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The quantum spectra analysis of the circular billiards in wells 被引量:2
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作者 张延惠 张丽琴 +3 位作者 徐学友 葛美华 林圣路 杜孟利 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第3期502-506,共5页
We use a recently defined quantum spectral function and apply the method of closed-orbit theory to the 2D circular billiard system. The quantum spectra contain rich information of all classical orbits connecting two a... We use a recently defined quantum spectral function and apply the method of closed-orbit theory to the 2D circular billiard system. The quantum spectra contain rich information of all classical orbits connecting two arbitrary points in the well. We study the correspondence between quantum spectra and classical orbits in the circular, 1/2 circular and 1/4 circular wells using the analytic and numerical methods. We find that the peak positions in the Fourier- transformed quantum spectra match accurately with the lengths of the classical orbits. These examples show evidently that semi-classlcal method provides a bridge between quantum and classical mechanics. 展开更多
关键词 circular billiard closed-orbit theory quantum spectra function Fourier-transformed spectra
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Characterization of the Rice Canopy Infested with Brown Spot Disease Using Field Hyperspectral Data 被引量:1
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作者 ZHAO Jinling ZHANG Dongyan +3 位作者 LUO Juhua DONG Yingying YANG Hao HUANG Wenjiang 《Wuhan University Journal of Natural Sciences》 CAS 2012年第1期86-92,共7页
Based on the field hyperspectral data from the analytical spectral devices (ASD) spectrometer, we characterized the spectral properties of rice canopies infested with brown spot disease and selected spectral regions... Based on the field hyperspectral data from the analytical spectral devices (ASD) spectrometer, we characterized the spectral properties of rice canopies infested with brown spot disease and selected spectral regions and bands sensitive to four severity degrees (severe, moderate, light, and healthy). The results show that the curves' variation on the original and the first- and second-order de- rivative curves are greatly different, but the spectral difference in the near-infrared region is the most obvious for each level. Specifically, the peaks are located at 822, 738, and 793 nm, while the valleys are located at 402, 570, and 753 run, respectively. The sensitive regions are between 430-520, 530-550, and 650-710 nm, and the bands are 498, 539, and 673 nm in the sensitivity analysis, while they are in the ranges of 401-530, 550-730 as well as at 498 nm and 678 nm in the continuum removal. 展开更多
关键词 rice brown spot disease sensitive bands disease severity degree derivative transformation spectra continuum removal method sensitivity analysis method
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Characteristic wavelength selection of volatile organic compounds infrared spectra based on improved interval partial least squares 被引量:2
