The good combination of mechanical and wear properties for cemented carbides is crucial.In this work,the wear behavior of functionally graded cemented carbide(FGCC)and non-graded cemented carbide(CC),with CoNiFeCr mul...The good combination of mechanical and wear properties for cemented carbides is crucial.In this work,the wear behavior of functionally graded cemented carbide(FGCC)and non-graded cemented carbide(CC),with CoNiFeCr multi-principal-element alloy(MPEA)binder,has been investigated by performing sliding wear tests and composition characterization.The results showed that compared with CC,FGCC had higher hardness,stronger fracture toughness,better wear performance,and similar TRS.FGCCs exhibited lower wear rates(3.44×10^(−7)–6.95×10^(−6)mm^(3)/(N m))and coefficients of friction(COFs)(0.27–0.39)than CCs from RT to 600℃due to mitigation of multiple risks caused by binder removal,fragmentation and pull-out of WC grains,high-temperature oxidation and softening.In the low-temperature wear stage,the MPEA binder underwent dynamic recrystallization(DRX)and twinning deformation before removing from the surface.The binder removal caused dislocation pile-ups and stacking faults(SFs)to form under high stress,resulting in fragmentation and pull-out of WC grains.The low-temperature wear was dominated by abrasive wear and adhesive wear,with a low wear rate and a high and unstable COF.In the high-temperature wear stage,initial pitting oxidation of WC grains generated many subgrain boundaries,reducing heat transfer and exacerbating oxidation,resulting in an oxide layer enriched with WO3,Mx Oy,and MWO4.High-temperature wear was dominated by oxidation wear and high-temperature softening,with a high wear rate and a low and smooth COF.The results from the present study do not only provide theoretical guidance for an understanding of the antiwear mechanism of WC-CoNiFeCr,but also a new approach for the preparation of cemented carbides with high wear resistance.展开更多
In recent years,the addition of Ni has been widely acknowledged to be capable of enhancing the mechanical properties of Al-Si alloys.However,the effect of Ni on the wear behaviors of Al-Si alloys and Al matrix composi...In recent years,the addition of Ni has been widely acknowledged to be capable of enhancing the mechanical properties of Al-Si alloys.However,the effect of Ni on the wear behaviors of Al-Si alloys and Al matrix composites,particularly at elevated temperat-ures,remains an understudied area.In this study,Al-Si-Cu-Mg-Ni/20wt%SiC particles(SiCp)composites with varying Ni contents were prepared by using a semisolid stir casting method.The effect of Ni content on the dry sliding wear behavior of the prepared compos-ites was investigated through sliding tests at 25 and 350℃.Results indicated that theθ-Al_(2)Cu phase gradually diminished and eventually disappeared as the Ni content increased from 0wt%to 3wt%.This change was accompanied by the formation and increase inδ-Al_(3)CuNi andε-Al_(3)Ni phases in microstructures.The hardness and ultimate tensile strength of the as-cast composites improved,and the wear rates of the composites decreased from 5.29×10^(−4)to 1.94×10^(−4)mm^(3)/(N∙m)at 25℃and from 20.2×10^(−4)to 7×10^(−4)mm^(3)/(N∙m)at 350℃with the increase in Ni content from 0wt%to 2wt%.The enhancement in performance was due to the presence of strengthening network structures and additional Ni-containing phases in the composites.However,the wear rate of the 3Ni composite was approximately two times higher than that of the 2Ni composite due to the fracture and debonding of theε-Al_(3)Ni phase.Abrasive wear,delamination wear,and oxidation wear were the predominant wear mechanisms of the investigated composites at 25℃,whereas delamination wear and oxid-ation wear were dominant during sliding at 350℃.展开更多
The tribological properties of the in-situ dendrite-reinforced metallic glass matrix composite（Ti42Zr22V14-Cu5Be17）prepared by copper mould casting were analyzed at different normal loads under the dry condition and...The tribological properties of the in-situ dendrite-reinforced metallic glass matrix composite（Ti42Zr22V14-Cu5Be17）prepared by copper mould casting were analyzed at different normal loads under the dry condition and rainwater.The results showed that the average value of the frictional coefficients and micro-hardness ascended with increasing the normal load,while the wear rate showed a trend of decline under the dry condition.The electrochemical test results showed that the surface of samples was pitting corroded in the rainwater.The matrices were corroded first.Then the dendrites were exposed,leading to the damage of the surface.Both the frictional coefficients and wear rate of the composite in the rainwater were larger than those under the dry condition,primarily owing to the corrosion of chloride ions on the worn surface.The wear mechanisms of composites were mainly adhesive wear,accompanied by the abrasive wear under the dry condition and corrosive wear in the rainwater.The composites have higher wear resistance both under the dry condition and rainwater due to the lower wear rate.展开更多
