The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combi...The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combines numerical simulation with machine learning techniques to explore this issue.It presents a summary of special-shaped tunnel geometries and introduces a shape coefficient.Through the finite element software,Plaxis3D,the study simulates six key parameters—shape coefficient,burial depth ratio,tunnel’s longest horizontal length,internal friction angle,cohesion,and soil submerged bulk density—that impact uplift resistance across different conditions.Employing XGBoost and ANN methods,the feature importance of each parameter was analyzed based on the numerical simulation results.The findings demonstrate that a tunnel shape more closely resembling a circle leads to reduced uplift resistance in the overlying soil,whereas other parameters exhibit the contrary effects.Furthermore,the study reveals a diminishing trend in the feature importance of buried depth ratio,internal friction angle,tunnel longest horizontal length,cohesion,soil submerged bulk density,and shape coefficient in influencing uplift resistance.展开更多
UHMWPE fibers exhibit impressive modulus and strength,but they have not reached their theoretical limits.Researchers focus on molecular weight,orientation,and crystallinity of UHMWPE,yet their contributions to mechani...UHMWPE fibers exhibit impressive modulus and strength,but they have not reached their theoretical limits.Researchers focus on molecular weight,orientation,and crystallinity of UHMWPE,yet their contributions to mechanical properties are unclear.Molecular dynamics simulations are valuable but often limited by computational constraints.Our aim is to simulate higher molecular weights to better represent real UHMWPE fibers.We used Packmol and Polyply methodologies to construct PE systems,with Polyply reproducing more reasonable properties of UHMWPE fibers.Additionally,tensile simulations showed that orientation and crystallinity greatly impact Young's modulus more than molecular weight.Energy decomposition indicated that higher molecular weights lead to covalent bonds that can withstand more energy during stretching,thus increasing breaking strength.Combining simulations with machine learning,we found that orientation has the most significant impact on Young's modulus,contributing 60%,and molecular weight plays the most crucial role in determining the breaking strength,accounting for 65%.This study provides a theoretical basis and guidelines for enhancing UHMWPE's modulus and strength.展开更多
Tunneling diodes hold significant promise for future rectification in the terahertz(THz)and visible light spectra,thanks to their femtosecond-scale transit-time tunneling capabilities.In this work,TiN/ZnO/Pt fin tunne...Tunneling diodes hold significant promise for future rectification in the terahertz(THz)and visible light spectra,thanks to their femtosecond-scale transit-time tunneling capabilities.In this work,TiN/ZnO/Pt fin tunneling diodes(FTDs)with tunneling distances of 10 and 5 nm are fabricated,which demonstrate remarkable characteristics,including ultrahigh asymmetry(1.6×10^(4)for 10 nm device and 1.6×10^(3) for 5 nm device),high responsivity(25.3 V^(-1) for 10 nm device and 28.3 V^(-1) for 5 nm device)at zero bias,surpassing the thermal voltage limit of conventional Schottky diodes,and low turn-on voltage(V_(on))of approximately 100 mV for both devices,making them ideal for power conversion applications.Using technology computer-aided design(TCAD)simulations,the observed asymmetry in electronic transport is attributed to the transition between Fowler-Nordheim tunneling(FNT)and trap-assisted tunneling(TAT)under different biasing conditions,as illustrated by the corresponding energy band profiles.Furthermore,by integrating the FTDs,a rectifier bridge circuit is designed and exhibits full-wave rectification behavior,validated through SPICE simulations for THz-band operations.This advancement offers a highly efficient solution for THz-band energy conversion and effective detection applications.展开更多
The single-event susceptibility of three silicon carbide(SiC)metal-oxide-semiconductor field-effect transistor(MOSFET)power devices structures(planar,trench and double trench)is researched by the technology computer-a...The single-event susceptibility of three silicon carbide(SiC)metal-oxide-semiconductor field-effect transistor(MOSFET)power devices structures(planar,trench and double trench)is researched by the technology computer-aided design(TCAD)simulation.Comparative analysis of the heavy-ion irradiation effects on three device structures reveals distinct susceptibility characteristics.The gate oxide region is identified as the most sensitive position in planar devices,while trench and doubletrench structures exhibit no localized sensitive regions.Furthermore,the single-event susceptibility demonstrates strong depth dependence across all three structures,with enhanced vulnerability observed at greater ion penetration depths.展开更多
