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Spatial analysis of carbon storage density of mid-subtropical forests using geostatistics: a case study in Jiangle County, southeast China 被引量:7
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作者 Zhuo Lin Lin Chao +3 位作者 Chengzhen Wu Wei Hong Tao Hong Xisheng Hu 《Acta Geochimica》 EI CAS CSCD 2018年第1期90-101,共12页
The mid-subtropical forest is one of the biggest sections of subtropical forest in China and plays a vital role in mitigating climate change by sequestering carbon.Studies have examined carbon storage density(CSD) dis... The mid-subtropical forest is one of the biggest sections of subtropical forest in China and plays a vital role in mitigating climate change by sequestering carbon.Studies have examined carbon storage density(CSD) distribution in temperate forests. However, our knowledge of CSD in subtropical forests is limited. In this study, Jiangle County was selected as a study case to explore geographic variation in CSD. A spatial heterogeneity analysis by semivariogram revealed that CSD varied at less than the mesoscale(approximately 2000–3000 m). CSD distribution mapped using Kriging regression revealed an increasing trend in CSD from west to east of the study area.Global spatial autocorrelation analysis indicated that CSD was clustered at the village level(at 5% significance).Some areas with local spatial autocorrelation were detected by Anselin Local Moran's I and Getis-Ord G*. A geographically weighted regression model showed different impacts on the different areas for each determinant. Generally, diameter at breast height, tree height, and stand density had positive correlation with CSD in Jiangle County, but varied substantially in magnitude by location.In contrast, coefficients of elevation and slope ranged from negative to positive. Based on these results, we propose certain measures to increase forest carbon storage,including increasing forested area, improving the quality of the current forests, and promoting reasonable forest management decisions and harvesting strategies. The established CSD model emphasizes the important role of midsubtropical forest in carbon sequestration and provides useful information for quantifying mid-subtropical forest carbon storage. 展开更多
关键词 Carbon storage density GEOSTATISTICS Mid-subtropical forests Spatial autocorrelation Spatial heterogeneity
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Fatigue-less relaxor ferroelectric thin films with high energy storage density via defect engineer 被引量:4
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作者 Baijie Song Shuanghao Wu +4 位作者 Hao Yan Kun Zhu Liuxue Xu Bo Shen Jiwei Zhai 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2021年第18期178-186,共9页
Thin film capacitors with excellent energy storage performances,thermal stability and fatigue endurance are strongly desired in modern electrical and electronic industry.Herein,we design and prepare lead-free0.7Sr_(0.... Thin film capacitors with excellent energy storage performances,thermal stability and fatigue endurance are strongly desired in modern electrical and electronic industry.Herein,we design and prepare lead-free0.7Sr_(0.7)Bi_(0.2)TiO_(3)-0.3BiFeO_(3)-x%Mn(x=0,0.5,1.5,2,3)thin films via sol-gel method.Mn ions of divalent valence combine with oxygen vacancies,forming defect complex,which results in marked decline in leakage current and obvious enhancement in breakdown strength.A high energy storage density~47.6 J cm^(-3)and good efficiency~65.68%are simultaneously achieved in 2%Mn doped 0.7Sr_(0.7)Bi_(0.2)TiO_(3)-0.3 BiFeO_(3)thin film capacitor.Moreover,the 2%Mn-doped thin film exhibits excellent thermal stability in wide operating temperature range(35–115℃)and strong fatigue endurance behaviors after 108 cycles.The above results demonstrate that 2%Mn-doped 0.7Sr_(0.7)Bi_(0.2)TiO_(3)-0.3 BiFeO_(3)thin film capacitor with superior energy storage performances is a potential candidate for electrostatic energy storage. 展开更多
关键词 Relaxor ferroelectric thin films Energy storage density Defect engineer
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Ultrahigh breakdown strength achieving exceptional recoverable energy storage density in NaNbO_(3)-based lead-free dielectrics
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作者 Yuhang HU Bing XIE +5 位作者 Shixian WU Hao ZU Zhiyong LIU Kun GUO Pu MAO Huajie LUO 《Science China(Technological Sciences)》 2026年第3期137-145,共9页
