We pioneered a study about how the geometric relationship of single-walled carbon nanotubes(SWCNT) is influenced by curvature factor and non-planar geometry factor in cylindrical coordinate system based on the assumpt...We pioneered a study about how the geometric relationship of single-walled carbon nanotubes(SWCNT) is influenced by curvature factor and non-planar geometry factor in cylindrical coordinate system based on the assumption of complete symmetry. The bond length and angle of every carbon-carbon bonds are determined by using the principle of the minimum energy. The results of the paper include(1) From the calculation result, the symmetry breaking appears for chiral carbon nanotubes, while the part symmetry appears for achiral carbon nanotubes with increasing curvature.(2) The synergistic effect of bond lengths and bond angles is first found.(3) We conclude that the influence of non-planar geometry factor can be completely ignored on bond lengths and bond angles when the curvature parameter has been included in the model.(4)The two fractal dimensions are given from the nanoscale to the macroscale for zigzag topology and armchair topology respectively. Fractal dimensions of SWCNT show special characteristics, varying with the length of SWCNT until the lengths approach infinity. The close and inevitable correlations among curvature, symmetry breaking and stability of SWCNTs can be summed up as: the increase of curvature causes symmetry breaking,and such symmetry breaking will further reduce the structural stability.展开更多
In the paper, a general framework for large scale modeling of macroeconomic and financial time series is introduced. The proposed approach is characterized by simplicity of implementation, performing well independentl...In the paper, a general framework for large scale modeling of macroeconomic and financial time series is introduced. The proposed approach is characterized by simplicity of implementation, performing well independently of persistence and heteroskedasticity properties, accounting for common deterministic and stochastic factors. Monte Carlo results strongly support the proposed methodology, validating its use also for relatively small cross-sectional and temporal samples.展开更多
The Canavese Zone(CZ)in the Western Alps represents the remnant of the distal passive margin of the Adria microplate,which was stretched and thinned during the Jurassic opening of the Alpine Tethys.Through detailed ge...The Canavese Zone(CZ)in the Western Alps represents the remnant of the distal passive margin of the Adria microplate,which was stretched and thinned during the Jurassic opening of the Alpine Tethys.Through detailed geological mapping,stratigraphic and structural analyses,we document that the continental break-up of Pangea and tectonic dismemberment of the Adria distal margin,up to mantle rocks exhumation and oceanization,did not simply result from the syn-rift Jurassic extension but was strongly favored by older structu ral inheritances(the Proto-Canavese Shear Zone),which controlled earlier lithospheric weakness.Our findings allowed to redefine in detail(i)the tectono-stratigraphic setting of the Variscan metamorphic basement and the Late Carbonife rous to Early Cretaceous CZ succession,(ii)the role played by inherited Late Carboniferous to Early Triassic structures and(iii)the significance of the CZ in the geodynamic evolution of the Alpine Tethys.The large amount of extensional displacement and crustal thinning occurred during different pulses of Late Carbonife rous-Early Triassic strike-slip tectonics is wellconsistent with the role played by long-lived regional-scale wrench faults(e.g.,the East-Variscan Shear Zone),suggesting a re-discussion of models of mantle exhumation driven by low-angle detachment faults as unique efficient mechanism in stretching and thinning continental crust.展开更多
Non-stationary time series could be divided into piecewise stationary stochastic signal. However, the number and locations of breakpoints, as well as the approximation function of the respective segment signal are unk...Non-stationary time series could be divided into piecewise stationary stochastic signal. However, the number and locations of breakpoints, as well as the approximation function of the respective segment signal are unknown. To solve this problem, a novel on-line structural breaks estimation algorithm based on piecewise autoregressive processes is proposed. In order to find the "best" combination of the number, lengths, and orders of the piecewise autoregressive (AR) processes, the Akaikes Information Criterion (AIC) and Yule-Walker equations are applied to estimate an AR model fit to the data. Numerical results demonstrate that the proposed estimation algorithm is suitable for different data series. Furthermore, the algorithm is used in a clinical study of electroencephalogram (EEG) with satisfactory results, and the ability to deal with real-time data is the most outstanding characteristic of on-line structural breaks estimation algorithm proposed.展开更多
