We have successfully demonstrated that high quality and high dielectric constant layers can be fabricated by low temperature photo-induced or -assisted processing. Ta_2O_5 and ZrO_2 have been deposited at t<400 ℃ ...We have successfully demonstrated that high quality and high dielectric constant layers can be fabricated by low temperature photo-induced or -assisted processing. Ta_2O_5 and ZrO_2 have been deposited at t<400 ℃ by means of a UV photo-CVD technique and HfO_2 by photo-assisted sol-gel processing with the aid of excimer lamps. The UV annealing of as-grown layers was found to significantly improve their electrical properties. Low leakage current densities on the order of 10 -8 A/cm 2 at 1 MV/cm for deposited ultrathin Ta_2O_5 films and ca.10 -6 A/cm 2 for the photo-CVD ZrO_2 layers and photo-irradiated sol-gel HfO_2 layers have been readily achieved. The improvement in the leakage properties of these layers is attributed to the UV-generated active oxygen species O( 1D) which strongly oxidize any suboxides to form more stoichiometric oxides on removing certain defects, oxygen vacancies and impurities present in the as-prepared layers. The photo-CVD Ta_2O_5 films deposited across 10.16-cm Si wafers exhibit a high thickness uniformity with a variation of less than \{±2.0%\} being obtained for ultrathin ca.10 nm thick films. The lamp technology can in principle be extended to larger area wafers, providing a promising low temperature route to the fabrication of a range of high quality thin films for future ULSI technology.展开更多
Water soluble fullerenols were synthesized and incorporated in SiO2, SiO2-TiO2, GPTMS-SiO2, GPTMS-ATPS inorganic and organic-inorganic materials by sol-gel processes. The maximum concentrations of C60(OH)n and C70(OH)...Water soluble fullerenols were synthesized and incorporated in SiO2, SiO2-TiO2, GPTMS-SiO2, GPTMS-ATPS inorganic and organic-inorganic materials by sol-gel processes. The maximum concentrations of C60(OH)n and C70(OH)n in the obtained SiO2 gels were estimated to be about 0.6% and 1.5% in weight, respectively. The characteristics of the UV/visible spectra of fullerenols in H2O and various gels were measured and compared. The thermal stability of fullerenols in gels was investigated with differential thermal analysis (DTA). The results indicate that the absorption features of fullerenols in solid gels are similar to those in H2O and the fullerenols in SiO2 are stable at 400℃. The optical limiting effect of the fullerenols was investigated preliminarily.展开更多
β-Na YF4:Yb3+,Er3+ microrods were synthesized through hydrothermal methods. Polyethylene glycol with molecular weight of 6000 was used as surfactant. A series of transparent silica gel films with upconversion lumines...β-Na YF4:Yb3+,Er3+ microrods were synthesized through hydrothermal methods. Polyethylene glycol with molecular weight of 6000 was used as surfactant. A series of transparent silica gel films with upconversion luminescence property was prepared through sol-gel method; the prepared β-Na YF4:Yb3+,Er3+ microrods were used as activator. The silica gel films show strong upconversion emission under excitation of 980-nm laser beam.展开更多
A complex Sol-Gel process has been used for synthesis of silica glasses designed to contain high-level nuclear wastes. Cs, Sr, Co, and Nd (generically denoted Me) were used, the last as surrogate for actinides. Gels i...A complex Sol-Gel process has been used for synthesis of silica glasses designed to contain high-level nuclear wastes. Cs, Sr, Co, and Nd (generically denoted Me) were used, the last as surrogate for actinides. Gels in the form of powders and sintered compacts were prepared by hydrolysis and polycondensation of tetraethoxide/Me nitrate solutions, which contained ascorbic acid as a catalyst. Thermal treatment studies were conducted on the resulting gels. Transformation to final products was studied by thermogravimetric analysis, infrared spectroscopy, and X-ray diffraction. Preliminary testing of Me leaching was also completed in quiescent water. Only a single dense form was resistant to展开更多
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ...Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.展开更多