Dielectric ceramic capacitors have attracted significant interest in advanced pulsed power systems owing to their ultrahigh power density and fast charge/discharge capabilities. The low breakdown strength(E_(b)) of di... Dielectric ceramic capacitors have attracted significant interest in advanced pulsed power systems owing to their ultrahigh power density and fast charge/discharge capabilities. The low breakdown strength(E_(b)) of dielectric ceramics poses a major bottleneck for achieving high recoverable energy storage density(W rec). In this study, using ingenious chemical component design, we achieved an ultrahigh Eb of 800 kV/cm and an excellent W rec value of 9.48 J/cm^(3) in the simple component 0.92NaNbO_(3)–0.08SmFeO_(3) ceramic. Finite element simulations corroborate that the optimized grain boundary network enables more uniform electric field distribution and effective suppression of breakdown propagation. The superior energy storage characteristics originate from two synergistic mechanisms:(Ι) the incorporation of SmFeO_(3) suppresses grain growth, resulting in refined microstructure with increased grain boundary density that substantially enhances E_(b);(II) the introduction of Sm^(3+) and Fe^(3+) ions causes a mismatch between the A/B site ions, inducing lattice distortion and high disorder, which enhances the local random fields and relaxor behavior. This study establishes a promising pathway for designing high-energy-density dielectric ceramic capacitors. 展开更多
关键词 relaxor ferroelectric breakdown strength energy storage density
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Achieving ultrahigh energy storage density and energy efficiency simultaneously in sodium niobate-based lead-free dielectric capacitors via microstructure modulation
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作者 Mingxing Zhou Ruihong Liang +1 位作者 Zhiyong Zhou Xianlin Dong 《Inorganic Chemistry Frontiers》 2019年第8期2148-2157,共10页
Recently,dielectric capacitors have drawn much attention from researchers and engineers due to their ultrahigh power density,ultrafast charge–discharge rate,and good temperature and fatigue stability.However,most rel... Recently,dielectric capacitors have drawn much attention from researchers and engineers due to their ultrahigh power density,ultrafast charge–discharge rate,and good temperature and fatigue stability.However,most related research mainly focuses on the improvement in dielectric breakdown strength and energy storage density rather than that in energy efficiency. 展开更多
关键词 energy storage density ultrahigh energy storage density energy efficiency lead free dielectric capacitors sodium niobate dielectric breakdown strength microstructure modulation
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Ultrahigh energy-storage density of a lead-free 0.85Bi_(0.5)Na_(0.5)TiO_(3)–0.15Ca(Nb_(0.5)Al_(0.5))O_(3) ceramic under low electric fields
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作者 Jiangtao Fan Gang He +3 位作者 Zhenzhu Cao Yongfan Cao Zhen Long Zhanggui Hu 《Inorganic Chemistry Frontiers》 2023年第5期1561-1573,共13页
The low energy density of dielectric ceramics at low electric fields is a limiting factor for their application in size-reduced integrated electronic devices.In this work,(Nb^(5+)+Al^(3+))and Ca^(2+) ion doped Bi_(0.5... The low energy density of dielectric ceramics at low electric fields is a limiting factor for their application in size-reduced integrated electronic devices.In this work,(Nb^(5+)+Al^(3+))and Ca^(2+) ion doped Bi_(0.5)Na_(0.5)TiO_(3) ceramics possessing high energy storage density at low electric fields were prepared.The microstructure,dielectric properties,energy storage and pulsed charge/discharge properties of the(1−x)Bi_(0.5)Na_(0.5)TiO_(3)–xCa(Nb_(0.5)Al_(0.5))O_(3)(x=0,0.05,0.075,0.1,0.15,0.2)[(1−x)BNT–xCNA]ceramics were investigated.Remarkably,the 0.85Bi_(0.5)Na_(0.5)TiO_(3)–0.15Ca(Nb_(0.5)Al_(0.5))O_(3) ceramic exhibits ultrahigh recoverable energy storage density(W_(re)c=4.41 J cm^(−3))and efficiency(η=88%)at a low electric field(210 kV cm^(−1)).Highly stable dielectric energy storage performance is observed over a wide temperature(20–200℃)and frequency(10–500 Hz)range.In addition,a high power density(Pd)of 49.8 WM cm^(−3) and a fast charge/discharge rate(t_(0.9)=61.2 ns)can be achieved simultaneously.The excellent properties of the lead-free 0.85Bi_(0.5)Na_(0.5)TiO_(3)–0.15Ca(Nb_(0.5)Al_(0.5))O_(3) ceramics originated from the P4bm polar nanoregions(PNRs),enhanced band gaps and refined grains in the modified non-homogeneous structure.The results show that the composite ion substitution strategy is an effective way to achieve high energy storage performance of BNT-based ceramics at low electric fields. 展开更多
关键词 energy storage lead free ceramics low electric fields ultrahigh energy storage density ca nbo alo o dielectric ceramics pulsed charge discharge dielectric properties
