[Background]Surfactin is a biosurfactant with remarkable surface/interfacial activity.Surfactin production suffers from high costs of carbon sources and severe foaming problem during fermentation.Unreasonable utilizat...[Background]Surfactin is a biosurfactant with remarkable surface/interfacial activity.Surfactin production suffers from high costs of carbon sources and severe foaming problem during fermentation.Unreasonable utilization of soybean residue(okara)can cause resource waste and environmental pollution.[Objective]To achieve sustainable production of surfactin and valueadded conversion of okara,we explored foam-free production of surfactin by Bacillus subtilis using okara as a low-cost substrate and evaluated its application prospects.[Methods]We evaluated and compared the feasibility of B.subtilis utilizing okara to synthesize surfactin through liquid and solid-state fermentation methods.Biosurfactants were extracted from solid-state culture via a weak alkaline water extraction method.The products were identified by HPLC-MS,and the physicochemical properties of the produced surfactin were analyzed.The solid-state medium for fermentation of okara was optimized by the response surface method.The viable count of B.subtilis in solid-state fermentation residue was determined by the plate colony counting method.[Results]The conversion rates of okara to surfactin were 0.6%−0.8%and 1.2%−1.5%in liquid and solid-state fermentation,respectively.Interestingly,solid-state fermentation of okara by B.subtilis achieved both high-yield and foam-free production of surfactin.Five surfactin homologues were produced from okara,mainly including surfactin-C13(34.16%),surfactin-C_(14)(23.95%),and surfactin-C_(15)(35.14%).The produced surfactin,with a critical micelle concentration of 35.0 mg/L,decreased water surface tension to(26.0±0.1)mN/m and emulsified crude oil with emulsifying activity index(EI24)(73.1±3.2)%.It was stable at 4−121℃,pH 5.0−11.0,and NaCl<150 g/L.Okara,NH_(4)Cl,and CaCl_(2)·2H_(2)O were significant components in the solid-state medium.The surfactin yield was increased by 52.1%through solid-state medium optimization.Adding wheat straw further enhanced surfactin production by improving aeration in the solid-state medium.B.subtilis AnPL-1 produced(263.2±7.8)mg surfactin in the optimized solid-state medium containing 14.8 g okara and 1.5 g wheat straw.The conversion rate of okara to surfactin was enhanced to 1.8%.In addition,the residue of solid-state fermentation was expected to be microbial fertilizer since it contained 4.27×10^(10)CFU/g of B.subtilis.[Conclusion]This study established a promising way for foam-free production of surfactin and value-added conversion of okara.展开更多
In this study,FeCr_(x)MnAlCu(x=0,0.5,1.0,1.5,2.0)high-entropy alloys were fabricated using vacuum arc melting,and the corrosion behavior of these alloys in 3.5wt%NaCl solution at room temperature was investigated by e...In this study,FeCr_(x)MnAlCu(x=0,0.5,1.0,1.5,2.0)high-entropy alloys were fabricated using vacuum arc melting,and the corrosion behavior of these alloys in 3.5wt%NaCl solution at room temperature was investigated by electrochemical dynamic potential polarization curves and immersion experiments.The microstructure results show that the high-entropy alloy with x=0 has a body-centered cubic phase structure,whereas the high-entropy alloys with x=0.5–2.0 have a mixed face-centered cubic+body-centered cubic dual-phase structure.The corrosion results show that the corrosion resistance of the high-entropy alloy is increased with the increase in Cr content.Among them,the high-entropy alloy with x=2.0 exhibits the optimal corrosion resistance:the highest self-corrosion potential(E_(corr)=−0.354 V vs.Ag/AgCl),the smallest self-corrosion current density(I_(corr)=1.991×10^(−6)A·cm^(−2)),and the smallest corrosion rate(0.0292 mm/a).The composite passivation film of oxides and hydroxides is formed on the surface of the corroded high-entropy alloys,and the Cr_(2)O_(3)content is increased with the increase in Cr content,which effectively improves the stability and protective properties of the passivation film.展开更多
Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic condu...Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic conductivity,which is particularly severe on a micro scale and in solid-state systems,leading to increased polarization and inferior electrochemical performance.Doping can broaden the transmission pathways and reduce the diffusion energy barrier for electrons and lithium ions.However,achieving effective,uniform doping in mSi is challenging due to its longer diffusion paths and higher energy barriers.Therefore,current doping research is primarily limited to nanosilicon.In this study,we successfully used a Joule-heating activated staged thermal treatment to achieve full-depth doping of germanium(Ge)in the mSi substrate.The Joule-heating process activated the mSi substrate,resulting in abundant vacancy defects that reduced the diffusion barrier of Ge into the silicon lattice and facilitated full-depth Ge doping.Surprisingly,the resulting Si-Ge anode exhibited significantly enhanced electrical conductivity(70 times).Meanwhile,the improved Li-ion conductivity in mSi and the reduced Young’s modulus enhance the electrode reaction kinetics and integrity after cycling.Ge-doped silicon anodes demonstrate excellent electrochemical performance when applied in sulfide solid-state half-cells and full-cells.This work provides substantial insights into the rational structural design of mSi alloyed anode materials,paving the way for the development of high-performance solid-state Li-ion batteries.展开更多
The application of polymer electrolytes is expected to revitalize solidstate lithium metal batteries(SSLMBs)with high energy density and enhanced safety.However,practical deployment faces challenges from inadequate me...The application of polymer electrolytes is expected to revitalize solidstate lithium metal batteries(SSLMBs)with high energy density and enhanced safety.However,practical deployment faces challenges from inadequate mechanical properties of electrolyte and unstable interfaces in high-voltage SSLMB s.Herein,we design an asymmetric composite solid-state electrolyte(ACSE)composed of a cellulose framework in situ self-assembled with zeolitic imidazolate framework nanosheets(CP@MOF)embedded in a polymer matrix.The CP@MOF network provides the electrolyte with an elastic modulus of 1.19 GPa,effectively resisting Li dendrite penetration.Furthermore,theoretical calculations guided the compositional design of ACSE to address asynchronous interfacial requirements at cathode/electrolyte and anode/electrolyte interfaces,facilitating stable interphase formation and thus ensuring prolonged cycling of SSLMBs.Consequently,Li symmetric cells achieve extended cycling stability(>5000 h)with minimal polarization.The NCM811|Li full cell maintains 84.9%capacity retention after 350 cycles.Notably,assembled NCM811 pouch cells deliver practical energy densities of 337.9 Wh kg^(-1)and 711.7 Wh L^(-1),demonstrating exceptional application potential.This work provides novel insights into the application of ACSEs for high-energy-density SSLMBs.展开更多