Oxide dispersion strengthened(ODS)alloys are extensively used owing to high thermostability and creep strength contributed from uniformly dispersed fine oxides particles.However,the existence of these strengthening pa...Oxide dispersion strengthened(ODS)alloys are extensively used owing to high thermostability and creep strength contributed from uniformly dispersed fine oxides particles.However,the existence of these strengthening particles also deteriorates the processability and it is of great importance to establish accurate processing maps to guide the thermomechanical processes to enhance the formability.In this study,we performed particle swarm optimization-based back propagation artificial neural network model to predict the high temperature flow behavior of 0.25wt%Al2O3 particle-reinforced Cu alloys,and compared the accuracy with that of derived by Arrhenius-type constitutive model and back propagation artificial neural network model.To train these models,we obtained the raw data by fabricating ODS Cu alloys using the internal oxidation and reduction method,and conducting systematic hot compression tests between 400 and800℃with strain rates of 10^(-2)-10 S^(-1).At last,processing maps for ODS Cu alloys were proposed by combining processing parameters,mechanical behavior,microstructure characterization,and the modeling results achieved a coefficient of determination higher than>99%.展开更多
Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network act...Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer deposition.This optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture capability.This approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs.展开更多
A novel sol-gel processing was developed to synthesize polycrystalline cerium-doped lutetium pyrosilicate （Lu2Si2O7Ce, LPS ：Ce） powders under low temperature. It was found that the addition of propylene oxide （PPO...A novel sol-gel processing was developed to synthesize polycrystalline cerium-doped lutetium pyrosilicate （Lu2Si2O7Ce, LPS ：Ce） powders under low temperature. It was found that the addition of propylene oxide （PPO） could promote the formation of Lu-O-Si bonds in precursor, which was beneficial to the formation of LPS phase. X-ray diffraction （XRD） patterns indicated that the single-phased LPS powder was well crystallized at 1050℃. Microstructure observation demonstrated that the synthetic LPS powder was composed of ellipsoidal grains with the mean size of 40 nm. The luminescent properties were characterized by photoluminescence （PL）, X-ray excited luminescence （XEL） and vacuum ultraviolet （VUV） spectroscopy at room temperature. The synthetic LPS：Ce powder emitted a broad emission spectrum centered at about 380 nm, which should be ascribed to the 5d→4f transition of Ce3＋. Decay time of the synthetic LPS：Ce powder was measured to be only 32 ns.展开更多
In general,the rapid growth of α-Fe clusters is a challenge in high Fe-content Fe-based amorphous alloys,negatively affecting their physical properties.Herein,we introduce an efficient and rapid post-treatment techni...In general,the rapid growth of α-Fe clusters is a challenge in high Fe-content Fe-based amorphous alloys,negatively affecting their physical properties.Herein,we introduce an efficient and rapid post-treatment technique known as ultrasonic vibration rapid processing(UVRP),which enables the formation of high-density strong magnetic α-Fe clusters,thereby enhancing the soft magnetic properties of Fe_(78)Si(13)B_(9) amorphous alloy ribbon.展开更多
Thin walls of an AZ91 magnesium alloy with fine equiaxed grains were fabricated via cold arc-based wire arc additive manufacturing(CA-WAAM),and the droplet transfer behaviours,microstructures,and mechanical properties...Thin walls of an AZ91 magnesium alloy with fine equiaxed grains were fabricated via cold arc-based wire arc additive manufacturing(CA-WAAM),and the droplet transfer behaviours,microstructures,and mechanical properties were investigated.The results showed that the cold arc process reduced splashing at the moment of liquid bridge breakage and effectively shortened the droplet transfer period.The microstructures of the deposited samples exhibited layered characteristics with alternating distributions of coarse and fine grains.During layer-by-layer deposition,the β-phase precipitated and grew preferentially along grain boundaries,while the fineη-Al_(8)Mn_(5)phase was dispersed in the α-Mg matrix.The mechanical properties of the CA-WAAM deposited sample showed isotropic characteristics.The ultimate tensile strength and elongation in the building direction(BD)were 282.7 MPa and 14.2%,respectively.The microhardness values of the deposited parts were relatively uniform,with an average value of HV 69.6.展开更多
Agricultural Products Processing and Storage (ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature) is an international,pect-review ed open access journal with the a...Agricultural Products Processing and Storage (ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature) is an international,pect-review ed open access journal with the aim to offer a platform for the rapid dissemination of significant,novel,and high-impact research in the fields of agricultural product processing science,technology,engineering,and nutrition.Additio nally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.展开更多