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Ultrahigh energy storage density in lead-free Bi_(0.5)Na_(0.5)TiO_(3)-based relaxor ferroelectric ceramics under moderate electric fields via phase fraction manipulation
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作者 Jiangtao Fan Linxiang Wang +4 位作者 Jiaxing Wang Zheng Cheng Langxiang Zhong Tiantian Yang Zhanggui Hu 《Inorganic Chemistry Frontiers》 2025年第4期1444-1454,共11页
Since electronic devices deteriorate when used in extremely high electric fields,it is essential to explore the potential of dielectric capacitors with high energy density under medium electric fields(MEFs).In this st... Since electronic devices deteriorate when used in extremely high electric fields,it is essential to explore the potential of dielectric capacitors with high energy density under medium electric fields(MEFs).In this study,a polymorphic multiscale domain construction strategy was proposed to optimize the energy storage performance(ESP)of(1-x)Bi_(0.5)Na_(0.5)TiO_(3)-xCa(Ta_(0.5)Al_(0.5))O_(3)(xCTA,x=0,0.05,0.1,0.15,0.2)under MEFs. 展开更多
关键词 lead free bi na tio based relaxor ferroelectric ceramics dielectric capacitors moderate electric fields polymorphic multiscale domain construction strategy ultrahigh energy storage density explore potential medium electric fields mefs energy storage performance esp x bi na tio xca ta al o xctax
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Balanced enhancement of energy storage density and self-healing property of polypropylene-based metallised film
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作者 Lu Cheng Ting Zhang +2 位作者 Zhiyuan Li Hongbo Liu Wenfeng Liu 《High Voltage》 2025年第4期930-938,共9页
Metallised film capacitors(MFC)can operate under much higher voltage compared to the foil capacitor due to their self-healing(SH)properties,which caters to their application with high energy storage density requiremen... Metallised film capacitors(MFC)can operate under much higher voltage compared to the foil capacitor due to their self-healing(SH)properties,which caters to their application with high energy storage density requirement.Excellent results were achieved on the enhancement of the energy storage density of the dielectric material,whereas the SH properties of the modified material were less concerned.In the present study,the simultaneous improvement of the energy storage density and the SH properties were proposed,by constructing double-layer metallised films of polypropylene(PP)and pol-ymethyl methacrylate(PMMA).The breakdown strength of the PP/PMMA first increased and then decreased with the rising thickness of the PMMA layer.The dielectric constant was also raised because of the introduced ester groups.The highest energy storage density of 5.93 J/cm3 was obtained,which was 62.47%higher than the neat PP,whereas the dielectric loss was maintained around 0.01.The SH properties of PP/PMMA were systematically evaluated,that the SH energy decreased with the increasing PMMA ratio,and the equivalent conductivity at the SH point of the PP/PMMA decreased to only 1%of the neat PP,which largely benefit the stability of the MFC with reduced tem-perature rise. 展开更多
关键词 modified material POLYPROPYLENE enhancement energy storage density energy storage energy storage density metallised film capacitors mfc can self healing properties dielectric materialwhereas
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Enhanced high-temperature energy storage density of polypropylene-based materials by micro-crosslinked structure design with N-type organic semiconductor
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作者 Hongbo Liu Lu Cheng +3 位作者 Zhiyuan Li Jiakai Zeng Wenfeng Liu Shengtao Li 《High Voltage》 2025年第3期738-745,共8页
In this study,the authors proposed a promising structure design,the micro-crosslinked polypropylene(PP),to enhance the high-temperature energy storage density.With the grafting of 1,6,7,12-tetrachlorinated perylene-N-... In this study,the authors proposed a promising structure design,the micro-crosslinked polypropylene(PP),to enhance the high-temperature energy storage density.With the grafting of 1,6,7,12-tetrachlorinated perylene-N-2-aminoethyl acrylate-Nʹ-dodecylamine-3,4,9,10-tetracarboxylic bisimide(PTCDA)onto PP molecules,the obtained PP-g-PTCDA achieved a superior energy storage density of 2.34 J/cm^(3)at 120℃ with the discharge efficiency above 90%,which was 585%higher than that of neat PP.The great enhancement,on the one hand,originated from the micro-crosslinked structure,since the restricted molecular motion can lead to the suppression of electrons'hopping across the molecular chains.On the other hand,deep traps were also introduced in PP-g-PTCDA,which restricted the electrons'hopping along the molecular chains simultaneously.This work provided an orientation to enhance the energy storage density at an elevated temperature of 120℃. 展开更多
