In this paper,a novel method is proposed and employed to design a single diffractive optical element（DOE） for implementing spectrum-splitting and beam-concentration（SSBC） functions simultaneously.We develop an opt...In this paper,a novel method is proposed and employed to design a single diffractive optical element（DOE） for implementing spectrum-splitting and beam-concentration（SSBC） functions simultaneously.We develop an optimization algorithm,through which the SSBC DOE can be optimized within an arbitrary thickness range according to the limitations of modern photolithography technology.Theoretical simulation results reveal that the designed SSBC DOE has a high optical focusing efficiency.It is expected that the designed SSBC DOE should have practical applications in high-efficiency solar cell systems.展开更多
Using the cross correlation function analysis method, this paper discusses shear wave splitting and crack-inducedanisotropy in the crust beneath Tangshan, North China, by the digital data from Tangshan strong ground m...Using the cross correlation function analysis method, this paper discusses shear wave splitting and crack-inducedanisotropy in the crust beneath Tangshan, North China, by the digital data from Tangshan strong ground monon temporary arrays. Sixteen of twenty-one stations in the arrays recorded earthquake events available forstudying from 1982 to 1984. Having calculated 131 available records, we get slower shear wave time delay r andfaster shear wave polarization azimuth Paz in Tangshan region, and the cracks density s is got further fromthem. The analysis shows that the stress field is very complicated in Tangshan region and has strongly regionalfeature. Because of the complicated distribution of faults, different shear wave splitting characteristics are shownin 16 stations, scattered r and different Paz. And they also were observed that the r and PaZ values were diversewithin the time scale of hours in more than one station. In Tangshan region the average results of r, Paz and Bare 0. 0071 s. km-1, northwest-west near to east-west and 0.022 respectively. Meantime, the standard devia.tions were calculated in this paper.展开更多
β-Ge3N4 loaded with nanoparticulate RuO2 as a cocatalyst is the first successful non-oxide photocatalyst for overall water splitting.To get an insight into the working mechanism of this particular photocatalytic syst...β-Ge3N4 loaded with nanoparticulate RuO2 as a cocatalyst is the first successful non-oxide photocatalyst for overall water splitting.To get an insight into the working mechanism of this particular photocatalytic system,we have calculated geometrical structures of low-index surfaces forβ-Ge3N4.Analysis of surface energies indicates that the most preferentially exposed surface is(100).The band gap of surface is narrower than that of bulk due to the dangling bonds.Dissociative water adsorption on(100)surface is thermodynamically favorable.The adsorption behavior of(RuO2)n(n=2,3,and 4)clusters on theβ-Ge3N4(100)surface has been explored.It is found that all the clusters bind to(100)surface strongly by forming interfacial bonds so that the adsorptions are exothermic processes.The calculation on density of states forβ-Ge3N4(100)surface loaded with(RuO2)nclusters reveals that photo-induced electrons tend to accumulate on(RuO2)nclusters and holes tend to stay inβ-Ge3N4.Based on the theoretical indication of Type-II staggered band alignment,we have proposed that in photocatalytic water splitting reaction,oxygen evolution reaction is inclined to occur on the surface ofβ-Ge3N4 while hydrogen evolution reaction is apt to occur on(RuO2)nclusters.In a word,loading RuO2 nanoparticles as a reduction cocatalyst benefits the charge separation inβ-Ge3N4.Furthermore,attaching(RuO2)nclusters ontoβ-Ge3N4(100)surface results in the redshift of absorption edge and the increase of absorption intensity.Our calculations have reasonably explained the experimental observation on the decomposition of water into H2 and O2 after loading RuO2 cocatalyst inβ-Ge3N4 photocatalyst.展开更多