Ti-10V-2Fe-3Al alloy with fine-grainedβphases was fabricated by friction stir processing with opti-mized processing parameters.The superplastic behavior of the specimens was investigated by tensile deformation at dif...Ti-10V-2Fe-3Al alloy with fine-grainedβphases was fabricated by friction stir processing with opti-mized processing parameters.The superplastic behavior of the specimens was investigated by tensile deformation at different strain rates and temperatures,and an optimal superplastic elongation of 634%was achieved at 700℃ and 3×10^(-4)/s.An annealing treatment at 650℃ for 60 min showed a mi-crostructure withαprecipitates distributed in theβmatrix in the friction stir specimen.Such pre-heat treatment improves the superplasticity of the specimen,achieving an elongation of up to 807%at 750℃ and 3×10^(-4)/s.The influences of tensile temperatures and strain rates on the microstructural evolution,such as grain size variation,grain morphology,and phase transformations,were discussed.The super-plastic deformation behavior of fine-grained Ti-10V-2Fe-3Al alloy is controlled by grain boundary sliding and accompanied by dynamic phase transformation and recrystallization.展开更多
The hot deformation characteristics of induction quenched Zr-Sn-Nb-Fe-Cr alloy forged rod in the temperature range of 600–900°C and strain rate range of 0.001–1 s^(-1)were studied by Gleeble3800 uniaxial hot co...The hot deformation characteristics of induction quenched Zr-Sn-Nb-Fe-Cr alloy forged rod in the temperature range of 600–900°C and strain rate range of 0.001–1 s^(-1)were studied by Gleeble3800 uniaxial hot compression experiment.The results show that the flow stress decreases with the decrease in strain rate and the increase in deformation temperature in the true stress-true strain curve of Zr-Sn-Nb-Fe-Cr alloy forged rod.Moreover,the hot deformation characteristics of the material can be described by the hyperbolic sine constitutive equation.Under the experimental conditions,the average thermal activation energy(Q)of the alloy was 412.9105 kJ/mol.The microstructure analysis of the processing map and the sample after hot compression shows that the optimum hot working parameters of the alloy are 795–900°C,0.001–0.0068 s^(-1),at the deformation temperature of 600–900°C,and the strain rate of 0.001–1 s^(-1).展开更多
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ...Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.展开更多
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ...Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.展开更多
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ...Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.展开更多
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ...Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.展开更多
Using a Gleeble 3500 thermomechanical simulation testing machine,the hot deformation characteristics of 23Cr-8Ni steel were investigated under the conditions of 1000–1250℃ and 0.001‒10 s^(−1).Furthermore,the microst...Using a Gleeble 3500 thermomechanical simulation testing machine,the hot deformation characteristics of 23Cr-8Ni steel were investigated under the conditions of 1000–1250℃ and 0.001‒10 s^(−1).Furthermore,the microstructure of the characterization region was analyzed to investigate the recrystallization behavior of 23Cr-8Ni steel.Results show that as the strain rate decreases and the deformation temperature increases,the flow stress decreases.Because the softening phenomenon occurs after the peak stress,the flow stress decreases.The stress index(n)is 4.28,and the thermal deformation activation energy(Q)is 588878 J/mol.Processing map is established,and an optimal thermal processing range of 0.001–0.1 s^(−1) and 1000–1200℃ is achieved,therefore greatly promoting the yield rate.展开更多
This critical review looks at the assessment of the application of artificial intelligence in handling legal documents with specific reference to medical negligence cases with a view of identifying its transformative ...This critical review looks at the assessment of the application of artificial intelligence in handling legal documents with specific reference to medical negligence cases with a view of identifying its transformative potentialities, issues and ethical concerns. The review consolidates findings that show the impact of AI in improving the efficiency, accuracy and justice delivery in the legal profession. The studies show increased efficiency in speed of document review and enhancement of the accuracy of the reviewed documents, with time efficiency estimates of 60% reduction of time. However, the review also outlines some of the problems that continue to characterize AI, such as data quality problems, biased algorithms and the problem of the opaque decision-making system. This paper assesses ethical issues related to patient