To study the influence of silicon(Si)on 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane(CL-20),NC/CL-20 composite explosives and Si/NC/CL-20 composite explosives were prepared by the electrostatic spraying ...To study the influence of silicon(Si)on 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane(CL-20),NC/CL-20 composite explosives and Si/NC/CL-20 composite explosives were prepared by the electrostatic spraying method.The morphology,structure and thermal decomposition properties of the samples were analyzed using scanning electron microscopy(SEM),X-ray energy spectroscopy(EDS),infrared spectroscopy(FT-IR),and simultaneous thermal analyzer(TG-DSC).Additionally,the combustion process of the samples was tested using a high-speed camera.The results show that the addition of nano-Si contributes to the formation of composite explosives with regular morphology and smaller particle size.The Si/NC/CL-20 composite explosive has better and more uniform sphericity,with an average particle size of 73.4 nm,compared to the NC/CL-20 composite explosive.The Si/NC/CL-20 composite explosive which produced by the electrostatic spraying method,achieves physically uniform distribution of the components including NC,CL-20,Si.The addition of Si promotes the thermal decomposition of CL-20.In comparison to the NC/CL-20 composite explosive,the activation energy of the Si/NC/CL-20 composite explosive decreases by 16.78 kJ/mol,and the self-accelerated decomposition temperature and the critical temperature of thermal explosion decreases by 3.12 K and 2.61 K,respectively.Furthermore,Si/NC/CL-20 composite explosive has shorter ignition delay time and faster combustion rate compared to the NC/CL-20 composite explosive,which shows that Si can improve the combustion performance of CL-20.展开更多
CuI thin films with nano-scale grains of about 35nm were deposited via spraying method with using acetonitrile as solvent. The influence of iodine doping concentration in acetonitrile solution on the structure, topogr...CuI thin films with nano-scale grains of about 35nm were deposited via spraying method with using acetonitrile as solvent. The influence of iodine doping concentration in acetonitrile solution on the structure, topographic and optical properties of CuI thin films was investigated. X-ray diffraction results showed that CuI iodine-doped films doped CuI：I2 were in γ-phase of zinc blende structure with （111） preferential plane. Scanning electron microscopy revealed that the microstructure of CuI films depended on the relative amount of doping iodine in the solution. When the iodine doping amount in acetonitrile solution was 0.025 g, the film was uniform and compact, the optical transmittance was 75.4% in the part of visible region and the energy band gap was close to 2.96 eV.展开更多
The robust magnesium surfaces with multi-functions are highly desirable,and the simple and scalable methods to construct such surfaces are urgently indispensable.Herein,we conducted a one-step spraying method to facil...The robust magnesium surfaces with multi-functions are highly desirable,and the simple and scalable methods to construct such surfaces are urgently indispensable.Herein,we conducted a one-step spraying method to facilely fabricate the robust coating with multi-functions on magnesium alloys.The as-sprayed magnesium alloys surface is superhydrophobic with a static water contact angle(WCA)of 157.0°and a roll-off angle of 6.0°.Such surface has excellent mechanical,chemical and thermal stabilities,even undergoing various physical and chemical damages,including sand impact(10 gmin^(-1),≥20 min),water impact(2 impacts s^(-1),≥180 min),abrasion(1.00 kPa,≥25 cycles),peeling(≥2.15 kPa),high temperature(200°C,≥24 h),strong acidic/salty/basic media(p H=113)and organic-solvent immersion(ethanol and n-hexane,≥24 h),demonstrating brilliant robustness.Notably,the surface displays multi-functions of corrosion protection,anti-fouling and heat insulation,which will undoubtedly promote the much wider applications of magnesium alloys.展开更多
