The characteristics of summertime raindrop size distribution(DSD) and associated relations in the semi-arid region over the Inner Mongolian Plateau(IMP) were investigated,utilizing five-year continuous observations by...The characteristics of summertime raindrop size distribution(DSD) and associated relations in the semi-arid region over the Inner Mongolian Plateau(IMP) were investigated,utilizing five-year continuous observations by a PARSIVEL2disdrometer in East Ujimqin County(EUC),China.It is found that only 7.94% of the 15 664 one-min precipitation samples meet classification criteria as convective rain(CR),but its contribution to the total rainfall amount is 63.87%.Notably,40.72% of the rainfall comes from large-sized raindrops(D> 3 mm),despite the fact that large-sized raindrops account for only 1.73% of the CR total number concentration.Further results show that the mean value of mass-weighted mean diameters(Dm) is larger(2.43 mm) and generalized intercepts(lgN_(W)) is lower(3.19) in CR,aligning with a "continentallike" cluster,which is mainly influenced by the joint impact of in-cloud ice-based processes and the below-cloud environmental background.Also,the empirical relationships of shape-slope(μ-Λ),radar reflectivity-rain rate(Z-R),and rainfall kinetic energy(KE_(time)-Rand KE_(time)-Z) are localized.To quantitatively analyze the impact of DSD parameters on kinetic energy estimation,power-law KE_(time)-R and KE_(time)-Z relationships are derived based on the normalized gamma distribution.N_(W)takes precedence over μ in affecting variabilities of multiplicative coefficients,especially for KE_(time)-R relationship where the multiplicative coefficient is proportional to N_(W)^(-0.287).It should be noted that although the proportion of CR occurring throughout the summer is small,raindrops with lower N_(W) and larger Dmwill generate higher KE_(time),which will bring a higher potential risk of soil erosion in semi-arid regions over IMP.展开更多
The mechanical behavior of cemented gangue backfill materials(CGBMs)is closely related to particle size distribution(PSD)of aggregates and properties of cementitious materials.Consequently,the true triaxial compressio...The mechanical behavior of cemented gangue backfill materials(CGBMs)is closely related to particle size distribution(PSD)of aggregates and properties of cementitious materials.Consequently,the true triaxial compression tests,CT scanning,SEM,and EDS tests were conducted on cemented gangue backfill samples(CGBSs)with various carbon nanotube concentrations(P_(CNT))that satisfied fractal theory for the PSD of aggregates.The mechanical properties,energy dissipations,and failure mechanisms of the CGBSs under true triaxial compression were systematically analyzed.The results indicate that appropriate carbon nanotubes(CNTs)effectively enhance the mechanical properties and energy dissipations of CGBSs through micropore filling and microcrack bridging,and the optimal effect appears at P_(CNT)of 0.08wt%.Taking PSD fractal dimension(D)of 2.500 as an example,compared to that of CGBS without CNT,the peak strength(σ_(p)),axial peak strain(ε_(1,p)),elastic strain energy(Ue),and dissipated energy(U_(d))increased by 12.76%,29.60%,19.05%,and90.39%,respectively.However,excessive CNTs can reduce the mechanical properties of CGBSs due to CNT agglomeration,manifesting a decrease inρ_(p),ε_(1,p),and the volumetric strain increment(Δε_(v))when P_(CNT)increases from 0.08wt%to 0.12wt%.Moreover,the addition of CNTs improved the integrity of CGBS after macroscopic failure,and crack extension in CGBSs appeared in two modes:detour and pass through the aggregates.Theσ_(p)and U_(d)firstly increase and then decrease with increasing D,and porosity shows the opposite trend.Theε_(1,p)andΔε_(v)are negatively correlated with D,and CGBS with D=2.150 has the maximum deformation parameters(ε_(1,p)=0.05079,Δε_(v)=0.01990)due to the frictional slip effect caused by coarse aggregates.With increasing D,the failure modes of CGBSs are sequentially manifested as oblique shear failure,"Y-shaped"shear failure,and conjugate shear failure.展开更多
To explore air contamination resulting from special biomass combustion and suspended dust in Lhasa,the present study focused on the size distribution and chemical characteristics of particulate matter(PM)emission resu...To explore air contamination resulting from special biomass combustion and suspended dust in Lhasa,the present study focused on the size distribution and chemical characteristics of particulate matter(PM)emission resulting from 7 types of non-fossil pollution sources.We investigated the concentration and size distribution of trace elements from 7 pollution sources collected in Lhasa.Combining Lhasa’s atmospheric particulate matter data,enrichment factors(EFs)have been calculated to examine the potential impact of those pollution sources on the atmosphere quality of Lhasa.The highest mass concentration of total elements of biomass combustion appeared at PM_(0.4),and the second highest concentration existed in the size fraction 0.4-1μm;the higher proportion(12%)of toxicmetals was produced by biomass combustion.The elemental composition of suspended dust and atmospheric particulate matter was close(except for As and Cd);the highest concentration of elements was all noted in PM_(2.5-10)(PM_(3-10)).Potassium was found to be one of the main biomass markers.The proportion of Cu in suspended dust is significantly lower than that of atmospheric particulate matter(0.53%and 3.75%),which indicates that there are other anthropogenic sources.The EFs analysis showed that the Cr,Cu,Zn,and Pb produced by biomass combustion were highly enriched(EFs>100)in all particle sizes.The EFs of most trace elements increased with decreasing particle size,indicating the greater influence of humanfactors on smaller particles.展开更多
Developing the railway transport sector is a challenging scientific,economic and social research topic starting with ensuring human security.The main topic that should be developed in that sense is the ballast stabili...Developing the railway transport sector is a challenging scientific,economic and social research topic starting with ensuring human security.The main topic that should be developed in that sense is the ballast stability and dynamical behaviour under external loading and environmental changes.This paper investigates the effect of particle size distribution and normal pressure on the mechanical response of a ballast bed.Grading curves of ballast layers with different sizes are illustrated to discuss their strength behaviour under various strains to deduce the significant effect on the direct shear performance of the ballast layer.Direct shear tests with different Particle Size Distribution(PSD)were reproduced using the Discrete Element Method(DEM).It is noticed that when the number of small-sized ballast increases,the shear strength and the friction angle increase to varying degrees under different normal pressures,with an average increase of 27%and 8%,respectively.When the number of large-sized ballast decreases,the shear strength and the friction angle decrease to varying degrees under different normal pressures,with an average decrease of 6%and 3%,respectively.展开更多