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作者 Wei Ju Changhua Lu +4 位作者 Yujun Zhang Weiwei Jiang Jizhou Wang Yi Bing Lu Feng Hong 《Journal of Innovative Optical Health Sciences》 SCIE EI CAS 2019年第2期35-53,共19页
As important components of air pollutant,volatile organic compounds(VOCs)can cause great harm to environment and human body.The concentration change of VOCs should be focused on in real-time environment monitoring sys... As important components of air pollutant,volatile organic compounds(VOCs)can cause great harm to environment and human body.The concentration change of VOCs should be focused on in real-time environment monitoring system.In order to solve the problem of wavelength redundancy in full spectrum partial least squares(PLS)modeling for VOCs concentration analysis,a new method based on improved interval PLS(iPLS)integrated with Monte-Carlo sampling,called iPLS-MC method,was proposed to select optimal characteristic wavelengths of VOCs spectra.This method uses iPLS modeling to preselect the characteristic wavebands of the spectra and generates random wavelength combinations from the selected wavebands by Monte-Carlo sampling.The wavelength combination with the best prediction result in regression model is selected as the characteristic wavelengths of the spectrum.Different wavelength selection methods were built,respectively,on Fourier transform infrared(FTIR)spectra of ethylene and ethanol gas at different concentrations obtained in the laboratory.When the interval number of iPLS model is set to 30 and the Monte-Carlo sampling runs 1000 times,the characteristic wavelengths selected by iPLS-MC method can reduce from 8916 to 10,which occupies only 0.22%of the full spectrum wavelengths.While the RMSECV and correlation coefficient(Rc)for ethylene are 0.2977 and 0.9999 ppm,and those for ethanol gas are 0.2977 ppm and 0.9999.The experimental results show that the iPLS-MC method can select the optimal characteristic wavelengths of VOCs FTIR spectra stably and effectively,and the prediction performance of the regression model can be significantly improved and simplified by using characteristic wavelengths. 展开更多
关键词 Ambient air monitoring Fourier transform infrared spectra analysis variable selection interval partial least square Monte-Carlo sampling
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Application of Embedded Zerotree Wavelet to the Compression of Infrared Spectra
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作者 MengLongLI HuaYiQI +2 位作者 FuShengNIE ZhiNingWEN BinKANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第11期1193-1195,共3页
In this paper the embedded zerotree wavelet (EZW) method and Huffman coding are proposed to compress infrared (IR) spectra. We found that this technique is much better than others in terms of efficiently coding wavele... In this paper the embedded zerotree wavelet (EZW) method and Huffman coding are proposed to compress infrared (IR) spectra. We found that this technique is much better than others in terms of efficiently coding wavelet coefficients because the zerotree quantization is an effective way of exploiting the self-similarities of wavelet coefficients at various resolutions. 展开更多
关键词 Embedded zerotree wavelet compress infrared spectra wavelet transform.
