An anomalous isotope effect exists in many heavy element isotope systems （e.g., Sr, Gd, Zn, U）. This effect used to be called the ＂odd--even isotope effect＂ because the odd mass number isotopes behave differently ...An anomalous isotope effect exists in many heavy element isotope systems （e.g., Sr, Gd, Zn, U）. This effect used to be called the ＂odd--even isotope effect＂ because the odd mass number isotopes behave differently from the even mass number isotopes. This mass-indepen- dent isotope fractionation driving force, which originates from the difference in the ground-state electronic energies caused by differences in nuclear size and shape, is cur- rently denoted as the nuclear field shift effect （NFSE）. It is found that the NFSE can drive isotope fractionation of some heavy elements （e.g., Hg, T1, U） to an astonishing degree, far more than the magnitude caused by the con- ventional mass-dependent effect （MDE）. For light ele- ments, the MDE is the dominant factor in isotope fractionation, while the NFSE is neglectable. Furthermore, the MDE and the NFSE both decrease as temperatures increase, though at different rates. The MDE decreases rapidly with a factor of 1/T2, while the NFSE decreases slowly with a factor of 1/T. As a result, even at high temperatures, the NFSE is still significant for many heavy element isotope systems. In this review paper, we begin with an introduction of the basic concept of the NSFE, including its history and recent progress, and follow with the potential implications of the inclusion of the NFSE into the kinetic isotope fractionation effect （KIE） and heavy isotope geochronology.展开更多
This study applies a double snap-through mechanism on a box-type oscillating buoy(OB)wave energy converter(WEC)-floating breakwater integrated system(OB WEC-FB)to simultaneously achieve efficient wave energy conversio...This study applies a double snap-through mechanism on a box-type oscillating buoy(OB)wave energy converter(WEC)-floating breakwater integrated system(OB WEC-FB)to simultaneously achieve efficient wave energy conversion and nearshore protection within a low-frequency bandwidth.This mechanism consists of four oblique springs and can operate in mono-stable,bi-stable,and tri-stable modes.A viscous-flow-based numerical model is established to investigate the hydrodynamic performance and dynamic behavior of the proposed multi-stable breakwater.The operational performance of the breakwater at different dynamic modes is first compared.The effects of the springs’original length and stiffness coefficient are then analyzed.The results show that the tri-stable breakwater has a wider resonance frequency tuning range than the bi-stable one,both of which outperform the mono-stable and linear ones in shifting the effective bandwidth to a lower frequency range.For a tri-stable breakwater,a large distance between outermost potential wells is conducive to tuning resonance frequency,whereas shallow potential wells limit this effect.The increase in spring stiffness distinctly causes a higher potential barrier and thus constrains the motion response of the breakwater.A well-designed double snap-through mechanism can excite large-amplitude inter-well motion,tune the resonance frequency of breakwater from 3.98 to 1.96 rad/s,and decrease the lower limit of the effective transmission bandwidth from 3.75 to 3.00 rad/s.It is crucial for improving the power absorption and wave attenuation capabilities of multi-stable OB WEC-FB.This study contributes to the limited research on the implementation of a double snap-through mechanism on multifunctional marine structures.It establishes the underlying connection between nonlinear dynamic behaviors and hydrodynamic coefficients.展开更多
Four thiophene derivatives were prepared by replacing the 3,4 positions of thiophene by―OCH3, ―CH3―COOCH3 and ―CN, respectively. The polycondensations via direct arylation took place between the four thiophene der...Four thiophene derivatives were prepared by replacing the 3,4 positions of thiophene by―OCH3, ―CH3―COOCH3 and ―CN, respectively. The polycondensations via direct arylation took place between the four thiophene derivatives and 2,7-dibromo-9,9-dioctylfluorene under six various catalytic conditions to investigate the substituent effects. The substituent can affect the electron cloud density of the active C―H bond, which can be monitored by the NMR chemical shift. The experimental results show that the reactivity decreases with increasing the chemical shift of active C―H bonds in the four thiophene derivatives, and thus can promote the direct arylation polycondensation. This phenomenon is explained by the electrophilic aromatic substitution（SEAr） mechanism. UV-Visible absorption and photoluminescence were studied to investigate the substituent effect on optical properties of the four copolymers. The results show that these alternating fluorene-thiophene copolymers with different substituents are good fluorescent materials and promising in PLED applications.展开更多