The raindrop size distribution(DSD) is a significant characteristic of precipitation physics,which plays a crucial role in improving the accuracy of radar quantitative precipitation estimation and prediction.There is ...The raindrop size distribution(DSD) is a significant characteristic of precipitation physics,which plays a crucial role in improving the accuracy of radar quantitative precipitation estimation and prediction.There is an effect of atmospheric circulation and weather sy stems in South China,with frequent precipitation and differences in regional features,resulting in a limited understanding of the DSD characteristics and their impact mechanisms in the region. In this study,six ground-based two-dimensional video di sdrometers(2DVDs) were used to analyze the DSD of inland and coastal in South China during the five-year(2016-2020) monsoon seasons(April to September),ERA5 reanalysis data and MODIS cloud property products were also used to investigate the dynamics and microphysical characteristics of monsoon precipitation.Compared to inland rainfall,coastal rainfall has a higher conentration of small,medium,and diameter of less than 4.7 mm large raindrops.Considering the contributions to precipitation,the inland and coastal rainfall are dominated by convective rain,accounting for 74.8% and 84.7% of the total rainfall,respectively.The coastal rainfall has a higher the mass-weiglited mean diameter(D_(m)) value than the inland rainfall D_(m) for both the stratiform and convective rainfall.The logarithmic mean of the generalized intercept parameter(log_(10)N_(w)) in inland stratiform rain is greater than that in coastal areas,while convective rain is relatively small.Due to the impact of precipitation types and climate conditions,The Z-R relationship between inland and coastal rainfall also shows obvious differences.Compared to inland areas,there is more frequent convective activity,relatively moist near-surface conditions,and lower cloud droplet number concentrations,which contribute to larger D_(m) of raindrops in coastal areas.This study deepens the understanding of changes in South China's coastal and inland DSD and provides support for improving numerical weather forecasting in the region.展开更多
Accurate simulation of ice accretion of supercooled large droplet(SLD)is pivotal for the international airworthiness certification of large aircraft.Its complex dynamics behavior and broad particle size distributions ...Accurate simulation of ice accretion of supercooled large droplet(SLD)is pivotal for the international airworthiness certification of large aircraft.Its complex dynamics behavior and broad particle size distributions pose significant challenges to reliable CFD predictions.A numerical model of multi-particle SLD coupling breaking,bouncing and splashing behaviors is established to explore the relationship between dynamics behavior and particle size.The results show that the peak value of droplet collection efficiencyβdecreases due to splashing.The bounce phenomenon will make the impact limit S_(m)of the water drops decrease.With the increase of the SLD particle size,the water drop bounce point gradually moves toward the trailing edge of the wing.The critical breaking diameter of SLD at an airflow velocity of 50 m/s is approximately 100μm.When the SLD particle size increases,the height of the water droplet shelter zone on the upper edge of the wing gradually decreases,and the velocity in the Y direction decreases first and then increases in the opposite direction,increasing the probability of SLD hitting the wing again.Large particle droplets have a higher effect on the impact limit S_(m)than smaller droplets.Therefore,in the numerical simulation of the SLD operating conditions,it is very important to ensure the proportion of large particle size water droplets.展开更多
The investigation of whether sediment samples contain representative grain size distribution information is important for the accurate extraction of sediment characteristics and conduct of related sedimentary record s...The investigation of whether sediment samples contain representative grain size distribution information is important for the accurate extraction of sediment characteristics and conduct of related sedimentary record studies.This study comparatively analyzed the numerical and qualitative differences and the degree of correlation of 36 sets of the characteristic parameters of surface sediment parallel sample grain size distribution from three sampling profiles at Jinsha Bay Beach in Zhanjiang,western Guangdong.At each sampling point,five parallel subsamples were established at intervals of 0,10,20,50,and 100 cm along the coastline.The research findings indicate the following:1)relatively large differences in the mean values of the different parallel samples(0.19–0.34Φ),with smaller differences observed in other characteristic grain sizes(D_(10),D_(50),and D_(90));2)small differences in characteristic values among various parallel sample grain size parameters,with at least 33%of the combinations of qualitative results showing inconsistency;3)50%of the regression equations between the skewness of different parallel samples displaying no significant correlation;4)relative deviations of−47.91%to 27.63%and−49.20%to 2.08%existing between the particle size parameters of a single sample and parallel samples(with the average obtained)at intervals of 10 and 50 cm,respectively.As such,small spatial differences,even within 100 cm,can considerably affect grain size parameters.Given the uncertain reasons underlying the representativeness of the samples,which may only cover the area immediately surrounding the sampling station,researchers are advised to design parallel sample collection strategies based on the spatiotemporal distribution characteristics of the parameters of interest during sediment sample collection.This study provides a typical case of the comparative analysis of parallel sample grain size parameters,with a focus on small spatial beach sediment,which contributes to the enhanced understanding of the accuracy and reliability of sediment sample collection strategies and extraction of grain size information.展开更多
A double-moment cloud microphysics scheme requires an assumption for cloud droplet size distributions(DSDs).However,since observations of cloud DSDs are limited,default values for shape parameters and cloud condensati...A double-moment cloud microphysics scheme requires an assumption for cloud droplet size distributions(DSDs).However,since observations of cloud DSDs are limited,default values for shape parameters and cloud condensation nuclei activation parameters are often used in numerical simulations.In this study,the effects of cloud DSDs on numerical simulations of warm stratiform precipitation around Tokyo are investigated using the Japan Meteorological Agency's non-hydrostatic model,which incorporates a double-moment cloud microphysics scheme.Simulations using the default cloud DSD showed higher cloud droplet number concentrations and lower radar reflectivity than observed data,suggesting that the default cloud DSD is too narrow.Simulations with a cloud DSD based on in situ cloud observations corrected these errors.In addition,observation-based cloud DSDs affected rainfall amounts through the autoconversion rate of cloud water and improved the threat scores.These results suggest that realistic cloud DSDs should be provided for double-moment cloud microphysics schemes in scientific studies.展开更多
Application of particle image velocity (PIV) techniques for measuringparticle size distribution and total number in an activation chamber of desulfurization system isintroduced. Watersheld algorithm is used to choose ...Application of particle image velocity (PIV) techniques for measuringparticle size distribution and total number in an activation chamber of desulfurization system isintroduced. Watersheld algorithm is used to choose the suitable initial gray level threshold whichis used to change the gray level images taken by PIV to black and white ones, then every particle inan image is isolated totally. For every isolating particle, its contour is tracked by the edgeenhancement filter function and kept by Freeman s chain code. Based on a set of particle s chincode, its size and size distribution are calculated and sorted. Finally, the experimental data ofcalcium particles and water drops, separately injected into the activation chamber, and the erroranalysis of data are given out.展开更多
Size distribution characteristics of intercity bus hubs in China from 1997 to 2(104 were analyzed regarding highway passenger volume as a size index of intercity bus hubs. Yearly fractal dimensions of intercity bus h...Size distribution characteristics of intercity bus hubs in China from 1997 to 2(104 were analyzed regarding highway passenger volume as a size index of intercity bus hubs. Yearly fractal dimensions of intercity bus hub sizes were exactly calculated by a novel model. Fractal dimensions of the 200 biggest intercity bus hubs from 2000 to 2004 were 1. 486 2 to 1. 511 8, and that is consistent with fractal dimensions of Chinese urban system sizes. It showed that the size distribution of intercity bus hubs had fractal structure. Fractal dimensions from 1997 to 2004 indicated that intercity bus hub size distribution grew from bi-fractal to single fractal. It is concluded that the intercity bus hub system is in evolutionary progress, and the Central Government should support large intercity bus hubs more to optimize system structure.展开更多