The study on slide stability of hydraulic structures on subbed soil was made. Using the slide test results of dragged concreting base plates on subbed soil pits, the decreased value of bearing capacity on slide after ...The study on slide stability of hydraulic structures on subbed soil was made. Using the slide test results of dragged concreting base plates on subbed soil pits, the decreased value of bearing capacity on slide after re- bound and repression influence of subbed soil was determined, and the envelope of ultimate slide shear resistance was also quantitatively determined. Due to the lack of similar mechanisms of slide stability on subbed soil and base plate of hydraulic structures, different safety coefficients for the slide stability were adopted. It was suggested to use the maximum compressive stress O＇m~ of eccentric load to predict structure displacement, slide and creepy slippage of subbed soil, to determine the sliding creepy contour and limit the maximum load on subbed soil. Two hydraulic structures that had been put into operation were reviewed by this method, and the results accorded with the real conditions.展开更多
Based on data of number of fog and haze days in Baoji City from 1981 to 2013,the changing trends and mutation of number of fog and haze days in Baoji over the past 33 years were analyzed by using trend coefficient,ten...Based on data of number of fog and haze days in Baoji City from 1981 to 2013,the changing trends and mutation of number of fog and haze days in Baoji over the past 33 years were analyzed by using trend coefficient,tendency rate,linear regression analysis,anomaly percentage,Mann-Kendall mutation test and sliding t test.The results showed that during the 33 years,the number of fog and haze days in Baoji declined by 16.253d/10 a,and there was a cyclical turbulence every 6,15 or 28years.The frequency of fog and haze weather was the highest in winter,followed by spring and autumn,while it was the lowest in summer.According to the anomaly percentage of the number of fog and haze days in 12 months during 1981-2013,the anomaly percentage changed most greatly in July,followed by September,October,April,May,June,August,February and March,but it fluctuated less greatly in January.The number of fog and haze days from 1981 to 2013had obvious mutation trends in a single year and a single season,and mutation types are different.展开更多
基金financially supported by the National Key Research and Development Program of China(No.2021YFB3701800)Special funding support for the Yuelu Mountain National University Science and Technology City“Ranking the Top of the List”Research Project:(Tunnel Boring Machine High-performance Long-life Cutting Tools)the State Key Laboratory of Powder Metallurgy,Central South University,Changsha,China.
文摘The good combination of mechanical and wear properties for cemented carbides is crucial.In this work,the wear behavior of functionally graded cemented carbide(FGCC)and non-graded cemented carbide(CC),with CoNiFeCr multi-principal-element alloy(MPEA)binder,has been investigated by performing sliding wear tests and composition characterization.The results showed that compared with CC,FGCC had higher hardness,stronger fracture toughness,better wear performance,and similar TRS.FGCCs exhibited lower wear rates(3.44×10^(−7)–6.95×10^(−6)mm^(3)/(N m))and coefficients of friction(COFs)(0.27–0.39)than CCs from RT to 600℃due to mitigation of multiple risks caused by binder removal,fragmentation and pull-out of WC grains,high-temperature oxidation and softening.In the low-temperature wear stage,the MPEA binder underwent dynamic recrystallization(DRX)and twinning deformation before removing from the surface.The binder removal caused dislocation pile-ups and stacking faults(SFs)to form under high stress,resulting in fragmentation and pull-out of WC grains.The low-temperature wear was dominated by abrasive wear and adhesive wear,with a low wear rate and a high and unstable COF.In the high-temperature wear stage,initial pitting oxidation of WC grains generated many subgrain boundaries,reducing heat transfer and exacerbating oxidation,resulting in an oxide layer enriched with WO3,Mx Oy,and MWO4.High-temperature wear was dominated by oxidation wear and high-temperature softening,with a high wear rate and a low and smooth COF.The results from the present study do not only provide theoretical guidance for an understanding of the antiwear mechanism of WC-CoNiFeCr,but also a new approach for the preparation of cemented carbides with high wear resistance.