This study uses the dynamic conditional correlation to investigate how technology subsector stocks interact with financial assets in the face of economic and financial uncertainty.Our results suggest that structural b...This study uses the dynamic conditional correlation to investigate how technology subsector stocks interact with financial assets in the face of economic and financial uncertainty.Our results suggest that structural breaks have diverse effects on financial asset connectedness and that the level of bond linkage increases when the trend breaks.We see a growing co-movement between the technology sector and major financial assets when uncertainty is considered.Overall,our findings indicate that the connectedness response varies depending on the type of uncertainty shock.展开更多
This study tests the hysteresis hypothesis of unemployment in fifteen OECD countries by using panel unit root tests which allow for structural breaks. We apply annual unemployment rates covering 1985-2008 periods. We ...This study tests the hysteresis hypothesis of unemployment in fifteen OECD countries by using panel unit root tests which allow for structural breaks. We apply annual unemployment rates covering 1985-2008 periods. We test whether unemployment rates are stationary by using second generation tests which allow cross section dependency among series and panel unit root test based on structural break advanced by Carrion-i-Silvestre, Barrio-Castro and Lopez-Bazo （2005）. We find series as a stationary process with structural breaks according to Carrion-i Silvestre et al. （2005） test, while we find series as unit root process with second generation panel unit root test. According to the Carrion-i Silvestre et al. （2005） test, we find the evidence of absence of hysteresis in analyzed countries. As a result, temporary shocks have temporary effects on unemployment instead of permanent effect. Structural factors can affect the natural rate of unemployment and, therefore, unemployment would be stationary around a process that is subject to structural breaks. So, there still exists a unique natural rate of unemployment to which the economy eventually will converge.展开更多
The vertical price transmission is generally considered as the relationship between two markets of the same production chain However, we can expand this concept to another relation which has not been deeply investiga...The vertical price transmission is generally considered as the relationship between two markets of the same production chain However, we can expand this concept to another relation which has not been deeply investigated： the joint products. They are the products which are produced in a single production process, but not correspond to the same chain. An especial case is the beef and milk markets in Costa Rica. Even if these products usually correspond to disconnect chains, in Costa Rica farms make use of cattle to produce both meat and milk. The cointegration framework is applied in order to indentify the price transmission among these markets. In addition, the asymmetric behavior and structural breaks are taken into account. Price transmission between each market pair was found. First, the cattle prices adjust in the milk-cattle relationship, second, beef meat prices adjust in the cattle-beef meat and in the milk - beef meat relationship. Finally, the equations allowing for structural breaks affect the estimates in the following three ways： after the break the elasticities became higher than 1, there is more evidence of cointegration, and the adjustment coefficients are significant only when a change in the long run is allowed.展开更多
The Patagonian Shelf is a very productive region with dif ferent ecosystem structures. A long history of fishing in the Southwestern Atlantic Ocean combined with a complex hydrographic structure, with a permanent fron...The Patagonian Shelf is a very productive region with dif ferent ecosystem structures. A long history of fishing in the Southwestern Atlantic Ocean combined with a complex hydrographic structure, with a permanent front over the shelf-break and dif ferent coastal frontal regions, and a wide non-frontal area in between have made the food web in this area more complex and have resulted in changes to the spatialtemporal scale. Stable isotopes of carbon and nitrogen were used to determine the trophic structure of the Patagonian shelf break which was previously poorly understood. The results indicated that the average δ^(15)N value of pelagic guild(I llex argentinus) was remarkable lower than those of the other guilds. The δ^(13)C values of almost all species ranged from-17‰ to-18‰, but S tromateus brasiliensis had a significant lower δ^(13)C value. Compared with the southern Patagonian shelf, short food chain length also occurred. The impact of complex oceanographic structures has resulted in food web structure change to the temporal-spatial scale on the Patagonian shelf. The Patagonian shelf break can be considered as a separated ecosystem structure with lower δ^(15)N values.展开更多