Recently,cell-free(CF)massive multipleinput multiple-output(MIMO)becomes a promising architecture for the next generation wireless communication system,where a large number of distributed access points(APs)are deploye...Recently,cell-free(CF)massive multipleinput multiple-output(MIMO)becomes a promising architecture for the next generation wireless communication system,where a large number of distributed access points(APs)are deployed to simultaneously serve multiple user equipments(UEs)for improved performance.Meanwhile,a clustered CF system is considered to tackle the backhaul overhead issue in the huge connection network.In this paper,taking into account the more realistic mobility scenarios,we propose a hybrid small-cell(SC)and clustered CF massive MIMO system through classifications of the UEs and APs,and constructing the corresponding pairs to run in SC or CF mode.A joint initial AP selection of this paradigm for all the UEs is firstly proposed,which is based on the statistics of estimated channel.Then,closed-form expressions of the downlink achievable rates for both the static and moving UEs are provided under Ricean fading channel and Doppler shift effect.We also develop a semi-heuristic search algorithm to deal with the AP selection for the moving UEs by maximizing the weight average achievable rate.Numerical results demonstrate the performance gains and effective rates balancing of the proposed system.展开更多
The theory of chemical shift effect of substituent was applied to the assignment of the 13 C NMR spectra of the ethylene/propylene and ethylene/octene 1 copolymers. Using the parameters derived above a...The theory of chemical shift effect of substituent was applied to the assignment of the 13 C NMR spectra of the ethylene/propylene and ethylene/octene 1 copolymers. Using the parameters derived above and the DEPT technique, we then entirely assigned the 13 C NMR spectra of the ethylene/propylene/octene 1 terpolymers synthesized in the presence of the same heterogeneous supported Ziegler Natta catalyst, TiCl 4/MgCl 2/ i Bu 3Al. The present paper also covers the terpolymer composition and the monomer sequence distributions of a series of ethylene/propylene/octene 1 terpolymers.展开更多
For studying the influence of smoking on temporary threshold shift (TTS), six normal subjects (3 smokers and 3 nonsmokers) were selected for carrying out this work. Nonsmokers were exposed separately for 7 min to 95 ...For studying the influence of smoking on temporary threshold shift (TTS), six normal subjects (3 smokers and 3 nonsmokers) were selected for carrying out this work. Nonsmokers were exposed separately for 7 min to 95 dB SPL in 1/3-octave band filtered noise centred at 2 kHz. Pre and post exposure thresholds (leftear) were recorded in a sound-proof booth using Bruel & Kjaer (B & K) Audiometer type 1800. For smokers, each one smoked a cigarette during the five minutes following the pre-exposure threshold measurement. All the assessments were conducted at a temperature between 22-25℃. The results indicated that smokers evidenced less TTS than did nonsmokers in the frequency range from 1 kHz to 5 kHz. At 6 kHz smokers evidenced nearly higher value. Maximum TTS was attained at frequency that was about 1/2-octave higher than that of the exposed noise. Comparison between recovery curves for smokers and nonsmokers was also made.展开更多
The Dirac neutrino masses could be simply generated by a neutrinophilic scalar doublet with a vacuum being dramatically different from the electroweak one.While the case with an eV-scale vacuum has been widely explore...The Dirac neutrino masses could be simply generated by a neutrinophilic scalar doublet with a vacuum being dramatically different from the electroweak one.While the case with an eV-scale vacuum has been widely explored previously,we exploit in this work the desert where the scalar vacuum is of O(keV)scale.In this regime,there would be rare hope to probe the keV-vacuum neutrinophilic scalar model via the lepton-flavor-violating processes,which makes it distinguishable from the widely considered eV-scale vacuum.Although such a keV-vacuum scenario is inert in the low-energy flavor physics,we show that the baryogenesis realized via the lightest Dirac neutrino can be a natural candidate in explaining the baryon asymmetry of the Universe.Furthermore,the Dirac neutrinos with a keV-vacuum scalar can generate a shift of the effective neutrino number within the range 0.097≤ΔN_(eff)≤0.112,which can be probed by the future Simons Observatory experiments.In particular,the model with a minimal valueΔN_(eff)=0.097 can already be falsified by the future CMB Stage-Ⅳand Large Scale Structure surveys,providing consequently striking exploratory avenues in the cosmological regime for such a keV-vacuum scenario.展开更多