关键词 energy storage density structure designthe high temperature energy storage micro crosslinked structure electron hopping discharge efficiency organic semiconductor polypropylene based materials
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Ultra-high energy storage density and efficiency at low electric fields/voltages in dielectric thin film capacitors through synergistic effects
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作者 Jamal Belhadi Zouhair Hanani +10 位作者 Nick A.Shepelin Urška Trstenjak Nina Daneu Arnold M.Müller Christof Vockenhuber Bojan Ambrožič Vid Bobnar Gertjan Koster Mimoun El Marssi Thomas Lippert MatjažSpreitzer 《Journal of Materiomics》 2025年第5期13-25,共13页
Ensuring reliable and safe operation of high-power electronic devices necessitates the development of high-quality dielectric nano-capacitors with high recoverable energy density(URec)and efficiency(η)at low applied ... Ensuring reliable and safe operation of high-power electronic devices necessitates the development of high-quality dielectric nano-capacitors with high recoverable energy density(URec)and efficiency(η)at low applied electric fields(E)/voltages.In this work,we demonstrate ultra-high URec andηat low E<500 kV/cm in as-grown epitaxial relaxor ferroelectric(RFE)PMN-33PT films,rivaling those typically achieved in state-of-the-art RFE and antiferroelectric(AFE)materials.The high energy storage properties were achieved using a synergistic strategy involving large polarization,a giant built-in potential/imprint(five times higher than the coercive field),and AFE like behavior.The structural,chemical,and electrical investigations revealed that these achievements mainly arise from the effects of strain,dipole defects,and chemical composition.For instance,at low E,the capacitors exhibit under 160 kV/cm(i.e.,8 V)and 400 kV/cm(i.e.,20 V),respectively,an ultra-highΔP(45μC/cm^(2)and 60μC/cm^(2)),UE=URec/E(21 J·MV/cm^(2)and 17 J·MV/cm^(2)),and UF=URec/(1-η)(20 J/cm^(3)and 47 J/cm^(3))with a robust charge-discharge fatigue endurance and outstanding frequency and thermal stability.Additionally,the designed films exhibit outstanding energy storage performance at higher E up to 2 MV/cm(ΔP≈78μC/cm^(2),UE≈17.3 J·MV/cm^(2)and UF≈288 J/cm^(3))due to their low leakage current density. 展开更多
关键词 EFFICIENCY high power electronic devices ultra high energy storage density dielectric thin film capacitors synergistic effects high quality dielectric nano capacitors epitaxial relaxor ferroelectric rfe pmn pt high energy storage properties
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Phase engineering in NaNbO_(3) antiferroelectrics for high energystorage density 被引量:7
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作者 Zhengu Chen Shuaifei Mao +9 位作者 Li Ma Gengguang Luo Qin Feng Zhenyong Cen Fujita Toyohisa Xiuning Peng Laijun Liu Huanfu Zhou Changzheng Hu Nengneng Luo 《Journal of Materiomics》 SCIE 2022年第4期753-762,共10页
The NaNbO_(3) antiferroelectrics have been considered as a potential candidate for dielectric capacitorsapplications. However, the high-electric-field-unstable antiferroelectric phase resulted in low energystorage den... The NaNbO_(3) antiferroelectrics have been considered as a potential candidate for dielectric capacitorsapplications. However, the high-electric-field-unstable antiferroelectric phase resulted in low energystorage density and efficiency. Herein, good energy storage properties were realized in (1-x)NaNbO_(3)- xNaTaO_(3) ceramics, by building a new phase boundary. As a result, a high recoverable energy density(Wrec) of 2.2 J/cm3 and efficiency (h) of 80.1% were achieved in 0.50NaNbO_(3)-0.50NaTaO_(3) ceramic at300 kV/cm. The excellent energy storage performance originates from an antiferroelectric-paraelectricphase boundary with simultaneously high polarization and low hysteresis, by tailoring the ratio ofantiferroelectric and paraelectric phases. Moreover, the 0.50NaNbO_(3)-0.50NaTaO_(3) ceramic also exhibitedgood temperature and frequency stability, together with excellent charge-discharge performance. Theresults pave a good way of designing new NaNbO_(3)-based antiferroelectrics with good energy storageperformance. 展开更多
关键词 NaNbO_(3)ceramics ANTIFERROELECTRICS Paraelectrics Energy storage density Dielectric capacitors
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Optimization of synergistic energy storage density and efficiency for eco-friendly(Na_(0.5)Bi_(0.5))_(0.6)Sr_(0.4)TiO_(3)-based relaxor ferroelectric ceramics 被引量:1
