The water extracted from the shale rock (shale water) through the pyrolysis process to obtain fuel oil and other products shows a composition based on organic compounds and a wide range of minerals and trace elements ...The water extracted from the shale rock (shale water) through the pyrolysis process to obtain fuel oil and other products shows a composition based on organic compounds and a wide range of minerals and trace elements with an important role in plant nutrition, suggesting its use as a fertilizer. Thus, the influence of foliar application of shale water (SW), with or without the micronutrients zinc (Zn), manganese (Mn), copper (Cu), boro (B) and molybdenum (Mo), was evaluated regarding yield and quality of maize grains. The yield, the total antioxidant activity, and the content of starch, phenolic compounds and carotenoids were improved in maize grains following the application of three doses of 7 L/ha of SW, which indicates that SW may influence the primary and secondary metabolisms. The application of SW with micronutrients resulted in the increase of grain yield;however, did not result in the improvement of grain quality. The foliar fertilizer formulations also had an influence in the content of minerals and aminoacids of the grain. The results indicate that SW has potential to be used in agriculture to improve yield and quality of maize.展开更多
Upper cretaceous and lower tertiary formations groundwater aquifers are associated with huge reserves of oil shale deposits in Harrana and Azraq Basins are evaluated in terms of water qualities and hydrochemical proce...Upper cretaceous and lower tertiary formations groundwater aquifers are associated with huge reserves of oil shale deposits in Harrana and Azraq Basins are evaluated in terms of water qualities and hydrochemical processes. The oil shale deposits are found within the Muwaqqar Chalk Marl Formation. The Muwaqqar Chalk Marl Formation represents the intermediate formation between the Lower Aquifer Amman Silicified Limestone and the overburden, which represents the overlying Upper Aquifers of Um Rijam Chalk and Wadi Shallala Chalk. This study aimed to improve the understanding of Muwaqqar Chalk Marl Formation as a sealing potential based on water quality and hydrochemical data of the different aquifers. Sixty water samples were collected from Amman Silicified Limestone Aquifer, High Grade Zone of Muwaqqar Chalk Marl Formation and from the overburden of Um Rijam Chalk and Wadi Shallala Chalk aquifers. The evaluations of the main hydrochemical processes affecting the groundwater quality were carried out by interpreting the ionic relationships and the water quality types using Piper and Durov diagrams. Comprehensive statistical analyses (Factor and Cluster Analyses) were conducted on the water quality parameters. The factor analyses can extract four factors from the water quality parameters of the Harrana wells Area-1 and for Azraq wells in Area-2. These factors are used to interpret the different geochemical processes affecting the groundwater quality parameters. Cluster analyses divided the Harrana wells into three groups. Cluster I included 26 wells with minimum mean concentrations of cations and anions, while cluster III included the wells with the highest concentrations in the water quality parameters. Cluster II included eight wells with intermediate concentrations. Azraq Area-2 wells are clustered into three groups. Cluster I includes seven wells with lowest water quality (highest concentrations);cluster II includes 12 wells and exhibits the lowest concentrations of ions and cluster III includes five wells that show intermediate ions concentrations. The interpretation indicated that the primary factors controlling the groundwater chemistry of Azraq and Harrana appeared to be dissolution processes of the carbonate rocks containing traces of evaporitic minerals, ion exchange and reversal ion exchange processes. Moreover, the water quality in the study areas is not suitable for drinking purposes.展开更多
As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental mode...As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental modelling of shale gas formation, the shale gas generation and accumulation mechanisms as well as their coupling relationships of deep-water shelf shales in Wufeng–Longmaxi Formation of Sichuan Basin were analyzed from petrology, mineralogy, and geochemistry. The high quality shales of Wufeng–Longmaxi Formation in Sichuan Basin are characterized by high thermal evolution, high hydrocarbon generation intensity, good material base, and good roof and floor conditions;the high quality deep-water shelf shale not only has high biogenic silicon content and organic carbon content, but also high porosity coupling. It is concluded that:(1) The shales had good preservation conditions and high retainment of crude oil in the early times, and the shale gas was mainly from cracking of crude oil.