autonomy, justice and non-malignant suffering, with particular focus on patient privacy and fair process, and on potential unfairness to patients. This paper’s review of AI innovations finds that regulations lag behind AI developments, leading to unsettled issues regarding legal responsibility for AI and user control over AI-generated results and findings in legal proceedings. Some of the future avenues that are presented in the study are the future of XAI for legal purposes, utilizing federated learning for resolving privacy issues, and the need to foster adaptive regulation. Finally, the review advocates for Legal Subject Matter Experts to collaborate with legal informatics experts, ethicists, and policy makers to develop the best solutions to implement AI in medical negligence claims. It reasons that there is great potential for AI to have a deep impact on the practice of law but when done, it must do so in a way that respects justice and on the Rights of Individuals.展开更多
Digital light processing(DLP)is widely used in ceramic additive manufacturing.However,it remains unexplored for metals.In this study,the regulatory mechanisms of the microstructure and mechanical properties of AISI 31...Digital light processing(DLP)is widely used in ceramic additive manufacturing.However,it remains unexplored for metals.In this study,the regulatory mechanisms of the microstructure and mechanical properties of AISI 316L stainless steel were investigated by optimizing a DLP-compatible metal slurry formulation and sintering process.A photosensitive resin system(mass ratio of 5:1:2:2 for U600,LA,ACMO,and HDDA,respectively)with 88 wt%solid content is designed to achieve a slurry with balanced rheology,photocurability,and low pyrolysis residue.Compared to vacuum sintering,which leads to brittle fracture of material,the Ar/H2 mixed gas(5%H2)effectively reduces carbon and oxygen impurities via reduction,mitigating carbide and oxide segregation at grain boundaries and within grains,thereby enhancing strength-ductility.In addition,the prolonged high-temperature sintering inducesδ-ferrite precipitation at grain boundaries,which fills residual pores to improve densification obviously.Under optimized sintering conditions(Ar/H2,1380°C,6 h),the material achieves 96.2%relative density with tensile strength and fracture elongation of 543.5 MPa and 58.7%,respectively,exhibiting uniform dimple-dominated fracture morphology.This synergistic optimization of the slurry formulation and sintering parameters improves the strength-ductility balance in DLP-fabricated metal materials,offering theoretical and technical insights for the additive manufacturing of complex high-performance metal components.展开更多
文摘We have successfully demonstrated that high quality and high dielectric constant layers can be fabricated by low temperature photo-induced or -assisted processing. Ta_2O_5 and ZrO_2 have been deposited at t<400 ℃ by means of a UV photo-CVD technique and HfO_2 by photo-assisted sol-gel processing with the aid of excimer lamps. The UV annealing of as-grown layers was found to significantly improve their electrical properties. Low leakage current densities on the order of 10 -8 A/cm 2 at 1 MV/cm for deposited ultrathin Ta_2O_5 films and ca.10 -6 A/cm 2 for the photo-CVD ZrO_2 layers and photo-irradiated sol-gel HfO_2 layers have been readily achieved. The improvement in the leakage properties of these layers is attributed to the UV-generated active oxygen species O( 1D) which strongly oxidize any suboxides to form more stoichiometric oxides on removing certain defects, oxygen vacancies and impurities present in the as-prepared layers. The photo-CVD Ta_2O_5 films deposited across 10.16-cm Si wafers exhibit a high thickness uniformity with a variation of less than \{±2.0%\} being obtained for ultrathin ca.10 nm thick films. The lamp technology can in principle be extended to larger area wafers, providing a promising low temperature route to the fabrication of a range of high quality thin films for future ULSI technology.
文摘Water soluble fullerenols were synthesized and incorporated in SiO2, SiO2-TiO2, GPTMS-SiO2, GPTMS-ATPS inorganic and organic-inorganic materials by sol-gel processes. The maximum concentrations of C60(OH)n and C70(OH)n in the obtained SiO2 gels were estimated to be about 0.6% and 1.5% in weight, respectively. The characteristics of the UV/visible spectra of fullerenols in H2O and various gels were measured and compared. The thermal stability of fullerenols in gels was investigated with differential thermal analysis (DTA). The results indicate that the absorption features of fullerenols in solid gels are similar to those in H2O and the fullerenols in SiO2 are stable at 400℃. The optical limiting effect of the fullerenols was investigated preliminarily.