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作者 Hu Di Pan Zhongbin +8 位作者 Wu Lukang Yang Fan Tang Luomeng Zhao Jinghao Shen Yihao Chen Yuyun Li Peng Zhai Jiwei Liu Jinjun 《Journal of Materiomics》 SCIE EI 2021年第4期869-878,共10页
Inspired by increasing demand of advanced pulsed power capacitors,the development of lead-free dielectric ceramic capacitors with high energy storage density and temperature-insensitive performance are extremely cruci... Inspired by increasing demand of advanced pulsed power capacitors,the development of lead-free dielectric ceramic capacitors with high energy storage density and temperature-insensitive performance are extremely crucial.Herein,the lead-free relaxor ferroelectric ceramics based on(1-x)(Na_(0.5)Bi_(0.5))0.6Sr_(0.4)TiO_(3-x)Sr_(0.7)La_(0.2)ZrO_(3)[abbreviated as(1-x)NBST-xSLZ]are prepared by the solid-state reaction route.The large recoverable energy density(Wrec)of 3.45 J/cm^(3)and efficiency(h)of 90.1%are simultaneously realized in 0.86NBST-0.14SLZ ceramic due to increased breakdown strength.Furthermore,both the Wrec and h of 0.86NBST-0.14SLZ ceramic display superior of thermal stability(20e180C),frequency stability(1e1000 Hz),and cycle stability(10^(4))within a satisfactory range of variation.In addition,the 0.86NBST-0.14SLZ ceramic can also achieve a large current density(CD)of 625 A/cm^(2),an ultrahigh power density(PD)of 50 MW/cm^(3)and a fast discharge rate(t0.90)of 160.8 ns at 160 kV/cm.These results demonstrate that the 0.86NBST-0.14SLZ ceramic could be a highly competitive and ecofriendly relaxor ferroelectric material for next-generation pulsed power capacitors. 展开更多
关键词 Lead-free ceramics Energy storage density (Na_(0.5)Bi_(0.5))_(0.6)Sr_(0.4)TiO_(3) Thermal stability Power density
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Pupil apodization for increasing data storage density
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作者 Vidal F.Canales Pedro J.Valle +1 位作者 Jose E.Oti Manuel P.Cagigal 《Chinese Optics Letters》 SCIE EI CAS CSCD 2009年第8期720-723,共4页
We introduce a technique for increasing density in optical data storage systems. This technique is based on the use of a superresolving filter at the pupil of a confocal readout system. The main characteristic of this... We introduce a technique for increasing density in optical data storage systems. This technique is based on the use of a superresolving filter at the pupil of a confocal readout system. The main characteristic of this confocal readout system is that the light beam traverses twice through the pupil filter. We describe how to analyze the system performance for general filters, but we focus the study on filters with no focus displacement. Although the storage density attainable depends on the filter characteristics, we show that the storage density can be easily duplicated. 展开更多
关键词 Pupil apodization for increasing data storage density PSF DATA
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Preparation and investigation on properties of BST-base ceramic with high-energy storage density
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作者 Yuanyuan Li Guixia Dong +1 位作者 Qiuxiang Liu Di Wu 《Journal of Advanced Dielectrics》 CAS 2013年第1期43-47,共5页
The Ba_(0.3)Sr_(0.6)Ca_(0.1)TiO_(3)(BSCT)powder was prepared through the solid-state reaction.And then preparing ceramic samples with quantitative doped-Bi_(2)O_(3)·3TiO_(2) and diferent doped-MgO.X-ray diffracto... The Ba_(0.3)Sr_(0.6)Ca_(0.1)TiO_(3)(BSCT)powder was prepared through the solid-state reaction.And then preparing ceramic samples with quantitative doped-Bi_(2)O_(3)·3TiO_(2) and diferent doped-MgO.X-ray diffractometer(XRD)and scanning electron microscopy(SEM)were used to investigate the phase compositions,distribution and morphology of the ceramic samples.SM-11J49 capacitance measurement instrument and CS2674A pressure tester were used to measure the dieletric properties of the samples.The results show that the compactness and the dielectric constant of the ceramics increases first and then decreases when the doped MgO content was changed from 1.5 to 4.5 wt.%.The trend of breakdown strength is characterized by M-shaped pattern with the increase of doped-MgO content.Calculation results demonstrate that when the doped-MgO content is 2.0%,the samples have the highest energy storage density. 展开更多
关键词 BSCT MgO doping dielectric property energy storage density
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Scaling behavior of different shapes of hysteresis loops and recoverable energy storage density in Na_(0.5)Bi_(0.5)TiO_(3), K_(0.5)Bi_(0.5)TiO_(3), and Na_(0.25)K_(0.25)Bi_(0.5)TiO_(3) ferroelectrics
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作者 Krishnarjun Banerjee Saket Asthana 《Journal of Materiomics》 SCIE 2022年第4期918-927,共10页