(2) The biogenic silicon(opal A) turned into crystal quartz in early times of burial diagenesis, lots of micro-size intergranular pores were produced in the same time;moreover, the biogenic silicon frame had high resistance to compaction, thus it provided the conditions not only for oil charge in the early stage, but also for formation and preservation of nanometer cellular-like pores, and was the key factor enabling the preservation of organic pores.(3) The high quality shale of Wufeng–Longmaxi Formation had high brittleness, strong homogeneity, siliceous intergranular micro-pores and nanometer organic pores, which were conducive to the formation of complicated fissure network connecting the siliceous intergranular nano-pores, and thus high and stable production of shale gas.展开更多
Oil shale samples from Sultani oil shale mine, south of Jordan, were pyrolyzed by a partial combustion to generate shale oil. The produced water was sent for analysis. The different samples were analyzed for carbon co...Oil shale samples from Sultani oil shale mine, south of Jordan, were pyrolyzed by a partial combustion to generate shale oil. The produced water was sent for analysis. The different samples were analyzed for carbon content, and results showed that the TOC was 2010 mg per liter of retorted water. Phenol and arsenic contents were measured and found to be 64 mg and 0.18 mg per liter respectively. Phosphate and sulfate were also determined and found to be 35.7 and 5022 mg per liter. On the other hand, ammonium was also found to be 2831 mg per liter. Several elements were traced and reported in the present work, in which arsenic, chrome and nickel are the most important, and the retorted water was found to contain 0.18, 0.7 and 0.5 mg per liter.展开更多
To better understand the mechanism of the strength weakening process of soft rocks in deep mines after interacting with water, a self-developed experimental system, Intelligent Testing System for Water Absorption in D...To better understand the mechanism of the strength weakening process of soft rocks in deep mines after interacting with water, a self-developed experimental system, Intelligent Testing System for Water Absorption in Deep Soft Rocks （ITSWADSR）, is employed to analyze the hydrophilic behavior of deep calcareous shale sampled from Daqiang coal mine. Experimental results demonstrate that the relation between water absorption and time can be expressed by power functions, and the soakage rate decreases while the soakage increases with time. In order to quantitatively calculate the weight coefficients of the influential factors for water absorbing capacity of rocks, a series of testing methods are adopted, including scanning electron microscope （SEM）, X-ray diffraction and mercury injection test. It is demonstrated that the effective porosity has a positive correlation with the water absorbing capacity of rocks and the contents of illite and illite/smectite. The initial water content presents a negative correlation with the water absorption capacity of rocks. According to the absolute value of weight coefficients of various influential factors, the order of magnitude from high to low is captured： initial water content, illite, illite/smectite formation （S=5%）, and the effective porosity. After water absorption tests, uniaxial compressive strength （UCS） tests were performed on rock specimens allowing a linear relationship between the UCS and the water content of rock to be established, indicating that the strength of calcareous shale decreases linearly with the increasing water content.展开更多
The X-ray fluorescence and ICP methods were used to analyze 60 outcrop samples of black shale, of which 15 were collected from Belait, 15 from the Setap Shale, 15 from Temburong, and 15 from the Trusmadi for- mations....The X-ray fluorescence and ICP methods were used to analyze 60 outcrop samples of black shale, of which 15 were collected from Belait, 15 from the Setap Shale, 15 from Temburong, and 15 from the Trusmadi for- mations. The average compositions of the shales from the study area are 64.62%, 63.95%, 62.32%, 63.84% SiO2, 1.84%, 2.14%, 2.04%, 1.99% MgO, 2.55%, 3.12%, 2.89%, 2.72% K2O, 0.32%, 0.30%, 0.32%, 0.53% CaO, 5.86%, 6.06%, 7.14%, 6.60% Fe2O3, 207×10-6, 180×10-6, 213×10-6, 200×10-6 Rb, and 56×10-6, 49×10-6, 50×10-6, 32×10-6 Sr for the Setap Shale, Temburong, Belait and Trusmadi samples, respectively. The high Rb/Sr ratios of 3.8, 3.7, 4.2, and 6.1 are attributed to the lowest contents of Sr due to reducing conditions prevailing. The high Rb/K ratio sug- gests either brackish marine or rapid deposition that prevented equilibrium between Rb and K in the shales and ma- rine waters.展开更多