The aerosol number concentration and size distribution were measured with the newly developed Wide-range Particle Spectrometer in summer and winter of 2006 at the urban site of Jinan City. Here reported the characteri...The aerosol number concentration and size distribution were measured with the newly developed Wide-range Particle Spectrometer in summer and winter of 2006 at the urban site of Jinan City. Here reported the characteristics of fine particles of the different observation seasons. Relative high number concentrations for the particles in the diameter range of 10-500 nm were observed in both seasons. It was found that the dominant number distributed in particle diameter smaller than 100 nm and the percentage over the number concentration of all air particles is much higher than what has been measured in other urban sites over the world. The number mean diameter in summer was much smaller than in winter, strongly suggesting the different origin of ultrafine particles in different seasons. That is, particles in ultrafine mode mainly came from nucleation and new particle formation in summer while from traffic emission in winter. The diurnal variation also supported this point. Number concentration in the diameter range of 10-200 um got their peak values at noontime, well correlated with the mixing ratio of SO2 and the intensity of solar radiation in summer. While in winter, those in the same diameter range showed the main peaks during the traffic hours happened in the morning and evening.展开更多
Particles of dust washed off streets by stormwater are an important pathway of polyaromatic hydrocarbons (PAHs) into urban streams. This article presented a comprehensive assessment of the size distribution of PAHs ...Particles of dust washed off streets by stormwater are an important pathway of polyaromatic hydrocarbons (PAHs) into urban streams. This article presented a comprehensive assessment of the size distribution of PAHs in street dust particles, the potential risks of the particles in urban streams, and the sources and sinks of PAHs in the stream network. This assessment was based on measurements of 16 PAHs from the USEPA priority list in street dust particles and river sediments in Xincheng, China. The content of total PAHs ranged from 1629 to 8986 Dg/kg in street dust particles, where smaller particles have a higher concentrations. Approximately 55% of the total PAHs were associated with particles less than 250 μm which accounted for 40% of the total mass of street dust. The PAH quantities increased from 2.41 to 46.86 μg/m2 in the sequence of new residential, rising through main roads, old town residential, commercial and industrial areas. The sediments in stream reaches in town were found to be sinks for street dust particle PAHs. The research findings suggested that particle size, land use and the hydrological conditions in the stream network were the factors which most influenced the total loads of PAH in the receiving water bodies.展开更多
Microphysical characteristics of the raindrop size distribution(RSD)in Typhoon Morakot(2009) have been studied through the PARSIVEL disdrometer measurements at one site in Fujian province,China during the passage of t...Microphysical characteristics of the raindrop size distribution(RSD)in Typhoon Morakot(2009) have been studied through the PARSIVEL disdrometer measurements at one site in Fujian province,China during the passage of the storm from 7 to 10 August 2009.The time evolution of the RSD reveals different segments of the storm.Significant difference was observed in the microphysical characteristics between the outer rainband and the eyewall;the eyewall precipitation had a broader size distribution(a smaller slope) than the outer rainband and eye region.The outer rainband and the eye region produced stratiform rains while the eyewall precipitation was convective or mixed stratiform-convective.The RSD was typically characterized by a single peak distribution and well represented by the gamma distribution.The relations between the shape(μ)and slope(Λ)of the gamma distribution and between the reflectivity(Z)and rainfall rate(R)have been investigated.Based on the NW-Dm relationships,we suggest that the stratiform rain for the outer rainband and the eye region was formed by the melting of graupel or rimed ice particles,which likely originated from the eyewall clouds.展开更多
The characteristics of raindrop size distribution (DSD) over the Tibetan Plateau and southern China are studied in this paper, using the DSD data from April to August 2014 collected by HSC-PS32 disdrometers in Nagqu...The characteristics of raindrop size distribution (DSD) over the Tibetan Plateau and southern China are studied in this paper, using the DSD data from April to August 2014 collected by HSC-PS32 disdrometers in Nagqu and Yangjiang, com- prising a total of 9430 and 63661-rain raindrop spectra, respectively. The raindrop spectra, characteristics of parameter variations with rainfall rate, and the relationships between reflectivity factor (Z) and rainfall rate (R) are analyzed, as well as their DSD changes with precipitation type and rainfall rate. The results show that the average raindrop spectra appear to be one-peak curves, the number concentration for larger drops increase significantly with rainfall rate, and its value over southern China is much higher, especially in convective rain larger drops, especially for convective rain in southern China. Standardized Gamma distributions better describe DSD for All three Gamma parameters for stratiform precipitation over the Tibetan Plateau are much higher, while its shape parameter (,u) and mass-weighted mean diameter (Dm), for convective precipitation, are less. In terms of parameter variation with rainfall rate, the normalized intercept parameter (Nw) over the Tibetan Plateau for stratiform rain increases with rainfall rate, which is opposite to the situation in convective rain. The/1 over the Tibetan Plateau for stratiform and convective precipitation types decreases with an increase in rainfall rate, which is opposite to the case for Dm variation. In Z-R relationships, like "Z = ARb'', the coefficient A over the Tibetan Plateau is smaller, while its b is higher, when the rain type transfers from stratiform to convective ones. Furthermore, with an increase in rainfall rate, parameters A and b over southern China increase gradually, while A over the Tibetan Plateau decreases sub- stantially, which differs from the findings of previous studies. In terms of geographic location and climate over the Tibetan Plateau and southern China, the precipitation in the pre-flood seasons is dominated by strong convective rain, while weak convective rain occurs frequently in northern Tibet with lower humidity and higher altitude.展开更多
The Mg-Gd-Y-Zn-Zr alloys are representational and potential age-hardening systems as reported in the past ten years,but their mechanical properties are still dependent on the grain size and its distribution.The effect...The Mg-Gd-Y-Zn-Zr alloys are representational and potential age-hardening systems as reported in the past ten years,but their mechanical properties are still dependent on the grain size and its distribution.The effect of bimodal structure on mechanical properties of Mg-8Gd-3Y-0.5Zr alloy with bimodal grain size distributions was investigated.The results suggested that the volume fraction of fine grain(FG)and coarse grain(CG)could be controlled by combined processes of hot forging,extrusion and annealing.And for the present alloys with bimodal grain size distribution,the improvement of strength is still attributed to the grain refinement.The morphology of bimodal grain size distribution has a marked impact on the ductility of the alloy,i.e.with the increase of coarse grain volume fraction,the elongation to failure increases at the beginning and then decreases.The mechanism of the toughening effect of bimodal grain size distribution on the Mg-Gd-Y-Zn-Zr alloys with bimodal grain size structure has been discussed.展开更多