为提高月径流时间序列预测精度,改进最小二乘孪生支持向量回归机(Least Squares Twin Support Vector Regression,LSTSVR)性能,首次基于高斯核函数、多项式核函数、线性核函数构建混合核函数,提出4种季节趋势分解(Seasonal and Trend de...为提高月径流时间序列预测精度,改进最小二乘孪生支持向量回归机(Least Squares Twin Support Vector Regression,LSTSVR)性能,首次基于高斯核函数、多项式核函数、线性核函数构建混合核函数,提出4种季节趋势分解(Seasonal and Trend decomposition using Loess,STL)-小波包变换(Wavelet Packet Transform,WPT)-裂狐优化(Rüppell's Fox Optimizer,RFO)算法-混合核最小二乘孪生支持向量回归机(Hybrid Kernel Least Squares Twin Support Vector Regression,HLSTSVR)模型,并构建STL-WPT-RFO-LSTSVR、STL-WPT-RFO-混合核最小二乘支持向量回归机(Hybrid Kerllel Least Squares Twin Suppart Vector Regression,HLSSVR)、STL-WPT-RFO-最小二乘支持向量回归机(Least Squares Support Vector Regression,LSSVR)等17种对比分析模型,通过云南省高桥、凤屯水文站月径流时间序列预测实例对21种模型进行验证。首先利用STL-WPT二次分解技术对月径流序列进行分解处理,合理划分训练集和验证集;然后基于高斯核函数、多项式核函数、线性核函数,采用“三三”线性组合和“两两”线性组合的方式构建4种混合核函数对月径流分解分量进行空间映射;最后利用RFO寻优HLSTSVR/LSTSVR/HLSSVR/LSSVR最佳超参数,利用最佳超参数建立21种模型对实例月径流序列各分解分量进行训练、预测和重构。结果表明:①4种STL-WPT-RFO-HLSTSVR模型能适应不同尺度的月径流数据分布,具有较好的模型性能和较小的预测误差,其中STL-WPT-RFO-HLSTSVR(高斯+多项式+线性)模型对高桥、凤屯站月径流预测的平均绝对百分比误差MAPE分别为2.85%、2.19%,决定系数R2均为0.9994,预测精度最高、效果最好;②混合核函数兼顾了不同核函数优势,能在模型复杂度与泛化能力之间取得平衡,显著提升模型性能和预测精度;③STL-WPT二次分解技术能有效解决复杂时间序列的非平稳性、非线性和多尺度特征,较STL更具分解优势;④组合模型融合了STL-WPT、RFO和HLSTSVR优点,具有较好的普适性和参考价值。展开更多
In this paper, we report on a series of computational simulations on hydrogen bonding in two ice phases （Ih and Ic） using CASTEP with PW91 and RPBE exchange-correlation based on ab initio density functional theory. ...In this paper, we report on a series of computational simulations on hydrogen bonding in two ice phases （Ih and Ic） using CASTEP with PW91 and RPBE exchange-correlation based on ab initio density functional theory. The strength of the H-bond is correlated with intramolecular O-H stretching, and the energy splitting exists for both the H-bond and covalent O-H stretching. By analyzing the dispersion relationship of to（q）, we observe the separation of the longitudinal optic （LO） mode from transverse optic （TO） mode at the gamma point, seemingly interpreting the controversial two H-bond peaks in the vibrational spectrum of ice recorded by inelastic incoherent neutron scattering experiments. The test of ambient environment on phonon density of sates （PDOS） shows that the relaxed tetrahedral structure is the most stable structural configuration for water clusters.展开更多
To better understand the effect of a new split variant of human asialoglycoprotein receptor (ASGPR H1b) on ASGPR ligands’ binding ability, we established a functional cell line which expresses ASGPR.The full lengths ...To better understand the effect of a new split variant of human asialoglycoprotein receptor (ASGPR H1b) on ASGPR ligands’ binding ability, we established a functional cell line which expresses ASGPR.The full lengths of ASGPRH1a and H2c fragments from human liver were amplified by reverse transcript PCR (RT-PCR) and inserted into eukaryotic expression vector pIRES2EFP, pCDNA3.1 (Zeo+) respectively.The recombinants were cotransfected into HeLa cells.After selection by using Neocin and Zeocin, a stably transfected cell line was established, which was designated 4-1-6.The transcription and expression of ASGPRH1a and H2c in 4-1-6 were confirmed by RT-PCR, Western blotting and immunofluorescence.The endocytosis function of the artificial "ASGPR" on the