To screen new biological formulations, accurate and efficient application technology, field test was conducted with 72% Bacillus thuringiensis(Bt)·monosultap WP, 8% lambda-cyhalothrin·emamectin benzoate SA a...To screen new biological formulations, accurate and efficient application technology, field test was conducted with 72% Bacillus thuringiensis(Bt)·monosultap WP, 8% lambda-cyhalothrin·emamectin benzoate SA and 3.6% lambda-cyhalothrin·Bt SA through manual spraying and unmanned aerial vehicle spraying. Test results and comprehensive evaluation analysis demonstrated that 72% Bt·monosultap WP and 8%lambda-cyhalothrin·emamectin benzoate SA by manual spraying and unmanned aerial vehicle spraying had good prevention and control effect on strains and internodes damaged by Tryporyza intacta Snellen in middle and late stage, which were ideal new biological formulations with high effi-ciency and low risk for prevention and control of T. intacta in middle and late stage, and could be popularized in sugarcane area. 72% Bt·monosultap WP at the dose of 3 000 g/hectare and 8% lambda-cyhalothrin·emamectin benzoate SA at the dose of 750 mL/hectare could be sprayed in mid September at the peak occurrence period of the forth and fifth generations of T. intacta and Proceras venosatus. Agents were diluted with 900 kg water per hectare, and manually sprayed with electric knapsack sprayer; or agents were diluted with 15 kg of Haoyang aerial control special addi-tives and water per hectare, and sprayed with unmanned aerial vehicle. The control effect against borer-damaged strain rate was above 81.3% and that against borer-damaged internode rate was above 88.6%.展开更多
The microstructure, phase consistence and microhardness of thermal sprayed coatings were investigated. The tungsten and chromium carbide coatings and also composite NiCrSiB coating were analyzed. The microstructure of...The microstructure, phase consistence and microhardness of thermal sprayed coatings were investigated. The tungsten and chromium carbide coatings and also composite NiCrSiB coating were analyzed. The microstructure of coatings were observed by using optical microscopy (MO), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Almost equiaxial carbide particles settled inside the surrounded material of coating were found. The cracks propagating thorough the particles and along boundaries between the particles and surrounded material were observed. This phenomenon was connected with the porosity of coatings. The decarburization process was detected in coatings by phase composition investigation using X-ray method. The decarburization process was the reason due to which beside initial Cr3C2 the Cr7C3 and Cr23C6 particles were found. In the tungsten coatings beside the initial WC carbides the W2Cones were found.展开更多
To overcome cartilage injury, strategies have been developed in the last few years based on tissue engineering to rebuild the defects. Cartilage engineering is principally based on three main biological factors: cells...To overcome cartilage injury, strategies have been developed in the last few years based on tissue engineering to rebuild the defects. Cartilage engineering is principally based on three main biological factors: cells (native cells (chondrocytes) or a more primitive ones as mesenchymal stem cells), scaffolds and functionalization factors (growth factors, mechanical stimulation and/or hypoxia). Cartilage tissue engineering strategies generally result in homogeneous tissue structures with little resemblance to native zonal organization of articular cartilage. The main objective of our work concerns the buildup of complex biomaterials aimed at reconstructing biological tissue with three dimensional cells construction for mimicking cartilage architecture. Our strategy is based on structures formation by simple and progressive spraying of mixed alginate hydrogel and human mesenchymal stem cells (hMSC). In this work, the comportment of cells and more precisely their chondrogenic differentiation potential is compared to a traditional making process: the mold. We report here that spraying method allowed to product a scaffold with hMSC that confer a favorable environment for neocartilage construction.展开更多
[Objective] The curative effect of onion on bacterial rotted gill disease in grass carp was researched [Method] The combination method of taking medicine through oral and spraying was used to cure sick grass carp for ...[Objective] The curative effect of onion on bacterial rotted gill disease in grass carp was researched [Method] The combination method of taking medicine through oral and spraying was used to cure sick grass carp for 1 period of treatment in room under artificial conditions. [Result] Different concentrations of onion generated different cure rates. When the combination was adding 1.0% - 2.0% medicine into feed and spraying 2.0 g,/m3 - 5.0 g,/m3, the curative result was the best with cure rate was 70% -90% [ Conclusion] The onion was effective on curing bacterial rotted gill disease in grass carp and could be taken as curative medicine.展开更多