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The quantum spectral analysis of the two-dimensional annular billiard system
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作者 张延惠 张记全 +1 位作者 徐学友 林圣路 《Chinese Physics B》 SCIE EI CAS CSCD 2009年第1期35-39,共5页
Based on the extended closed-orbit theory together with spectral analysis, this paper studies the correspondence between quantum mechanics and the classical counterpart in a two-dimensional annular billiard. The resul... Based on the extended closed-orbit theory together with spectral analysis, this paper studies the correspondence between quantum mechanics and the classical counterpart in a two-dimensional annular billiard. The results demonstrate that the Fourier-transformed quantum spectra are in very good accordance with the lengths of the classical ballistic trajectories, whereas spectral strength is intimately associated with the shapes of possible open orbits connecting arbitrary two points in the annular cavity. This approach facilitates an intuitive understanding of basic quantum features such as quantum interference, locations of the wavefunctions, and allows quantitative calculations in the range of high energies, where full quantum calculations may become impractical in general. This treatment provides a thread to explore the properties of microjunction transport and even quantum chaos under the much more general system. 展开更多
关键词 closed-orbit theory Fourier-transformed spectra annular billiard geometrical effect
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On Choosing Fourier Transforms for Practical Geoscience Applications
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作者 David Boteler 《International Journal of Geosciences》 2012年第5期952-959,共8页
The variety of definitions of Fourier transforms can create confusion for practical applications. This paper examines the choice of formulas for Fourier transforms and determines the appropriate choices for geoscience... The variety of definitions of Fourier transforms can create confusion for practical applications. This paper examines the choice of formulas for Fourier transforms and determines the appropriate choices for geoscience applications. One set of Discrete Fourier Transforms can be defined that approximate Fourier integrals and provide transforms between sampled continuous functions in both domains. For applications involving transforms between a continuous function and a discrete function a second set of Discrete Fourier Transforms is needed with different scaling factors. Two classes of application are presented: those where either form of transforms can be used and those where it is necessary to use a particular transform to obtain the correct results. 展开更多
关键词 FOURIER transforms FILTERING spectra IMPULSE Response
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Translational Motion of a Free Large Polaron and Broadening of Absorption Spectra
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作者 Vladimir Mukhomorov 《Journal of Modern Physics》 2010年第1期9-16,共8页