Quinoid structures are considered to be conducive to the charge transport of organic molecules,but this hypothesis is rarely proven at single-molecule level.Herein,as a proof of concept,the single-molecule conductance...Quinoid structures are considered to be conducive to the charge transport of organic molecules,but this hypothesis is rarely proven at single-molecule level.Herein,as a proof of concept,the single-molecule conductance of two furan-based isomers,3,3'-bis(4-(methylthio)phenyl)-2,2'-bifuran(2,2'-SMPBF)and 4,4'-bis(4-(methylthio)phenyl)-3,3'-bifuran(3,3'-SMPBF),is investigated by the scanning tunneling microscopy break junction(STM-BJ)technique and theoretical simulation.2,2'-SMPBF prefers to adopt a nearly planar conformation with intact alternating single and double bonds extended via2,2'-bifuran moiety and therefore exhibits goodπ-conjugation and a prominent quinoid structure.However,theπ-conjugation of 3,3'-SMPBF is interrupted due to ineffective cross-conjugation in the 3,3'-bifuran moiety,leading to the absence of a quinoid structure.2,2'-SMPBF displays switchable multiple conductances induced by the interconversion between folded and unfolded conformations and an abnormal rebound of conductance along with the increases of electrode displacement,which is demonstrated to be caused by the quinoid structure in a nearly planar conformation during the stretching process.However,3,3'-SMPBF without a quinoid structure in unfolded conformation exhibits extremely low conductance that cannot be captured in STM-BJ measurements.These results reveal the significant contribution of quinoid structure to molecular charge transport and provide valuable information on the structure-transport relationship for the design of efficient organic semiconductors.展开更多
To study ice-induced vibration of a compliant conical structure, a series of model tests were performed from 2004 to 2005. In the tests, the ice sheet before the compliant conical structure was found to fail in two-ti...To study ice-induced vibration of a compliant conical structure, a series of model tests were performed from 2004 to 2005. In the tests, the ice sheet before the compliant conical structure was found to fail in two-time breaking. From 2005 to 2006, this type of ice failure was studied through more groups of tests. The tests show that two-time breaking is the typical failure of ice before steep conical structures, and is controlled by other factors at the same time, such as ice speed and the angle of the cone.展开更多
For the study on the ice-induced vibration of a compliant mono-cone structure,a series of model tests were performed from 2004 to 2006.In these tests,the ice sheet before the compliant conical structure was found to b...For the study on the ice-induced vibration of a compliant mono-cone structure,a series of model tests were performed from 2004 to 2006.In these tests,the ice sheet before the compliant conical structure was found to be failed in two-time breaking.Based on this important finding,model tests study of the ice force on a compliant multi-cone structure were performed from 2006 to 2007.In these tests,the ice sheet broke before each single cone non-simultaneously.The exciting energy of the total ice force was found to be in a wide range of frequencies,and the structure can be easily excited with nonlinear resonance.展开更多
Floating structures are commonly seen in coastal and offshore engineering. They are often subjected to extreme waves and, therefore, their nonlinear dynamic behaviors are of great concern. In this paper, an in-house C...Floating structures are commonly seen in coastal and offshore engineering. They are often subjected to extreme waves and, therefore, their nonlinear dynamic behaviors are of great concern. In this paper, an in-house CFD code is developed to investigate the accurate prediction of nonlinear dynamic behaviors of a two-dimensional（2-D） box-shaped floating structure in focused waves. Computations are performed by an enhanced Constrained Interpolation Profile（CIP）-based Cartesian grid model, in which a more accurate VOF（Volume of Fluid） method, the THINC/SW scheme（THINC： tangent of hyperbola for interface capturing; SW： Slope Weighting）, is used for interface capturing. A focusing wave theory is used for the focused wave generation. The wave component of constant steepness is chosen. Comparisons between predictions and physical measurements show good agreement including body motions and free surface profiles. Although the overall agreement is good, some discrepancies are observed for impact pressure on the superstructure due to water on deck. The effect of grid resolution on the results is checked. With a fine grid, no obvious improvement is seen in the global body motions and impact pressures due to water on deck. It is concluded that highly nonlinear phenomena, such as distorted free surface, large-amplitude body motions, and violent impact flow, have been predicted successfully.展开更多