In China,marine natural gas hydrate(NGH)resources are mainly distributed in the deepwater areas of 300-3000 m deep in the coastal continental shelf,and they are characterized by weak cementation and non-diagenesis.In ...In China,marine natural gas hydrate(NGH)resources are mainly distributed in the deepwater areas of 300-3000 m deep in the coastal continental shelf,and they are characterized by weak cementation and non-diagenesis.In order to test and study this type of NGH,it is necessary to prepare samples quickly in situ in large quantities.At present,the commonly used preparation technologies(e.g.stirring method,spraying method and bubbling method)are defective with slow generation and low gas storage density.In view of this,the 1062 L rapid non-diagenetic NGH preparation kettle was designed and developed independently.Then,based on the physical properties of non-diagenetic NGH in the South China Sea,NGH preparation tests were carried out on stirring method,spraying method,bubbling method and“three-in-one”method(the combination of stirring method,spraying method and bubbling method).Temperature,pressure,resistivity and reaction time in the process of test were tested,and NGH generation situations and preparation efficiency of different preparation processes were analyzed and compared.And the following research results were obtained.First,in the process of NGH preparation by stirring method,spraying method and bubbling method,respectively,the generated NGH increases slowly and spreads the whole liquid level gradually.Second,inducing period is obvious in the preparation process by the stirring method,but not obvious by the spraying method,the bubbling method and the“three-in-one”method.Third,in the process of NGH preparation by stirring method,spraying method,bubbling method and“three-in-one”method,the resistivity increases as the reaction goes,and its change trend is basically accordant with the NGH preparation rate.Fourth,the preparation cycle of NGH by“three-in-one”method is greatly shorter than that by single preparation method.The preparation time by stirring method,spraying method and bubbling method is about 5.14 times,3.59 times and 3.16 times that of“three-in-one”method respectively.In conclusion,the 1062 L rapid NGH preparation kettle developed in this paper can prepare marine non-diagenetic NGH samples quickly in situ.And compared with single preparation method,“three-in-one”method is much higher in NGH preparation efficiency.展开更多
To mitigate the damages produced by flood discharges of hydropower stations, a three-dimensional numerical model of the aerated water jet restricted by gravity, air resistance and air buoyancy is proposed. Based on th...To mitigate the damages produced by flood discharges of hydropower stations, a three-dimensional numerical model of the aerated water jet restricted by gravity, air resistance and air buoyancy is proposed. Based on theoretical analysis and prototype data, a three-dimensional stochastic model is constructed using Monte Carlo method to evaluate the range of atomization and intensity of rainfall in gorges, which are strongly affected by complex terrain and various wind conditions. The prototype data observed from two hydropower stations are selected in the feedback and verification analysis to verify the proposed model. The result shows that the computational solutions fit the prototype data well. This model can be used to forecast the atomization of a hydropower station that is being designed or constructed.展开更多
