The electrochemical behaviors and coupling behaviors of the Mg2Si and Si phases with α（Al） were investigated, the corrosion morphologies of Al alloys containing Mg2Si and Si particles were observed, and the corrosi...The electrochemical behaviors and coupling behaviors of the Mg2Si and Si phases with α（Al） were investigated, the corrosion morphologies of Al alloys containing Mg2Si and Si particles were observed, and the corrosion mechanism associated with them in Al-Mg-Si alloys was advanced. The results show that Si particle is always cathodic to the alloy base, Mg2Si is anodic to the alloy base and corrosion occurs on its surface at the beginning. However, during its corrosion process, the preferential dissolution of Mg and the enrichment of Si make Mg2Si transform to cathode from anode, leading to the anodic dissolution and corrosion of the alloy base at its adjacent periphery at a later stage. As the mole ratio of Mg to Si in an Al-Mg-Si alloy is less than 1.73, it contains Mg2Si and Si particles simultaneously in the grain boundary area, and corrosion initiates on the Mg2Si surface and the precipitate-free zone （PFZ） at the adjacent periphery of Si particle. As corrosion time is extended, Si particle leads to severe anodic dissolution and corrosion of the PFZ at its adjacent periphery, expedites the polarity transformation between Mg2Si and the PFZ and accelerates the corrosion of PFZ at the adjacent periphery of Mg2Si particle.展开更多
采用全矢量交替方向隐含迭代方法系统分析了高折射率 Si ON薄膜对 Si基 Si O2 阵列波导光栅中波导应力双折射的影响 .分析结果表明在芯区上或下表面沉积 Si ON薄膜可以明显减小 Si基 Si O2 阵列波导光栅 (AWG)中波导的应力双折射 ,但这...采用全矢量交替方向隐含迭代方法系统分析了高折射率 Si ON薄膜对 Si基 Si O2 阵列波导光栅中波导应力双折射的影响 .分析结果表明在芯区上或下表面沉积 Si ON薄膜可以明显减小 Si基 Si O2 阵列波导光栅 (AWG)中波导的应力双折射 ,但这两种补偿方法容易使模场偏移中心位置 ,不利于波导与光纤的耦合 .理想的补偿方法是在芯区上下同时补偿 ,可减小模场偏移 ,并用该方法设计了偏振无关的 1 6通道 AWG.展开更多
基金Project (21073162) supported by the National Natural Science Foundation of ChinaProject (2008) supported by the Scientific and Technological Projects of Ningxia, China+1 种基金Project (08JC1421600) supported by the Science and Technology Commission of Shanghai Municipality, ChinaProject (2008AZ2018) supported by the Science and Technology Bureau of Jiaxing City, China
文摘The electrochemical behaviors and coupling behaviors of the Mg2Si and Si phases with α（Al） were investigated, the corrosion morphologies of Al alloys containing Mg2Si and Si particles were observed, and the corrosion mechanism associated with them in Al-Mg-Si alloys was advanced. The results show that Si particle is always cathodic to the alloy base, Mg2Si is anodic to the alloy base and corrosion occurs on its surface at the beginning. However, during its corrosion process, the preferential dissolution of Mg and the enrichment of Si make Mg2Si transform to cathode from anode, leading to the anodic dissolution and corrosion of the alloy base at its adjacent periphery at a later stage. As the mole ratio of Mg to Si in an Al-Mg-Si alloy is less than 1.73, it contains Mg2Si and Si particles simultaneously in the grain boundary area, and corrosion initiates on the Mg2Si surface and the precipitate-free zone （PFZ） at the adjacent periphery of Si particle. As corrosion time is extended, Si particle leads to severe anodic dissolution and corrosion of the PFZ at its adjacent periphery, expedites the polarity transformation between Mg2Si and the PFZ and accelerates the corrosion of PFZ at the adjacent periphery of Mg2Si particle.
