration’s inherent obsession with decoupling,polarization and jolting of global trade,they can be laid to rest.A series of statements and measures have been made by the U.S.government on economic relations with China including administrative decision to hit Chinese goods with additional tariffs despite China.展开更多
The year 2025 marks the 75th anniversary of the establishment of diplomatic relations between China and Indonesia.Over the past 75 years,the bilateral relationship has made significant progress across various fields,l...The year 2025 marks the 75th anniversary of the establishment of diplomatic relations between China and Indonesia.Over the past 75 years,the bilateral relationship has made significant progress across various fields,laying a solid foundation for regional stability.China Report ASEAN interviewed Indonesian Ambassador to China Djauhari Oratmangun to reflect on the remarkable journey of Indonesia-China relations over the past 75 years.展开更多
This year marks the 50th anniversary of the establishment of diplomatic relations between China and the EU.Over half a century,China and the EU have steadily enhanced political mutual trust,deepened mutually beneficia...This year marks the 50th anniversary of the establishment of diplomatic relations between China and the EU.Over half a century,China and the EU have steadily enhanced political mutual trust,deepened mutually beneficial cooperation,and firmly upheld multilateralism,bringing tangible benefits to both peoples and making a significant contribution to global peace and development.展开更多
This article attempts to distinguish public relations(PRs)from propaganda,within the context of information management.Speedy dissemination of information is an important feature of contemporary communication practice...This article attempts to distinguish public relations(PRs)from propaganda,within the context of information management.Speedy dissemination of information is an important feature of contemporary communication practice globally.In this era,the information content of communication is an important element requiring critical evaluation.This is so,because of the need to safeguard the information ecosystem,considering the thin line between public relations and propaganda.While both propaganda and public relations aim to shape perceptions,influence attitudes,and sway opinions,one key distinction lies in their ethical considerations.Public relations emphasize honesty,accuracy,accountability,and a commitment to the truth.In contrast,propaganda may involve manipulation,distortion,or even fabrication of information to advance a particular agenda,often at the expense of truth and transparency.Hinged on The Excellence Theory and the Two-Way Symmetrical Model,the paper focuses on the meeting points and differences between public relations and propaganda,with a view to safeguarding the integrity of the information ecosystem.The study adopted the survey research method,with interview as research instrument.The study discovered that while propaganda is not entirely a bad practice,it has a heavy tilt towards bias.It therefore recommends that deliberate steps be taken by relevant professional organisations and other stakeholders towards educating the citizens on ways of distinguishing between public relations and propaganda contents.展开更多
Purpose:This paper presents a new semi-automatic methodology for identifying inter-actor relationships by discerning viewpoints in non-social,political textual corpora.Although previous research has successfully disce...Purpose:This paper presents a new semi-automatic methodology for identifying inter-actor relationships by discerning viewpoints in non-social,political textual corpora.Although previous research has successfully discerned viewpoints,biases,and affiliations based on textual features,the task of relationship analysis in the absence of interactional data remains unaddressed.Design/methodology/approach:We introduce a new paradigm for topic representation as a dynamic,continuous,multi-viewpoint spectrum based on the representation of viewpoints as vectors that capture common topical themes.As a proof of concept,we applied this paradigm to scrutinize the inter-state relationships reflected in the speeches of the UN General Assembly Debate Corpus(UNGDC).Findings:The proposed paradigm effectively identifies discursive trends in UNGDC.Our analysis reveals common attitudes towards the topic and their prominence among different groups of actors and facilitates the analysis of relationships between actors through a quantitative representation of viewpoint similarity.The method also successfully captured temporal shifts in viewpoints and overall discourse trends,correlating with major geopolitical events.Research limitations:One limitation of this study is the method’s sensitivity to data sparsity,which can skew viewpoint representations in cases of low topic involvement.Practical implications:The proposed paradigm can be utilized by scholars in political science and other domains as a tool for semi-automated unsupervised textual analysis of various non-social textual sources,enabling the discovery of latent relationships between actors and the modeling of viewpoints in complex topics.Originality/value:This study presents a novel framework for unsupervised semi-automatic textual analysis of relationships in non-social corpora through a new approach for the representation of viewpoints as thematic vectors.展开更多