Polylactide(PLA) microspheres were prepared using the solid-in-oil(S/O) spray-drying method to achieve the sustained release of a hydrophilic drug for the treatment of tuberculosis, via intratracheal instillation. Iso...Polylactide(PLA) microspheres were prepared using the solid-in-oil(S/O) spray-drying method to achieve the sustained release of a hydrophilic drug for the treatment of tuberculosis, via intratracheal instillation. Isoniazid(IN), a low-molecular-weight hydrophilic drug, was used as a model drug. The effects of various sizes of micronized IN powder, different drug/polymer ratios, spray-drying process parameters, and drug-release characteristics were studied to optimize the manufacturing parameters. A high entrapment efficiency(87.3%) was obtained using this method; furthermore, the microspheres were spherical and smooth. They were individually and homogenously distributed, with a mean diameter of 5.6 μm; furthermore, they showed a satisfactory extended sustained-release phase. After administration of the microspheres to rats, pulmonary drug concentrations were maintained at a relatively stable level for up to 4 weeks.展开更多
基金National Natural Science Foundation of China(No.22275150)。
文摘To study the influence of silicon(Si)on 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane(CL-20),NC/CL-20 composite explosives and Si/NC/CL-20 composite explosives were prepared by the electrostatic spraying method.The morphology,structure and thermal decomposition properties of the samples were analyzed using scanning electron microscopy(SEM),X-ray energy spectroscopy(EDS),infrared spectroscopy(FT-IR),and simultaneous thermal analyzer(TG-DSC).Additionally,the combustion process of the samples was tested using a high-speed camera.The results show that the addition of nano-Si contributes to the formation of composite explosives with regular morphology and smaller particle size.The Si/NC/CL-20 composite explosive has better and more uniform sphericity,with an average particle size of 73.4 nm,compared to the NC/CL-20 composite explosive.The Si/NC/CL-20 composite explosive which produced by the electrostatic spraying method,achieves physically uniform distribution of the components including NC,CL-20,Si.The addition of Si promotes the thermal decomposition of CL-20.In comparison to the NC/CL-20 composite explosive,the activation energy of the Si/NC/CL-20 composite explosive decreases by 16.78 kJ/mol,and the self-accelerated decomposition temperature and the critical temperature of thermal explosion decreases by 3.12 K and 2.61 K,respectively.Furthermore,Si/NC/CL-20 composite explosive has shorter ignition delay time and faster combustion rate compared to the NC/CL-20 composite explosive,which shows that Si can improve the combustion performance of CL-20.
基金Project (2091003) supported by Beijing Natural Science Foundation, China
文摘CuI thin films with nano-scale grains of about 35nm were deposited via spraying method with using acetonitrile as solvent. The influence of iodine doping concentration in acetonitrile solution on the structure, topographic and optical properties of CuI thin films was investigated. X-ray diffraction results showed that CuI iodine-doped films doped CuI：I2 were in γ-phase of zinc blende structure with （111） preferential plane. Scanning electron microscopy revealed that the microstructure of CuI films depended on the relative amount of doping iodine in the solution. When the iodine doping amount in acetonitrile solution was 0.025 g, the film was uniform and compact, the optical transmittance was 75.4% in the part of visible region and the energy band gap was close to 2.96 eV.
基金supported by the National Natural Science Foundation of China(21773019,21972012)the Graduate Research and Innovation Foundation of Chongqing(CYB18044)the sharing fund of Chongqing University s Large-scale Equipment
文摘The robust magnesium surfaces with multi-functions are highly desirable,and the simple and scalable methods to construct such surfaces are urgently indispensable.Herein,we conducted a one-step spraying method to facilely fabricate the robust coating with multi-functions on magnesium alloys.The as-sprayed magnesium alloys surface is superhydrophobic with a static water contact angle(WCA)of 157.0°and a roll-off angle of 6.0°.Such surface has excellent mechanical,chemical and thermal stabilities,even undergoing various physical and chemical damages,including sand impact(10 gmin^(-1),≥20 min),water impact(2 impacts s^(-1),≥180 min),abrasion(1.00 kPa,≥25 cycles),peeling(≥2.15 kPa),high temperature(200°C,≥24 h),strong acidic/salty/basic media(p H=113)and organic-solvent immersion(ethanol and n-hexane,≥24 h),demonstrating brilliant robustness.Notably,the surface displays multi-functions of corrosion protection,anti-fouling and heat insulation,which will undoubtedly promote the much wider applications of magnesium alloys.
