Two new rearranged diterpenoids, tomocinol C （1） and spirocaesalmin C （2） were isolated from the seeds of Caesalpinia sappan. Their structures were elucidated based on comprehensive analysis of spectroscopic data,...Two new rearranged diterpenoids, tomocinol C （1） and spirocaesalmin C （2） were isolated from the seeds of Caesalpinia sappan. Their structures were elucidated based on comprehensive analysis of spectroscopic data, and their absolute configurations were established by single crystal X-ray crystallography.展开更多
基金financial support of the National Science & Technology Major Project ‘‘Key New Drug Creation and Manufacturing Program’’ (No.2012ZX09301001-001)the National Natural Science Funds (No.81302657,81473112,81573305)+1 种基金the Chinese Academy of Sciences (No.KSZD-EW-Z-004-01)the Shanghai Commission of Science and Technology (No.12JC1410300)
文摘Two new rearranged diterpenoids, tomocinol C （1） and spirocaesalmin C （2） were isolated from the seeds of Caesalpinia sappan. Their structures were elucidated based on comprehensive analysis of spectroscopic data, and their absolute configurations were established by single crystal X-ray crystallography.