In contemporary society,language transcends its function as a mere tool for communication.It is intrinsically linked to a people’s culture,values,and worldview.This observation is particularly salient in our globaliz...In contemporary society,language transcends its function as a mere tool for communication.It is intrinsically linked to a people’s culture,values,and worldview.This observation is particularly salient in our globalized world,where linguistic considerations have assumed strategic importance.Recognizing this potential,numerous states are seeking to bolster their international relations by prioritizing the teaching of their languages.It is within this context that we focus our attention on the teaching of Chinese in Congo-Brazzaville.Our objective is to investigate the significance of this language in consolidating bilateral relations between China and Congo.To achieve this,we analyze the current state of Chinese language instruction within the Congolese educational system,emphasize the implications of its dissemination,and propose potential avenues for improvement.Our approach is qualitative,drawing upon observations,interviews,and a review of existing literature.We aim to understand how the teaching of Chinese can contribute to the economic,cultural,and social development of Congo,while simultaneously strengthening ties with China.展开更多
文摘An oil-in-water (O/W) solvent evaporation method was used to prepare biodegradable microspheresbased on poly(D,L-lactic acid) (PLA). Nifedipine, a hydrophobic drug, was chosen as a model molecule in the studyof drug entrapment and release. Effect of preparation conditions on the size, morphology, drug loading, and releaseprofiles of micropheres was investigated. Based on in vitro release experimental findings, a diffusion/dissolutionmodel was presented for quantitative description of the resulting release behaviors and drug release kinetics fromPLA microspheres analyzed. The mathematical models were used to predict the effect of microstructure on theresulting drug release. It provided an approach to determine the suitable structure parameters for microspheres toachieve desired drug release behaviors.
基金Projects(20775010,21075011) supported by the National Natural Science Foundation of ChinaProject(2008AA05Z405) supported by the National High Technology Research and Development Program of China+2 种基金Project(09JJ3016) supported by Hunan Provincial Natural Science Foundation,ChinaProject(09C066) supported by Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(2010CL01) supported by the Foundation of Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation,China
文摘A novel quantitative structure-property relationship （QSPR） model for estimating the solution surface tension of 92 organic compounds at 20℃ was developed based on newly introduced atom-type topological indices. The data set contained non-polar and polar liquids, and saturated and unsaturated compounds. The regression analysis shows that excellent result is obtained with multiple linear regression. The predictive power of the proposed model was discussed using the leave-one-out （LOO） cross-validated （CV） method. The correlation coefficient （R） and the leave-one-out cross-validation correlation coefficient （Rcv） of multiple linear regression model are 0.991 4 and 0.991 3, respectively. The new model gives the average absolute relative deviation of 1.81% for 92 substances. The result demonstrates that novel topological indices based on the equilibrium electro-negativity of atom and the relative bond length are useful model parameters for QSPR analysis of compounds.
基金supported by the National Science Fund for Distinguished Young Scholars(No.22125101).
文摘The ring-opening polymerization of heterocyclic monomers and the reversed ring-closing depolymerization of corresponding polymers with neutral thermodynamics are broadly explored to establish a circular economy of next-generation plastics.Polythioesters(PTEs),analogues of polyesters,are emerging materials for this purpose due to their high refractive index,high crystallinity,dynamic property and responsiveness.In this work,we synthesize and polymerize a series of D-penicillamine-derivedβ-thiolactones(NRPenTL)with varied side chain alkyl groups,and study the structure-property relationship of the resulting polymers.The obtained PTEs exhibit tunable glass transition temperature in a wide range of 130–50℃,and melting temperature of 90–105℃.In addition,copolymerizations of monomers with different side chains are effective in modulating material properties.The obtained homo and copolymers can be fully depolymerized to recycle monomers.This work provides a robust molecular platform and detailed structure-property relationship of PTEs with potential of achieving sustainable plastics.
基金supported by the National Natural Science Foundation of China (51871104)the Fundamental Research Funds for the Central Universities (No.2019kfy RCPY074)。
文摘As the scaling down of semiconductor devices, it would be necessary to discover the structure-property relationship of semiconductor nanomaterials at nanometer scale. In this review, the quantitative characterization technique off-axis electron holography is introduced in details, followed by its applications in various semiconductor nanomaterials including group IV, compound and two-dimensional semiconductor nanostructures in static states as well as under various stimuli. The advantages and disadvantages of off-axis electron holography in material analysis are discussed, the challenges facing in-situ electron holographic study of semiconductor devices at working conditions are presented, and all the possible influencing factors need to be considered to achieve the final goal of fulfilling quantitative characterization of the structure-property relationship of semiconductor devices at their working conditions.