Combining the phase-field method and the moving boundary method,a three-dimensional phase-field simulation was conducted for the growth and grain evolution of Ti films deposited by physical vapor deposition under diff...Combining the phase-field method and the moving boundary method,a three-dimensional phase-field simulation was conducted for the growth and grain evolution of Ti films deposited by physical vapor deposition under different deposition rates and grain orientations.The evolution of grain morphology and grain orientation was also taken into consideration.Simulation results show that at lower deposition rates,the surface of the formed Ti film exhibits a distinct oriented texture structure.The surface roughness of the Ti film is positively correlated with the grain misorientation.Moreover,the surface roughness obtained from the simulation is in good agreement with the experiment results.展开更多
The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the...The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the TiNb binary alloy system during spinodal decomposition,and then the formation mechanism of core-shell structure was revealed.In addition,the influences of initial temperature gradient,average temperature,and initial concentration distribution of the system on the core-shell structure were investigated.Results show that the initial concentration gradient is the key factor for forming the core-shell structure.Besides,larger initial temperature gradient and higher average temperature can promote the formation of core-shell structure,which can be stabilized by adjusting the initial concentration distribution of the Nb-rich region in TiNb binary alloy.As a theoretical basis,this research provides a novel and simple strategy for the preparation of TiNb-based alloys and other materials with peculiar core-shell structures and desirable mechanical and physical properties.展开更多
The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorp...The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorption temperature,adsorption time and adsorbent dosage on their adsorptive denitrification performance were systematically investigated.The experimental results demonstrated that under a fixed adsorbent dosage of 0.05 g and a simulated fuel volume of 10 mL,the optimal removal efficiency for aniline was achieved at 30℃ within 30 min,whereas higher temperatures and longer times(40℃and 40 min)were required for effective removal of pyridine and quinoline.Density Functional Theory(DFT)calculations were conducted via Materials Studio(MS)software to study the adsorptive denitrification mechanism of MIL-101(Cr)toward these three basic nitrogen-containing compounds.The simulation calculation results revealed that the interaction between pyridine and MIL-101(Cr)primarily involved coordination adsorption.In contrast,the interaction between aniline or quinoline and MIL-101(Cr)proceeded mainly through coordination,with additional contributions fromπ-complexation and hydrogen bonding.The overall adsorption strength order is pyridine>aniline>quinoline.During the adsorption process,pyridine and quinoline transfer electrons to the MIL-101(Cr)surface through the H→C→N→Cr^(3+)pathway,while aniline transfers electrons to the MIL-101(Cr)surface through various pathways,including N→Cr^(3+),N→C→Cr^(3+)and N→H→O.Furthermore,adsorption kinetics studies indicated that the adsorption processes for all three basic nitrogen-containing compounds followed the quasi second order kinetic models.The experimental results on the effect of benzene on the adsorptive denitrification performance of MIL-101(Cr)-0.5 demonstrated that benzene exerted a more significant impact on the adsorption of aniline and quinoline.Finally,the adsorbent was regenerated using ethanol washing.It was found that MIL-101(Cr)-0.5 retained stable denitrification performance after two regeneration cycles.展开更多
Utilizing finite element analysis,the ballistic protection provided by a combination of perforated D-shaped and base armor plates,collectively referred to as radiator armor,is evaluated.ANSYS Explicit Dynamics is empl...Utilizing finite element analysis,the ballistic protection provided by a combination of perforated D-shaped and base armor plates,collectively referred to as radiator armor,is evaluated.ANSYS Explicit Dynamics is employed to simulate the ballistic impact of 7.62 mm armor-piercing projectiles on Aluminum AA5083-H116 and Steel Secure 500 armors,focusing on the evaluation of material deformation and penetration resistance at varying impact points.While the D-shaped armor plate is penetrated by the armor-piercing projectiles,the combination of the perforated D-shaped and base armor plates successfully halts penetration.A numerical model based on the finite element method is developed using software such as SolidWorks and ANSYS to analyze the interaction between radiator armor and bullet.The perforated design of radiator armor is to maintain airflow for radiator function,with hole sizes smaller than the bullet core diameter to protect radiator assemblies.Predictions are made regarding the brittle fracture resulting from the projectile core′s bending due to asymmetric impact,and the resulting fragments failed to penetrate the perforated base armor plate.Craters are formed on the surface of the perforated D-shaped armor plate due to the impact of projectile fragments.The numerical model accurately predicts hole growth and projectile penetration upon impact with the armor,demonstrating effective protection of the radiator assemblies by the radiator armor.展开更多
Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing addit...Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.展开更多
The capture of atmospheric carbon dioxide by adsorbents is an important strategy to deal with the greenhouse effect.Compared with traditional CO_(2) adsorption materials like activated carbon,silica gel,and zeolite mo...The capture of atmospheric carbon dioxide by adsorbents is an important strategy to deal with the greenhouse effect.Compared with traditional CO_(2) adsorption materials like activated carbon,silica gel,and zeolite molecular sieves,covalent organic frameworks(COFs)have excellent thermal and chemical stabilities and can be produced in many different forms.Using their different possible construction units,ordered structures for specific applications can be produced,giving them broad prospects in fields such as gas storage.This review analyzes the different types of COFs that have been synthesized and their different methods of CO_(2) capture.It then discusses different ways to increase CO_(2) adsorption by changing the internal structure of COFs and modifying their surfaces.The limitations of COF-derived carbon materials in CO_(2) capture are reviewed and,finally,the key role of machine learning and computational simulation in improving CO_(2) adsorption is mentioned,and the current status and future possible uses of COFs are summarized.展开更多
In Chin.Phys.B 34114704(2025),Eq.(7)and the associated unit notation were incorrect.The correct ones are present here.Since Eq.(7)is an in-built expression in the simulation package,the correction is purely typographi...In Chin.Phys.B 34114704(2025),Eq.(7)and the associated unit notation were incorrect.The correct ones are present here.Since Eq.(7)is an in-built expression in the simulation package,the correction is purely typographical and does not affect the simulation procedure,numerical results,or the conclusions.展开更多
Most existing path planning approaches rely on discrete expansions or localized heuristics that can lead to extended re-planning,inefficient detours,and limited adaptability to complex obstacle distributions.These iss...Most existing path planning approaches rely on discrete expansions or localized heuristics that can lead to extended re-planning,inefficient detours,and limited adaptability to complex obstacle distributions.These issues are particularly pronounced when navigating cluttered or large-scale environments that demand both global coverage and smooth trajectory generation.To address these challenges,this paper proposes a Wave Water Simulator(WWS)algorithm,leveraging a physically motivated wave equation to achieve inherently smooth,globally consistent path planning.In WWS,wavefront expansions naturally identify safe corridors while seamlessly avoiding local minima,and selective corridor focusing reduces computational overhead in large or dense maps.Comprehensive simulations and real-world validations-encompassing both indoor and outdoor scenarios-demonstrate that WWS reduces path length by 2%-13%compared to conventional methods,while preserving gentle curvature and robust obstacle clearance.Furthermore,WWS requires minimal parameter tuning across diverse domains,underscoring its broad applicability to warehouse robotics,field operations,and autonomous service vehicles.These findings confirm that the proposed wave-based framework not only bridges the gap between local heuristics and global coverage but also sets a promising direction for future extensions toward dynamic obstacle scenarios and multi-agent coordination.展开更多
We investigated the phase behavior of diblock copolymer AB/homopolymer C blends in concentrated aqueous solutions using a simulated annealing method.Phase diagrams were constructed as a function of the concentration o...We investigated the phase behavior of diblock copolymer AB/homopolymer C blends in concentrated aqueous solutions using a simulated annealing method.Phase diagrams were constructed as a function of the concentration of all polymers(Φ)and the volume fraction of homopolymer(fC).Rich phase transition sequences were observed,especially reentrant phase transitions,such as lamellae→inverted cylinders→gyroids→lamellae→disorder,for a givenΦwith increasing fC.By analyzing the variations in the average contact numbers between different components and the effective volume fractions of B-domains,we elucidated the mechanisms of the reentrant phase transitions.We found that the strong attraction between B and C leads to the swelling of B-domains upon addition of homopolymer.Concurrently,the solvent preferentially swells the A-domains over the B+C-domains.The competing swelling effects of the solvent and homopolymer on the A-domains and B-domains,respectively,triggered the reentrant phase behavior in the symmetric AB copolymer system upon addition of homopolymer.展开更多
