In order to study the influence of highland barley straw ash (HBSA) prepared under certain conditions on the durability of magnesium oxychloride cement mortar (MOCM) under freeze-thaw damage,rapid freeze-thaw cycle te...In order to study the influence of highland barley straw ash (HBSA) prepared under certain conditions on the durability of magnesium oxychloride cement mortar (MOCM) under freeze-thaw damage,rapid freeze-thaw cycle tests were carried out firstly.The relative mass evaluation parameters and the relative compressive strength evaluation parameters,which represent the degradation of freeze-thaw resistance,were used as the indices to study the degradation rule of MOCM.Secondly,nuclear magnetic resonance (NMR) tests were carried out on MOCM under different freeze-thaw cycles to analyze the pore diameter changes in the freeze-thaw process.The microstructure of MOCM was tested by Fourier transform infrared spectroscopy (FTIR),X-ray diffraction (XRD) and scanning electron microscopy (SEM),and then the effect mechanism of HBSA on the anti-freezing performance of MOCM was revealed.Finally,the two-parameter Weibull distribution function was used to analyze the reliability of durability degradation of MOCM added with HBSA under freeze-thaw cycles.The specific conclusions are as follows:With the increase of HBSA's addition,the freeze-thaw resistance of MOCM increase firstly and then decrease.When the addition of HBSA is 10%,the decay rate of relative mass evaluation parameters and relative compressive strength evaluation parameters is the slowest,and the frost resistance is the best.The proportion of harmful pores and more harmful pores in MOCM added with 10% HBSA decreases by 25.11% and 21.34%,compared with that without HBSA before and after freeze-thaw cycles.A lot of magnesium silicate hydrate (M-S-H) gels are generated in MOCM with HBSA content of 10%,which fills part of the pores,so that the proportion of harmful pores and more harmful pores is the lowest.The Weibull function can be effectively applied to the reliability analysis of the freeze-thaw cycle of MOCM added with HBSA,and the theoretical results are in good agreement with the experimental results.展开更多
This research explores the utilization of wheat straw ash(WSA),an agricultural by-product enriched with amorphous silica,as a partial cement replacement in concrete production.The WSA content ranged from 4%to 16%by ma...This research explores the utilization of wheat straw ash(WSA),an agricultural by-product enriched with amorphous silica,as a partial cement replacement in concrete production.The WSA content ranged from 4%to 16%by mass,with water-to-cement(w/c)ratios varying between 0.4 and 0.6.Using response surface methodology(RSM)combined with central composite design,this study optimized mix designs and developed predictive models for key performance indicators,including workability and mechanical properties of concrete.The results demonstrate that an optimal balance of the WSA and a reduced w/c ratio significantly enhance both the workability and mechanical performance of concrete.The pozzolanic reaction between WSA and calcium hydroxide promotes the formation of calcium silicate hydrate(C-S-H)gel.The optimal mix composition,comprising 10.12%w(WSA)with a w/c ratio of 0.45,achieved a desirability score of 71.83%.This ground-breaking research underscores the viability of WSA as a supplementary cementitious material,offering a sustainable solution for concrete production while simultaneously enhancing its workability and mechanical properties.展开更多
The effect of calcination temperature on the pozzolanic activity of maize straw stem ash(MSSA)was evaluated.The MSSA samples calcined at temperature values of 500,700,and 850℃ were dissolved in portlandite solution f...The effect of calcination temperature on the pozzolanic activity of maize straw stem ash(MSSA)was evaluated.The MSSA samples calcined at temperature values of 500,700,and 850℃ were dissolved in portlandite solution for 6 h,thereby obtaining residual samples.The MSSA and MSSA residual samples were analyzed using Fourier transform infrared spectroscopy,X-ray powder diffraction scanning electron microscopy,and X-ray photoelectron spectroscopy to determine vibration bonds,minerals,microstructures,and Si 2p transformation behavior.The conductivity,pH value,and loss of conductivity with dissolving time of the MSSA-portlandite mixed solution were also determined.The main oxide composition of MSSA was silica and potassium oxide.The dissolution of the Si^(4+) content of MSSA at 500℃ was higher than those of the other calcination temperatures.The conductivity and loss of conductivity of MSSA at 700℃ were higher than those of the other calcination temperatures at a particular dissolving time due to the higher KCl content in MSSA at 700℃.C-S-H was easily identified in MSSA samples using X-ray powder diffraction,and small cubic and nearly spherical particles of C-S-H were found in the MSSA residual samples.In conclusion,the optimum calcination temperature of MSSA having the best pozzolanic activity is 500℃,but excessive agglomeration must be prevented.展开更多