基金supported by the National Natural Science Foundation of China(NSFC,No.22065031)the Key R&D Program of Gansu Province(No.21YF5GA066)+4 种基金Gansu Province College Industry Support Plan Project(No.2022CYZC-18)Natural Science Foundation of Gansu Province(Nos.2020-0405-JCC-630,20JR10RA088)Fundamental Research Funds for the Central Universities(Nos.31920190041,31920200002,31920190018,31920190013)Young Doctor Foundation of Gansu Province(No.2021QB-148)The Science and Technology Project Funded by Social Capital in Longnan City of Gansu Province(No.2021-SZ-01)。
文摘In recent twenty years,aggregation-induced emission(AIE),due to its excellent application prospect,has aroused widespread interests.The development of novel and easy to make AIE luminogens(AIEgens)is an attractive subject.For this purpose,it is very important to study the structure-property relationship of AIEgens.Because azine derivatives are easy to synthesis and some of them have nice AIE properties,herein,a series of azine derivatives(ADs)were employed as models to study the influence of different functional groups,electronic effects and structures on the AIE properties of azine derivatives.The AIE mechanism were studied by single crystal analysis,density functional theory(DFT)calculations and so on.The results indicated that the o-hydroxyl aryl substituted azine compounds could show good AIE properties.Meanwhile,the AIE properties of o-hydroxyl aryl substituted azine compounds were also influenced by the electronic effects of the aryl groups in the azine compounds.The o-hydroxyl groups could form intramolecular hydrogen bond with imine group,which play key role to restrict the intramolecular rotation of the aryl groups and act as base stone for the AIE process of this kind compounds.The HOMO-LUMO energy gaps of o-hydroxyl substituted azine are smaller than other homologous compounds,which is agree with the proposed AIE mechanism.Finally,thanks to the AIE properties,the o-hydroxy-substituted azines could be used as efficient Al^(3+)and Cu^(2+)fluorescent chemosensors in different conditions.In addition,test strips based on AD10 has been prepared,which can conveniently detect Cu^(2+)in industrial wastewater.This research supplied a way for the design of novel easy to make AIEgens through simple azine derivatives.
基金the National Natural Science Foundation of China(to grant No.29903006 and 29973023)the Visiting Scholar Foundation of Key Laboratory in University of China for their financial support
文摘A quantitative structure-property relationship (QSPR) study has been made for the prediction of the surface tension of nonionic surfactants in aqueous solution. The regressed model includes a topological descriptor, the Kier & Hall index of zero order (KH0) of the hydrophobic segment of surfactant and a quantum chemical one, the heat of formation (fHD) of surfactant molecules. The established general QSPR between the surface tension and the descriptors produces a correlation coefficient of multiple determination, 2r=0.9877, for 30 studied nonionic surfactants.
文摘X-ray crystal structures of 2,2',3,3'-and 3, 3',4,4'-biphenyltetracarboxylic dianhydride (2,2',3,3'- and 3,3',4,4'-BPDA) were determined. The dianhydride isomers have different symmetry caused by difference in two anhydride group positions and the dihedral angles between the two phenyl rings are 62.9°for 2,2',3,3',-BPDA and 0°for 3,3',4,4'-BPDA respectively. The polyimides from 2,2',3,3'-BPDA exhibit enhanced solubility, higher thermal stability, and higher glasstransition temperature (Tg) compared with those from 3,3',4,4'-BPDA.
基金supported by the National Natural Science Foundation of China(22325605,U21A20296,22076185,22406185)the Natural Science Foundation of Fujian Province(2024J08105)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB1170000)。
文摘Efficient removal of^(137)Cs and^(90)Sr from radioactive waste liquids is challenging due to their strong radioactivity,solubility,and mobility.Herein,the efficient Cs^(+)/Sr^(2+)capture has been achieved by layered thioniobates and thiotantalate with radiation resistance,namely K_(0.36)NbS_(2)·0.54H_(2)O(K-NbS_(2)),Rb_(0.36)NbS_(2)·0.54H_(2)O(Rb-NbS_(2)),and K_(0.33)TaS_(2)·0.75H_2O(K-TaS_(2)).In particular,K-NbS_(2)exhibits high adsorption capacities,fast kinetics,and fantastic p H durability.K-NbS_(2)is an unprecedented scavenger for selective Sr^(2+)capture in acidic solutions containing excess Na^(+)/Mg^(2+)ions.They show successful cleanup for acidic^(90)Sr-liquid-waste generated during industrial production.Importantly,the removal mechanism is revealed as the ion exchange between Cs^(+)/Sr^(2+)and interlayer K^(+)in thioniobates and thiotantalate due to their appropriate interlayer distances,flexible and adjustable frameworks,and strong affinity of soft basic S^(2-)for Cs^(+)/Sr^(2+).Further,the structure-property relationship study indicates that there is an inverted U-curve rule for the relationship between interlayer distances of layered metal sulfides and ion exchange performance.The rule combined with the factors affecting interlayer distance can be used to direct the structural design and predict properties for the specific recognition and separation of radionuclides.This is a pioneering work on the development of thioniobates/thiotantalate ion exchangers with a deep insight into structure-property relationship for radionuclide remediation.