In this study,a straightforward one-step hydrothermal method was successfully utilized to synthesize the solid solution Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)(NNMTO-x),where x denotes the molar perce...In this study,a straightforward one-step hydrothermal method was successfully utilized to synthesize the solid solution Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)(NNMTO-x),where x denotes the molar percentage of Na_(2)Ni_(2)Ti_(6)O_(16)(NNTO)within Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)(NMTO),with x values of 10,20,30,40,and 50.Both XPS(X-ray Photoelectron Spectroscopy)and EDX(Energy Dispersive X-ray Spectroscopy)analyses unequivocally validated the formation of the NNMTO-x solid solutions.It was observed that when x is below 40,the NNMTO-x solid solution retains the structural characteristics of the original NMTO.However,beyond this threshold,significant alterations in crystal morphology were noted,accompanied by a noticeable decline in photocatalytic activity.Notably,the absorption edge of NNMTO-x(x<40)exhibited a shift towards the visible-light spectrum,thereby substantially broadening the absorption range.The findings highlight that NNMTO-30 possesses the most pronounced photocatalytic activity for the reduction of CO_(2).Specifically,after a 6 h irradiation period,the production rates of CO and CH_(4)were recorded at 42.38 and 1.47μmol/g,respectively.This investigation provides pivotal insights that are instrumental in the advancement of highly efficient and stable photocatalysts tailored for CO_(2)reduction processes.展开更多
To investigate the effect of solution treatment and aging process parameters on the microstructure and mechanical properties of TB18 titanium alloy,process optimization research was conducted based on the mixed-level ...To investigate the effect of solution treatment and aging process parameters on the microstructure and mechanical properties of TB18 titanium alloy,process optimization research was conducted based on the mixed-level orthogonal experiment design of factor levels.Results show that through range analysis,the significance order of process parameters is determined as follows:solution cooling method>solution temperature>aging time>aging temperature>solution time.Considering the strength-ductility matching and engineering application requirements,the benchmark parameters are selected as solution time of 1 h,solution cooling method of air cooling(AC),aging temperature of 525℃,and aging time of 4 h.Furthermore,the effects of solution temperature in the range of 790–870℃ on the impact toughness and micro-fracture characteristics of the alloy were studied.The results reveal that the larger the area of shear lip and fibrous zone,and the smaller the area of radiation zone,the better the toughness of the alloy.With the increase in solution temperature,the length of secondary cracks on the fracture surface increases,the number of dimples increases,and the toughness is enhanced.Based on the collaborative optimization of strength and toughness,the optimal heat treatment process for TB18 alloy is determined as 870℃/1 h,AC+525℃/4 h,AC.展开更多
In this paper,we consider a Schr¨odinger-Poisson system with sublinear nonlinearity.The growth of nonlinearity depends on potential function and a bounded function.We first obtain the existence of nontrivial solu...In this paper,we consider a Schr¨odinger-Poisson system with sublinear nonlinearity.The growth of nonlinearity depends on potential function and a bounded function.We first obtain the existence of nontrivial solution sequence with negative energy for the system via a variant Clark’s theorem.Then we get the asymptotical property of the solution sequence by L∞norm.展开更多
This study investigates the dimensionless quasi-geostrophic potential vorticity(QG-PV)equation with external sources.Employing the Gardner-Morikawa transformation and weakly nonlinear perturbation expansion,we derive ...This study investigates the dimensionless quasi-geostrophic potential vorticity(QG-PV)equation with external sources.Employing the Gardner-Morikawa transformation and weakly nonlinear perturbation expansion,we derive the nonlinear Boussinesq equation with external sources.We demonstrate the existence of explicit zero-order and first-order Wronskian solutions for the model equation whenα_4=0.Furthermore,using a modified Jacobi elliptic function method,we obtain soliton-like solutions for bothα_4=0 andα_4≠0.Analysis of these solutions reveals that the generalizedβ-plane approximation and shear flow are significant factors in inducing nonlinear Rossby waves,and that external sources play a crucial role in influencing Rossby wave behavior.展开更多
2D MXenes,particularly Ti_(3)C_(2)T_(x),have emerged as promising multifu nctional materials for advancing solidstate batteries(SSBs).While SSBs offer superior safety and energy density over liquid-electrolyte systems...2D MXenes,particularly Ti_(3)C_(2)T_(x),have emerged as promising multifu nctional materials for advancing solidstate batteries(SSBs).While SSBs offer superior safety and energy density over liquid-electrolyte systems,critical challenges such as interfacial resistance,limited ion transport,dendrite growth,and mechanical degradation hinder their widespread adoption.This review aims to provide a comprehensive analysis of the roles and fu nctions of Ti_(3)C_(2)T_(x) MXenes in SSBs,emphasizing their application as interlayers,anode/cathode additives,and current collectors,and highlighting their impact on interracial stability,ionic/electro nic transport,electrochemical performance,and cycling durability in SSB architectures.Unlike other 2D materials,Ti_(3)C_(2)T_(x) exhibits outsta nding metallic conductivity,tu nable surface terminations,hydrophilicity,and excellent mechanical flexibility,making it ideal for multifu nctional integration in SSBs,As a component in solid-state electrolytes(SSEs),Ti_(3)C_(2)T_(x) improves ionic conductivity and mecha nical strength.When used in electrodes,it serves as a conductive scaffold that enhances charge transport and structural durability.Additionally,its role as an interfacial interlayer effectively reduces interfacial impedance,accommodates volume changes,and suppresses dendrite formation.Its lightweight and high conductivity enable its use as a current collector.This review highlights recent advances in Ti_(3)C_(2)T_(x)-based components for SSBs like Li-,Na-,Zn,Li-S,etc.,emphasizing enha ncements in ion/electron transport,interfacial stability,and structural robustness.Finally,the review outlines challenges and opportunities along with a future outlook focused on improving the MXene oxidation,tailoring surface terminations,improving long-term stability,and exploring scalable fabrication strategies for MXene-based SSB components.展开更多