基金Supported by Special Fund of China Agricultural (Sugar) Industry Research System(CARS-170303)Training Project of Yunling Industry and Technology Leading Talents "Control of Sugarcane Harm-ful Organisms"(2018LJRC56)Special Fund of Agricultural Industry Research System in Yunnan Province
文摘To screen new biological formulations, accurate and efficient application technology, field test was conducted with 72% Bacillus thuringiensis(Bt)·monosultap WP, 8% lambda-cyhalothrin·emamectin benzoate SA and 3.6% lambda-cyhalothrin·Bt SA through manual spraying and unmanned aerial vehicle spraying. Test results and comprehensive evaluation analysis demonstrated that 72% Bt·monosultap WP and 8%lambda-cyhalothrin·emamectin benzoate SA by manual spraying and unmanned aerial vehicle spraying had good prevention and control effect on strains and internodes damaged by Tryporyza intacta Snellen in middle and late stage, which were ideal new biological formulations with high effi-ciency and low risk for prevention and control of T. intacta in middle and late stage, and could be popularized in sugarcane area. 72% Bt·monosultap WP at the dose of 3 000 g/hectare and 8% lambda-cyhalothrin·emamectin benzoate SA at the dose of 750 mL/hectare could be sprayed in mid September at the peak occurrence period of the forth and fifth generations of T. intacta and Proceras venosatus. Agents were diluted with 900 kg water per hectare, and manually sprayed with electric knapsack sprayer; or agents were diluted with 15 kg of Haoyang aerial control special addi-tives and water per hectare, and sprayed with unmanned aerial vehicle. The control effect against borer-damaged strain rate was above 81.3% and that against borer-damaged internode rate was above 88.6%.
基金financially supported by polish project NR15 0001 06the Ministry of Higher Education and Science/AGH University of Science and Technology,Krakow,Poland,grant number 11.11.180.255 is greatly acknowledged.
文摘The microstructure, phase consistence and microhardness of thermal sprayed coatings were investigated. The tungsten and chromium carbide coatings and also composite NiCrSiB coating were analyzed. The microstructure of coatings were observed by using optical microscopy (MO), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Almost equiaxial carbide particles settled inside the surrounded material of coating were found. The cracks propagating thorough the particles and along boundaries between the particles and surrounded material were observed. This phenomenon was connected with the porosity of coatings. The decarburization process was detected in coatings by phase composition investigation using X-ray method. The decarburization process was the reason due to which beside initial Cr3C2 the Cr7C3 and Cr23C6 particles were found. In the tungsten coatings beside the initial WC carbides the W2Cones were found.
文摘To overcome cartilage injury, strategies have been developed in the last few years based on tissue engineering to rebuild the defects. Cartilage engineering is principally based on three main biological factors: cells (native cells (chondrocytes) or a more primitive ones as mesenchymal stem cells), scaffolds and functionalization factors (growth factors, mechanical stimulation and/or hypoxia). Cartilage tissue engineering strategies generally result in homogeneous tissue structures with little resemblance to native zonal organization of articular cartilage. The main objective of our work concerns the buildup of complex biomaterials aimed at reconstructing biological tissue with three dimensional cells construction for mimicking cartilage architecture. Our strategy is based on structures formation by simple and progressive spraying of mixed alginate hydrogel and human mesenchymal stem cells (hMSC). In this work, the comportment of cells and more precisely their chondrogenic differentiation potential is compared to a traditional making process: the mold. We report here that spraying method allowed to product a scaffold with hMSC that confer a favorable environment for neocartilage construction.
基金The Natural Science Project of Xichang College(xA0509)~~
文摘[Objective] The curative effect of onion on bacterial rotted gill disease in grass carp was researched [Method] The combination method of taking medicine through oral and spraying was used to cure sick grass carp for 1 period of treatment in room under artificial conditions. [Result] Different concentrations of onion generated different cure rates. When the combination was adding 1.0% - 2.0% medicine into feed and spraying 2.0 g,/m3 - 5.0 g,/m3, the curative result was the best with cure rate was 70% -90% [ Conclusion] The onion was effective on curing bacterial rotted gill disease in grass carp and could be taken as curative medicine.
基金supported by the National Key R&D Program of China“Innovative technologies for test of marine natural gas hydrates through solid fluidization”(No.:2016YFC0304008)National Key R&D Program of China“Technologies and processes for dual-gradient drilling system with riser inflation”(No.:2018YFC0310203)+1 种基金the Medium-and Long-term Development Strategy Research Project of Chinese Academy of Engineering for Engineering Science and Technology“Research on deep-sea natural gas hydrate development strategies,2035”(No.:2017-ZCQ-5)the Fundamental Research for Application Projects of Sichuan Province“Researches on mechanisms and application technologies for the largest and fastest natural gas hydrate preparation in the world”(No.:2019YJ0351).