基金Supported by the National Natural Science Foundation of China(No.61308085)
文摘β-Na YF4:Yb3+,Er3+ microrods were synthesized through hydrothermal methods. Polyethylene glycol with molecular weight of 6000 was used as surfactant. A series of transparent silica gel films with upconversion luminescence property was prepared through sol-gel method; the prepared β-Na YF4:Yb3+,Er3+ microrods were used as activator. The silica gel films show strong upconversion emission under excitation of 980-nm laser beam.
基金part of studies that will be contin-ued within Polish Governmental Project“Technology Supporting Development of Safe Nuclear Power,”Part“Development of Techniques and Technologies Supporting Management of Spent Nuclear Fuel and Radioactive Waste.”
文摘A complex Sol-Gel process has been used for synthesis of silica glasses designed to contain high-level nuclear wastes. Cs, Sr, Co, and Nd (generically denoted Me) were used, the last as surrogate for actinides. Gels in the form of powders and sintered compacts were prepared by hydrolysis and polycondensation of tetraethoxide/Me nitrate solutions, which contained ascorbic acid as a catalyst. Thermal treatment studies were conducted on the resulting gels. Transformation to final products was studied by thermogravimetric analysis, infrared spectroscopy, and X-ray diffraction. Preliminary testing of Me leaching was also completed in quiescent water. Only a single dense form was resistant to
文摘Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.
基金financial support of the National Natural Science Foundation of China(No.52371103)the Fundamental Research Funds for the Central Universities,China(No.2242023K40028)+1 种基金the Open Research Fund of Jiangsu Key Laboratory for Advanced Metallic Materials,China(No.AMM2023B01).financial support of the Research Fund of Shihezi Key Laboratory of AluminumBased Advanced Materials,China(No.2023PT02)financial support of Guangdong Province Science and Technology Major Project,China(No.2021B0301030005)。
文摘Oxide dispersion strengthened(ODS)alloys are extensively used owing to high thermostability and creep strength contributed from uniformly dispersed fine oxides particles.However,the existence of these strengthening particles also deteriorates the processability and it is of great importance to establish accurate processing maps to guide the thermomechanical processes to enhance the formability.In this study,we performed particle swarm optimization-based back propagation artificial neural network model to predict the high temperature flow behavior of 0.25wt%Al2O3 particle-reinforced Cu alloys,and compared the accuracy with that of derived by Arrhenius-type constitutive model and back propagation artificial neural network model.To train these models,we obtained the raw data by fabricating ODS Cu alloys using the internal oxidation and reduction method,and conducting systematic hot compression tests between 400 and800℃with strain rates of 10^(-2)-10 S^(-1).At last,processing maps for ODS Cu alloys were proposed by combining processing parameters,mechanical behavior,microstructure characterization,and the modeling results achieved a coefficient of determination higher than>99%.
基金Technology Development Program of Jilin Province(YDZJ202201ZYTS640)the National Key Research and Development Program of China(2022YFB4200400)funded by MOST+4 种基金the National Natural Science Foundation of China(52172048 and 52103221)Shandong Provincial Natural Science Foundation(ZR2021QB024 and ZR2021ZD06)Guangdong Basic and Applied Basic Research Foundation(2023A1515012323,2023A1515010943,and 2024A1515010023)the Qingdao New Energy Shandong Laboratory open Project(QNESL OP 202309)the Fundamental Research Funds of Shandong University.
文摘Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer deposition.This optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture capability.This approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs.