The translational motion of a large polaron as whole is analyzed in the context of its effect on the broadening of an absorption optical spectrum. It was open question how important the role of translational degrees o... The translational motion of a large polaron as whole is analyzed in the context of its effect on the broadening of an absorption optical spectrum. It was open question how important the role of translational degrees of freedom and the corresponding velocities are on the broadening. The Bogolyubov method of canonical transformation of coordinates is formulated for a system of an electron and field, taking into account rigorous fulfillment of the conservation laws. Separation of variables is carried out for the coordinates describing the translational degrees of freedom and the electron oscillations in a polarization well. The equations obtained for the electronic states explicitly depend on the velocity of the free polaron as a whole. An estimate is made for free polaron in ammonia. 展开更多
关键词 LARGE POLARON TRANSLATIONAL Motion CANONICAL transformation BROADENING Absorption spectra Ammonia
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Effect of the nonlinearity of the CCD in Fourier transform profilometry on spectrum overlapping and measurement accuracy
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作者 乔闹生 邹北骥 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第1期237-242,共6页
In Fourier transform profilometry (FTP), we must restrain spectrum overlapping caused by the nonlinearity of the charge coupled device (CCD) and increase the measurement accuracy of the object shape. Firstly, the ... In Fourier transform profilometry (FTP), we must restrain spectrum overlapping caused by the nonlinearity of the charge coupled device (CCD) and increase the measurement accuracy of the object shape. Firstly, the causes of producing higher-order spectrum components and inducing spectrum overlapping are analysed theoretically, and a simple physical ex- planation and analytical deduction are given. Secondly, aiming to suppress spectrum overlapping and improve measurement accuracy, the influence of spatial carrier frequency of projection grating on them is analysed. A method of increasing the spatial carrier frequency of projection grating to restrain or reduce the spectrum overlapping significantly is proposed. We then analyze the mechanism of how the spectrum overlapping is reduced. Finally, the simulation results and experimental measurements verify the correction of the proposed theory and method. 展开更多
关键词 spectra overlapping measurement accuracy nonlinearity of CCD Fourier transform profilometry
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Study of blood fat concentration based on serum ultraviolet absorption spectra and neural network
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作者 Wei-Hua Zhu Zhi-Min Zhao +2 位作者 Xin Guo Le-Xin Wang Hui Chen 《Journal of Biomedical Science and Engineering》 2009年第6期400-404,共5页