Solid-state sodium batteries(SSSBs)have been highly prized as a promising alternative to conventional battery systems using organic liquid electrolytes due to their improved safety,higher energy density,and substantia...Solid-state sodium batteries(SSSBs)have been highly prized as a promising alternative to conventional battery systems using organic liquid electrolytes due to their improved safety,higher energy density,and substantial resources and low cost of sodium.Na_(3)Zr_(2)Si_(2)PO_(12)(NZSP)solid electrolyte is attracting considerable interest owing to its excellent thermal and chemical stability and favorable compatibility with Na metal anode and high-voltage cathode.However,two main challenges of poor roomtemperature ionic conductivity and high interfacial resistance limit the application of NZSP electrolyte in SSSBs.So far,intensive efforts have been devoted to developing modification strategies to improve the room-temperature ionic conductivity of NZSP.This review aims to provide a comprehensive summary and discussion of some optimization strategies for enhancing the room-temperature ionic conductivity of the NZSP solid electrolyte.These optimization strategies are categorized into foreignion doping or substitution,sintering behavior modulation,and regulation of chemical composition based on precursors,and their optimization mechanisms are also elaborated.Finally,the prospects of NZSP-based solid electrolytes are presented.This review is expected to offer better guidance for designing and developing high-performance NZSP-based solid electrolytes for accelerating the practical application of SSSBs.展开更多
Sulfide solid electrolytes are considered promising candidates for all-solid-state lithium batteries(ASSLBs)because of their high ionic conductivity and favorable mechanical properties.However,the uncontrolled growth ...Sulfide solid electrolytes are considered promising candidates for all-solid-state lithium batteries(ASSLBs)because of their high ionic conductivity and favorable mechanical properties.However,the uncontrolled growth of lithium dendrites at the lithium metal-electrolytes interface remains a major obstacle to their practical application.In this work,we introduced a scalable three-dimensional(3D)Li-B skeleton structure designed to suppress dendrite formation.The alloy anode demonstrates a lower Young's modulus,which helps alleviate the accumulation of localized stresses at the interface.Additionally,the 3D alloy anode provided a uniform potential distribution,which promoted homogeneous lithium deposition.Benefiting from these structural advantages,symmetric cells with the Li-B alloy achieved a high critical current density of 2.8 mA cm^(-2).Notably,Li-B‖LPSCI‖LVO-NCM ASSLBs exhibited long-term cycling stability,retaining 97.8%of their capacity after 1500 cycles at 2 C.Furthermore,ASSLBs incorporating the Li-B alloy showed cycling stability comparable with Li-In-based cells,while delivering a higher energy density.Overall,this work presents a practical strategy that may accelerate the commercialization of sulfide-based ASSLBs.展开更多
Polyethylene oxide(PEO)-based solid polymer electrolytes(SPEs)have long faced limitations due to low ionic conductivity at ambient temperature and poor interfacial stability with lithium metal anodes.Here,we present a...Polyethylene oxide(PEO)-based solid polymer electrolytes(SPEs)have long faced limitations due to low ionic conductivity at ambient temperature and poor interfacial stability with lithium metal anodes.Here,we present a structural engineering strategy to address these challenges through shear-induced crystallization of concentrated PEO-LiTFSI solutions,which self-assemble into flower-like spherulites with radially aligned lamellar crystals.This unique structure creates continuous Li^(+)transport highways through densely packed crystalline domains,achieving a record-high ionic conductivity of 1.70×10^(-4) S/cm at 25℃ for pristine PEO-based systems.Strategic incorporation of lithium montmorillonite(MMTli,10 wt%)further optimizes the composite electrolyte,balancing high ionic conductivity(1.47×10^(-4) S/cm)with enhanced electrochemical stability(4.99 V vs.Li^(+)/Li),elevated Li^(+)transference number(0.62),and mechanical robustness.The composite electrolyte enables stable Li plating/stripping over 800 h in symmetric Li||Li cells and powers LiFePO_(4)||Li solid-state batteries with 82%capacity retention after 200 cycles at 0.2 C under ambient conditions.This work pioneers a scalable processing paradigm for crystalline polymer electrolytes,offering new insights into ion transport mechanisms and validating clay minerals as multifunctional additives for next-generation energy storage systems.展开更多
All-solid-state batteries(ASSBs)represent a next-generation energy storage technology,offering enhanced safety,higher energy density,and improved cycling stability compared to conventional liquid-electrolyte-based lit...All-solid-state batteries(ASSBs)represent a next-generation energy storage technology,offering enhanced safety,higher energy density,and improved cycling stability compared to conventional liquid-electrolyte-based lithium-ion batteries.Understanding and optimizing the complex chemistries and interfaces that underpin ASSB performance present significant challenges from both experimental and modeling perspectives.In particular,atomistic simulations face difficulties in capturing the complex structure,disorder,and dynamic evolution of materials and interfaces under practically relevant conditions.While established methods such as density functional theory and classical force fields have provided valuable insights,some questions remain difficult to address,particularly those involving large system sizes or long timescales.Recently,machine learning interatomic potentials(MLIPs)have emerged as a transformative tool,enabling atomistic simulations at length and time scales that were previously challenging to access with conventional approaches.By delivering near first-principles accuracy with much greater efficiency,MLIPs open new avenues for large-scale,long-timescale,and high-throughput simulations of solid-state battery materials.In this review,we present a comparative overview of density functional theory,classical force fields,and MLIPs,highlighting their respective strengths and limitations in ASSB research.We then discuss how MLIPs enable simulations that reach longer timescales,larger system sizes,and support high-throughput calculations,providing unique insights into ion transport and interfacial evolution in ASSBs.Finally,we conclude with a summary and outlook on current challenges and future opportunities for expanding MLIP capabilities and accelerating their impact in solid-state battery research.展开更多