surface of 4-1-6 was tested by FACS.It was found that the cell line 4-1-6 could bind ASGPR natural ligand molecular asialo-orosomucoid (ASOR).After the eukaryotic plasmid H1b/pCDNA3.1 (neo) was transfected into cell line 4-1-6, H1b did not down-regulate the ligand binding ability of ASGPR.The eukaryotic expression plasmid H1b/pcDNA3.1 (neo) and H2c/pcDNA3.1 (neo) were co-transfected transiently into Hela cell.Neither single H1b nor H1b and H2c could bind ASOR.In conclusion, a functional cell line of human asialoglycoprotein receptor (ASGPR) which expresses both H1a and H2c stably was established.The new split variant H1b has no effect on ASGPR binding to ASOR.ASGPRH1b alone can’t bind to ASOR, it yet can’t form functional complex with ASGPRH2c.展开更多
The increased concern over global climate change and lack of long-term sustainability of fossil fuels in the projected future has prompted further research into advanced alternative fuel vehicles to reduce vehicle emi...The increased concern over global climate change and lack of long-term sustainability of fossil fuels in the projected future has prompted further research into advanced alternative fuel vehicles to reduce vehicle emissions and fuel consumption. One of the primary advanced vehicle research areas involves electrification and hybridization of vehicles. As hybrid-electric vehicle technology has advanced, so has the need for more innovative control schemes for hybrid vehicles, including the development and optimization of hybrid powertrain transmission shift schedules. The hybrid shift schedule works in tandem with a cost function-based torque split algorithm that dynamically determines the optimal torque command for the electric motor and engine. The focus of this work is to develop and analyze the benefits and limitations of two different shift schedules for a position-3 (P3) parallel hybrid-electric vehicle. a traditional two-parameter shift schedule that operates as a function of vehicle accelerator position and vehicle speed (state of charge (SOC) independent shift schedule), and a three-parameter shift schedule that also adapts to fluctuations in the state of charge of the high voltage batteries (SOC dependent shift schedule). The shift schedules were generated using an exhaustive search coupled with a fitness function to evaluate all possible vehicle operating points. The generated shift schedules were then tested in the software-in-the-loop (SIL) environment and the vehicle-in-the-loop (VIL) environment and compared to each other, as well as to the stock 8L45 8-speed transmission shift schedule. The results show that both generated shift schedules improved upon the stock transmission shift schedule used in the hybrid powertrain comparing component efficiency, vehicle efficiency, engine fuel economy, and vehicle fuel economy.展开更多
针对串行抵消列表(Successive Cancellation List,SCL)译码框架下基于搜索集的路径分裂选择策略的缺陷,提出两种改进策略:基于可靠性函数的路径分裂策略和依靠辅助路径度量值(Auxiliary Path Metric,APM)的剪枝策略。在此基础上,提出一...针对串行抵消列表(Successive Cancellation List,SCL)译码框架下基于搜索集的路径分裂选择策略的缺陷,提出两种改进策略:基于可靠性函数的路径分裂策略和依靠辅助路径度量值(Auxiliary Path Metric,APM)的剪枝策略。在此基础上,提出一种新的译码算法——基于可靠性函数的路径分裂选择策略辅助串行抵消列表(Path Splitting Selecting Strategy Based on Reliability Function under the Successive Cancellation List,PSS-RF-SCL)译码算法。该算法在译码阶段,每个信息比特在进行路径分裂前,会计算所有路径的路径度量(Path Metric,PM)值。利用这些PM值,进一步计算该比特的可靠性函数值。算法将可靠性函数值低于其平均值(即阈值α)的信息比特视为需要进行路径分裂的比特,从而减少了多余的路径分裂次数。此外,算法计算每条路径的APM值,并将APM值高于正确译码路径的APM平均值(即阈值β)的路径视为不可靠路径,对不可靠路径进行剪枝,有效控制了译码列表总数。仿真结果表明,相较于传统的基于搜索集的路径分裂策略辅助的SCL译码算法,所提出的PSS-RF-SCL译码算法在保持相同译码性能的前提条件下,显著降低了译码复杂度。展开更多
基金Project supported by the National Basic Research Program of China (Grant No. 2011CB301801)the National Natural Science Foundation of China (GrantNos. 91233202,10904099,11204188,61205097,and 11174211)