In wind tunnel experiments,support devices inevitably disturb the surrounding flow field,thereby degrading the accuracy of measured aerodynamic data.A new subsonic and transonic wind tunnel has recently been construct...In wind tunnel experiments,support devices inevitably disturb the surrounding flow field,thereby degrading the accuracy of measured aerodynamic data.A new subsonic and transonic wind tunnel has recently been constructed,and the support system for dynamic six degree of freedom experiments is currently under conceptual design.A key challenge is to optimize the support configuration while satisfying stringent flow quality requirements.In this study,the influence of different support configurations on the flow field is investigated numerically by analyzing velocity and pressure distributions.The results show that the optimized six degree of freedom support significantly reduces disturbances in both pressure and velocity fields,with the improvement becoming more pronounced as the Mach number increases.The main optimization measures include the addition of a tail fairing,reduction of the thickness of the connecting bases between the support rods and the sting,and downsizing of the anchor feet.In contrast,the effect of the tail support poles is found to be negligible.It is shown that,overall,the extent of upstream flow disturbance is governed primarily by the separation region and associated momentum loss induced by the support sting,the connecting bases and the anchor feet.Flow separation originates from spiral points or separation lines on the model surface,resulting from viscous effects combined with shock waves generated by the support system.展开更多
Heavy-ion collisions(HICs)is a unique experimental tool for investigating the properties of nuclear matter under extreme conditions in the laboratory.At HIRFL-CSR energies,HICs can create nuclear matter with 2-3 times...Heavy-ion collisions(HICs)is a unique experimental tool for investigating the properties of nuclear matter under extreme conditions in the laboratory.At HIRFL-CSR energies,HICs can create nuclear matter with 2-3 times the saturation density(ρ_(0)).The HIRFL-CSR external-target experiment(CEE)is a large-acceptance spectrometer designed to explore frontier topics in high-energy nuclear physics,such as the QCD phase structure and nuclear matter equation of states.In this letter,we introduce simulation and analysis software for the CEE experiment(CeeROOT).Based on the CEE conceptual design and CeeROOT software,the configurations of its subdetectors were optimized by considering foreseeable physical constraints.The final detector layout of the CEE spectrometer and its acceptances were validated through simulations of U+U collisions at 500 MeV/u and pp collisions at 2.8 GeV,which demonstrated that the CEE experiment will serve as a detector with wide acceptance and multi-particle identification capabilities for studying high-energy nuclear physics topics at HIRFL-CSR energies with pp,pA,and A A collisions.展开更多
Quasi-hemispherical magnetized collisionless shocks have been generated at the SG-II laser facility through the interaction between a laserproduced supersonic plasma flow and a magnetized ambient plasma,exhibiting an ...Quasi-hemispherical magnetized collisionless shocks have been generated at the SG-II laser facility through the interaction between a laserproduced supersonic plasma flow and a magnetized ambient plasma,exhibiting an angular asymmetric shock profile accompanied by asymmetric ion acceleration.We have conducted test particle simulations using the electromagnetic fields derived from 2D MHD simulations to investigate the asymmetry of ion acceleration.The simulations reproduce the angular asymmetry of the shock and the ion acceleration observed in experiments.The results indicate that shock drift acceleration is the primary mechanism for ion energization in the present quasiperpendicular magnetized shock.The asymmetric shock structure caused by nonuniform ambient plasma forms an asymmetric accelerated electric field,ultimately leading to angular asymmetric ion acceleration,which is consistent with space observations and our experimental results.Our study provides a plausible explanation for the discrepancies reported in previous ion acceleration experiments,and could contribute to understanding of the collisionless shock acceleration.展开更多
基金Guangzhou Metro Scientific Research Project(No.JT204-100111-23001)Chongqing Municipal Special Project for Technological Innovation and Application Development(No.CSTB2022TIAD-KPX0101)Science and Technology Research and Development Program of China State Railway Group Co.,Ltd.(No.N2023G045)。
文摘The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combines numerical simulation with machine learning techniques to explore this issue.It presents a summary of special-shaped tunnel geometries and introduces a shape coefficient.Through the finite element software,Plaxis3D,the study simulates six key parameters—shape coefficient,burial depth ratio,tunnel’s longest horizontal length,internal friction angle,cohesion,and soil submerged bulk density—that impact uplift resistance across different conditions.Employing XGBoost and ANN methods,the feature importance of each parameter was analyzed based on the numerical simulation results.The findings demonstrate that a tunnel shape more closely resembling a circle leads to reduced uplift resistance in the overlying soil,whereas other parameters exhibit the contrary effects.Furthermore,the study reveals a diminishing trend in the feature importance of buried depth ratio,internal friction angle,tunnel longest horizontal length,cohesion,soil submerged bulk density,and shape coefficient in influencing uplift resistance.