The treatment of wheat straw is very difficult,and its utilization rate is very low;accumulation causes air pollution and even fire.To make full use of wheat straw resources,we examined how using different physical an...The treatment of wheat straw is very difficult,and its utilization rate is very low;accumulation causes air pollution and even fire.To make full use of wheat straw resources,we examined how using different physical and chemical methods to treat the wheat straw which can improve its strength abilities,or enhance the activity of wheat straw ash.In terms of concrete additives,it can reduce the amount of cement used.In this paper,we found that alkali treatment can significantly improve the tensile strength of wheat straw fiber,but polyvinyl alcohol treatment has no obvious effect on the strength of wheat straw fiber after alkali treatment.At the same time,we analyzed the wheat straw fiber microstructure through scanning electron microscopy,and we also studied the wheat straw ash chemical composition after 600℃ high-temperature treatment.Through the compressive strength test,we found that the strength of concrete decreases with increasing of wheat straw fiber and wheat straw powder content,and the compressive strength of concrete with wheat straw ash instead of 5%cement decreases little,and the strength of the concrete also decreases with the increasing of wheat straw ash.Through the macroscopic observation of the failure form of concrete,we found that the failure form of concrete with wheat straw ash is similar to that of common concrete,while the failure degree of concrete with wheat straw fiber and wheat straw powder is weakened.Through the scanning electron microscope test of the concrete,it was found that wheat straw fiber has an effect on the cracking of concrete and the inner compactness of concrete can also be affected by adding wheat straw ash and wheat straw powder.展开更多
基金Funded by the National Natural Science Foundation of China (No.51868044)Basic Research Program of Qinghai Province (No.2022-ZJ-921)。
文摘In order to study the influence of highland barley straw ash (HBSA) prepared under certain conditions on the durability of magnesium oxychloride cement mortar (MOCM) under freeze-thaw damage,rapid freeze-thaw cycle tests were carried out firstly.The relative mass evaluation parameters and the relative compressive strength evaluation parameters,which represent the degradation of freeze-thaw resistance,were used as the indices to study the degradation rule of MOCM.Secondly,nuclear magnetic resonance (NMR) tests were carried out on MOCM under different freeze-thaw cycles to analyze the pore diameter changes in the freeze-thaw process.The microstructure of MOCM was tested by Fourier transform infrared spectroscopy (FTIR),X-ray diffraction (XRD) and scanning electron microscopy (SEM),and then the effect mechanism of HBSA on the anti-freezing performance of MOCM was revealed.Finally,the two-parameter Weibull distribution function was used to analyze the reliability of durability degradation of MOCM added with HBSA under freeze-thaw cycles.The specific conclusions are as follows:With the increase of HBSA's addition,the freeze-thaw resistance of MOCM increase firstly and then decrease.When the addition of HBSA is 10%,the decay rate of relative mass evaluation parameters and relative compressive strength evaluation parameters is the slowest,and the frost resistance is the best.The proportion of harmful pores and more harmful pores in MOCM added with 10% HBSA decreases by 25.11% and 21.34%,compared with that without HBSA before and after freeze-thaw cycles.A lot of magnesium silicate hydrate (M-S-H) gels are generated in MOCM with HBSA content of 10%,which fills part of the pores,so that the proportion of harmful pores and more harmful pores is the lowest.The Weibull function can be effectively applied to the reliability analysis of the freeze-thaw cycle of MOCM added with HBSA,and the theoretical results are in good agreement with the experimental results.