To investigate the impact on urban air pollution by crop residual burning outside Nanjing, aerosol concentration, pollution gas concentration, mass concentration, and water-soluble ion size distribution were observed ...To investigate the impact on urban air pollution by crop residual burning outside Nanjing, aerosol concentration, pollution gas concentration, mass concentration, and water-soluble ion size distribution were observed during one event of November 4-9, 2010. Results show that the size distribution of aerosol concentration is bimodal on pollution days and normal days, with peak values at 60- 70 and 200-300 nm, respectively. Aerosol concentration is 104 cm-3.nm-1 on pollution days. The peak value of spectrum distribution of aerosol concentration on pollution days is 1.5-3.3 times higher than that on a normal day. Crop residual burning has a great impact on the concentration of fine particles. Diurnal variation of aerosol concentration is trimodal on pollution days and normal days, with peak values at 03:00, 09:00 and 19:00 local standard time. The first peak is impacted by meteorological elements, while the second and third peaks are due to human activities, such as rush hour traffic. Crop residual burning has the greatest impact on SO2 concentration, followed by NO2, 03 is hardly affected. The impact of crop residual burning on fine particles (〈 2.1 μm) is larger than on coarse particles (〉 2.1 μm), thus ion concentration in fine particles is higher than that in coarse particles. Crop residual burning leads to similar increase in all ion components, thus it has a small impact on the water-soluble ions order. Crop residual burning has a strong impact on the size distribution of K^+, Cl^-, Na^+, and F- and has a weak impact on the size distributions of NH4^+, Ca^2+, NO3^- and SO4^2-.展开更多
Nanobubble flotation technology is an important research topic in the field of fine mineral particle separation.The basic characteristics of nanobubbles,including their size,concentration,surface zeta potential,and st...Nanobubble flotation technology is an important research topic in the field of fine mineral particle separation.The basic characteristics of nanobubbles,including their size,concentration,surface zeta potential,and stability have a significant impact on the nanobubble flotation performance.In this paper,bulk nanobubbles generated based on the principle of hydrodynamic cavitation were investigated to determine the effects of different parameters(e.g.,surfactant(frother)dosage,air flow,air pressure,liquid flow rate,and solution pH value)on their size distribution and zeta potential,as measured using a nanoparticle analyzer.The results demonstrated that the nanobubble size decreased with increasing pH value,surfactant concentration,and cavitation-tube liquid flow rate but increased with increasing air pressure and increasing air flow rate.The magnitude of the negative surface charge of the nanobubbles was positively correlated with the pH value,and a certain relationship was observed between the zeta potential of the nanobubbles and their size.The structural parameters of the cavitation tube also strongly affected the characteristics of the nanobubbles.The results of this study offer certain guidance for optimizing the nanobubble flotation technology.展开更多
New particle formation is a key process in shaping the size distribution of aerosols in the atmosphere.We present here the measurement results of number and size distribution of aerosol particles (10–10000 nm in dia...New particle formation is a key process in shaping the size distribution of aerosols in the atmosphere.We present here the measurement results of number and size distribution of aerosol particles (10–10000 nm in diameter) obtained in the summer of 2008,at a suburban site in Beijing,China.We firstly reported the pollution level,particle number size distribution,diurnal variation of the particle number size distribution and then introduced the characteristics of the particle formation processes.The results showed that the number concentration of ultrafine particles was much lower than the values measured in other urban or suburban areas in previous studies.Sharp increases of ultrafine particle count were frequently observed at noon.An examination of the diurnal pattern suggested that the burst of ultrafine particles was mainly due to new particle formation promoted by photochemical processes.In addition,high relative humidity was a key factor driving the growth of the particles in the afternoon.During the 2-month observations,new particle formation from homogeneous nucleation was observed for 42.7% of the study period.The average growth rate of newly formed particles was 3.2 nm/hr,and varied from 1.2 to 8.0 nm/hr.The required concentration of condensable vapor was 4.4×10 7 cm-3,and its source rate was 1.2×10 6 cm-3 sec-1.Further calculation on the source rate of sulphuric acid vapor indicated that the average participation of sulphuric acid to particle growth rates was 28.7%.展开更多
In the present study,AZ31 magnesium alloy sheets were processed by friction stir processing(FSP)to investigate the effect of the grain refinement and grain size distribution on the corrosion behavior.Grain refinement ...In the present study,AZ31 magnesium alloy sheets were processed by friction stir processing(FSP)to investigate the effect of the grain refinement and grain size distribution on the corrosion behavior.Grain refinement from a starting size of 16.4±6.8µm to 3.2±1.2µm was attained after FSP.Remarkably,bimodal grain size distribution was observed in the nugget zone with a combination of coarse(11.62±8.4µm)and fine grains(3.2±1.2µm).Due to the grain refinement,a slight improvement in the hardness was found in the nugget zone of FSPed AZ31.The bimodal grain size distribution in the stir zone showed pronounced influence on the corrosion rate of FSPed AZ31 as observed from the immersion and electrochemical tests.From the X-ray diffraction analysis,more amount of Mg(OH)_(2) was observed on FSPed AZ31 compared with the unprocessed AZ31.Polarization measurements demonstrated the higher corrosion current density for FSPed AZ31(8.92×10^(−5)A/cm^(2))compared with the unprocessed condition(2.90×10^(−5)A/cm^(2))that can be attributed to the texture effect and large variations in the grain size which led to non-uniform galvanic intensities.展开更多
In order to understand the size distribution and the main kind of heavy metals in particulate matter on the lead and zinc smelting affected area, particulate matter (PM) and the source samples were collected in Zhuz...In order to understand the size distribution and the main kind of heavy metals in particulate matter on the lead and zinc smelting affected area, particulate matter (PM) and the source samples were collected in Zhuzhou, Hunan Province from December 2011 to January 2012 and the results were discussed and interpreted. Atmospheric particles were collected with different sizes by a cascade impactor. The concentrations of heavy metals in atmospheric particles of different sizes, collected from the air and from factories, were measured using an inductively coupled plasma mass spectrometry (ICP-MS). The results indicated that the average concentration of PM, chromium (Cr), arsenic (As), cadmium (Cd) and lead (Pb) in PM was 177.3 ± 33.2 μg/m^3, 37.3 ± 8.8 ng/m^3, 17.3 ± 8.1 ng/m^3, 4.8 ± 3.1 ng/m^3 and 141.6 ± 49.1 ng/m^3, respectively. The size distribution of PM displayed a bimodal distribution; the maximum PM size distribution was at 1.1-2.1 μm, followed by 9-10 μm. The size distribution of As, cd and Pb in PM was similar to the distribution of the PM mass, with peaks observed at the range of 1.1-2.1 μm and 9-10 μm ranges while for Cr, only a single-mode at 4.7-5.8 μm was observed. PM (64.7%, As (72.5%), cd (72.2%) and Pb (75.8%) were associated with the fine mode below 2.1 μm, respectively, while Cr (46.6%) was associated with the coarse mode. The size distribution characteristics, enrichment factor, correlation coefficient values, source information and the analysis of source samples showed that As, Cd and Pb in PM were the typical heavy metal in lead and zinc smelting affected areas, which originated mainly from lead and zinc smelting sources.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.42325503,42075063,42075066,and 42021004)the Hubei Provincial Natural Science Foundation and the Meteorological Innovation and Development Project of China(Grant No.2023AFD096)the Beijige Foundation of NJIAS(Grant No.BJG202304).