Blood plays an important role in the clinical di-agnosis and treatment, the analysis of blood will be of very important practical significance. The experiment shows that the absorption spectra of blood are of serious ... Blood plays an important role in the clinical di-agnosis and treatment, the analysis of blood will be of very important practical significance. The experiment shows that the absorption spectra of blood are of serious noise in the wave band of 200 to 300 nm, which hides the useful spectral characteristics. The effective separation of the noise was achieved by db4 wavelet transform, and the signals of reconstruction have been obviously improved in the noise serious wave band, reflecting some useful information. The absorption peaks of different samples are displaced to some degrees. The correlation between absorbance at 278nm and blood fat concentration is no significant and random. Based on the evident correlation between serum absorption spectrum and blood fat con-centration in the wave band of 265 to 282nm, a neural network model was built to forecast the blood fat concentration, bringing a relatively good prediction. This provides a new spectral test method of blood fat concentration. 展开更多
关键词 Blood FAT CONCENTRATION ULTRAVIOLET Absorption spectra Neural Network (NN) SERUM Wavelet transform
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Power and Cross-Spectra for the Turbulent Atmospheric Motion and Transports in the Domain of Wave Number Frequency Space: Theoretical Aspects
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作者 M. Y. Totagi 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 1994年第4期491-498,共8页
The study of large-scale atmospheric turbulence and transport processes is of vital importance in the general circulation of the atmosphere. The governing equations of the power and cross-spectra for the atmospheric m... The study of large-scale atmospheric turbulence and transport processes is of vital importance in the general circulation of the atmosphere. The governing equations of the power and cross-spectra for the atmospheric motion and transports in the domain of wave number frequency space have been derived. The contributions of the nonlinear interactions of the atmospheric waves in velocity and temperature fields to the conversion of kinetic and potential energies and to the meridional transports of angular momentum and sensible heat in the atmosphere have been discussed. 展开更多
关键词 spectral analysis Fourier transform Power and cross-spectra Atmospheric turbulence Wave number frequency space Kinetic and potential energies Transports of angular momentum and sensible heat
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牡蛎(近江牡蛎)药材、煅牡蛎饮片及其标准汤剂的物相变化及量质传递分析 被引量:3
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作者 张洪怡 周靖惟 +12 位作者 刘佳雯 费文波 黄仕如 陈玉梅 李重阳 李菲菲 马巧伶 王福 胡媛 刘友平 陈士林 陈林 陈鸿平 《中国中药杂志》 北大核心 2025年第5期1209-1223,共15页
该研究对17批牡蛎(近江牡蛎)“药材-煅制饮片-饮片标准汤剂”过程的物相变化及量质传递进行分析。采用化学滴定法测定其主要成分碳酸钙(CaCO_(3))含量,计算出膏率和转移率,牡蛎药材、饮片、标准汤剂的CaCO_(3)质量分数范围分别为94.39%~... 该研究对17批牡蛎(近江牡蛎)“药材-煅制饮片-饮片标准汤剂”过程的物相变化及量质传递进行分析。采用化学滴定法测定其主要成分碳酸钙(CaCO_(3))含量,计算出膏率和转移率,牡蛎药材、饮片、标准汤剂的CaCO_(3)质量分数范围分别为94.39%~98.80%、95.03%~99.22%、84.58%~90.47%,药材-饮片得率范围96.85%~98.55%,CaCO_(3)转移率范围96.92%~99.27%,饮片-标准汤剂出膏率范围2.86%~5.48%,CaCO_(3)转移率范围2.59%~5.13%。X射线荧光光谱(X-ray fluorescence,XRF)分析结果显示三者主要含钙(Ca)、钠(Na)、镁(Mg)、硅(Si)、氯(Cl)、溴(Br)、铝(Al)、铁(Fe)、铬(Cr)、锰(Mn)、钾(K)等元素,化学计量学结果显示药材-饮片差异性元素Cr、Fe、Si相对含量增加,饮片-标准汤剂Mg、Al、Br、K、Cl、Na等差异性元素的相对含量增加。