基金financially supported by the National Natural Science Foundation of China(Nos.52303298 and 52233002)。
文摘UHMWPE fibers exhibit impressive modulus and strength,but they have not reached their theoretical limits.Researchers focus on molecular weight,orientation,and crystallinity of UHMWPE,yet their contributions to mechanical properties are unclear.Molecular dynamics simulations are valuable but often limited by computational constraints.Our aim is to simulate higher molecular weights to better represent real UHMWPE fibers.We used Packmol and Polyply methodologies to construct PE systems,with Polyply reproducing more reasonable properties of UHMWPE fibers.Additionally,tensile simulations showed that orientation and crystallinity greatly impact Young's modulus more than molecular weight.Energy decomposition indicated that higher molecular weights lead to covalent bonds that can withstand more energy during stretching,thus increasing breaking strength.Combining simulations with machine learning,we found that orientation has the most significant impact on Young's modulus,contributing 60%,and molecular weight plays the most crucial role in determining the breaking strength,accounting for 65%.This study provides a theoretical basis and guidelines for enhancing UHMWPE's modulus and strength.
基金National Key Research and Development Program of China(2024YFA1410700,2021YFA1200700)National Natural Science Foundation of China(62474065,T2222025,62174053)+3 种基金Natural Science Foundation of Chongqing(CSTB2024NSCQ-JQX0005)Shanghai Science and Technology Innovation Action Plan(24QA2702300,24YF2710400)National Postdoctoral Program(GZB20240225)Fundamental Research Funds for the Central Universities。
文摘Tunneling diodes hold significant promise for future rectification in the terahertz(THz)and visible light spectra,thanks to their femtosecond-scale transit-time tunneling capabilities.In this work,TiN/ZnO/Pt fin tunneling diodes(FTDs)with tunneling distances of 10 and 5 nm are fabricated,which demonstrate remarkable characteristics,including ultrahigh asymmetry(1.6×10^(4)for 10 nm device and 1.6×10^(3) for 5 nm device),high responsivity(25.3 V^(-1) for 10 nm device and 28.3 V^(-1) for 5 nm device)at zero bias,surpassing the thermal voltage limit of conventional Schottky diodes,and low turn-on voltage(V_(on))of approximately 100 mV for both devices,making them ideal for power conversion applications.Using technology computer-aided design(TCAD)simulations,the observed asymmetry in electronic transport is attributed to the transition between Fowler-Nordheim tunneling(FNT)and trap-assisted tunneling(TAT)under different biasing conditions,as illustrated by the corresponding energy band profiles.Furthermore,by integrating the FTDs,a rectifier bridge circuit is designed and exhibits full-wave rectification behavior,validated through SPICE simulations for THz-band operations.This advancement offers a highly efficient solution for THz-band energy conversion and effective detection applications.
基金National Key Research and Development Program of China(2023YFA1609000)National Natural Science Foundation of China(62474190,U22B2043,U2267210)。
文摘The single-event susceptibility of three silicon carbide(SiC)metal-oxide-semiconductor field-effect transistor(MOSFET)power devices structures(planar,trench and double trench)is researched by the technology computer-aided design(TCAD)simulation.Comparative analysis of the heavy-ion irradiation effects on three device structures reveals distinct susceptibility characteristics.The gate oxide region is identified as the most sensitive position in planar devices,while trench and doubletrench structures exhibit no localized sensitive regions.Furthermore,the single-event susceptibility demonstrates strong depth dependence across all three structures,with enhanced vulnerability observed at greater ion penetration depths.