In this work,the dependency of the polarization(P)-electric field(E)loop area A of lead free ferro-electrics Na_(0.5)Bi_(0.5)TiO_(3)(NBT), K_(0.5)Bi_(0.5)TiO_(3)(KBT),and Na_(0.25)K_(0.25)Bi_(0.5)TiO_(3)(NKBT)on the a... In this work,the dependency of the polarization(P)-electric field(E)loop area A of lead free ferro-electrics Na_(0.5)Bi_(0.5)TiO_(3)(NBT), K_(0.5)Bi_(0.5)TiO_(3)(KBT),and Na_(0.25)K_(0.25)Bi_(0.5)TiO_(3)(NKBT)on the amplitude(E0)of the electric field is studied.Based on the nature of the hysteresis loop with increasing E0,the lnA versus lnE0 graph is divided into three stages and the scaling exponents of each stage are estimated.In the third stage,NBT,KBT,and NKBT show different shapes of P-E loops(square,slanted and pinched,respectively).Although,almost similar slopes in the third stage are obtained from the lnA versus lnE0 graphs of KBT and NKBT,the formation of pinched P-E loop of NKBT is discussed based on the current-time curve under a complete cycle of the applied electric field.The shape of the P-E loop also affects the recoverable energy storage density(Wrec)of the material.Similar to the scaling of A,the variation of lnWrec with lnE0 of NBT,KBT and NKBT are examined.Interestingly,three stages are only noticed in the lnWrec-lnE0 curve of pinched P-E loop(NKBT),whereas lnWrec linearly increases with lnE0 for square and slanted P-E loop.Such type of behavior of Wrec of NKBT is explained based on the reversible domain switching mechanism of the pinched P-E loop. 展开更多
关键词 Scaling Recoverable energy storage density Lead free ferroelectric
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High-performance Vanillin-derived Dielectric Polymer Films for Sustainable Energy Storage
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作者 Lei-Peng Liu Bo-Yi Tian +7 位作者 Rui-Ying Xie Shu-Ping Wei Peng-Fei Yuan Yuan-Duo Duan Xiao-Fei Chen Yu-Xuan Wang Sheng-Hua Lv Yue-Hong Zhang 《Chinese Journal of Polymer Science》 2025年第10期1804-1813,共10页
Dielectric films are critical components in the fabrication of capacitors. However, their reliance on petroleum-derived polymers presents significant environmental challenges. To address this issue, we report on a hig... Dielectric films are critical components in the fabrication of capacitors. However, their reliance on petroleum-derived polymers presents significant environmental challenges. To address this issue, we report on a high-performance biomass-based dielectric material derived from vanillin(VA), a renewable aromatic aldehyde. Vanillin was first esterified to synthesize vanillin methacrylate(VMA), which was then copolymerized with methyl methacrylate(MMA) via free-radical polymerization to yield P(VMA-MMA). By crosslinking the aldehyde groups in VMA with the amine groups in the polyether amine D400(PEA), we fabricated a series of P(VMA-MMA)@PEA dielectric films with precisely tunable crosslinking densities. The unique molecular structure of vanillin, featuring both a benzene ring and an ester group, facilitates strong δ-π interactions and dipolar polarization, synergistically enhancing energy storage density while minimizing dielectric loss. At an optimal P(VMA-MMA) ratio of 1:10and 80% theoretical crosslinking degree, the dielectric constant reaches 3.4 at 10^(-3 )Hz, while the breakdown strength reaches 670.2 MV/m. Furthermore, the film exhibits an energy storage density of 7.1 J/cm3at 500 MV/m while maintaining a charge-discharge efficiency exceeding 90%.This study demonstrates a green and reliable strategy for designing biomass-based dielectric materials and opens new avenues for the development of eco-friendly energy-storage technologies. 展开更多
关键词 Biomass-based dielectric material VANILLIN CROSSLINKING Dielectric constant Energy storage density
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Improved breakdown strength and energy density of polyimide composites by interface engineering between BN and BaTiO3 fibers 被引量:4
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作者 Baoquan Wan Haiyu Li +2 位作者 Yunhui Xiao Zhongbin Pan Qiwei Zhang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2021年第15期1-10,共10页