基金supported by the National Natural Science Foundation of China(Grant No.51172139)
文摘A novel sol-gel processing was developed to synthesize polycrystalline cerium-doped lutetium pyrosilicate （Lu2Si2O7Ce, LPS ：Ce） powders under low temperature. It was found that the addition of propylene oxide （PPO） could promote the formation of Lu-O-Si bonds in precursor, which was beneficial to the formation of LPS phase. X-ray diffraction （XRD） patterns indicated that the single-phased LPS powder was well crystallized at 1050℃. Microstructure observation demonstrated that the synthetic LPS powder was composed of ellipsoidal grains with the mean size of 40 nm. The luminescent properties were characterized by photoluminescence （PL）, X-ray excited luminescence （XEL） and vacuum ultraviolet （VUV） spectroscopy at room temperature. The synthetic LPS：Ce powder emitted a broad emission spectrum centered at about 380 nm, which should be ascribed to the 5d→4f transition of Ce3＋. Decay time of the synthetic LPS：Ce powder was measured to be only 32 ns.
基金supported by the Major Science and Technology Project of Zhongshan City(No.2022AJ004)the Key Basic and Applied Research Program of Guangdong Province(Nos.2019B030302010 and 2022B1515120082)Guangdong Science and Technology Innovation Project(No.2021TX06C111).
文摘In general,the rapid growth of α-Fe clusters is a challenge in high Fe-content Fe-based amorphous alloys,negatively affecting their physical properties.Herein,we introduce an efficient and rapid post-treatment technique known as ultrasonic vibration rapid processing(UVRP),which enables the formation of high-density strong magnetic α-Fe clusters,thereby enhancing the soft magnetic properties of Fe_(78)Si(13)B_(9) amorphous alloy ribbon.
基金supported by the National Natural Science Foundation of China(No.51805265)the Fundamental Research Funds for the Central Universities,China(No.30922010921).
文摘Thin walls of an AZ91 magnesium alloy with fine equiaxed grains were fabricated via cold arc-based wire arc additive manufacturing(CA-WAAM),and the droplet transfer behaviours,microstructures,and mechanical properties were investigated.The results showed that the cold arc process reduced splashing at the moment of liquid bridge breakage and effectively shortened the droplet transfer period.The microstructures of the deposited samples exhibited layered characteristics with alternating distributions of coarse and fine grains.During layer-by-layer deposition,the β-phase precipitated and grew preferentially along grain boundaries,while the fineη-Al_(8)Mn_(5)phase was dispersed in the α-Mg matrix.The mechanical properties of the CA-WAAM deposited sample showed isotropic characteristics.The ultimate tensile strength and elongation in the building direction(BD)were 282.7 MPa and 14.2%,respectively.The microhardness values of the deposited parts were relatively uniform,with an average value of HV 69.6.
文摘Agricultural Products Processing and Storage (ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature) is an international,pect-review ed open access journal with the aim to offer a platform for the rapid dissemination of significant,novel,and high-impact research in the fields of agricultural product processing science,technology,engineering,and nutrition.Additio nally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.
基金financially supported by the National Natural Science Foundation of China(No.52105373)the China Scholarship Council(No.202106020094).
文摘Ti-10V-2Fe-3Al alloy with fine-grainedβphases was fabricated by friction stir processing with opti-mized processing parameters.The superplastic behavior of the specimens was investigated by tensile deformation at different strain rates and temperatures,and an optimal superplastic elongation of 634%was achieved at 700℃ and 3×10^(-4)/s.An annealing treatment at 650℃ for 60 min showed a mi-crostructure withαprecipitates distributed in theβmatrix in the friction stir specimen.Such pre-heat treatment improves the superplasticity of the specimen,achieving an elongation of up to 807%at 750℃ and 3×10^(-4)/s.The influences of tensile temperatures and strain rates on the microstructural evolution,such as grain size variation,grain morphology,and phase transformations,were discussed.The super-plastic deformation behavior of fine-grained Ti-10V-2Fe-3Al alloy is controlled by grain boundary sliding and accompanied by dynamic phase transformation and recrystallization.
文摘The hot deformation characteristics of induction quenched Zr-Sn-Nb-Fe-Cr alloy forged rod in the temperature range of 600–900°C and strain rate range of 0.001–1 s^(-1)were studied by Gleeble3800 uniaxial hot compression experiment.The results show that the flow stress decreases with the decrease in strain rate and the increase in deformation temperature in the true stress-true strain curve of Zr-Sn-Nb-Fe-Cr alloy forged rod.Moreover,the hot deformation characteristics of the material can be described by the hyperbolic sine constitutive equation.Under the experimental conditions,the average thermal activation energy(Q)of the alloy was 412.9105 kJ/mol.The microstructure analysis of the processing map and the sample after hot compression shows that the optimum hot working parameters of the alloy are 795–900°C,0.001–0.0068 s^(-1),at the deformation temperature of 600–900°C,and the strain rate of 0.001–1 s^(-1).