基金National MCF Energy R&D Program of China(2018YFE0306100)Natural Science Foundation of Hunan Province for Distinguished Young Scholars(2021JJ10062)+1 种基金National Natural Science Foundation of China(52101028)China Postdoctoral Science Foundation(2021M703628)。
文摘Combining the phase-field method and the moving boundary method,a three-dimensional phase-field simulation was conducted for the growth and grain evolution of Ti films deposited by physical vapor deposition under different deposition rates and grain orientations.The evolution of grain morphology and grain orientation was also taken into consideration.Simulation results show that at lower deposition rates,the surface of the formed Ti film exhibits a distinct oriented texture structure.The surface roughness of the Ti film is positively correlated with the grain misorientation.Moreover,the surface roughness obtained from the simulation is in good agreement with the experiment results.
基金National Natural Science Foundation of China(12372152)Guangdong Basic and Applied Basic Research Foundation(2023A1515011819,2024A1515012469)Shandong Provincial Natural Science Foundation(ZR2023MA058)。
文摘The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the TiNb binary alloy system during spinodal decomposition,and then the formation mechanism of core-shell structure was revealed.In addition,the influences of initial temperature gradient,average temperature,and initial concentration distribution of the system on the core-shell structure were investigated.Results show that the initial concentration gradient is the key factor for forming the core-shell structure.Besides,larger initial temperature gradient and higher average temperature can promote the formation of core-shell structure,which can be stabilized by adjusting the initial concentration distribution of the Nb-rich region in TiNb binary alloy.As a theoretical basis,this research provides a novel and simple strategy for the preparation of TiNb-based alloys and other materials with peculiar core-shell structures and desirable mechanical and physical properties.
基金Supported by Basic Scientific Research Project of the Liaoning Provincial Department of Education Has Been Unveiled to Facilitate Local Project Funding (JYTMS20230835)Enhanced Scientific Research Project Funded by the Departmentof Higher Education in Liaoning Province (General program)(JYTMS20230852)。
文摘The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorption temperature,adsorption time and adsorbent dosage on their adsorptive denitrification performance were systematically investigated.The experimental results demonstrated that under a fixed adsorbent dosage of 0.05 g and a simulated fuel volume of 10 mL,the optimal removal efficiency for aniline was achieved at 30℃ within 30 min,whereas higher temperatures and longer times(40℃and 40 min)were required for effective removal of pyridine and quinoline.Density Functional Theory(DFT)calculations were conducted via Materials Studio(MS)software to study the adsorptive denitrification mechanism of MIL-101(Cr)toward these three basic nitrogen-containing compounds.The simulation calculation results revealed that the interaction between pyridine and MIL-101(Cr)primarily involved coordination adsorption.In contrast,the interaction between aniline or quinoline and MIL-101(Cr)proceeded mainly through coordination,with additional contributions fromπ-complexation and hydrogen bonding.The overall adsorption strength order is pyridine>aniline>quinoline.During the adsorption process,pyridine and quinoline transfer electrons to the MIL-101(Cr)surface through the H→C→N→Cr^(3+)pathway,while aniline transfers electrons to the MIL-101(Cr)surface through various pathways,including N→Cr^(3+),N→C→Cr^(3+)and N→H→O.Furthermore,adsorption kinetics studies indicated that the adsorption processes for all three basic nitrogen-containing compounds followed the quasi second order kinetic models.The experimental results on the effect of benzene on the adsorptive denitrification performance of MIL-101(Cr)-0.5 demonstrated that benzene exerted a more significant impact on the adsorption of aniline and quinoline.Finally,the adsorbent was regenerated using ethanol washing.It was found that MIL-101(Cr)-0.5 retained stable denitrification performance after two regeneration cycles.