Conventionally,interface effects between polymers and fillers are essential for determining the breakdown strength and energy storage density of polymer-based dielectric composites.In this study,we found that interfac... Conventionally,interface effects between polymers and fillers are essential for determining the breakdown strength and energy storage density of polymer-based dielectric composites.In this study,we found that interface effects between different fillers have similar behavior.BN and Ba TiO3 fiber composite fillers with three different interface bonding strengths were successfully achieved by controlling composite processes(BT-fiber/BN<BT-fiber@BN<BT-fiber&BN),and introduced into a polyimide(PI)matrix to form composite films.Considerably enhanced breakdown strength and energy storage density were obtained in BT-fiber&BN/PI composites owing to strong interface bonding,compared to other two composite fillers,which are well supported by the data from the finite element simulation.Specifically,PI composites with only 3 wt%BT-fiber&BN possess an optimized energy storage density of approximately 4.25 J/cm^(3)at 4343 k V/cm.These results provide an effective way for adjusting and improving the energy storage properties of polymer-based composites. 展开更多
关键词 Interface effects Breakdown strength Energy storage density POLYIMIDE
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Enhanced High-Temperature Energy Storage Performance of All-Organic Composite Dielectric via Constructing Fiber-Re in forced Structure 被引量:1
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作者 Mengjia Feng Yu Feng +5 位作者 Changhai Zhang Tiandong Zhang Xu Tong Qiang Gao Qingguo Chen Qingguo Chi 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期299-307,共9页
Optimizing the high-temperature energy storage characteristics of energy storage dielectrics is of great significance for the development of pulsed power devices and power control systems.Selecting a polymer with a hi... Optimizing the high-temperature energy storage characteristics of energy storage dielectrics is of great significance for the development of pulsed power devices and power control systems.Selecting a polymer with a higher glass transition temperature(T_(g))as the matrix is one of the effective ways to increase the upper limit of the polymer operating temperature.However,current high-T_(g)polymers have limitations,and it is difficult to meet the demand for high-temperature energy storage dielectrics with only one polymer.For example,polyetherimide has high-energy storage efficiency,but low breakdown strength at high temperatures.Polyimide has high corona resistance,but low high-temperature energy storage efficiency.In this work,combining the advantages of two polymer,a novel high-T_(g)polymer fiber-reinforced microstructure is designed.Polyimide is designed as extremely fine fibers distributed in the composite dielectric,which will facilitate the reduction of high-temperature conductivity loss for polyimide.At the same time,due to the high-temperature resistance and corona resistance of polyimide,the high-temperature breakdown strength of the composite dielectric is enhanced.After the polyimide content with the best high-temperature energy storage characteristics is determined,molecular semiconductors(ITIC)are blended into the polyimide fibers to further improve the high-temperature efficiency.Ultimately,excellent high-temperature energy storage properties are obtained.The 0.25 vol%ITIC-polyimide/polyetherimide composite exhibits high-energy density and high discharge efficiency at 150℃(2.9 J cm^(-3),90%)and 180℃(2.16 J cm^(-3),90%).This work provides a scalable design idea for high-performance all-organic high-temperature energy storage dielectrics. 展开更多
关键词 all-organic energy storage density high-temperature high-temperature breakdown strength
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Effects of Co_(2)O_(3)Addition on Microstructure and Properties of SiC Composite Ceramics for Solar Absorber and Storage
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作者 ZHOU Yang WU Jianfeng +3 位作者 TIAN Kezhong XU Xiaohong MA Sitong LIU Shaoheng 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第6期1269-1277,共9页
SiC composite ceramics for solar absorber and storage integration are new concentrating solar power materials.SiC composite ceramics for solar absorber and storage integration were fabricated using SiC,black corundum ... SiC composite ceramics for solar absorber and storage integration are new concentrating solar power materials.SiC composite ceramics for solar absorber and storage integration were fabricated using SiC,black corundum and kaolin as the raw materials,Co_(2)O_(3)as the additive via pressureless graphite-buried sintering method in this study.Influences of Co_(2)O_(3)on the microstructure and properties of SiC composite ceramics for solar absorber and storage integration were studied.The results indicate that sample D2(5wt%Co_(2)O_(3))sintered at 1480℃exhibits optimal performances for 119.91 MPa bending strength,93%solar absorption,981.5 kJ/kg(25-800℃)thermal storage density.The weight gain ratio is 12.58 mg/cm2after 100 h oxidation at 1000℃.The Co_(2)O_(3)can decrease the liquid phase formation temperature and reduce the viscosity of liquid phase during sintering.The liquid with low viscosity not only promotes the elimination of pores to achieve densification,but also increases bending strength,solar absorption,thermal storage density and oxidation resistance.A dense SiO_(2) layer was formed on the surface of SiC after 100 h oxidation at 1000℃,which protects the sample from further oxidation.However,excessive Co_(2)O_(3)will make the microstructure loose,which is disadvantageous to the performances of samples. 展开更多