文摘In this paper,a novel method is proposed and employed to design a single diffractive optical element（DOE） for implementing spectrum-splitting and beam-concentration（SSBC） functions simultaneously.We develop an optimization algorithm,through which the SSBC DOE can be optimized within an arbitrary thickness range according to the limitations of modern photolithography technology.Theoretical simulation results reveal that the designed SSBC DOE has a high optical focusing efficiency.It is expected that the designed SSBC DOE should have practical applications in high-efficiency solar cell systems.
文摘Using the cross correlation function analysis method, this paper discusses shear wave splitting and crack-inducedanisotropy in the crust beneath Tangshan, North China, by the digital data from Tangshan strong ground monon temporary arrays. Sixteen of twenty-one stations in the arrays recorded earthquake events available forstudying from 1982 to 1984. Having calculated 131 available records, we get slower shear wave time delay r andfaster shear wave polarization azimuth Paz in Tangshan region, and the cracks density s is got further fromthem. The analysis shows that the stress field is very complicated in Tangshan region and has strongly regionalfeature. Because of the complicated distribution of faults, different shear wave splitting characteristics are shownin 16 stations, scattered r and different Paz. And they also were observed that the r and PaZ values were diversewithin the time scale of hours in more than one station. In Tangshan region the average results of r, Paz and Bare 0. 0071 s. km-1, northwest-west near to east-west and 0.022 respectively. Meantime, the standard devia.tions were calculated in this paper.
基金the National Natural Science Foundation of China under Grant 21473183the open fund of Key Laboratory of Computational Physical Sciences(Fudan University),Ministry of Education.
文摘β-Ge3N4 loaded with nanoparticulate RuO2 as a cocatalyst is the first successful non-oxide photocatalyst for overall water splitting.To get an insight into the working mechanism of this particular photocatalytic system,we have calculated geometrical structures of low-index surfaces forβ-Ge3N4.Analysis of surface energies indicates that the most preferentially exposed surface is(100).The band gap of surface is narrower than that of bulk due to the dangling bonds.Dissociative water adsorption on(100)surface is thermodynamically favorable.The adsorption behavior of(RuO2)n(n=2,3,and 4)clusters on theβ-Ge3N4(100)surface has been explored.It is found that all the clusters bind to(100)surface strongly by forming interfacial bonds so that the adsorptions are exothermic processes.The calculation on density of states forβ-Ge3N4(100)surface loaded with(RuO2)nclusters reveals that photo-induced electrons tend to accumulate on(RuO2)nclusters and holes tend to stay inβ-Ge3N4.Based on the theoretical indication of Type-II staggered band alignment,we have proposed that in photocatalytic water splitting reaction,oxygen evolution reaction is inclined to occur on the surface ofβ-Ge3N4 while hydrogen evolution reaction is apt to occur on(RuO2)nclusters.In a word,loading RuO2 nanoparticles as a reduction cocatalyst benefits the charge separation inβ-Ge3N4.Furthermore,attaching(RuO2)nclusters ontoβ-Ge3N4(100)surface results in the redshift of absorption edge and the increase of absorption intensity.Our calculations have reasonably explained the experimental observation on the decomposition of water into H2 and O2 after loading RuO2 cocatalyst inβ-Ge3N4 photocatalyst.