In the realm of large-scale power system energy storage,sodium-based batteries represent a cost-effective post-lithium energy storage technology,making inorganic solid-state sodium batteries(ISSSB)a critical branch of...In the realm of large-scale power system energy storage,sodium-based batteries represent a cost-effective post-lithium energy storage technology,making inorganic solid-state sodium batteries(ISSSB)a critical branch of this development.Inorganic solid-state electrolytes(ISSEs)are the core components of sodium batteries;however,they face significant challenges such as insufficient ionic conductivity,interfacial instability,and dendrite growth,all of which severely hinder practical application.This review critically assesses experimental protocols and theoretical frameworks related to mainstream ISSEs and systematizes optimization strategies aimed at overcoming these challenges.Leveraging integrated insights from both experimental and computational studies,the review first categorizes and summarizes the primary types of ISSEs,namely oxide-,sulfide-,and halide-based electrolytes.It then details interfacial optimization strategies focused on addressing three core interfacial issues:ion transport barriers resulting from mechanical incompatibility,side reactions stemming from electrochemical mismatch,and dendrite formation.Finally,the review advocates prioritizing in-depth research that integrates experimental and theoretical approaches to establish a closed-loop methodology encompassing predictive design,multiscale investigation,mechanistic exploration,and high-throughput automated experimentation,with feedback-driven refinement.This work serves as a comprehensive reference and systematic roadmap for future research on solid-state electrolytes(SSEs).展开更多
Thermoplastic polyurethane(TPU)consists of a hardsegment and a soft segment,where the former affords mechanical strength and thermalstability,while the latter provides a possibility of good ionic conductivity by promo...Thermoplastic polyurethane(TPU)consists of a hardsegment and a soft segment,where the former affords mechanical strength and thermalstability,while the latter provides a possibility of good ionic conductivity by promoting dissociation of ions from the lithium salt.Thus,TPU attracts a wide interest recently as a promising polymer electrolyte for solid-state lithium batteries.However,the relatively low ionic conductivity of TPU still restricts its actual applications due to the aggregation of polymer chains,which greatly reduces the dissociation of lithium salts.Herein,a strategy to address this challenge was adopted by in situ polymerization poly(ethylene glycol diacrylate)(PEGDA)in fully dispersed TPU.Hence a stretchable solid-state electrolyte(denoted as TELL and the contrast sample was denoted as TLL)with high ionic conductivity of 7.18×10^(-4) S/cm was obtained at room temperature.The Li^(+)transference number is 0.85 in Li|TELL|Li cell and can stably undergo charge-discharge cycles for 1400 h at a current density of 0.1 mA/cm^(2),while the contrast sample is short-circuited after 634 h of cycling.The LiFePO_(4)|TELL|Li cell achieves a capacity retention of 78.93%after 200 cycles at 2 C.The LiFePO_(4)|TLL| Li cellonly gains the capacity retention of 51.9%after 50 cyclesat the same current density.So,the method adopted here may provide a new approach to realize a flexible solid-state electrolyte with high ion-conductivity.展开更多
Let A be a 3×3 singular or diagonalizable matrix,all solutions to the Yang-Baxter-like matrix equation have been determined.However,finding all solutions for full rank,non-diagonalizable matrices remains challeng...Let A be a 3×3 singular or diagonalizable matrix,all solutions to the Yang-Baxter-like matrix equation have been determined.However,finding all solutions for full rank,non-diagonalizable matrices remains challenging.By utilizing classification techniques,we establish all solutions of the Yang-Baxter-like matrix equation in this paper when the coefficient matrix A is similar to non-diagonalizable matrix diag(λ,J_(2)(λ))withλ̸=0.More specifically,we divide the non-diagonal elements of the solution into 10 different cases.By discussing each situation,we establish all solutions of the Yang-Baxter-like matrix equation.The results of this work enrich the existing ones.展开更多
Li_(7)La_(3)Zr_(2)O_(12)-based electrolytes have got great promise for solid-state lithium(Li)metal batteries because of their high elastic modulus and wide electrochemical stability window.However,the insufficient co...Li_(7)La_(3)Zr_(2)O_(12)-based electrolytes have got great promise for solid-state lithium(Li)metal batteries because of their high elastic modulus and wide electrochemical stability window.However,the insufficient contact and heterogeneous Li deposition severely hinder their practical applications.Here,a flexible ternary polymethacrylate(PMA)matrix is designed to incorporate with Ta-doped Li_(7)La_(3)Zr_(2)O_(12)(LLZTO-PMA).The PMA matrix ensures excellent interfacial contact,while the synergistic effects of its polar carbonyl groups and its interaction with LLZTO creating fast interfacial Li^(+)pathways yield a high ionic conductivity of 0.266 mS cm^(-1)at 20℃.Moreover,the interaction between LLZTO and PMA matrix further guides the formation of a hybrid LiF/Li_(3)N-rich solid electrolyte interphase,which allows a fast Li^(+)interfacial kinetic due to its lowered Li^(+)diffusion barrier.Consequently,the LLZTO-PMA electrolyte contributes an ultra-stable Li anode interphase,attaining a lifespan exceeding 10,000 h in symmetric cells and retaining over 96%capacity after 600 cycles in full battery,demonstrating a breakthrough for high-performance solid-state batteries.展开更多
ZnO thin-film transistors(TFTs)with channel layers fabricated by spin-coating are demonstrated.A nano ZnO colloidal aqueous solution with zinc nitrate dissolved in it was first deposited on the ATO/ITO/glass substrate...ZnO thin-film transistors(TFTs)with channel layers fabricated by spin-coating are demonstrated.A nano ZnO colloidal aqueous solution with zinc nitrate dissolved in it was first deposited on the ATO/ITO/glass substrate by spin-coating process.The thin-film transistor with well-controlled and densely packed ZnO crystalline layer was obtained by thermal annealing the system of colloidal solution film coated ATO/ITO/glass substrate.By optimizing the fabrication conditions,the fabricated thin-film transistors exhibited superior field-effect properties,which were stable,highly transparent,n-channel and enhancement-mode with a channel mobility as large as 3.02 cm^(2)·V^(-1).s^(-1).Our method of fabricating ZnO thin-film transistors was simple,high efficiency,and feasible for the batch production with low cost.展开更多
This paper is concerned with an initial boundary value problem for the planar magnetohydrodynamic compressible flow with temperature dependent heat conductivity in a half-line.In particular,the transverse magnetic fie...This paper is concerned with an initial boundary value problem for the planar magnetohydrodynamic compressible flow with temperature dependent heat conductivity in a half-line.In particular,the transverse magnetic field is assumed to satisfy the Neumann boundary condition,which was first investigated by Kazhikhov in 1987.We establish the global existence of the unique strong solutions to the MHD equations without any smallness conditions on the initial data.More precisely,our result can be regarded as a natural generalization of Kazhikov’s result for applying the constant heat-conductivity in bounded domains to the degenerate case in unbounded domains.展开更多
基金supported by the Research Start-up Foundation for Introduced Talent of Qufu Normal University(609601)。