基金the financial support from Ningbo Institute of Technology, Beihang University
文摘In recent years,the addition of Ni has been widely acknowledged to be capable of enhancing the mechanical properties of Al-Si alloys.However,the effect of Ni on the wear behaviors of Al-Si alloys and Al matrix composites,particularly at elevated temperat-ures,remains an understudied area.In this study,Al-Si-Cu-Mg-Ni/20wt%SiC particles(SiCp)composites with varying Ni contents were prepared by using a semisolid stir casting method.The effect of Ni content on the dry sliding wear behavior of the prepared compos-ites was investigated through sliding tests at 25 and 350℃.Results indicated that theθ-Al_(2)Cu phase gradually diminished and eventually disappeared as the Ni content increased from 0wt%to 3wt%.This change was accompanied by the formation and increase inδ-Al_(3)CuNi andε-Al_(3)Ni phases in microstructures.The hardness and ultimate tensile strength of the as-cast composites improved,and the wear rates of the composites decreased from 5.29×10^(−4)to 1.94×10^(−4)mm^(3)/(N∙m)at 25℃and from 20.2×10^(−4)to 7×10^(−4)mm^(3)/(N∙m)at 350℃with the increase in Ni content from 0wt%to 2wt%.The enhancement in performance was due to the presence of strengthening network structures and additional Ni-containing phases in the composites.However,the wear rate of the 3Ni composite was approximately two times higher than that of the 2Ni composite due to the fracture and debonding of theε-Al_(3)Ni phase.Abrasive wear,delamination wear,and oxidation wear were the predominant wear mechanisms of the investigated composites at 25℃,whereas delamination wear and oxid-ation wear were dominant during sliding at 350℃.
基金Item Sponsored by National Natural Science Foundation of China(51371122,51401141)Program for the Innovative Talents of Higher Learning Institutions of Shanxi Province of China(2013)Youth Science Foundation of Shanxi Province of China(2014021017-3)
文摘The tribological properties of the in-situ dendrite-reinforced metallic glass matrix composite（Ti42Zr22V14-Cu5Be17）prepared by copper mould casting were analyzed at different normal loads under the dry condition and rainwater.The results showed that the average value of the frictional coefficients and micro-hardness ascended with increasing the normal load,while the wear rate showed a trend of decline under the dry condition.The electrochemical test results showed that the surface of samples was pitting corroded in the rainwater.The matrices were corroded first.Then the dendrites were exposed,leading to the damage of the surface.Both the frictional coefficients and wear rate of the composite in the rainwater were larger than those under the dry condition,primarily owing to the corrosion of chloride ions on the worn surface.The wear mechanisms of composites were mainly adhesive wear,accompanied by the abrasive wear under the dry condition and corrosive wear in the rainwater.The composites have higher wear resistance both under the dry condition and rainwater due to the lower wear rate.
文摘The study on slide stability of hydraulic structures on subbed soil was made. Using the slide test results of dragged concreting base plates on subbed soil pits, the decreased value of bearing capacity on slide after re- bound and repression influence of subbed soil was determined, and the envelope of ultimate slide shear resistance was also quantitatively determined. Due to the lack of similar mechanisms of slide stability on subbed soil and base plate of hydraulic structures, different safety coefficients for the slide stability were adopted. It was suggested to use the maximum compressive stress O＇m~ of eccentric load to predict structure displacement, slide and creepy slippage of subbed soil, to determine the sliding creepy contour and limit the maximum load on subbed soil. Two hydraulic structures that had been put into operation were reviewed by this method, and the results accorded with the real conditions.
基金Supported by the National Natural Science Foundation of China(41071359)
文摘Based on data of number of fog and haze days in Baoji City from 1981 to 2013,the changing trends and mutation of number of fog and haze days in Baoji over the past 33 years were analyzed by using trend coefficient,tendency rate,linear regression analysis,anomaly percentage,Mann-Kendall mutation test and sliding t test.The results showed that during the 33 years,the number of fog and haze days in Baoji declined by 16.253d/10 a,and there was a cyclical turbulence every 6,15 or 28years.The frequency of fog and haze weather was the highest in winter,followed by spring and autumn,while it was the lowest in summer.According to the anomaly percentage of the number of fog and haze days in 12 months during 1981-2013,the anomaly percentage changed most greatly in July,followed by September,October,April,May,June,August,February and March,but it fluctuated less greatly in January.The number of fog and haze days from 1981 to 2013had obvious mutation trends in a single year and a single season,and mutation types are different.