文摘The characteristics of summertime raindrop size distribution(DSD) and associated relations in the semi-arid region over the Inner Mongolian Plateau(IMP) were investigated,utilizing five-year continuous observations by a PARSIVEL2disdrometer in East Ujimqin County(EUC),China.It is found that only 7.94% of the 15 664 one-min precipitation samples meet classification criteria as convective rain(CR),but its contribution to the total rainfall amount is 63.87%.Notably,40.72% of the rainfall comes from large-sized raindrops(D> 3 mm),despite the fact that large-sized raindrops account for only 1.73% of the CR total number concentration.Further results show that the mean value of mass-weighted mean diameters(Dm) is larger(2.43 mm) and generalized intercepts(lgN_(W)) is lower(3.19) in CR,aligning with a "continentallike" cluster,which is mainly influenced by the joint impact of in-cloud ice-based processes and the below-cloud environmental background.Also,the empirical relationships of shape-slope(μ-Λ),radar reflectivity-rain rate(Z-R),and rainfall kinetic energy(KE_(time)-Rand KE_(time)-Z) are localized.To quantitatively analyze the impact of DSD parameters on kinetic energy estimation,power-law KE_(time)-R and KE_(time)-Z relationships are derived based on the normalized gamma distribution.N_(W)takes precedence over μ in affecting variabilities of multiplicative coefficients,especially for KE_(time)-R relationship where the multiplicative coefficient is proportional to N_(W)^(-0.287).It should be noted that although the proportion of CR occurring throughout the summer is small,raindrops with lower N_(W) and larger Dmwill generate higher KE_(time),which will bring a higher potential risk of soil erosion in semi-arid regions over IMP.
基金financially supported by the National Natural Science Foundation of China(Nos.52174092,51904290,and 52374147)the Natural Science Foundation of Jiangsu Province,China(No.BK20220157)+2 种基金the Fundamental Research Funds for the Central Universities,China(No.2022YCPY0202)the National Key Research and Development Program of China(No.2023YFC3804204)the Major Program of Xinjiang Uygur Autonomous Region S cience and Technology(No.2023A01002)。
文摘The mechanical behavior of cemented gangue backfill materials(CGBMs)is closely related to particle size distribution(PSD)of aggregates and properties of cementitious materials.Consequently,the true triaxial compression tests,CT scanning,SEM,and EDS tests were conducted on cemented gangue backfill samples(CGBSs)with various carbon nanotube concentrations(P_(CNT))that satisfied fractal theory for the PSD of aggregates.The mechanical properties,energy dissipations,and failure mechanisms of the CGBSs under true triaxial compression were systematically analyzed.The results indicate that appropriate carbon nanotubes(CNTs)effectively enhance the mechanical properties and energy dissipations of CGBSs through micropore filling and microcrack bridging,and the optimal effect appears at P_(CNT)of 0.08wt%.Taking PSD fractal dimension(D)of 2.500 as an example,compared to that of CGBS without CNT,the peak strength(σ_(p)),axial peak strain(ε_(1,p)),elastic strain energy(Ue),and dissipated energy(U_(d))increased by 12.76%,29.60%,19.05%,and90.39%,respectively.However,excessive CNTs can reduce the mechanical properties of CGBSs due to CNT agglomeration,manifesting a decrease inρ_(p),ε_(1,p),and the volumetric strain increment(Δε_(v))when P_(CNT)increases from 0.08wt%to 0.12wt%.Moreover,the addition of CNTs improved the integrity of CGBS after macroscopic failure,and crack extension in CGBSs appeared in two modes:detour and pass through the aggregates.Theσ_(p)and U_(d)firstly increase and then decrease with increasing D,and porosity shows the opposite trend.Theε_(1,p)andΔε_(v)are negatively correlated with D,and CGBS with D=2.150 has the maximum deformation parameters(ε_(1,p)=0.05079,Δε_(v)=0.01990)due to the frictional slip effect caused by coarse aggregates.With increasing D,the failure modes of CGBSs are sequentially manifested as oblique shear failure,"Y-shaped"shear failure,and conjugate shear failure.
基金supported by the Natural Science Foundation of China (No.11775180).
文摘To explore air contamination resulting from special biomass combustion and suspended dust in Lhasa,the present study focused on the size distribution and chemical characteristics of particulate matter(PM)emission resulting from 7 types of non-fossil pollution sources.We investigated the concentration and size distribution of trace elements from 7 pollution sources collected in Lhasa.Combining Lhasa’s atmospheric particulate matter data,enrichment factors(EFs)have been calculated to examine the potential impact of those pollution sources on the atmosphere quality of Lhasa.The highest mass concentration of total elements of biomass combustion appeared at PM_(0.4),and the second highest concentration existed in the size fraction 0.4-1μm;the higher proportion(12%)of toxicmetals was produced by biomass combustion.The elemental composition of suspended dust and atmospheric particulate matter was close(except for As and Cd);the highest concentration of elements was all noted in PM_(2.5-10)(PM_(3-10)).Potassium was found to be one of the main biomass markers.The proportion of Cu in suspended dust is significantly lower than that of atmospheric particulate matter(0.53%and 3.75%),which indicates that there are other anthropogenic sources.The EFs analysis showed that the Cr,Cu,Zn,and Pb produced by biomass combustion were highly enriched(EFs>100)in all particle sizes.The EFs of most trace elements increased with decreasing particle size,indicating the greater influence of humanfactors on smaller particles.
基金"PSPC Régions n°2"("Projets Structurants des Pôles de Compétitivitéen région")funded by Conseil Régional Hauts-de-France and BPI.
文摘Developing the railway transport sector is a challenging scientific,economic and social research topic starting with ensuring human security.The main topic that should be developed in that sense is the ballast stability and dynamical behaviour under external loading and environmental changes.This paper investigates the effect of particle size distribution and normal pressure on the mechanical response of a ballast bed.Grading curves of ballast layers with different sizes are illustrated to discuss their strength behaviour under various strains to deduce the significant effect on the direct shear performance of the ballast layer.Direct shear tests with different Particle Size Distribution(PSD)were reproduced using the Discrete Element Method(DEM).It is noticed that when the number of small-sized ballast increases,the shear strength and the friction angle increase to varying degrees under different normal pressures,with an average increase of 27%and 8%,respectively.When the number of large-sized ballast decreases,the shear strength and the friction angle decrease to varying degrees under different normal pressures,with an average decrease of 6%and 3%,respectively.