文摘[Background]Surfactin is a biosurfactant with remarkable surface/interfacial activity.Surfactin production suffers from high costs of carbon sources and severe foaming problem during fermentation.Unreasonable utilization of soybean residue(okara)can cause resource waste and environmental pollution.[Objective]To achieve sustainable production of surfactin and valueadded conversion of okara,we explored foam-free production of surfactin by Bacillus subtilis using okara as a low-cost substrate and evaluated its application prospects.[Methods]We evaluated and compared the feasibility of B.subtilis utilizing okara to synthesize surfactin through liquid and solid-state fermentation methods.Biosurfactants were extracted from solid-state culture via a weak alkaline water extraction method.The products were identified by HPLC-MS,and the physicochemical properties of the produced surfactin were analyzed.The solid-state medium for fermentation of okara was optimized by the response surface method.The viable count of B.subtilis in solid-state fermentation residue was determined by the plate colony counting method.[Results]The conversion rates of okara to surfactin were 0.6%−0.8%and 1.2%−1.5%in liquid and solid-state fermentation,respectively.Interestingly,solid-state fermentation of okara by B.subtilis achieved both high-yield and foam-free production of surfactin.Five surfactin homologues were produced from okara,mainly including surfactin-C13(34.16%),surfactin-C_(14)(23.95%),and surfactin-C_(15)(35.14%).The produced surfactin,with a critical micelle concentration of 35.0 mg/L,decreased water surface tension to(26.0±0.1)mN/m and emulsified crude oil with emulsifying activity index(EI24)(73.1±3.2)%.It was stable at 4−121℃,pH 5.0−11.0,and NaCl<150 g/L.Okara,NH_(4)Cl,and CaCl_(2)·2H_(2)O were significant components in the solid-state medium.The surfactin yield was increased by 52.1%through solid-state medium optimization.Adding wheat straw further enhanced surfactin production by improving aeration in the solid-state medium.B.subtilis AnPL-1 produced(263.2±7.8)mg surfactin in the optimized solid-state medium containing 14.8 g okara and 1.5 g wheat straw.The conversion rate of okara to surfactin was enhanced to 1.8%.In addition,the residue of solid-state fermentation was expected to be microbial fertilizer since it contained 4.27×10^(10)CFU/g of B.subtilis.[Conclusion]This study established a promising way for foam-free production of surfactin and value-added conversion of okara.
基金Gansu Provincial Science and Technology Major Special Program(24ZDWA008)Fourth Batch of Top Leading Talents Fund Projects in Gansu Province(ZZ2023G50100013)。
文摘In this study,FeCr_(x)MnAlCu(x=0,0.5,1.0,1.5,2.0)high-entropy alloys were fabricated using vacuum arc melting,and the corrosion behavior of these alloys in 3.5wt%NaCl solution at room temperature was investigated by electrochemical dynamic potential polarization curves and immersion experiments.The microstructure results show that the high-entropy alloy with x=0 has a body-centered cubic phase structure,whereas the high-entropy alloys with x=0.5–2.0 have a mixed face-centered cubic+body-centered cubic dual-phase structure.The corrosion results show that the corrosion resistance of the high-entropy alloy is increased with the increase in Cr content.Among them,the high-entropy alloy with x=2.0 exhibits the optimal corrosion resistance:the highest self-corrosion potential(E_(corr)=−0.354 V vs.Ag/AgCl),the smallest self-corrosion current density(I_(corr)=1.991×10^(−6)A·cm^(−2)),and the smallest corrosion rate(0.0292 mm/a).The composite passivation film of oxides and hydroxides is formed on the surface of the corroded high-entropy alloys,and the Cr_(2)O_(3)content is increased with the increase in Cr content,which effectively improves the stability and protective properties of the passivation film.
基金financially supported by the National Key Research and Development Program(2022YFE0127400)the National Natural Science Foundation of China(52172040,52202041,and U23B2077)+1 种基金Taishan Scholar Project of Shandong Province(tsqn202211086,ts202208832,tsqnz20221118)the Fundamental Research Funds for the Central Universities(23CX06055A).
文摘Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic conductivity,which is particularly severe on a micro scale and in solid-state systems,leading to increased polarization and inferior electrochemical performance.Doping can broaden the transmission pathways and reduce the diffusion energy barrier for electrons and lithium ions.However,achieving effective,uniform doping in mSi is challenging due to its longer diffusion paths and higher energy barriers.Therefore,current doping research is primarily limited to nanosilicon.In this study,we successfully used a Joule-heating activated staged thermal treatment to achieve full-depth doping of germanium(Ge)in the mSi substrate.The Joule-heating process activated the mSi substrate,resulting in abundant vacancy defects that reduced the diffusion barrier of Ge into the silicon lattice and facilitated full-depth Ge doping.Surprisingly,the resulting Si-Ge anode exhibited significantly enhanced electrical conductivity(70 times).Meanwhile,the improved Li-ion conductivity in mSi and the reduced Young’s modulus enhance the electrode reaction kinetics and integrity after cycling.Ge-doped silicon anodes demonstrate excellent electrochemical performance when applied in sulfide solid-state half-cells and full-cells.This work provides substantial insights into the rational structural design of mSi alloyed anode materials,paving the way for the development of high-performance solid-state Li-ion batteries.
基金the financial support from the National Natural Science Foundation of China(52072307,22408198)the Fundamental Research Funds for the Central Universities(XJJSKYQD202533)。
文摘The application of polymer electrolytes is expected to revitalize solidstate lithium metal batteries(SSLMBs)with high energy density and enhanced safety.However,practical deployment faces challenges from inadequate mechanical properties of electrolyte and unstable interfaces in high-voltage SSLMB s.Herein,we design an asymmetric composite solid-state electrolyte(ACSE)composed of a cellulose framework in situ self-assembled with zeolitic imidazolate framework nanosheets(CP@MOF)embedded in a polymer matrix.The CP@MOF network provides the electrolyte with an elastic modulus of 1.19 GPa,effectively resisting Li dendrite penetration.Furthermore,theoretical calculations guided the compositional design of ACSE to address asynchronous interfacial requirements at cathode/electrolyte and anode/electrolyte interfaces,facilitating stable interphase formation and thus ensuring prolonged cycling of SSLMBs.Consequently,Li symmetric cells achieve extended cycling stability(>5000 h)with minimal polarization.The NCM811|Li full cell maintains 84.9%capacity retention after 350 cycles.Notably,assembled NCM811 pouch cells deliver practical energy densities of 337.9 Wh kg^(-1)and 711.7 Wh L^(-1),demonstrating exceptional application potential.This work provides novel insights into the application of ACSEs for high-energy-density SSLMBs.