基金National Natural Science Foundation of China (No. 10602028)Student Research Train Program of BeiHang University
文摘We pioneered a study about how the geometric relationship of single-walled carbon nanotubes(SWCNT) is influenced by curvature factor and non-planar geometry factor in cylindrical coordinate system based on the assumption of complete symmetry. The bond length and angle of every carbon-carbon bonds are determined by using the principle of the minimum energy. The results of the paper include(1) From the calculation result, the symmetry breaking appears for chiral carbon nanotubes, while the part symmetry appears for achiral carbon nanotubes with increasing curvature.(2) The synergistic effect of bond lengths and bond angles is first found.(3) We conclude that the influence of non-planar geometry factor can be completely ignored on bond lengths and bond angles when the curvature parameter has been included in the model.(4)The two fractal dimensions are given from the nanoscale to the macroscale for zigzag topology and armchair topology respectively. Fractal dimensions of SWCNT show special characteristics, varying with the length of SWCNT until the lengths approach infinity. The close and inevitable correlations among curvature, symmetry breaking and stability of SWCNTs can be summed up as: the increase of curvature causes symmetry breaking,and such symmetry breaking will further reduce the structural stability.
文摘In the paper, a general framework for large scale modeling of macroeconomic and financial time series is introduced. The proposed approach is characterized by simplicity of implementation, performing well independently of persistence and heteroskedasticity properties, accounting for common deterministic and stochastic factors. Monte Carlo results strongly support the proposed methodology, validating its use also for relatively small cross-sectional and temporal samples.
基金supported by research grants from Universita di Torino (Ricerca Locale "ex 60%" 2014—2018)the Italian Ministry of University and Research ("Finanziamento annuale individuale delle attivita base di ricerca" 2017) to A.Festa and G.Balestro, and from "Comune di Tavagnasco" to S.De Caroli and A.Succo
文摘The Canavese Zone(CZ)in the Western Alps represents the remnant of the distal passive margin of the Adria microplate,which was stretched and thinned during the Jurassic opening of the Alpine Tethys.Through detailed geological mapping,stratigraphic and structural analyses,we document that the continental break-up of Pangea and tectonic dismemberment of the Adria distal margin,up to mantle rocks exhumation and oceanization,did not simply result from the syn-rift Jurassic extension but was strongly favored by older structu ral inheritances(the Proto-Canavese Shear Zone),which controlled earlier lithospheric weakness.Our findings allowed to redefine in detail(i)the tectono-stratigraphic setting of the Variscan metamorphic basement and the Late Carbonife rous to Early Cretaceous CZ succession,(ii)the role played by inherited Late Carboniferous to Early Triassic structures and(iii)the significance of the CZ in the geodynamic evolution of the Alpine Tethys.The large amount of extensional displacement and crustal thinning occurred during different pulses of Late Carbonife rous-Early Triassic strike-slip tectonics is wellconsistent with the role played by long-lived regional-scale wrench faults(e.g.,the East-Variscan Shear Zone),suggesting a re-discussion of models of mantle exhumation driven by low-angle detachment faults as unique efficient mechanism in stretching and thinning continental crust.
基金supported by Fund of National Science & Technology monumental projects under Grants No. 2012ZX03005012, 2011ZX03005-004-03, 2009ZX03003-007
文摘Non-stationary time series could be divided into piecewise stationary stochastic signal. However, the number and locations of breakpoints, as well as the approximation function of the respective segment signal are unknown. To solve this problem, a novel on-line structural breaks estimation algorithm based on piecewise autoregressive processes is proposed. In order to find the "best" combination of the number, lengths, and orders of the piecewise autoregressive (AR) processes, the Akaikes Information Criterion (AIC) and Yule-Walker equations are applied to estimate an AR model fit to the data. Numerical results demonstrate that the proposed estimation algorithm is suitable for different data series. Furthermore, the algorithm is used in a clinical study of electroencephalogram (EEG) with satisfactory results, and the ability to deal with real-time data is the most outstanding characteristic of on-line structural breaks estimation algorithm proposed.