基金support of the Shanghai Young Outstanding Academic Leaders Plan(Overseas)the Shanghai Pujiang Program(23PJ1409300)+2 种基金the National key research and development program(2023YFB250400)the National Natural Science Foundation of China(52271222)the Science and Technology Commission of Shanghai Municipal(23DZ1202500 and 21010503100).
文摘Spinels have been widely concerned as a promising class of electrocatalysts due to their appealing catalytic properties and the tunability of their compositions and structures.Ligand field theory(LFT),which describes the origins and the consequences of metal-ligand interactions,offers crucial insights for the design of spinel-type electrocatalysts.In this review,we timely summarize the research progress of spinel electrocatalysts that leverage LFT for structure-property insights,providing a pioneering perspective in this field.This review explores how LFT plays a pivotal role in optimizing the electrocatalytic properties of spinels.It covers important aspects such as identifying the origin of the catalytic properties,tuning the number of active sites,manipulating the eg-filling and the spin state of metal cations,and modulating the 2p band of ligands.We anticipate that this review will provide valuable theoretical guidance and inspire creative spinel designs that excel in electrocatalytic applications.
基金the Science and Engineering Re-search Board(SERB),India for providing the financial assistance to support this work(Project No.SRG/2020/002449).
文摘Since antiquity,humans have been involved in designing materials through alloying strategies to meet the ever-growing technological demands.In 2004,this endeavor witnessed a significant breakthrough with the discovery of high-entropy alloys(HEAs)comprising multi-principal elements.Owing to the four“core-effects”,these alloys exhibit exceptional properties including better structural stability,high strength and ductility,improved fatigue/fracture toughness,high corrosion and oxidation resistance,superconductiv-ity,magnetic properties,and good thermal properties.Different synthesis routes have been designed and used to meet the properties of interest for particular applications with varying dimensions.How-ever,HEAs are providing new opportunities and challenges for computational modelling of the complex structure-property correlations and in predictions of phase stability necessary for optimum performance of the alloy.Several attempts have been made to understand these alloys by empirical and computa-tional models,and data-driven approaches to accelerate the materials discovery with a desired set of properties.The present review discusses advances and inferences from simulations and models spanning multiple length and time scales explaining a comprehensive set of structure-properties relations.Addi-tionally,the role of machine learning approaches is also reviewed,underscoring the transformative role of computational modelling in unravelling the multifaceted properties and applications of HEAs,and the scope for future efforts in this direction.
文摘During Donald Trump’s first term,the“Trump Shock”brought world politics into an era of uncertainties and pulled the transatlantic alliance down to its lowest point in history.The Trump 2.0 tsunami brewed by the 2024 presidential election of the United States has plunged the U.S.-Europe relations into more gloomy waters,ushering in a more complex and turbulent period of adjustment.
文摘I am delighted to join my Thai and Chinese friends in celebrating the 50th anniversary of the establishment of diplomatic relations between our two great nations.It is the“Golden Jubilee”of Thailand-China friendship.Half a century ago when Thailand’s then Prime Minister M.R.Kukrit Pramoj and China’s Premier Zhou Enlai signed a Joint Communique on the Establishment of Diplomatic Relations on July 1,1975,the foundation for a profound and mutually beneficial partnership was laid,fostering enduring friendship,cooperation,and understanding between our two nations.This bond has stood the test of time amidst the ever-changing international landscape and been further enhanced by both countries’commitment to advancing the Comprehensive Strategic Cooperative Partnership and building a Thailand-China community with a shared future for enhanced stability,prosperity,and sustainability through a forwardlooking and people-centered vision.
文摘The year 2025 marks the 50th anniversary of diplomatic relations between China and the Philippines.Over the past half century,despite ups and downs,China-Philippines relations have maintained a steady momentum of development with continuous progress in political,economic,and cultural exchanges.Since the second half of 2023,the Philippines’freguent provocations in the South China Sea have negatively impacted bilateral relations.