基金Supported by the Doctoral Research Start-up Project of Yuncheng University(YQ-2023067)Project of Shanxi Natural Science Foundation(202303021211189)+1 种基金Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Provinces(20220036)Shanxi ProvinceIntelligent Optoelectronic Sensing Application Technology Innovation Center and Shanxi Province Optoelectronic Information Science and TechnologyLaboratory,Yuncheng University.
文摘In this study,a straightforward one-step hydrothermal method was successfully utilized to synthesize the solid solution Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)(NNMTO-x),where x denotes the molar percentage of Na_(2)Ni_(2)Ti_(6)O_(16)(NNTO)within Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)(NMTO),with x values of 10,20,30,40,and 50.Both XPS(X-ray Photoelectron Spectroscopy)and EDX(Energy Dispersive X-ray Spectroscopy)analyses unequivocally validated the formation of the NNMTO-x solid solutions.It was observed that when x is below 40,the NNMTO-x solid solution retains the structural characteristics of the original NMTO.However,beyond this threshold,significant alterations in crystal morphology were noted,accompanied by a noticeable decline in photocatalytic activity.Notably,the absorption edge of NNMTO-x(x<40)exhibited a shift towards the visible-light spectrum,thereby substantially broadening the absorption range.The findings highlight that NNMTO-30 possesses the most pronounced photocatalytic activity for the reduction of CO_(2).Specifically,after a 6 h irradiation period,the production rates of CO and CH_(4)were recorded at 42.38 and 1.47μmol/g,respectively.This investigation provides pivotal insights that are instrumental in the advancement of highly efficient and stable photocatalysts tailored for CO_(2)reduction processes.
基金Key Program of National Natural Science Foundation of China(52431001)。
文摘To investigate the effect of solution treatment and aging process parameters on the microstructure and mechanical properties of TB18 titanium alloy,process optimization research was conducted based on the mixed-level orthogonal experiment design of factor levels.Results show that through range analysis,the significance order of process parameters is determined as follows:solution cooling method>solution temperature>aging time>aging temperature>solution time.Considering the strength-ductility matching and engineering application requirements,the benchmark parameters are selected as solution time of 1 h,solution cooling method of air cooling(AC),aging temperature of 525℃,and aging time of 4 h.Furthermore,the effects of solution temperature in the range of 790–870℃ on the impact toughness and micro-fracture characteristics of the alloy were studied.The results reveal that the larger the area of shear lip and fibrous zone,and the smaller the area of radiation zone,the better the toughness of the alloy.With the increase in solution temperature,the length of secondary cracks on the fracture surface increases,the number of dimples increases,and the toughness is enhanced.Based on the collaborative optimization of strength and toughness,the optimal heat treatment process for TB18 alloy is determined as 870℃/1 h,AC+525℃/4 h,AC.
基金Supported by the National Natural Science Foundation of China(12226412)Natural Science Foundation of Jiangsu Province(BK20221339)。
文摘In this paper,we consider a Schr¨odinger-Poisson system with sublinear nonlinearity.The growth of nonlinearity depends on potential function and a bounded function.We first obtain the existence of nontrivial solution sequence with negative energy for the system via a variant Clark’s theorem.Then we get the asymptotical property of the solution sequence by L∞norm.
基金supported by the National Natural Science Foundation of China(Grant No.12362027)the Scientific Research Ability of Youth Teachers of Inner Mongolia Agricultural University(Grant No.BR230110)+3 种基金Inner Mongolia National Science Fund for Excellent Young Scholars(Grant No.2025YQ033)Foundation for Basic Science Research Initiation at Inner Mongolia Agricultural University(Grant No.JC2021001)The Natural Science Foundation of Inner Mongolia Autonomous Region(2025MS01020)Supported by the Basic and Applied Basic Research Science and Technology Program Projects of Hohhot(2025-rule-basic-60)。
文摘This study investigates the dimensionless quasi-geostrophic potential vorticity(QG-PV)equation with external sources.Employing the Gardner-Morikawa transformation and weakly nonlinear perturbation expansion,we derive the nonlinear Boussinesq equation with external sources.We demonstrate the existence of explicit zero-order and first-order Wronskian solutions for the model equation whenα_4=0.Furthermore,using a modified Jacobi elliptic function method,we obtain soliton-like solutions for bothα_4=0 andα_4≠0.Analysis of these solutions reveals that the generalizedβ-plane approximation and shear flow are significant factors in inducing nonlinear Rossby waves,and that external sources play a crucial role in influencing Rossby wave behavior.
基金supported by a National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(NRF-2020R1A6A1A03043435 and 2020R1A2C1099862)supported by the Korea Institute for Advancement of Technology(KIAT)grant funded by the Korean Government(MOTIE)(P0012451,The Competency Development Program for Industry Specialist)。
文摘2D MXenes,particularly Ti_(3)C_(2)T_(x),have emerged as promising multifu nctional materials for advancing solidstate batteries(SSBs).While SSBs offer superior safety and energy density over liquid-electrolyte systems,critical challenges such as interfacial resistance,limited ion transport,dendrite growth,and mechanical degradation hinder their widespread adoption.This review aims to provide a comprehensive analysis of the roles and fu nctions of Ti_(3)C_(2)T_(x) MXenes in SSBs,emphasizing their application as interlayers,anode/cathode additives,and current collectors,and highlighting their impact on interracial stability,ionic/electro nic transport,electrochemical performance,and cycling durability in SSB architectures.Unlike other 2D materials,Ti_(3)C_(2)T_(x) exhibits outsta nding metallic conductivity,tu nable surface terminations,hydrophilicity,and excellent mechanical flexibility,making it ideal for multifu nctional integration in SSBs,As a component in solid-state electrolytes(SSEs),Ti_(3)C_(2)T_(x) improves ionic conductivity and mecha nical strength.When used in electrodes,it serves as a conductive scaffold that enhances charge transport and structural durability.Additionally,its role as an interfacial interlayer effectively reduces interfacial impedance,accommodates volume changes,and suppresses dendrite formation.Its lightweight and high conductivity enable its use as a current collector.This review highlights recent advances in Ti_(3)C_(2)T_(x)-based components for SSBs like Li-,Na-,Zn,Li-S,etc.,emphasizing enha ncements in ion/electron transport,interfacial stability,and structural robustness.Finally,the review outlines challenges and opportunities along with a future outlook focused on improving the MXene oxidation,tailoring surface terminations,improving long-term stability,and exploring scalable fabrication strategies for MXene-based SSB components.