文摘Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.
文摘Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.
文摘Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.
文摘Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.
文摘Using a Gleeble 3500 thermomechanical simulation testing machine,the hot deformation characteristics of 23Cr-8Ni steel were investigated under the conditions of 1000–1250℃ and 0.001‒10 s^(−1).Furthermore,the microstructure of the characterization region was analyzed to investigate the recrystallization behavior of 23Cr-8Ni steel.Results show that as the strain rate decreases and the deformation temperature increases,the flow stress decreases.Because the softening phenomenon occurs after the peak stress,the flow stress decreases.The stress index(n)is 4.28,and the thermal deformation activation energy(Q)is 588878 J/mol.Processing map is established,and an optimal thermal processing range of 0.001–0.1 s^(−1) and 1000–1200℃ is achieved,therefore greatly promoting the yield rate.
文摘This critical review looks at the assessment of the application of artificial intelligence in handling legal documents with specific reference to medical negligence cases with a view of identifying its transformative potentialities, issues and ethical concerns. The review consolidates findings that show the impact of AI in improving the efficiency, accuracy and justice delivery in the legal profession. The studies show increased efficiency in speed of document review and enhancement of the accuracy of the reviewed documents, with time efficiency estimates of 60% reduction of time. However, the review also outlines some of the problems that continue to characterize AI, such as data quality problems, biased algorithms and the problem of the opaque decision-making system. This paper assesses ethical issues related to patient autonomy, justice and non-malignant suffering, with particular focus on patient privacy and fair process, and on potential unfairness to patients. This paper’s review of AI innovations finds that regulations lag behind AI developments, leading to unsettled issues regarding legal responsibility for AI and user control over AI-generated results and findings in legal proceedings. Some of the future avenues that are presented in the study are the future of XAI for legal purposes, utilizing federated learning for resolving privacy issues, and the need to foster adaptive regulation. Finally, the review advocates for Legal Subject Matter Experts to collaborate with legal informatics experts, ethicists, and policy makers to develop the best solutions to implement AI in medical negligence claims. It reasons that there is great potential for AI to have a deep impact on the practice of law but when done, it must do so in a way that respects justice and on the Rights of Individuals.
基金supported by National Natural Science Foundation of China(Grant Nos.52205231,52205196)Taishan Scholars Program,and Research Project of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai(Grant Nos.AMGM0613,AMGM0620).
文摘Digital light processing(DLP)is widely used in ceramic additive manufacturing.However,it remains unexplored for metals.In this study,the regulatory mechanisms of the microstructure and mechanical properties of AISI 316L stainless steel were investigated by optimizing a DLP-compatible metal slurry formulation and sintering process.A photosensitive resin system(mass ratio of 5:1:2:2 for U600,LA,ACMO,and HDDA,respectively)with 88 wt%solid content is designed to achieve a slurry with balanced rheology,photocurability,and low pyrolysis residue.Compared to vacuum sintering,which leads to brittle fracture of material,the Ar/H2 mixed gas(5%H2)effectively reduces carbon and oxygen impurities via reduction,mitigating carbide and oxide segregation at grain boundaries and within grains,thereby enhancing strength-ductility.In addition,the prolonged high-temperature sintering inducesδ-ferrite precipitation at grain boundaries,which fills residual pores to improve densification obviously.Under optimized sintering conditions(Ar/H2,1380°C,6 h),the material achieves 96.2%relative density with tensile strength and fracture elongation of 543.5 MPa and 58.7%,respectively,exhibiting uniform dimple-dominated fracture morphology.This synergistic optimization of the slurry formulation and sintering parameters improves the strength-ductility balance in DLP-fabricated metal materials,offering theoretical and technical insights for the additive manufacturing of complex high-performance metal components.