文摘Utilizing finite element analysis,the ballistic protection provided by a combination of perforated D-shaped and base armor plates,collectively referred to as radiator armor,is evaluated.ANSYS Explicit Dynamics is employed to simulate the ballistic impact of 7.62 mm armor-piercing projectiles on Aluminum AA5083-H116 and Steel Secure 500 armors,focusing on the evaluation of material deformation and penetration resistance at varying impact points.While the D-shaped armor plate is penetrated by the armor-piercing projectiles,the combination of the perforated D-shaped and base armor plates successfully halts penetration.A numerical model based on the finite element method is developed using software such as SolidWorks and ANSYS to analyze the interaction between radiator armor and bullet.The perforated design of radiator armor is to maintain airflow for radiator function,with hole sizes smaller than the bullet core diameter to protect radiator assemblies.Predictions are made regarding the brittle fracture resulting from the projectile core′s bending due to asymmetric impact,and the resulting fragments failed to penetrate the perforated base armor plate.Craters are formed on the surface of the perforated D-shaped armor plate due to the impact of projectile fragments.The numerical model accurately predicts hole growth and projectile penetration upon impact with the armor,demonstrating effective protection of the radiator assemblies by the radiator armor.
基金National Key Research and Development Program of China(2022YFB4600902)Shandong Provincial Science Foundation for Outstanding Young Scholars(ZR2024YQ020)。
文摘Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.
文摘The capture of atmospheric carbon dioxide by adsorbents is an important strategy to deal with the greenhouse effect.Compared with traditional CO_(2) adsorption materials like activated carbon,silica gel,and zeolite molecular sieves,covalent organic frameworks(COFs)have excellent thermal and chemical stabilities and can be produced in many different forms.Using their different possible construction units,ordered structures for specific applications can be produced,giving them broad prospects in fields such as gas storage.This review analyzes the different types of COFs that have been synthesized and their different methods of CO_(2) capture.It then discusses different ways to increase CO_(2) adsorption by changing the internal structure of COFs and modifying their surfaces.The limitations of COF-derived carbon materials in CO_(2) capture are reviewed and,finally,the key role of machine learning and computational simulation in improving CO_(2) adsorption is mentioned,and the current status and future possible uses of COFs are summarized.
文摘In Chin.Phys.B 34114704(2025),Eq.(7)and the associated unit notation were incorrect.The correct ones are present here.Since Eq.(7)is an in-built expression in the simulation package,the correction is purely typographical and does not affect the simulation procedure,numerical results,or the conclusions.
文摘Most existing path planning approaches rely on discrete expansions or localized heuristics that can lead to extended re-planning,inefficient detours,and limited adaptability to complex obstacle distributions.These issues are particularly pronounced when navigating cluttered or large-scale environments that demand both global coverage and smooth trajectory generation.To address these challenges,this paper proposes a Wave Water Simulator(WWS)algorithm,leveraging a physically motivated wave equation to achieve inherently smooth,globally consistent path planning.In WWS,wavefront expansions naturally identify safe corridors while seamlessly avoiding local minima,and selective corridor focusing reduces computational overhead in large or dense maps.Comprehensive simulations and real-world validations-encompassing both indoor and outdoor scenarios-demonstrate that WWS reduces path length by 2%-13%compared to conventional methods,while preserving gentle curvature and robust obstacle clearance.Furthermore,WWS requires minimal parameter tuning across diverse domains,underscoring its broad applicability to warehouse robotics,field operations,and autonomous service vehicles.These findings confirm that the proposed wave-based framework not only bridges the gap between local heuristics and global coverage but also sets a promising direction for future extensions toward dynamic obstacle scenarios and multi-agent coordination.
基金financially supported by the Natural Science Foundation of Shandong Province(Nos.ZR2023QA136,ZR2021MA073 and ZR2024QA235)the National Natural Science Foundation of China(No.22173051).
文摘We investigated the phase behavior of diblock copolymer AB/homopolymer C blends in concentrated aqueous solutions using a simulated annealing method.Phase diagrams were constructed as a function of the concentration of all polymers(Φ)and the volume fraction of homopolymer(fC).Rich phase transition sequences were observed,especially reentrant phase transitions,such as lamellae→inverted cylinders→gyroids→lamellae→disorder,for a givenΦwith increasing fC.By analyzing the variations in the average contact numbers between different components and the effective volume fractions of B-domains,we elucidated the mechanisms of the reentrant phase transitions.We found that the strong attraction between B and C leads to the swelling of B-domains upon addition of homopolymer.Concurrently,the solvent preferentially swells the A-domains over the B+C-domains.The competing swelling effects of the solvent and homopolymer on the A-domains and B-domains,respectively,triggered the reentrant phase behavior in the symmetric AB copolymer system upon addition of homopolymer.