文摘In China,marine natural gas hydrate(NGH)resources are mainly distributed in the deepwater areas of 300-3000 m deep in the coastal continental shelf,and they are characterized by weak cementation and non-diagenesis.In order to test and study this type of NGH,it is necessary to prepare samples quickly in situ in large quantities.At present,the commonly used preparation technologies(e.g.stirring method,spraying method and bubbling method)are defective with slow generation and low gas storage density.In view of this,the 1062 L rapid non-diagenetic NGH preparation kettle was designed and developed independently.Then,based on the physical properties of non-diagenetic NGH in the South China Sea,NGH preparation tests were carried out on stirring method,spraying method,bubbling method and“three-in-one”method(the combination of stirring method,spraying method and bubbling method).Temperature,pressure,resistivity and reaction time in the process of test were tested,and NGH generation situations and preparation efficiency of different preparation processes were analyzed and compared.And the following research results were obtained.First,in the process of NGH preparation by stirring method,spraying method and bubbling method,respectively,the generated NGH increases slowly and spreads the whole liquid level gradually.Second,inducing period is obvious in the preparation process by the stirring method,but not obvious by the spraying method,the bubbling method and the“three-in-one”method.Third,in the process of NGH preparation by stirring method,spraying method,bubbling method and“three-in-one”method,the resistivity increases as the reaction goes,and its change trend is basically accordant with the NGH preparation rate.Fourth,the preparation cycle of NGH by“three-in-one”method is greatly shorter than that by single preparation method.The preparation time by stirring method,spraying method and bubbling method is about 5.14 times,3.59 times and 3.16 times that of“three-in-one”method respectively.In conclusion,the 1062 L rapid NGH preparation kettle developed in this paper can prepare marine non-diagenetic NGH samples quickly in situ.And compared with single preparation method,“three-in-one”method is much higher in NGH preparation efficiency.
基金Supported by Natural Science Foundation of China (No.50379033)Program for New Century Excellent Talents in University.
文摘To mitigate the damages produced by flood discharges of hydropower stations, a three-dimensional numerical model of the aerated water jet restricted by gravity, air resistance and air buoyancy is proposed. Based on theoretical analysis and prototype data, a three-dimensional stochastic model is constructed using Monte Carlo method to evaluate the range of atomization and intensity of rainfall in gorges, which are strongly affected by complex terrain and various wind conditions. The prototype data observed from two hydropower stations are selected in the feedback and verification analysis to verify the proposed model. The result shows that the computational solutions fit the prototype data well. This model can be used to forecast the atomization of a hydropower station that is being designed or constructed.
基金supported by the 12th Five-Year Important National Science & Technology Specific Projectsthe National Science & Technology Major Special Project on the Prevention and Cure of Acquired Immune Deficiency Syndrome and Virus Hepatitis (2012ZX10003009-001-002)
文摘Polylactide(PLA) microspheres were prepared using the solid-in-oil(S/O) spray-drying method to achieve the sustained release of a hydrophilic drug for the treatment of tuberculosis, via intratracheal instillation. Isoniazid(IN), a low-molecular-weight hydrophilic drug, was used as a model drug. The effects of various sizes of micronized IN powder, different drug/polymer ratios, spray-drying process parameters, and drug-release characteristics were studied to optimize the manufacturing parameters. A high entrapment efficiency(87.3%) was obtained using this method; furthermore, the microspheres were spherical and smooth. They were individually and homogenously distributed, with a mean diameter of 5.6 μm; furthermore, they showed a satisfactory extended sustained-release phase. After administration of the microspheres to rats, pulmonary drug concentrations were maintained at a relatively stable level for up to 4 weeks.