基金National Natural Science Foundation of China(U2242203, 41975138, 42075086, 42275008)Guangdong Basic and Applied Basic Research Foundation (2023A1515011971)Science Technology Research Program of Guangdong Meteorological Service (GRMC2021Q01)。
文摘The raindrop size distribution(DSD) is a significant characteristic of precipitation physics,which plays a crucial role in improving the accuracy of radar quantitative precipitation estimation and prediction.There is an effect of atmospheric circulation and weather sy stems in South China,with frequent precipitation and differences in regional features,resulting in a limited understanding of the DSD characteristics and their impact mechanisms in the region. In this study,six ground-based two-dimensional video di sdrometers(2DVDs) were used to analyze the DSD of inland and coastal in South China during the five-year(2016-2020) monsoon seasons(April to September),ERA5 reanalysis data and MODIS cloud property products were also used to investigate the dynamics and microphysical characteristics of monsoon precipitation.Compared to inland rainfall,coastal rainfall has a higher conentration of small,medium,and diameter of less than 4.7 mm large raindrops.Considering the contributions to precipitation,the inland and coastal rainfall are dominated by convective rain,accounting for 74.8% and 84.7% of the total rainfall,respectively.The coastal rainfall has a higher the mass-weiglited mean diameter(D_(m)) value than the inland rainfall D_(m) for both the stratiform and convective rainfall.The logarithmic mean of the generalized intercept parameter(log_(10)N_(w)) in inland stratiform rain is greater than that in coastal areas,while convective rain is relatively small.Due to the impact of precipitation types and climate conditions,The Z-R relationship between inland and coastal rainfall also shows obvious differences.Compared to inland areas,there is more frequent convective activity,relatively moist near-surface conditions,and lower cloud droplet number concentrations,which contribute to larger D_(m) of raindrops in coastal areas.This study deepens the understanding of changes in South China's coastal and inland DSD and provides support for improving numerical weather forecasting in the region.
基金supported in part by the National Natural Science Foundation of China(No.52276009)。
文摘Accurate simulation of ice accretion of supercooled large droplet(SLD)is pivotal for the international airworthiness certification of large aircraft.Its complex dynamics behavior and broad particle size distributions pose significant challenges to reliable CFD predictions.A numerical model of multi-particle SLD coupling breaking,bouncing and splashing behaviors is established to explore the relationship between dynamics behavior and particle size.The results show that the peak value of droplet collection efficiencyβdecreases due to splashing.The bounce phenomenon will make the impact limit S_(m)of the water drops decrease.With the increase of the SLD particle size,the water drop bounce point gradually moves toward the trailing edge of the wing.The critical breaking diameter of SLD at an airflow velocity of 50 m/s is approximately 100μm.When the SLD particle size increases,the height of the water droplet shelter zone on the upper edge of the wing gradually decreases,and the velocity in the Y direction decreases first and then increases in the opposite direction,increasing the probability of SLD hitting the wing again.Large particle droplets have a higher effect on the impact limit S_(m)than smaller droplets.Therefore,in the numerical simulation of the SLD operating conditions,it is very important to ensure the proportion of large particle size water droplets.
基金supported by the Innovation Driven Development Foundation of Guangxi(No.AD22080035)the Open Project Funding of the Key Laboratory of Tropical Marine Ecosystem and Bioresource,Ministry of Natural Resources(No.2023-QN04)+1 种基金the Guangdong Provincial Ordinary University Youth Innovative Talent Project in 2024(No.2024KQNCX134)the Guangdong Provincial Special Fund Project for Talent Development Strategy in 2024(No.2024R3005).
文摘The investigation of whether sediment samples contain representative grain size distribution information is important for the accurate extraction of sediment characteristics and conduct of related sedimentary record studies.This study comparatively analyzed the numerical and qualitative differences and the degree of correlation of 36 sets of the characteristic parameters of surface sediment parallel sample grain size distribution from three sampling profiles at Jinsha Bay Beach in Zhanjiang,western Guangdong.At each sampling point,five parallel subsamples were established at intervals of 0,10,20,50,and 100 cm along the coastline.The research findings indicate the following:1)relatively large differences in the mean values of the different parallel samples(0.19–0.34Φ),with smaller differences observed in other characteristic grain sizes(D_(10),D_(50),and D_(90));2)small differences in characteristic values among various parallel sample grain size parameters,with at least 33%of the combinations of qualitative results showing inconsistency;3)50%of the regression equations between the skewness of different parallel samples displaying no significant correlation;4)relative deviations of−47.91%to 27.63%and−49.20%to 2.08%existing between the particle size parameters of a single sample and parallel samples(with the average obtained)at intervals of 10 and 50 cm,respectively.As such,small spatial differences,even within 100 cm,can considerably affect grain size parameters.Given the uncertain reasons underlying the representativeness of the samples,which may only cover the area immediately surrounding the sampling station,researchers are advised to design parallel sample collection strategies based on the spatiotemporal distribution characteristics of the parameters of interest during sediment sample collection.This study provides a typical case of the comparative analysis of parallel sample grain size parameters,with a focus on small spatial beach sediment,which contributes to the enhanced understanding of the accuracy and reliability of sediment sample collection strategies and extraction of grain size information.
基金supported by Grants in Aid from the Japan Society for the Promotion of Science(JSPS)KAKENHI[grant numbers JP21H01163 and JP23H00149].
文摘A double-moment cloud microphysics scheme requires an assumption for cloud droplet size distributions(DSDs).However,since observations of cloud DSDs are limited,default values for shape parameters and cloud condensation nuclei activation parameters are often used in numerical simulations.In this study,the effects of cloud DSDs on numerical simulations of warm stratiform precipitation around Tokyo are investigated using the Japan Meteorological Agency's non-hydrostatic model,which incorporates a double-moment cloud microphysics scheme.Simulations using the default cloud DSD showed higher cloud droplet number concentrations and lower radar reflectivity than observed data,suggesting that the default cloud DSD is too narrow.Simulations with a cloud DSD based on in situ cloud observations corrected these errors.In addition,observation-based cloud DSDs affected rainfall amounts through the autoconversion rate of cloud water and improved the threat scores.These results suggest that realistic cloud DSDs should be provided for double-moment cloud microphysics schemes in scientific studies.
基金The Special Funds for State Key Projects for Fun- damental Research (G1999022201-04).
文摘Application of particle image velocity (PIV) techniques for measuringparticle size distribution and total number in an activation chamber of desulfurization system isintroduced. Watersheld algorithm is used to choose the suitable initial gray level threshold whichis used to change the gray level images taken by PIV to black and white ones, then every particle inan image is isolated totally. For every isolating particle, its contour is tracked by the edgeenhancement filter function and kept by Freeman s chain code. Based on a set of particle s chincode, its size and size distribution are calculated and sorted. Finally, the experimental data ofcalcium particles and water drops, separately injected into the activation chamber, and the erroranalysis of data are given out.
基金The Ph.D.Programs Foundation of Ministry of Edu-cation of China(No20050710006)
文摘Size distribution characteristics of intercity bus hubs in China from 1997 to 2(104 were analyzed regarding highway passenger volume as a size index of intercity bus hubs. Yearly fractal dimensions of intercity bus hub sizes were exactly calculated by a novel model. Fractal dimensions of the 200 biggest intercity bus hubs from 2000 to 2004 were 1. 486 2 to 1. 511 8, and that is consistent with fractal dimensions of Chinese urban system sizes. It showed that the size distribution of intercity bus hubs had fractal structure. Fractal dimensions from 1997 to 2004 indicated that intercity bus hub size distribution grew from bi-fractal to single fractal. It is concluded that the intercity bus hub system is in evolutionary progress, and the Central Government should support large intercity bus hubs more to optimize system structure.