文摘为提高月径流时间序列预测精度,改进最小二乘孪生支持向量回归机(Least Squares Twin Support Vector Regression,LSTSVR)性能,首次基于高斯核函数、多项式核函数、线性核函数构建混合核函数,提出4种季节趋势分解(Seasonal and Trend decomposition using Loess,STL)-小波包变换(Wavelet Packet Transform,WPT)-裂狐优化(Rüppell's Fox Optimizer,RFO)算法-混合核最小二乘孪生支持向量回归机(Hybrid Kernel Least Squares Twin Support Vector Regression,HLSTSVR)模型,并构建STL-WPT-RFO-LSTSVR、STL-WPT-RFO-混合核最小二乘支持向量回归机(Hybrid Kerllel Least Squares Twin Suppart Vector Regression,HLSSVR)、STL-WPT-RFO-最小二乘支持向量回归机(Least Squares Support Vector Regression,LSSVR)等17种对比分析模型,通过云南省高桥、凤屯水文站月径流时间序列预测实例对21种模型进行验证。首先利用STL-WPT二次分解技术对月径流序列进行分解处理,合理划分训练集和验证集;然后基于高斯核函数、多项式核函数、线性核函数,采用“三三”线性组合和“两两”线性组合的方式构建4种混合核函数对月径流分解分量进行空间映射;最后利用RFO寻优HLSTSVR/LSTSVR/HLSSVR/LSSVR最佳超参数,利用最佳超参数建立21种模型对实例月径流序列各分解分量进行训练、预测和重构。结果表明:①4种STL-WPT-RFO-HLSTSVR模型能适应不同尺度的月径流数据分布,具有较好的模型性能和较小的预测误差,其中STL-WPT-RFO-HLSTSVR(高斯+多项式+线性)模型对高桥、凤屯站月径流预测的平均绝对百分比误差MAPE分别为2.85%、2.19%,决定系数R2均为0.9994,预测精度最高、效果最好;②混合核函数兼顾了不同核函数优势,能在模型复杂度与泛化能力之间取得平衡,显著提升模型性能和预测精度;③STL-WPT二次分解技术能有效解决复杂时间序列的非平稳性、非线性和多尺度特征,较STL更具分解优势;④组合模型融合了STL-WPT、RFO和HLSTSVR优点,具有较好的普适性和参考价值。
基金Project supported by the National Natural Science Foundation of China (Grant No.11075094)
文摘In this paper, we report on a series of computational simulations on hydrogen bonding in two ice phases （Ih and Ic） using CASTEP with PW91 and RPBE exchange-correlation based on ab initio density functional theory. The strength of the H-bond is correlated with intramolecular O-H stretching, and the energy splitting exists for both the H-bond and covalent O-H stretching. By analyzing the dispersion relationship of to（q）, we observe the separation of the longitudinal optic （LO） mode from transverse optic （TO） mode at the gamma point, seemingly interpreting the controversial two H-bond peaks in the vibrational spectrum of ice recorded by inelastic incoherent neutron scattering experiments. The test of ambient environment on phonon density of sates （PDOS） shows that the relaxed tetrahedral structure is the most stable structural configuration for water clusters.