采用粉末X射线衍射光谱(X-ray diffraction,XRD)技术建立了牡蛎药材、饮片和标准汤剂的XRD特征图谱,分析可见药材-饮片-标准汤剂过程中,三者主要物相均为方解石型CaCO_(3),未见晶型的转变或新物相的产生。采用傅里叶变换红外光谱(Fourier transform infrared spectroscopy,FTIR)技术建立了牡蛎药材、饮片和标准汤剂的FTIR特征图谱,分析结果显示药材中存在O-H、C-H、C=O、C-O和CO_(3)^(2-)等基团的内部振动,煅制后因有机质成分损失,饮片及其标准汤剂未见C-H、C=O、C-O等基团对应的特征峰信息。综上,该研究通过测定CaCO_(3)含量,计算出膏率和转移率,比较药材-饮片-标准汤剂三者的元素变化,FTIR特征图谱及XRD特征图谱的差异,阐明了牡蛎药材-煅牡蛎饮片-标准汤剂过程的量质传递及物相变化,结果合理可靠,为后续煅牡蛎(近江牡蛎)配方颗粒的工艺研究和质量标准制定奠定了基础,为牡蛎等介类中药“药材-饮片-标准汤剂-配方颗粒”的全过程质量控制提供了思路与方法。 展开更多
关键词 牡蛎 标准汤剂 量质传递 物相变化 特征图谱 X射线荧光光谱 X射线衍射光谱 傅里叶变换红外光谱
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基于拉曼光谱技术的变压器绝缘油老化研究
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作者 周宇含 刘庆珍 《电气技术》 2025年第6期8-16,28,共10页
针对变压器绝缘油的实测拉曼光谱数据,以拉曼光谱技术为手段,以准确判别变压器绝缘老化状态为目的,开展基于拉曼光谱数据处理、特征提取和老化诊断的研究。首先,结合拉曼光谱噪声的变化规律,基于小波变换理论提出全局阈值小波变换滤波法... 针对变压器绝缘油的实测拉曼光谱数据,以拉曼光谱技术为手段,以准确判别变压器绝缘老化状态为目的,开展基于拉曼光谱数据处理、特征提取和老化诊断的研究。首先,结合拉曼光谱噪声的变化规律,基于小波变换理论提出全局阈值小波变换滤波法,有效地去除拉曼光谱中的噪声信号。然后,基于自适应迭代重加权惩罚最小二乘法(airPLS)提出一种改进的基线校正方法,准确地去除拉曼光谱的荧光背景。其次,运用连续投影算法(SPA)提取拉曼光谱中的老化特征信息,并分析其与变压器绝缘油老化程度之间的关系。最后,基于轻量级梯度提升机(LightGBM)分类模型实现对变压器绝缘老化状态的准确判别,并以极限梯度提升(XGBoost)模型作为对照,比较二者的诊断精度。实验结果表明,轻量级梯度提升机模型的诊断精度具有明显优势,验证了所提取老化特征信息的有效性。 展开更多
关键词 变压器绝缘油 拉曼光谱 噪声 荧光背景 特征提取 老化判别
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苹果硬度的傅里叶变换近红外光谱无损检测 被引量:26
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作者 李桂峰 赵国建 +1 位作者 刘兴华 肖春玲 《农业机械学报》 EI CAS CSCD 北大核心 2009年第1期120-123,共4页
利用傅里叶变换近红外光谱技术探讨快速无损检测苹果硬度方法的可行性。通过解析苹果样品的近红外光谱图,用一阶导数、多元散射校正和矢量归一等方法进行预处理,再用偏最小二乘法建立模型。结果表明,多元散射校正能够有效消除光谱基线... 利用傅里叶变换近红外光谱技术探讨快速无损检测苹果硬度方法的可行性。通过解析苹果样品的近红外光谱图,用一阶导数、多元散射校正和矢量归一等方法进行预处理,再用偏最小二乘法建立模型。结果表明,多元散射校正能够有效消除光谱基线平移和偏移现象,提高原光谱的信噪比,选取有效信息波长范围为1 408~2 355 nm。偏最小二乘法结合多元散射校正所建模型的预测效果最好,模型的决定系数R2为0.985 2,内部交叉验证均方根差RMSECV和预测标准偏差RMSEP分别为0.039 8 kg/cm2和0.016 6 kg/cm2。进一步通过剔除异常值优化模型,并验证检验组的25个样品,模型的R2为0.990 8,RMSEP为0.014 7 kg/cm2。结果表明:建立的模型可靠,预测效果好,能满足苹果硬度快速检测的要求。 展开更多
关键词 苹果 硬度 近红外光谱 傅里叶变换 偏最小二乘法
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风化煤中腐植酸的提取及其光谱学研究 被引量:31
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作者 阳虹 李永生 +1 位作者 范云场 张磊 《煤炭转化》 CAS CSCD 北大核心 2013年第2期87-91,共5页
探讨了从风化煤中提取棕腐酸和黑腐酸的方法,分别用紫外可见光谱、傅立叶变换红外光谱和三维荧光光谱对提取的腐植酸进行了表征,并说明了两种腐植酸结构上的差异.结果表明,棕腐植酸和黑腐植酸官能团种类相似,但含量总体是棕腐酸高于黑腐... 探讨了从风化煤中提取棕腐酸和黑腐酸的方法,分别用紫外可见光谱、傅立叶变换红外光谱和三维荧光光谱对提取的腐植酸进行了表征,并说明了两种腐植酸结构上的差异.结果表明,棕腐植酸和黑腐植酸官能团种类相似,但含量总体是棕腐酸高于黑腐酸.两种腐植酸的紫外可见光谱在整个区间的吸光度是随着波长的增大而减小的混合光谱.两种腐植酸都有荧光效应,且无论随着浓度增加或者pH值增加,棕腐植酸和黑腐植酸的发光峰都有红移现象. 展开更多
关键词 腐植酸 紫外可见光谱 傅立叶红外光谱 荧光光谱 风化煤
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(2+1)维光折变波导阵列的制作 被引量:29
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作者 杨立森 陈晓虎 +3 位作者 刘思敏 汪大云 赵红娥 张万林 《光子学报》 EI CAS CSCD 北大核心 2002年第10期1200-1204,共5页
对四个点光源进行光学傅里叶变换 ,在自散焦光折变晶体中成功地制作了 6μm× 6μm间隔的并行 ( 2 + 1 )维阵列波导 30 0余条 ,并证明了阵列波导实质上是二维体相位栅 实验研究了点光源间距、点光源尺寸及写入时间对阵列波导制作... 对四个点光源进行光学傅里叶变换 ,在自散焦光折变晶体中成功地制作了 6μm× 6μm间隔的并行 ( 2 + 1 )维阵列波导 30 0余条 ,并证明了阵列波导实质上是二维体相位栅 实验研究了点光源间距、点光源尺寸及写入时间对阵列波导制作的影响 。 展开更多
关键词 制作 波导阵列 空间频谱 光折变 傅里叶变换
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红外光谱小波压缩性能的评价 被引量:9
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作者 李梦龙 康彬 +1 位作者 戚华溢 文志宁 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2002年第7期1281-1284,共4页