The development of unconventional resources in tight shales has stimulated considerable growth of oil and gas production in Northeastern Colorado, but has led to concerns about added demands on the region’s strained ...The development of unconventional resources in tight shales has stimulated considerable growth of oil and gas production in Northeastern Colorado, but has led to concerns about added demands on the region’s strained water resources. Northeastern Colorado’s semi-arid environment, population growth, competing water demands and uncertainty about drilling and hydraulic fracturing water requirements have resulted in scrutiny and conflict surrounding water use for tight shales. This study collects water use data from wells in Northeastern Colorado to improve water estimates and to better understand important contributing factors. Most water resource studies use estimates for the number of future wells to predict water demands. This study shows that the number of hydraulic fracturing stages is a better measure of the future water demands for horizontal wells. Vertical wells use significantly less water than horizontal wells and will be less prevalent in the future.展开更多
水力压裂液回流废水(Flowback Produced Water,FPW)是压裂液混合地层水后伴随油气资源回流至地表的废水,是页岩油气资源开采过程中的副产品之一。与常规油气开采不同,压裂作业经历更广泛的时空变化和地质化学变化,FPW中组分更加复杂,稳...水力压裂液回流废水(Flowback Produced Water,FPW)是压裂液混合地层水后伴随油气资源回流至地表的废水,是页岩油气资源开采过程中的副产品之一。与常规油气开采不同,压裂作业经历更广泛的时空变化和地质化学变化,FPW中组分更加复杂,稳定性更强,处理更加复杂。分级处理通过一系列分步处理工艺对采出水进行分层净化,目的是去除不同粒径、成分和浓度的污染物,使其达到再利用或排放标准。综述了水力压裂液回流废水的环境危害及分级处理方法。系统总结了各分步处理工艺、目标污染物及其去除效果,并展望了该领域未来的重点研究方向。展开更多
文摘The water extracted from the shale rock (shale water) through the pyrolysis process to obtain fuel oil and other products shows a composition based on organic compounds and a wide range of minerals and trace elements with an important role in plant nutrition, suggesting its use as a fertilizer. Thus, the influence of foliar application of shale water (SW), with or without the micronutrients zinc (Zn), manganese (Mn), copper (Cu), boro (B) and molybdenum (Mo), was evaluated regarding yield and quality of maize grains. The yield, the total antioxidant activity, and the content of starch, phenolic compounds and carotenoids were improved in maize grains following the application of three doses of 7 L/ha of SW, which indicates that SW may influence the primary and secondary metabolisms. The application of SW with micronutrients resulted in the increase of grain yield;however, did not result in the improvement of grain quality. The foliar fertilizer formulations also had an influence in the content of minerals and aminoacids of the grain. The results indicate that SW has potential to be used in agriculture to improve yield and quality of maize.
文摘Upper cretaceous and lower tertiary formations groundwater aquifers are associated with huge reserves of oil shale deposits in Harrana and Azraq Basins are evaluated in terms of water qualities and hydrochemical processes. The oil shale deposits are found within the Muwaqqar Chalk Marl Formation. The Muwaqqar Chalk Marl Formation represents the intermediate formation between the Lower Aquifer Amman Silicified Limestone and the overburden, which represents the overlying Upper Aquifers of Um Rijam Chalk and Wadi Shallala Chalk. This study aimed to improve the understanding of Muwaqqar Chalk Marl Formation as a sealing potential based on water quality and hydrochemical data of the different aquifers. Sixty water samples were collected from Amman Silicified Limestone Aquifer, High Grade Zone of Muwaqqar Chalk Marl Formation and from the overburden of Um Rijam Chalk and Wadi Shallala Chalk aquifers. The evaluations of the main hydrochemical processes affecting the groundwater quality were carried out by interpreting the ionic relationships and the water quality types using Piper and Durov diagrams. Comprehensive statistical analyses (Factor and Cluster Analyses) were conducted on the water quality parameters. The factor analyses can extract four factors from the water quality parameters of the Harrana wells Area-1 and for Azraq wells in Area-2. These factors are used to interpret the different geochemical processes affecting the groundwater quality parameters. Cluster analyses divided the Harrana wells into three groups. Cluster I included 26 wells with minimum mean concentrations of cations and anions, while cluster III included the wells with the highest concentrations in the water quality parameters. Cluster II included eight wells with intermediate concentrations. Azraq Area-2 wells are clustered into three groups. Cluster I includes seven wells with lowest water quality (highest concentrations);cluster II includes 12 wells and exhibits the lowest concentrations of ions and cluster III includes five wells that show intermediate ions concentrations. The interpretation indicated that the primary factors controlling the groundwater chemistry of Azraq and Harrana appeared to be dissolution processes of the carbonate rocks containing traces of evaporitic minerals, ion exchange and reversal ion exchange processes. Moreover, the water quality in the study areas is not suitable for drinking purposes.