基金funding support from the973 Program(2014CB440904)Chinese NSF projects(41225012,41490635,41530210)
文摘An anomalous isotope effect exists in many heavy element isotope systems （e.g., Sr, Gd, Zn, U）. This effect used to be called the ＂odd--even isotope effect＂ because the odd mass number isotopes behave differently from the even mass number isotopes. This mass-indepen- dent isotope fractionation driving force, which originates from the difference in the ground-state electronic energies caused by differences in nuclear size and shape, is cur- rently denoted as the nuclear field shift effect （NFSE）. It is found that the NFSE can drive isotope fractionation of some heavy elements （e.g., Hg, T1, U） to an astonishing degree, far more than the magnitude caused by the con- ventional mass-dependent effect （MDE）. For light ele- ments, the MDE is the dominant factor in isotope fractionation, while the NFSE is neglectable. Furthermore, the MDE and the NFSE both decrease as temperatures increase, though at different rates. The MDE decreases rapidly with a factor of 1/T2, while the NFSE decreases slowly with a factor of 1/T. As a result, even at high temperatures, the NFSE is still significant for many heavy element isotope systems. In this review paper, we begin with an introduction of the basic concept of the NSFE, including its history and recent progress, and follow with the potential implications of the inclusion of the NFSE into the kinetic isotope fractionation effect （KIE） and heavy isotope geochronology.
基金supported by the National Natural Science Foundation of China Program(No.51739010).
文摘This study applies a double snap-through mechanism on a box-type oscillating buoy(OB)wave energy converter(WEC)-floating breakwater integrated system(OB WEC-FB)to simultaneously achieve efficient wave energy conversion and nearshore protection within a low-frequency bandwidth.This mechanism consists of four oblique springs and can operate in mono-stable,bi-stable,and tri-stable modes.A viscous-flow-based numerical model is established to investigate the hydrodynamic performance and dynamic behavior of the proposed multi-stable breakwater.The operational performance of the breakwater at different dynamic modes is first compared.The effects of the springs’original length and stiffness coefficient are then analyzed.The results show that the tri-stable breakwater has a wider resonance frequency tuning range than the bi-stable one,both of which outperform the mono-stable and linear ones in shifting the effective bandwidth to a lower frequency range.For a tri-stable breakwater,a large distance between outermost potential wells is conducive to tuning resonance frequency,whereas shallow potential wells limit this effect.The increase in spring stiffness distinctly causes a higher potential barrier and thus constrains the motion response of the breakwater.A well-designed double snap-through mechanism can excite large-amplitude inter-well motion,tune the resonance frequency of breakwater from 3.98 to 1.96 rad/s,and decrease the lower limit of the effective transmission bandwidth from 3.75 to 3.00 rad/s.It is crucial for improving the power absorption and wave attenuation capabilities of multi-stable OB WEC-FB.This study contributes to the limited research on the implementation of a double snap-through mechanism on multifunctional marine structures.It establishes the underlying connection between nonlinear dynamic behaviors and hydrodynamic coefficients.
基金financially supported by the National Natural Science Foundation of China(Nos.60976019 and 61250016)Education Department Program(No.JA12069)and Program for Innovative Research Team in Science and Technology in Fujian Province
文摘Four thiophene derivatives were prepared by replacing the 3,4 positions of thiophene by―OCH3, ―CH3―COOCH3 and ―CN, respectively. The polycondensations via direct arylation took place between the four thiophene derivatives and 2,7-dibromo-9,9-dioctylfluorene under six various catalytic conditions to investigate the substituent effects. The substituent can affect the electron cloud density of the active C―H bond, which can be monitored by the NMR chemical shift. The experimental results show that the reactivity decreases with increasing the chemical shift of active C―H bonds in the four thiophene derivatives, and thus can promote the direct arylation polycondensation. This phenomenon is explained by the electrophilic aromatic substitution（SEAr） mechanism. UV-Visible absorption and photoluminescence were studied to investigate the substituent effect on optical properties of the four copolymers. The results show that these alternating fluorene-thiophene copolymers with different substituents are good fluorescent materials and promising in PLED applications.