提出了用于红外光谱小波压缩中压缩性能的评价方法 .所建立的控制恢复根均方差算法能在给定恢复根均方差的情况下得到压缩比 ,控制的精度较高 ,相对标准偏差约为 8% ,可以满足对恢复谱图的误差估计和最佳压缩参数评价的需要 .对于不同... 提出了用于红外光谱小波压缩中压缩性能的评价方法 .所建立的控制恢复根均方差算法能在给定恢复根均方差的情况下得到压缩比 ,控制的精度较高 ,相对标准偏差约为 8% ,可以满足对恢复谱图的误差估计和最佳压缩参数评价的需要 .对于不同的信号 ,同一小波函数所表现出来的压缩性能也不一样 ,所以在预控根均方差算法下评价压缩性能时 ,还应考虑选择有代表性的红外谱图来进行 . 展开更多
关键词 小波压缩 红外光谱 小波变换 光谱图 光谱分析 数据处理
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花青素对大豆蛋白质二级结构影响的多重光谱分析 被引量:28
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作者 朱颖 王中江 +3 位作者 李杨 齐宝坤 隋晓楠 江连洲 《农业机械学报》 EI CAS CSCD 北大核心 2018年第6期368-374,426,共8页
以大豆分离蛋白-花青素复合体系为研究对象,综合利用多重光谱技术对其进行分析。利用荧光光谱探究大豆分离蛋白和花青素间的相互作用方式,采用同步荧光光谱和紫外-可见光谱探究花青素对大豆分离蛋白氨基酸残基微环境的影响,从而得出花... 以大豆分离蛋白-花青素复合体系为研究对象,综合利用多重光谱技术对其进行分析。利用荧光光谱探究大豆分离蛋白和花青素间的相互作用方式,采用同步荧光光谱和紫外-可见光谱探究花青素对大豆分离蛋白氨基酸残基微环境的影响,从而得出花青素对大豆分离蛋白构象的影响,再采用傅里叶变换红外光谱法和圆二色谱法研究花青素对大豆分离蛋白二级结构的影响。结果表明:花青素对大豆分离蛋白有较强的荧光猝灭作用且为静态猝灭,其中,花青素与大豆分离蛋白在298、306、314 K时相互作用的表观结合常数分别为3.343×104、4.507×104、5.525×104L/mol,对应的结合位点数分别为0.917 8、0.954 6、0.938 1。热力学数据分析结果表明:花青素与大豆分离蛋白反应的作用力主要是疏水相互作用;同步荧光光谱和紫外-可见光谱结果表明花青素改变了芳香氨基酸残基在空间结构中所处的微环境,使大豆分离蛋白的分子构象发生改变,且同步荧光光谱显示花青素与大豆分离蛋白中色氨酸残基发生相互作用,使其周围的疏水作用减少。傅里叶变换红外光谱和圆二色谱结果表明花青素引起大豆分离蛋白的二级结构发生改变。 展开更多
关键词 大豆分离蛋白 花青素 荧光光谱 紫外-可见光谱 傅里叶变换红外光谱 圆二色谱
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天体光谱信号去噪的小波域复合阈值新算法 被引量:11
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作者 赵瑞珍 胡占义 胡绍海 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2007年第8期1644-1647,共4页
利用谱线和噪声在小波域内的不同相关特性,提出了一种小波域复合阈值去噪算法。首先将小波系数作NeighShrink阈值处理,然后对得到的小波系数进行二值化,在此基础上定义了每一小波系数所对应的横向相关性指数和纵向相关性指数,最后确定... 利用谱线和噪声在小波域内的不同相关特性,提出了一种小波域复合阈值去噪算法。首先将小波系数作NeighShrink阈值处理,然后对得到的小波系数进行二值化,在此基础上定义了每一小波系数所对应的横向相关性指数和纵向相关性指数,最后确定出决定小波系数取舍的决策系数。由于该决策系数是通过多重判据得到的,因此该方法克服了简单阈值方法过保留或过扼杀的缺点,同时可以去除大脉冲噪声,实验结果表明了该方法的有效性。 展开更多
关键词 天体光谱 小波变换 复合阈值 去噪
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基于荧光光谱的生菜农药残留检测 被引量:17
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作者 孙俊 周鑫 +3 位作者 毛罕平 武小红 杨宁 张晓东 《农业工程学报》 EI CAS CSCD 北大核心 2016年第19期302-307,共6页
为了研究采用荧光光谱技术对生菜农药残留快速无损定性鉴别的可行性,该文通过采集180个生菜样品(3个浓度农药残留生菜,每个浓度农残生菜样本数为60,其中农药与水配比为1:500、1:1 000、1:1 200,即重度超标、轻微超标、标准农残)的荧光... 为了研究采用荧光光谱技术对生菜农药残留快速无损定性鉴别的可行性,该文通过采集180个生菜样品(3个浓度农药残留生菜,每个浓度农残生菜样本数为60,其中农药与水配比为1:500、1:1 000、1:1 200,即重度超标、轻微超标、标准农残)的荧光发射光谱,结合Savitzky-Golay(SG)、标准正态变量变换(standard normalized variable,SNV)、标准正态变量变换结合去趋势(standard normalized variable detrending,SNV detrending)、SG与SNV算法组合(SG-SNV)、SG与SNV detrending算法组合(SG-SNV detrending)对提取的荧光光谱进行预处理,基于全光谱、荧光特征峰值、小波特征建立支持向量机(Support Vector Machine,SVM)分类模型。其中,小波特征通过小波变换对原始光谱以及预处理后光谱进行特征选择获取,分别采用db4、db6、sym5、sym7作为小波基函数。试验结果表明:基于小波特征、荧光特征峰值建立的SVM模型预测集识别率要高于基于全光谱建立的SVM模型。以sym5作为小波基函数,基于SG-SNV detrending预处理光谱选择的小波特征建立的SVM模型取得最优的预测集识别率93.33%,最佳小波分解层数为4。结果表明应用荧光光谱技术对生菜农药残留鉴别是可行的,为生菜农药残留快速、无损检测分析提供了参考。 展开更多
关键词 农作物 无损检测 农药 荧光光谱 生菜 小波变换 特征提取
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茶叶近红外光谱数据的离散余弦变换压缩方法 被引量:7
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作者 林敏 吕进 +3 位作者 徐立恒 郑颖君 于良子 鲁成银 《中国计量学院学报》 2003年第4期268-270,共3页
利用离散余弦变换具有的去相关能力,通过引入阈值和保留能量来定量描述茶叶近红外光谱数据 离散余弦变换后的特性.结果表明,离散余弦变换对近红外光谱具有较强的压缩能力。
关键词 茶叶 近红外光谱 离散余弦变换 阈值 保留能量 压缩能力
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