基金Project supported by the National Basic Research Project(973)of China(No.2005CB422203)the National Post-Doctor Foundation of China(No.20060390990).
文摘The aerosol number concentration and size distribution were measured with the newly developed Wide-range Particle Spectrometer in summer and winter of 2006 at the urban site of Jinan City. Here reported the characteristics of fine particles of the different observation seasons. Relative high number concentrations for the particles in the diameter range of 10-500 nm were observed in both seasons. It was found that the dominant number distributed in particle diameter smaller than 100 nm and the percentage over the number concentration of all air particles is much higher than what has been measured in other urban sites over the world. The number mean diameter in summer was much smaller than in winter, strongly suggesting the different origin of ultrafine particles in different seasons. That is, particles in ultrafine mode mainly came from nucleation and new particle formation in summer while from traffic emission in winter. The diurnal variation also supported this point. Number concentration in the diameter range of 10-200 um got their peak values at noontime, well correlated with the mixing ratio of SO2 and the intensity of solar radiation in summer. While in winter, those in the same diameter range showed the main peaks during the traffic hours happened in the morning and evening.
基金supported by the Key Project of Zhe-jiang Province (No. 2006C13057)the CAS Program(No. KZCX1-YW-06-02)the Jiaxing City Project(No. 2005AZ3040).
文摘Particles of dust washed off streets by stormwater are an important pathway of polyaromatic hydrocarbons (PAHs) into urban streams. This article presented a comprehensive assessment of the size distribution of PAHs in street dust particles, the potential risks of the particles in urban streams, and the sources and sinks of PAHs in the stream network. This assessment was based on measurements of 16 PAHs from the USEPA priority list in street dust particles and river sediments in Xincheng, China. The content of total PAHs ranged from 1629 to 8986 Dg/kg in street dust particles, where smaller particles have a higher concentrations. Approximately 55% of the total PAHs were associated with particles less than 250 μm which accounted for 40% of the total mass of street dust. The PAH quantities increased from 2.41 to 46.86 μg/m2 in the sequence of new residential, rising through main roads, old town residential, commercial and industrial areas. The sediments in stream reaches in town were found to be sinks for street dust particle PAHs. The research findings suggested that particle size, land use and the hydrological conditions in the stream network were the factors which most influenced the total loads of PAH in the receiving water bodies.
基金National Natural Science Foundation of China(40730948,40830958,40921160382)National Grand Fundamental Research 973 Program of China(2009CB421502)
文摘Microphysical characteristics of the raindrop size distribution(RSD)in Typhoon Morakot(2009) have been studied through the PARSIVEL disdrometer measurements at one site in Fujian province,China during the passage of the storm from 7 to 10 August 2009.The time evolution of the RSD reveals different segments of the storm.Significant difference was observed in the microphysical characteristics between the outer rainband and the eyewall;the eyewall precipitation had a broader size distribution(a smaller slope) than the outer rainband and eye region.The outer rainband and the eye region produced stratiform rains while the eyewall precipitation was convective or mixed stratiform-convective.The RSD was typically characterized by a single peak distribution and well represented by the gamma distribution.The relations between the shape(μ)and slope(Λ)of the gamma distribution and between the reflectivity(Z)and rainfall rate(R)have been investigated.Based on the NW-Dm relationships,we suggest that the stratiform rain for the outer rainband and the eye region was formed by the melting of graupel or rimed ice particles,which likely originated from the eyewall clouds.
基金supported jointly by the China Meteorological Administration Special Public Welfare Research Fund (Grant No. GYHY201406001)the National (Key) Basic Research and Development (973) Program of China (Grant No. 2012CB417202)the National Natural Science Foundation of China (Grant No. 41175038)
文摘The characteristics of raindrop size distribution (DSD) over the Tibetan Plateau and southern China are studied in this paper, using the DSD data from April to August 2014 collected by HSC-PS32 disdrometers in Nagqu and Yangjiang, com- prising a total of 9430 and 63661-rain raindrop spectra, respectively. The raindrop spectra, characteristics of parameter variations with rainfall rate, and the relationships between reflectivity factor (Z) and rainfall rate (R) are analyzed, as well as their DSD changes with precipitation type and rainfall rate. The results show that the average raindrop spectra appear to be one-peak curves, the number concentration for larger drops increase significantly with rainfall rate, and its value over southern China is much higher, especially in convective rain larger drops, especially for convective rain in southern China. Standardized Gamma distributions better describe DSD for All three Gamma parameters for stratiform precipitation over the Tibetan Plateau are much higher, while its shape parameter (,u) and mass-weighted mean diameter (Dm), for convective precipitation, are less. In terms of parameter variation with rainfall rate, the normalized intercept parameter (Nw) over the Tibetan Plateau for stratiform rain increases with rainfall rate, which is opposite to the situation in convective rain. The/1 over the Tibetan Plateau for stratiform and convective precipitation types decreases with an increase in rainfall rate, which is opposite to the case for Dm variation. In Z-R relationships, like "Z = ARb'', the coefficient A over the Tibetan Plateau is smaller, while its b is higher, when the rain type transfers from stratiform to convective ones. Furthermore, with an increase in rainfall rate, parameters A and b over southern China increase gradually, while A over the Tibetan Plateau decreases sub- stantially, which differs from the findings of previous studies. In terms of geographic location and climate over the Tibetan Plateau and southern China, the precipitation in the pre-flood seasons is dominated by strong convective rain, while weak convective rain occurs frequently in northern Tibet with lower humidity and higher altitude.
基金supports of the National Key Research and Development Plan(Grant Nos.2016YFB0701201 and 2016YFB0301103)the National Natural Science Foundation of China(Grant Nos.51771109 and 51631006).
文摘The Mg-Gd-Y-Zn-Zr alloys are representational and potential age-hardening systems as reported in the past ten years,but their mechanical properties are still dependent on the grain size and its distribution.The effect of bimodal structure on mechanical properties of Mg-8Gd-3Y-0.5Zr alloy with bimodal grain size distributions was investigated.The results suggested that the volume fraction of fine grain(FG)and coarse grain(CG)could be controlled by combined processes of hot forging,extrusion and annealing.And for the present alloys with bimodal grain size distribution,the improvement of strength is still attributed to the grain refinement.The morphology of bimodal grain size distribution has a marked impact on the ductility of the alloy,i.e.with the increase of coarse grain volume fraction,the elongation to failure increases at the beginning and then decreases.The mechanism of the toughening effect of bimodal grain size distribution on the Mg-Gd-Y-Zn-Zr alloys with bimodal grain size structure has been discussed.