文摘If there were any doubts about the Trump administration’s inherent obsession with decoupling,polarization and jolting of global trade,they can be laid to rest.A series of statements and measures have been made by the U.S.government on economic relations with China including administrative decision to hit Chinese goods with additional tariffs despite China.
文摘The year 2025 marks the 75th anniversary of the establishment of diplomatic relations between China and Indonesia.Over the past 75 years,the bilateral relationship has made significant progress across various fields,laying a solid foundation for regional stability.China Report ASEAN interviewed Indonesian Ambassador to China Djauhari Oratmangun to reflect on the remarkable journey of Indonesia-China relations over the past 75 years.
文摘This year marks the 50th anniversary of the establishment of diplomatic relations between China and the EU.Over half a century,China and the EU have steadily enhanced political mutual trust,deepened mutually beneficial cooperation,and firmly upheld multilateralism,bringing tangible benefits to both peoples and making a significant contribution to global peace and development.
文摘This article attempts to distinguish public relations(PRs)from propaganda,within the context of information management.Speedy dissemination of information is an important feature of contemporary communication practice globally.In this era,the information content of communication is an important element requiring critical evaluation.This is so,because of the need to safeguard the information ecosystem,considering the thin line between public relations and propaganda.While both propaganda and public relations aim to shape perceptions,influence attitudes,and sway opinions,one key distinction lies in their ethical considerations.Public relations emphasize honesty,accuracy,accountability,and a commitment to the truth.In contrast,propaganda may involve manipulation,distortion,or even fabrication of information to advance a particular agenda,often at the expense of truth and transparency.Hinged on The Excellence Theory and the Two-Way Symmetrical Model,the paper focuses on the meeting points and differences between public relations and propaganda,with a view to safeguarding the integrity of the information ecosystem.The study adopted the survey research method,with interview as research instrument.The study discovered that while propaganda is not entirely a bad practice,it has a heavy tilt towards bias.It therefore recommends that deliberate steps be taken by relevant professional organisations and other stakeholders towards educating the citizens on ways of distinguishing between public relations and propaganda contents.
基金part of the research project “What Are States Talking About?”(ISF Grant 2109/19),funded by the Israeli Science Foundation。
文摘Purpose:This paper presents a new semi-automatic methodology for identifying inter-actor relationships by discerning viewpoints in non-social,political textual corpora.Although previous research has successfully discerned viewpoints,biases,and affiliations based on textual features,the task of relationship analysis in the absence of interactional data remains unaddressed.Design/methodology/approach:We introduce a new paradigm for topic representation as a dynamic,continuous,multi-viewpoint spectrum based on the representation of viewpoints as vectors that capture common topical themes.As a proof of concept,we applied this paradigm to scrutinize the inter-state relationships reflected in the speeches of the UN General Assembly Debate Corpus(UNGDC).Findings:The proposed paradigm effectively identifies discursive trends in UNGDC.Our analysis reveals common attitudes towards the topic and their prominence among different groups of actors and facilitates the analysis of relationships between actors through a quantitative representation of viewpoint similarity.The method also successfully captured temporal shifts in viewpoints and overall discourse trends,correlating with major geopolitical events.Research limitations:One limitation of this study is the method’s sensitivity to data sparsity,which can skew viewpoint representations in cases of low topic involvement.Practical implications:The proposed paradigm can be utilized by scholars in political science and other domains as a tool for semi-automated unsupervised textual analysis of various non-social textual sources,enabling the discovery of latent relationships between actors and the modeling of viewpoints in complex topics.Originality/value:This study presents a novel framework for unsupervised semi-automatic textual analysis of relationships in non-social corpora through a new approach for the representation of viewpoints as thematic vectors.
文摘In contemporary society,language transcends its function as a mere tool for communication.It is intrinsically linked to a people’s culture,values,and worldview.This observation is particularly salient in our globalized world,where linguistic considerations have assumed strategic importance.Recognizing this potential,numerous states are seeking to bolster their international relations by prioritizing the teaching of their languages.It is within this context that we focus our attention on the teaching of Chinese in Congo-Brazzaville.Our objective is to investigate the significance of this language in consolidating bilateral relations between China and Congo.To achieve this,we analyze the current state of Chinese language instruction within the Congolese educational system,emphasize the implications of its dissemination,and propose potential avenues for improvement.Our approach is qualitative,drawing upon observations,interviews,and a review of existing literature.We aim to understand how the teaching of Chinese can contribute to the economic,cultural,and social development of Congo,while simultaneously strengthening ties with China.