文摘This research explores the utilization of wheat straw ash(WSA),an agricultural by-product enriched with amorphous silica,as a partial cement replacement in concrete production.The WSA content ranged from 4%to 16%by mass,with water-to-cement(w/c)ratios varying between 0.4 and 0.6.Using response surface methodology(RSM)combined with central composite design,this study optimized mix designs and developed predictive models for key performance indicators,including workability and mechanical properties of concrete.The results demonstrate that an optimal balance of the WSA and a reduced w/c ratio significantly enhance both the workability and mechanical performance of concrete.The pozzolanic reaction between WSA and calcium hydroxide promotes the formation of calcium silicate hydrate(C-S-H)gel.The optimal mix composition,comprising 10.12%w(WSA)with a w/c ratio of 0.45,achieved a desirability score of 71.83%.This ground-breaking research underscores the viability of WSA as a supplementary cementitious material,offering a sustainable solution for concrete production while simultaneously enhancing its workability and mechanical properties.
基金financially supported by the Distinguished Youth Funds of National Natural Science Foundation of China(No.51925402)the Ten Thousand Talent Program of China for Leading Scientists in Science,Technology and Innovation,the Shanxi Science and Technology Major Project Funds(No.20201102004)+3 种基金the Shanxi“1331 Project”Fundsthe Shanxi Province Key Laboratory Construction Project Fundsthe Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering(Nos.2021SX-TD001 and 2021SX-TD002)the Shanxi Province Postgraduate Education Innovation Project(No.2021Y191).
文摘The effect of calcination temperature on the pozzolanic activity of maize straw stem ash(MSSA)was evaluated.The MSSA samples calcined at temperature values of 500,700,and 850℃ were dissolved in portlandite solution for 6 h,thereby obtaining residual samples.The MSSA and MSSA residual samples were analyzed using Fourier transform infrared spectroscopy,X-ray powder diffraction scanning electron microscopy,and X-ray photoelectron spectroscopy to determine vibration bonds,minerals,microstructures,and Si 2p transformation behavior.The conductivity,pH value,and loss of conductivity with dissolving time of the MSSA-portlandite mixed solution were also determined.The main oxide composition of MSSA was silica and potassium oxide.The dissolution of the Si^(4+) content of MSSA at 500℃ was higher than those of the other calcination temperatures.The conductivity and loss of conductivity of MSSA at 700℃ were higher than those of the other calcination temperatures at a particular dissolving time due to the higher KCl content in MSSA at 700℃.C-S-H was easily identified in MSSA samples using X-ray powder diffraction,and small cubic and nearly spherical particles of C-S-H were found in the MSSA residual samples.In conclusion,the optimum calcination temperature of MSSA having the best pozzolanic activity is 500℃,but excessive agglomeration must be prevented.
基金Supported by the Opening Project of Tunnel and Underground Engineering Research Center of Jiangsu Province (TERC) (2021-SDJJ-08).
文摘The treatment of wheat straw is very difficult,and its utilization rate is very low;accumulation causes air pollution and even fire.To make full use of wheat straw resources,we examined how using different physical and chemical methods to treat the wheat straw which can improve its strength abilities,or enhance the activity of wheat straw ash.In terms of concrete additives,it can reduce the amount of cement used.In this paper,we found that alkali treatment can significantly improve the tensile strength of wheat straw fiber,but polyvinyl alcohol treatment has no obvious effect on the strength of wheat straw fiber after alkali treatment.At the same time,we analyzed the wheat straw fiber microstructure through scanning electron microscopy,and we also studied the wheat straw ash chemical composition after 600℃ high-temperature treatment.Through the compressive strength test,we found that the strength of concrete decreases with increasing of wheat straw fiber and wheat straw powder content,and the compressive strength of concrete with wheat straw ash instead of 5%cement decreases little,and the strength of the concrete also decreases with the increasing of wheat straw ash.Through the macroscopic observation of the failure form of concrete,we found that the failure form of concrete with wheat straw ash is similar to that of common concrete,while the failure degree of concrete with wheat straw fiber and wheat straw powder is weakened.Through the scanning electron microscope test of the concrete,it was found that wheat straw fiber has an effect on the cracking of concrete and the inner compactness of concrete can also be affected by adding wheat straw ash and wheat straw powder.