基金supported by the Ministry of Education of the Republic of Korea and the National Research Foundation of Korea(NRF-2022S1A5A2A01038422).
文摘This study uses the dynamic conditional correlation to investigate how technology subsector stocks interact with financial assets in the face of economic and financial uncertainty.Our results suggest that structural breaks have diverse effects on financial asset connectedness and that the level of bond linkage increases when the trend breaks.We see a growing co-movement between the technology sector and major financial assets when uncertainty is considered.Overall,our findings indicate that the connectedness response varies depending on the type of uncertainty shock.
文摘This study tests the hysteresis hypothesis of unemployment in fifteen OECD countries by using panel unit root tests which allow for structural breaks. We apply annual unemployment rates covering 1985-2008 periods. We test whether unemployment rates are stationary by using second generation tests which allow cross section dependency among series and panel unit root test based on structural break advanced by Carrion-i-Silvestre, Barrio-Castro and Lopez-Bazo （2005）. We find series as a stationary process with structural breaks according to Carrion-i Silvestre et al. （2005） test, while we find series as unit root process with second generation panel unit root test. According to the Carrion-i Silvestre et al. （2005） test, we find the evidence of absence of hysteresis in analyzed countries. As a result, temporary shocks have temporary effects on unemployment instead of permanent effect. Structural factors can affect the natural rate of unemployment and, therefore, unemployment would be stationary around a process that is subject to structural breaks. So, there still exists a unique natural rate of unemployment to which the economy eventually will converge.
文摘The vertical price transmission is generally considered as the relationship between two markets of the same production chain However, we can expand this concept to another relation which has not been deeply investigated： the joint products. They are the products which are produced in a single production process, but not correspond to the same chain. An especial case is the beef and milk markets in Costa Rica. Even if these products usually correspond to disconnect chains, in Costa Rica farms make use of cattle to produce both meat and milk. The cointegration framework is applied in order to indentify the price transmission among these markets. In addition, the asymmetric behavior and structural breaks are taken into account. Price transmission between each market pair was found. First, the cattle prices adjust in the milk-cattle relationship, second, beef meat prices adjust in the cattle-beef meat and in the milk - beef meat relationship. Finally, the equations allowing for structural breaks affect the estimates in the following three ways： after the break the elasticities became higher than 1, there is more evidence of cointegration, and the adjustment coefficients are significant only when a change in the long run is allowed.
基金Supported by the National Key Technology R&D Program of China(No.2013BAD13B03)the National Natural Science Foundation of China(No.41776185)the Special Fund for Agro-Scientifi c Research in the Public Interest of China(No.201203018)
文摘The Patagonian Shelf is a very productive region with dif ferent ecosystem structures. A long history of fishing in the Southwestern Atlantic Ocean combined with a complex hydrographic structure, with a permanent front over the shelf-break and dif ferent coastal frontal regions, and a wide non-frontal area in between have made the food web in this area more complex and have resulted in changes to the spatialtemporal scale. Stable isotopes of carbon and nitrogen were used to determine the trophic structure of the Patagonian shelf break which was previously poorly understood. The results indicated that the average δ^(15)N value of pelagic guild(I llex argentinus) was remarkable lower than those of the other guilds. The δ^(13)C values of almost all species ranged from-17‰ to-18‰, but S tromateus brasiliensis had a significant lower δ^(13)C value. Compared with the southern Patagonian shelf, short food chain length also occurred. The impact of complex oceanographic structures has resulted in food web structure change to the temporal-spatial scale on the Patagonian shelf. The Patagonian shelf break can be considered as a separated ecosystem structure with lower δ^(15)N values.