关键词 SiC composite ceramics Co_(2)O_(3) microstructure solar absorption thermal storage density
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Dielectric and energy storage properties of PbO–SrO–Nb_(2)O_(5)–Na_(2)O–Si thin films by annealing
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作者 Fei-Hu Tan Qing-Meng Zhang +3 位作者 Feng Wei Hong-Bin Zhao Xiao Zhang Jun Du 《Rare Metals》 SCIE EI CAS CSCD 2024年第1期351-355,共5页
Dielectric and energy storage properties of PbOSrO-Na_(2)O-Nb_(2)O_(5)-SiO_(2)(PSNNS) thin films with annealing temperature from 700 to 850 ℃ were investigated by measuring their capacitance-electric filed curve and ... Dielectric and energy storage properties of PbOSrO-Na_(2)O-Nb_(2)O_(5)-SiO_(2)(PSNNS) thin films with annealing temperature from 700 to 850 ℃ were investigated by measuring their capacitance-electric filed curve and hysteresis loops.The results show that the highest dielectric constant and energy density are 81.2 and 17.0 J·cm^(-3),respectively,which is obtained in the sample with annealing temperature of 800 ℃.Annealed from 700 to800 ℃,the dielectric constant and energy storage performance of PSNNS films are continuously improved.However,with annealing temperature up to 850 ℃,their dielectric constant decreases,which might be related with the removal of interfacial defects as a function of annealing temperature.Defect is one of the causes of space charge phenomenon,resulting in the increase in dielectric constant.Moreover,the micro structure analysis by X-ray diffraction(XRD) and transmission electron microscope(TEM) indicates that the change of crystallization phase and interfacial polarization takes responsibility to the results. 展开更多
关键词 Thin film Pulse laser deposition Annealing temperature Energy storage density
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Effects of Forest Type and Urbanization on Carbon Storage of Urban Forests in Changchun, Northeast China 被引量:10
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作者 ZHANG Dan ZHENG Haifeng +5 位作者 REN Zhibin ZHAI Chang SHEN Guoqiang MAO Zhixia WANG Peijiang HE Xingyuan 《Chinese Geographical Science》 SCIE CSCD 2015年第2期147-158,共12页
Rapid urbanization has led to dramatic changes in urban forest structures and functions, and consequently affects carbon(C) storage in cities. In this study, field surveys were combined with high resolution images to ... Rapid urbanization has led to dramatic changes in urban forest structures and functions, and consequently affects carbon(C) storage in cities. In this study, field surveys were combined with high resolution images to investigate the variability of C storage of urban forests in Changchun, Northeast China. The main objectives of this study were to quantify the C storage of urban forests in Changchun City, Northeast China and understand the effects of forest type and urbanization on C storage of urban forests. The results showed that the mean C density and the total C storage of urban forests in Changchun were 4.41 kg/m2 and 4.74 × 108 kg, respectively. There were significant differences in C density among urban forest types. Landscape and relaxation forest(LF) had the highest C density with 5.41 kg/m2, while production and management forest(PF) had the lowest C density with 1.46 kg/m2. These differences demonstrate that urban forest type is an important factor needed to be considered when the C storage is accurately estimated. Further findings revealed significant differences in different gradients of urbanization, and the mean C density decreased from the first ring(6.99 kg/m2) to the fourth ring(2.87 kg/m2). The total C storage increased from the first ring to the third ring. These results indicate that C storage by urban forests will be significantly changed during the process of urbanization. The results can provide insights for decision-makers and urban planners to better understand the effects of forest type and urbanization on C storage of urban forests in Changchun, and make better management plans for urban forests. 展开更多
关键词 urban forest carbon storage carbon density urbanization gradients climate change
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