基金supported by the Guiding Project of Scientific Research Plan of Hubei Education Department of China[Grant No.B2020227].
文摘In wind tunnel experiments,support devices inevitably disturb the surrounding flow field,thereby degrading the accuracy of measured aerodynamic data.A new subsonic and transonic wind tunnel has recently been constructed,and the support system for dynamic six degree of freedom experiments is currently under conceptual design.A key challenge is to optimize the support configuration while satisfying stringent flow quality requirements.In this study,the influence of different support configurations on the flow field is investigated numerically by analyzing velocity and pressure distributions.The results show that the optimized six degree of freedom support significantly reduces disturbances in both pressure and velocity fields,with the improvement becoming more pronounced as the Mach number increases.The main optimization measures include the addition of a tail fairing,reduction of the thickness of the connecting bases between the support rods and the sting,and downsizing of the anchor feet.In contrast,the effect of the tail support poles is found to be negligible.It is shown that,overall,the extent of upstream flow disturbance is governed primarily by the separation region and associated momentum loss induced by the support sting,the connecting bases and the anchor feet.Flow separation originates from spiral points or separation lines on the model surface,resulting from viscous effects combined with shock waves generated by the support system.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB34030000)the National Natural Science Foundation of China(Nos.11927901 and 12475133)+1 种基金the Youth Team Program in Basic Research Fields Stably Supported by the Chinese Academy of Sciences(No.YSBR-088)the Western Light Project of the Chinese Academy of Sciences。
文摘Heavy-ion collisions(HICs)is a unique experimental tool for investigating the properties of nuclear matter under extreme conditions in the laboratory.At HIRFL-CSR energies,HICs can create nuclear matter with 2-3 times the saturation density(ρ_(0)).The HIRFL-CSR external-target experiment(CEE)is a large-acceptance spectrometer designed to explore frontier topics in high-energy nuclear physics,such as the QCD phase structure and nuclear matter equation of states.In this letter,we introduce simulation and analysis software for the CEE experiment(CeeROOT).Based on the CEE conceptual design and CeeROOT software,the configurations of its subdetectors were optimized by considering foreseeable physical constraints.The final detector layout of the CEE spectrometer and its acceptances were validated through simulations of U+U collisions at 500 MeV/u and pp collisions at 2.8 GeV,which demonstrated that the CEE experiment will serve as a detector with wide acceptance and multi-particle identification capabilities for studying high-energy nuclear physics topics at HIRFL-CSR energies with pp,pA,and A A collisions.
基金supported by the National Natural Science Foundation of China(Grant Nos.12205298 and 12175230)the Natural Science Foundation of Heilongjiang Province of China(Grant No.LH2024A010)+1 种基金the Fundamental Research Funds for the Central Universities,Controversial and Disruptive Projects of the Chinese Academy of Sciences(Grant No.FGSDFX-0001)the USTC Research Funds of the Double First-Class Initiative(Grant No.YD2140002006).
文摘Quasi-hemispherical magnetized collisionless shocks have been generated at the SG-II laser facility through the interaction between a laserproduced supersonic plasma flow and a magnetized ambient plasma,exhibiting an angular asymmetric shock profile accompanied by asymmetric ion acceleration.We have conducted test particle simulations using the electromagnetic fields derived from 2D MHD simulations to investigate the asymmetry of ion acceleration.The simulations reproduce the angular asymmetry of the shock and the ion acceleration observed in experiments.The results indicate that shock drift acceleration is the primary mechanism for ion energization in the present quasiperpendicular magnetized shock.The asymmetric shock structure caused by nonuniform ambient plasma forms an asymmetric accelerated electric field,ultimately leading to angular asymmetric ion acceleration,which is consistent with space observations and our experimental results.Our study provides a plausible explanation for the discrepancies reported in previous ion acceleration experiments,and could contribute to understanding of the collisionless shock acceleration.