基金National Natural Science Foundation of China,Grant/Award Number:52272225。
文摘Solid-state sodium batteries(SSSBs)have been highly prized as a promising alternative to conventional battery systems using organic liquid electrolytes due to their improved safety,higher energy density,and substantial resources and low cost of sodium.Na_(3)Zr_(2)Si_(2)PO_(12)(NZSP)solid electrolyte is attracting considerable interest owing to its excellent thermal and chemical stability and favorable compatibility with Na metal anode and high-voltage cathode.However,two main challenges of poor roomtemperature ionic conductivity and high interfacial resistance limit the application of NZSP electrolyte in SSSBs.So far,intensive efforts have been devoted to developing modification strategies to improve the room-temperature ionic conductivity of NZSP.This review aims to provide a comprehensive summary and discussion of some optimization strategies for enhancing the room-temperature ionic conductivity of the NZSP solid electrolyte.These optimization strategies are categorized into foreignion doping or substitution,sintering behavior modulation,and regulation of chemical composition based on precursors,and their optimization mechanisms are also elaborated.Finally,the prospects of NZSP-based solid electrolytes are presented.This review is expected to offer better guidance for designing and developing high-performance NZSP-based solid electrolytes for accelerating the practical application of SSSBs.
基金supported by the National Natural Science Foundation of China(Grant Nos.52002094)the Guangdong Basic and Applied Basic Research Foundation(Grant Nos.2025A1515011995)+3 种基金the Shenzhen Science and Technology Innovation Program(GXWD20221030205923001)the Shandong Provincial Natural Science Foundation of China(Grant Nos.ZR2024QE525)the Shenzhen Key Laboratory of New Materials Technology(Grant Nos.SYSPG20241211173609003)the State Key Laboratory of Precision Welding&Joining of Materials and Structures(Grant Nos.2024-Z-17,2024-T-08)。
文摘Sulfide solid electrolytes are considered promising candidates for all-solid-state lithium batteries(ASSLBs)because of their high ionic conductivity and favorable mechanical properties.However,the uncontrolled growth of lithium dendrites at the lithium metal-electrolytes interface remains a major obstacle to their practical application.In this work,we introduced a scalable three-dimensional(3D)Li-B skeleton structure designed to suppress dendrite formation.The alloy anode demonstrates a lower Young's modulus,which helps alleviate the accumulation of localized stresses at the interface.Additionally,the 3D alloy anode provided a uniform potential distribution,which promoted homogeneous lithium deposition.Benefiting from these structural advantages,symmetric cells with the Li-B alloy achieved a high critical current density of 2.8 mA cm^(-2).Notably,Li-B‖LPSCI‖LVO-NCM ASSLBs exhibited long-term cycling stability,retaining 97.8%of their capacity after 1500 cycles at 2 C.Furthermore,ASSLBs incorporating the Li-B alloy showed cycling stability comparable with Li-In-based cells,while delivering a higher energy density.Overall,this work presents a practical strategy that may accelerate the commercialization of sulfide-based ASSLBs.
基金supported by the National Natural Science Foundation of China(No.42272044)the High-performance Computing Platform of China University of Geosciences Beijing。
文摘Polyethylene oxide(PEO)-based solid polymer electrolytes(SPEs)have long faced limitations due to low ionic conductivity at ambient temperature and poor interfacial stability with lithium metal anodes.Here,we present a structural engineering strategy to address these challenges through shear-induced crystallization of concentrated PEO-LiTFSI solutions,which self-assemble into flower-like spherulites with radially aligned lamellar crystals.This unique structure creates continuous Li^(+)transport highways through densely packed crystalline domains,achieving a record-high ionic conductivity of 1.70×10^(-4) S/cm at 25℃ for pristine PEO-based systems.Strategic incorporation of lithium montmorillonite(MMTli,10 wt%)further optimizes the composite electrolyte,balancing high ionic conductivity(1.47×10^(-4) S/cm)with enhanced electrochemical stability(4.99 V vs.Li^(+)/Li),elevated Li^(+)transference number(0.62),and mechanical robustness.The composite electrolyte enables stable Li plating/stripping over 800 h in symmetric Li||Li cells and powers LiFePO_(4)||Li solid-state batteries with 82%capacity retention after 200 cycles at 0.2 C under ambient conditions.This work pioneers a scalable processing paradigm for crystalline polymer electrolytes,offering new insights into ion transport mechanisms and validating clay minerals as multifunctional additives for next-generation energy storage systems.
文摘All-solid-state batteries(ASSBs)represent a next-generation energy storage technology,offering enhanced safety,higher energy density,and improved cycling stability compared to conventional liquid-electrolyte-based lithium-ion batteries.Understanding and optimizing the complex chemistries and interfaces that underpin ASSB performance present significant challenges from both experimental and modeling perspectives.In particular,atomistic simulations face difficulties in capturing the complex structure,disorder,and dynamic evolution of materials and interfaces under practically relevant conditions.While established methods such as density functional theory and classical force fields have provided valuable insights,some questions remain difficult to address,particularly those involving large system sizes or long timescales.Recently,machine learning interatomic potentials(MLIPs)have emerged as a transformative tool,enabling atomistic simulations at length and time scales that were previously challenging to access with conventional approaches.By delivering near first-principles accuracy with much greater efficiency,MLIPs open new avenues for large-scale,long-timescale,and high-throughput simulations of solid-state battery materials.In this review,we present a comparative overview of density functional theory,classical force fields,and MLIPs,highlighting their respective strengths and limitations in ASSB research.We then discuss how MLIPs enable simulations that reach longer timescales,larger system sizes,and support high-throughput calculations,providing unique insights into ion transport and interfacial evolution in ASSBs.Finally,we conclude with a summary and outlook on current challenges and future opportunities for expanding MLIP capabilities and accelerating their impact in solid-state battery research.