基金supported by grants from the National Major Science and Technology Special Project for Infectious Diseases of China (No.2008ZX10002-011)National High Technology Research and Development of China (Program 863) (No.2006AA02Z128)the National Natural Science Foundation of China (Nos.30700701,30571646)
文摘To better understand the effect of a new split variant of human asialoglycoprotein receptor (ASGPR H1b) on ASGPR ligands’ binding ability, we established a functional cell line which expresses ASGPR.The full lengths of ASGPRH1a and H2c fragments from human liver were amplified by reverse transcript PCR (RT-PCR) and inserted into eukaryotic expression vector pIRES2EFP, pCDNA3.1 (Zeo+) respectively.The recombinants were cotransfected into HeLa cells.After selection by using Neocin and Zeocin, a stably transfected cell line was established, which was designated 4-1-6.The transcription and expression of ASGPRH1a and H2c in 4-1-6 were confirmed by RT-PCR, Western blotting and immunofluorescence.The endocytosis function of the artificial "ASGPR" on the surface of 4-1-6 was tested by FACS.It was found that the cell line 4-1-6 could bind ASGPR natural ligand molecular asialo-orosomucoid (ASOR).After the eukaryotic plasmid H1b/pCDNA3.1 (neo) was transfected into cell line 4-1-6, H1b did not down-regulate the ligand binding ability of ASGPR.The eukaryotic expression plasmid H1b/pcDNA3.1 (neo) and H2c/pcDNA3.1 (neo) were co-transfected transiently into Hela cell.Neither single H1b nor H1b and H2c could bind ASOR.In conclusion, a functional cell line of human asialoglycoprotein receptor (ASGPR) which expresses both H1a and H2c stably was established.The new split variant H1b has no effect on ASGPR binding to ASOR.ASGPRH1b alone can’t bind to ASOR, it yet can’t form functional complex with ASGPRH2c.
文摘The increased concern over global climate change and lack of long-term sustainability of fossil fuels in the projected future has prompted further research into advanced alternative fuel vehicles to reduce vehicle emissions and fuel consumption. One of the primary advanced vehicle research areas involves electrification and hybridization of vehicles. As hybrid-electric vehicle technology has advanced, so has the need for more innovative control schemes for hybrid vehicles, including the development and optimization of hybrid powertrain transmission shift schedules. The hybrid shift schedule works in tandem with a cost function-based torque split algorithm that dynamically determines the optimal torque command for the electric motor and engine. The focus of this work is to develop and analyze the benefits and limitations of two different shift schedules for a position-3 (P3) parallel hybrid-electric vehicle. a traditional two-parameter shift schedule that operates as a function of vehicle accelerator position and vehicle speed (state of charge (SOC) independent shift schedule), and a three-parameter shift schedule that also adapts to fluctuations in the state of charge of the high voltage batteries (SOC dependent shift schedule). The shift schedules were generated using an exhaustive search coupled with a fitness function to evaluate all possible vehicle operating points. The generated shift schedules were then tested in the software-in-the-loop (SIL) environment and the vehicle-in-the-loop (VIL) environment and compared to each other, as well as to the stock 8L45 8-speed transmission shift schedule. The results show that both generated shift schedules improved upon the stock transmission shift schedule used in the hybrid powertrain comparing component efficiency, vehicle efficiency, engine fuel economy, and vehicle fuel economy.
文摘针对串行抵消列表(Successive Cancellation List,SCL)译码框架下基于搜索集的路径分裂选择策略的缺陷,提出两种改进策略:基于可靠性函数的路径分裂策略和依靠辅助路径度量值(Auxiliary Path Metric,APM)的剪枝策略。在此基础上,提出一种新的译码算法——基于可靠性函数的路径分裂选择策略辅助串行抵消列表(Path Splitting Selecting Strategy Based on Reliability Function under the Successive Cancellation List,PSS-RF-SCL)译码算法。该算法在译码阶段,每个信息比特在进行路径分裂前,会计算所有路径的路径度量(Path Metric,PM)值。利用这些PM值,进一步计算该比特的可靠性函数值。算法将可靠性函数值低于其平均值(即阈值α)的信息比特视为需要进行路径分裂的比特,从而减少了多余的路径分裂次数。此外,算法计算每条路径的APM值,并将APM值高于正确译码路径的APM平均值(即阈值β)的路径视为不可靠路径,对不可靠路径进行剪枝,有效控制了译码列表总数。仿真结果表明,相较于传统的基于搜索集的路径分裂策略辅助的SCL译码算法,所提出的PSS-RF-SCL译码算法在保持相同译码性能的前提条件下,显著降低了译码复杂度。