基金This work was supported by the China National Key Research and Development Plan(No.2020YFB1807204).
文摘Recently,cell-free(CF)massive multipleinput multiple-output(MIMO)becomes a promising architecture for the next generation wireless communication system,where a large number of distributed access points(APs)are deployed to simultaneously serve multiple user equipments(UEs)for improved performance.Meanwhile,a clustered CF system is considered to tackle the backhaul overhead issue in the huge connection network.In this paper,taking into account the more realistic mobility scenarios,we propose a hybrid small-cell(SC)and clustered CF massive MIMO system through classifications of the UEs and APs,and constructing the corresponding pairs to run in SC or CF mode.A joint initial AP selection of this paradigm for all the UEs is firstly proposed,which is based on the statistics of estimated channel.Then,closed-form expressions of the downlink achievable rates for both the static and moving UEs are provided under Ricean fading channel and Doppler shift effect.We also develop a semi-heuristic search algorithm to deal with the AP selection for the moving UEs by maximizing the weight average achievable rate.Numerical results demonstrate the performance gains and effective rates balancing of the proposed system.
基金Supported by the Foundation of Educational Ministry of China.
文摘The theory of chemical shift effect of substituent was applied to the assignment of the 13 C NMR spectra of the ethylene/propylene and ethylene/octene 1 copolymers. Using the parameters derived above and the DEPT technique, we then entirely assigned the 13 C NMR spectra of the ethylene/propylene/octene 1 terpolymers synthesized in the presence of the same heterogeneous supported Ziegler Natta catalyst, TiCl 4/MgCl 2/ i Bu 3Al. The present paper also covers the terpolymer composition and the monomer sequence distributions of a series of ethylene/propylene/octene 1 terpolymers.
文摘For studying the influence of smoking on temporary threshold shift (TTS), six normal subjects (3 smokers and 3 nonsmokers) were selected for carrying out this work. Nonsmokers were exposed separately for 7 min to 95 dB SPL in 1/3-octave band filtered noise centred at 2 kHz. Pre and post exposure thresholds (leftear) were recorded in a sound-proof booth using Bruel & Kjaer (B & K) Audiometer type 1800. For smokers, each one smoked a cigarette during the five minutes following the pre-exposure threshold measurement. All the assessments were conducted at a temperature between 22-25℃. The results indicated that smokers evidenced less TTS than did nonsmokers in the frequency range from 1 kHz to 5 kHz. At 6 kHz smokers evidenced nearly higher value. Maximum TTS was attained at frequency that was about 1/2-octave higher than that of the exposed noise. Comparison between recovery curves for smokers and nonsmokers was also made.
基金Supported by the National Natural Science Foundation of China(12135006,12075097,12047527,11775092)by the Fundamental Research Funds for the Central Universities(CCNU20TS007,CCNU19TD012,CCNU22LJ004)。
文摘The Dirac neutrino masses could be simply generated by a neutrinophilic scalar doublet with a vacuum being dramatically different from the electroweak one.While the case with an eV-scale vacuum has been widely explored previously,we exploit in this work the desert where the scalar vacuum is of O(keV)scale.In this regime,there would be rare hope to probe the keV-vacuum neutrinophilic scalar model via the lepton-flavor-violating processes,which makes it distinguishable from the widely considered eV-scale vacuum.Although such a keV-vacuum scenario is inert in the low-energy flavor physics,we show that the baryogenesis realized via the lightest Dirac neutrino can be a natural candidate in explaining the baryon asymmetry of the Universe.Furthermore,the Dirac neutrinos with a keV-vacuum scalar can generate a shift of the effective neutrino number within the range 0.097≤ΔN_(eff)≤0.112,which can be probed by the future Simons Observatory experiments.In particular,the model with a minimal valueΔN_(eff)=0.097 can already be falsified by the future CMB Stage-Ⅳand Large Scale Structure surveys,providing consequently striking exploratory avenues in the cosmological regime for such a keV-vacuum scenario.