基金the National Natural Science Foundation of China (52076076, 52006065)Fundamental Research Funds for Central Universities (2025JC003)Beijing Municipal Natural Science Foundation (3242022)
文摘In the realm of large-scale power system energy storage,sodium-based batteries represent a cost-effective post-lithium energy storage technology,making inorganic solid-state sodium batteries(ISSSB)a critical branch of this development.Inorganic solid-state electrolytes(ISSEs)are the core components of sodium batteries;however,they face significant challenges such as insufficient ionic conductivity,interfacial instability,and dendrite growth,all of which severely hinder practical application.This review critically assesses experimental protocols and theoretical frameworks related to mainstream ISSEs and systematizes optimization strategies aimed at overcoming these challenges.Leveraging integrated insights from both experimental and computational studies,the review first categorizes and summarizes the primary types of ISSEs,namely oxide-,sulfide-,and halide-based electrolytes.It then details interfacial optimization strategies focused on addressing three core interfacial issues:ion transport barriers resulting from mechanical incompatibility,side reactions stemming from electrochemical mismatch,and dendrite formation.Finally,the review advocates prioritizing in-depth research that integrates experimental and theoretical approaches to establish a closed-loop methodology encompassing predictive design,multiscale investigation,mechanistic exploration,and high-throughput automated experimentation,with feedback-driven refinement.This work serves as a comprehensive reference and systematic roadmap for future research on solid-state electrolytes(SSEs).
基金financially supported by the National Natural Science Foundation of China(Nos.52263010 and 52372188)2023 Introduction of studying abroad talent program,Henan Provincial Key Scientific Research Project of Collegesand Universities(No.23A150038)+1 种基金Key Scientific Research Project of Education Department of Henan Province(No.22A150042)the National students'platform for innovation and entrepreneurship training program(No.201910476010).
文摘Thermoplastic polyurethane(TPU)consists of a hardsegment and a soft segment,where the former affords mechanical strength and thermalstability,while the latter provides a possibility of good ionic conductivity by promoting dissociation of ions from the lithium salt.Thus,TPU attracts a wide interest recently as a promising polymer electrolyte for solid-state lithium batteries.However,the relatively low ionic conductivity of TPU still restricts its actual applications due to the aggregation of polymer chains,which greatly reduces the dissociation of lithium salts.Herein,a strategy to address this challenge was adopted by in situ polymerization poly(ethylene glycol diacrylate)(PEGDA)in fully dispersed TPU.Hence a stretchable solid-state electrolyte(denoted as TELL and the contrast sample was denoted as TLL)with high ionic conductivity of 7.18×10^(-4) S/cm was obtained at room temperature.The Li^(+)transference number is 0.85 in Li|TELL|Li cell and can stably undergo charge-discharge cycles for 1400 h at a current density of 0.1 mA/cm^(2),while the contrast sample is short-circuited after 634 h of cycling.The LiFePO_(4)|TELL|Li cell achieves a capacity retention of 78.93%after 200 cycles at 2 C.The LiFePO_(4)|TLL| Li cellonly gains the capacity retention of 51.9%after 50 cyclesat the same current density.So,the method adopted here may provide a new approach to realize a flexible solid-state electrolyte with high ion-conductivity.
基金Supported by National Natural Science Foundation of China(Grant No.62173161).
文摘Let A be a 3×3 singular or diagonalizable matrix,all solutions to the Yang-Baxter-like matrix equation have been determined.However,finding all solutions for full rank,non-diagonalizable matrices remains challenging.By utilizing classification techniques,we establish all solutions of the Yang-Baxter-like matrix equation in this paper when the coefficient matrix A is similar to non-diagonalizable matrix diag(λ,J_(2)(λ))withλ̸=0.More specifically,we divide the non-diagonal elements of the solution into 10 different cases.By discussing each situation,we establish all solutions of the Yang-Baxter-like matrix equation.The results of this work enrich the existing ones.
基金supported by the National Natural Science Foundation of China(No.22305106)the Postdoctoral Fellowship Program of CPSF(GZC20230682)Beijing Key Laboratory of High-Entropy Energy materials and Devices,Beijing Institute of Nanoenergy and Nanosystems(No.GS 2025ZD005)。
文摘Li_(7)La_(3)Zr_(2)O_(12)-based electrolytes have got great promise for solid-state lithium(Li)metal batteries because of their high elastic modulus and wide electrochemical stability window.However,the insufficient contact and heterogeneous Li deposition severely hinder their practical applications.Here,a flexible ternary polymethacrylate(PMA)matrix is designed to incorporate with Ta-doped Li_(7)La_(3)Zr_(2)O_(12)(LLZTO-PMA).The PMA matrix ensures excellent interfacial contact,while the synergistic effects of its polar carbonyl groups and its interaction with LLZTO creating fast interfacial Li^(+)pathways yield a high ionic conductivity of 0.266 mS cm^(-1)at 20℃.Moreover,the interaction between LLZTO and PMA matrix further guides the formation of a hybrid LiF/Li_(3)N-rich solid electrolyte interphase,which allows a fast Li^(+)interfacial kinetic due to its lowered Li^(+)diffusion barrier.Consequently,the LLZTO-PMA electrolyte contributes an ultra-stable Li anode interphase,attaining a lifespan exceeding 10,000 h in symmetric cells and retaining over 96%capacity after 600 cycles in full battery,demonstrating a breakthrough for high-performance solid-state batteries.
文摘ZnO thin-film transistors(TFTs)with channel layers fabricated by spin-coating are demonstrated.A nano ZnO colloidal aqueous solution with zinc nitrate dissolved in it was first deposited on the ATO/ITO/glass substrate by spin-coating process.The thin-film transistor with well-controlled and densely packed ZnO crystalline layer was obtained by thermal annealing the system of colloidal solution film coated ATO/ITO/glass substrate.By optimizing the fabrication conditions,the fabricated thin-film transistors exhibited superior field-effect properties,which were stable,highly transparent,n-channel and enhancement-mode with a channel mobility as large as 3.02 cm^(2)·V^(-1).s^(-1).Our method of fabricating ZnO thin-film transistors was simple,high efficiency,and feasible for the batch production with low cost.
基金supported by the National Natural Science Foundation of China(12401279,12371219)the Academic and Technical Leaders Training Plan of Jiangxi Province(20212BCJ23027).
文摘This paper is concerned with an initial boundary value problem for the planar magnetohydrodynamic compressible flow with temperature dependent heat conductivity in a half-line.In particular,the transverse magnetic field is assumed to satisfy the Neumann boundary condition,which was first investigated by Kazhikhov in 1987.We establish the global existence of the unique strong solutions to the MHD equations without any smallness conditions on the initial data.More precisely,our result can be regarded as a natural generalization of Kazhikov’s result for applying the constant heat-conductivity in bounded domains to the degenerate case in unbounded domains.