基金financially supported by the National Natural Science Foundation of China(Nos.U23A20594,22375066 and 21788102)Guang Dong Basic and Applied Basic Research Foundation(No.2023B1515040003)。
文摘Quinoid structures are considered to be conducive to the charge transport of organic molecules,but this hypothesis is rarely proven at single-molecule level.Herein,as a proof of concept,the single-molecule conductance of two furan-based isomers,3,3'-bis(4-(methylthio)phenyl)-2,2'-bifuran(2,2'-SMPBF)and 4,4'-bis(4-(methylthio)phenyl)-3,3'-bifuran(3,3'-SMPBF),is investigated by the scanning tunneling microscopy break junction(STM-BJ)technique and theoretical simulation.2,2'-SMPBF prefers to adopt a nearly planar conformation with intact alternating single and double bonds extended via2,2'-bifuran moiety and therefore exhibits goodπ-conjugation and a prominent quinoid structure.However,theπ-conjugation of 3,3'-SMPBF is interrupted due to ineffective cross-conjugation in the 3,3'-bifuran moiety,leading to the absence of a quinoid structure.2,2'-SMPBF displays switchable multiple conductances induced by the interconversion between folded and unfolded conformations and an abnormal rebound of conductance along with the increases of electrode displacement,which is demonstrated to be caused by the quinoid structure in a nearly planar conformation during the stretching process.However,3,3'-SMPBF without a quinoid structure in unfolded conformation exhibits extremely low conductance that cannot be captured in STM-BJ measurements.These results reveal the significant contribution of quinoid structure to molecular charge transport and provide valuable information on the structure-transport relationship for the design of efficient organic semiconductors.
基金This project is financially supported by the National High Technology Research Development Program of China(863Program) by the National Natural Science Foundation of China(Grant No.50609015)
文摘To study ice-induced vibration of a compliant conical structure, a series of model tests were performed from 2004 to 2005. In the tests, the ice sheet before the compliant conical structure was found to fail in two-time breaking. From 2005 to 2006, this type of ice failure was studied through more groups of tests. The tests show that two-time breaking is the typical failure of ice before steep conical structures, and is controlled by other factors at the same time, such as ice speed and the angle of the cone.
基金supported bythe National High Technology Research and Development Program of China(863Program,Grant No.2003AA602150-3)the National Natural Science Foundation of China(Grant No.50609015)
文摘For the study on the ice-induced vibration of a compliant mono-cone structure,a series of model tests were performed from 2004 to 2006.In these tests,the ice sheet before the compliant conical structure was found to be failed in two-time breaking.Based on this important finding,model tests study of the ice force on a compliant multi-cone structure were performed from 2006 to 2007.In these tests,the ice sheet broke before each single cone non-simultaneously.The exciting energy of the total ice force was found to be in a wide range of frequencies,and the structure can be easily excited with nonlinear resonance.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.51209184 and 51479175)Zhejiang Provincial Natural Science Foundation of China(Grant No.LR16E090002)the Open Foundation of State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering(Grant No.2013490211)
文摘Floating structures are commonly seen in coastal and offshore engineering. They are often subjected to extreme waves and, therefore, their nonlinear dynamic behaviors are of great concern. In this paper, an in-house CFD code is developed to investigate the accurate prediction of nonlinear dynamic behaviors of a two-dimensional（2-D） box-shaped floating structure in focused waves. Computations are performed by an enhanced Constrained Interpolation Profile（CIP）-based Cartesian grid model, in which a more accurate VOF（Volume of Fluid） method, the THINC/SW scheme（THINC： tangent of hyperbola for interface capturing; SW： Slope Weighting）, is used for interface capturing. A focusing wave theory is used for the focused wave generation. The wave component of constant steepness is chosen. Comparisons between predictions and physical measurements show good agreement including body motions and free surface profiles. Although the overall agreement is good, some discrepancies are observed for impact pressure on the superstructure due to water on deck. The effect of grid resolution on the results is checked. With a fine grid, no obvious improvement is seen in the global body motions and impact pressures due to water on deck. It is concluded that highly nonlinear phenomena, such as distorted free surface, large-amplitude body motions, and violent impact flow, have been predicted successfully.