基金supported by the National Basic Research Program (973) of China (No. 2010CB428505)the National Natural Science Foundation of China (No. 41030962,40875078)+2 种基金the Research Fund for the Doctoral Program of Higher Education of China (No. 20093228110003)the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe Jiangsu Provinc eGraduate Cultivation Innovative Project (No. CXZZ11-0616)
文摘To investigate the impact on urban air pollution by crop residual burning outside Nanjing, aerosol concentration, pollution gas concentration, mass concentration, and water-soluble ion size distribution were observed during one event of November 4-9, 2010. Results show that the size distribution of aerosol concentration is bimodal on pollution days and normal days, with peak values at 60- 70 and 200-300 nm, respectively. Aerosol concentration is 104 cm-3.nm-1 on pollution days. The peak value of spectrum distribution of aerosol concentration on pollution days is 1.5-3.3 times higher than that on a normal day. Crop residual burning has a great impact on the concentration of fine particles. Diurnal variation of aerosol concentration is trimodal on pollution days and normal days, with peak values at 03:00, 09:00 and 19:00 local standard time. The first peak is impacted by meteorological elements, while the second and third peaks are due to human activities, such as rush hour traffic. Crop residual burning has the greatest impact on SO2 concentration, followed by NO2, 03 is hardly affected. The impact of crop residual burning on fine particles (〈 2.1 μm) is larger than on coarse particles (〉 2.1 μm), thus ion concentration in fine particles is higher than that in coarse particles. Crop residual burning leads to similar increase in all ion components, thus it has a small impact on the water-soluble ions order. Crop residual burning has a strong impact on the size distribution of K^+, Cl^-, Na^+, and F- and has a weak impact on the size distributions of NH4^+, Ca^2+, NO3^- and SO4^2-.
文摘Nanobubble flotation technology is an important research topic in the field of fine mineral particle separation.The basic characteristics of nanobubbles,including their size,concentration,surface zeta potential,and stability have a significant impact on the nanobubble flotation performance.In this paper,bulk nanobubbles generated based on the principle of hydrodynamic cavitation were investigated to determine the effects of different parameters(e.g.,surfactant(frother)dosage,air flow,air pressure,liquid flow rate,and solution pH value)on their size distribution and zeta potential,as measured using a nanoparticle analyzer.The results demonstrated that the nanobubble size decreased with increasing pH value,surfactant concentration,and cavitation-tube liquid flow rate but increased with increasing air pressure and increasing air flow rate.The magnitude of the negative surface charge of the nanobubbles was positively correlated with the pH value,and a certain relationship was observed between the zeta potential of the nanobubbles and their size.The structural parameters of the cavitation tube also strongly affected the characteristics of the nanobubbles.The results of this study offer certain guidance for optimizing the nanobubble flotation technology.
基金supported by the National Department Public Benefit Research Foundation of China (No.201009001)the National Natural Science Foundation of China (No.41005065)the Basic Foundation for Public Benefit-Research Academies from the Central Government (No.2008KYYW01)
文摘New particle formation is a key process in shaping the size distribution of aerosols in the atmosphere.We present here the measurement results of number and size distribution of aerosol particles (10–10000 nm in diameter) obtained in the summer of 2008,at a suburban site in Beijing,China.We firstly reported the pollution level,particle number size distribution,diurnal variation of the particle number size distribution and then introduced the characteristics of the particle formation processes.The results showed that the number concentration of ultrafine particles was much lower than the values measured in other urban or suburban areas in previous studies.Sharp increases of ultrafine particle count were frequently observed at noon.An examination of the diurnal pattern suggested that the burst of ultrafine particles was mainly due to new particle formation promoted by photochemical processes.In addition,high relative humidity was a key factor driving the growth of the particles in the afternoon.During the 2-month observations,new particle formation from homogeneous nucleation was observed for 42.7% of the study period.The average growth rate of newly formed particles was 3.2 nm/hr,and varied from 1.2 to 8.0 nm/hr.The required concentration of condensable vapor was 4.4×10 7 cm-3,and its source rate was 1.2×10 6 cm-3 sec-1.Further calculation on the source rate of sulphuric acid vapor indicated that the average participation of sulphuric acid to particle growth rates was 28.7%.
文摘In the present study,AZ31 magnesium alloy sheets were processed by friction stir processing(FSP)to investigate the effect of the grain refinement and grain size distribution on the corrosion behavior.Grain refinement from a starting size of 16.4±6.8µm to 3.2±1.2µm was attained after FSP.Remarkably,bimodal grain size distribution was observed in the nugget zone with a combination of coarse(11.62±8.4µm)and fine grains(3.2±1.2µm).Due to the grain refinement,a slight improvement in the hardness was found in the nugget zone of FSPed AZ31.The bimodal grain size distribution in the stir zone showed pronounced influence on the corrosion rate of FSPed AZ31 as observed from the immersion and electrochemical tests.From the X-ray diffraction analysis,more amount of Mg(OH)_(2) was observed on FSPed AZ31 compared with the unprocessed AZ31.Polarization measurements demonstrated the higher corrosion current density for FSPed AZ31(8.92×10^(−5)A/cm^(2))compared with the unprocessed condition(2.90×10^(−5)A/cm^(2))that can be attributed to the texture effect and large variations in the grain size which led to non-uniform galvanic intensities.
基金supported by the National Natural Science Foundation of China (No. 41205093)the National Department Public Benefit Research Foundation (No. 201109005)+1 种基金the Fundamental Research Funds for Central Public Welfare Scientific Research Institutes of China (No. 2016YSKY-025)National Research Program for Key Issues in Air Pollution Control (No. DQGG0304)
文摘In order to understand the size distribution and the main kind of heavy metals in particulate matter on the lead and zinc smelting affected area, particulate matter (PM) and the source samples were collected in Zhuzhou, Hunan Province from December 2011 to January 2012 and the results were discussed and interpreted. Atmospheric particles were collected with different sizes by a cascade impactor. The concentrations of heavy metals in atmospheric particles of different sizes, collected from the air and from factories, were measured using an inductively coupled plasma mass spectrometry (ICP-MS). The results indicated that the average concentration of PM, chromium (Cr), arsenic (As), cadmium (Cd) and lead (Pb) in PM was 177.3 ± 33.2 μg/m^3, 37.3 ± 8.8 ng/m^3, 17.3 ± 8.1 ng/m^3, 4.8 ± 3.1 ng/m^3 and 141.6 ± 49.1 ng/m^3, respectively. The size distribution of PM displayed a bimodal distribution; the maximum PM size distribution was at 1.1-2.1 μm, followed by 9-10 μm. The size distribution of As, cd and Pb in PM was similar to the distribution of the PM mass, with peaks observed at the range of 1.1-2.1 μm and 9-10 μm ranges while for Cr, only a single-mode at 4.7-5.8 μm was observed. PM (64.7%, As (72.5%), cd (72.2%) and Pb (75.8%) were associated with the fine mode below 2.1 μm, respectively, while Cr (46.6%) was associated with the coarse mode. The size distribution characteristics, enrichment factor, correlation coefficient values, source information and the analysis of source samples showed that As, Cd and Pb in PM were the typical heavy metal in lead and zinc smelting affected areas, which originated mainly from lead and zinc smelting sources.