基金Supported by the China National Science and Technology Major Project(2017ZX05036,2017ZX05036001).
文摘As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental modelling of shale gas formation, the shale gas generation and accumulation mechanisms as well as their coupling relationships of deep-water shelf shales in Wufeng–Longmaxi Formation of Sichuan Basin were analyzed from petrology, mineralogy, and geochemistry. The high quality shales of Wufeng–Longmaxi Formation in Sichuan Basin are characterized by high thermal evolution, high hydrocarbon generation intensity, good material base, and good roof and floor conditions;the high quality deep-water shelf shale not only has high biogenic silicon content and organic carbon content, but also high porosity coupling. It is concluded that:(1) The shales had good preservation conditions and high retainment of crude oil in the early times, and the shale gas was mainly from cracking of crude oil.(2) The biogenic silicon(opal A) turned into crystal quartz in early times of burial diagenesis, lots of micro-size intergranular pores were produced in the same time;moreover, the biogenic silicon frame had high resistance to compaction, thus it provided the conditions not only for oil charge in the early stage, but also for formation and preservation of nanometer cellular-like pores, and was the key factor enabling the preservation of organic pores.(3) The high quality shale of Wufeng–Longmaxi Formation had high brittleness, strong homogeneity, siliceous intergranular micro-pores and nanometer organic pores, which were conducive to the formation of complicated fissure network connecting the siliceous intergranular nano-pores, and thus high and stable production of shale gas.
文摘Oil shale samples from Sultani oil shale mine, south of Jordan, were pyrolyzed by a partial combustion to generate shale oil. The produced water was sent for analysis. The different samples were analyzed for carbon content, and results showed that the TOC was 2010 mg per liter of retorted water. Phenol and arsenic contents were measured and found to be 64 mg and 0.18 mg per liter respectively. Phosphate and sulfate were also determined and found to be 35.7 and 5022 mg per liter. On the other hand, ammonium was also found to be 2831 mg per liter. Several elements were traced and reported in the present work, in which arsenic, chrome and nickel are the most important, and the retorted water was found to contain 0.18, 0.7 and 0.5 mg per liter.
基金Supported by the Key Basic Research Program of China(2006CB202200)the National Major Project of Ministry of Education of China(304005)
文摘To better understand the mechanism of the strength weakening process of soft rocks in deep mines after interacting with water, a self-developed experimental system, Intelligent Testing System for Water Absorption in Deep Soft Rocks （ITSWADSR）, is employed to analyze the hydrophilic behavior of deep calcareous shale sampled from Daqiang coal mine. Experimental results demonstrate that the relation between water absorption and time can be expressed by power functions, and the soakage rate decreases while the soakage increases with time. In order to quantitatively calculate the weight coefficients of the influential factors for water absorbing capacity of rocks, a series of testing methods are adopted, including scanning electron microscope （SEM）, X-ray diffraction and mercury injection test. It is demonstrated that the effective porosity has a positive correlation with the water absorbing capacity of rocks and the contents of illite and illite/smectite. The initial water content presents a negative correlation with the water absorption capacity of rocks. According to the absolute value of weight coefficients of various influential factors, the order of magnitude from high to low is captured： initial water content, illite, illite/smectite formation （S=5%）, and the effective porosity. After water absorption tests, uniaxial compressive strength （UCS） tests were performed on rock specimens allowing a linear relationship between the UCS and the water content of rock to be established, indicating that the strength of calcareous shale decreases linearly with the increasing water content.
文摘The X-ray fluorescence and ICP methods were used to analyze 60 outcrop samples of black shale, of which 15 were collected from Belait, 15 from the Setap Shale, 15 from Temburong, and 15 from the Trusmadi for- mations. The average compositions of the shales from the study area are 64.62%, 63.95%, 62.32%, 63.84% SiO2, 1.84%, 2.14%, 2.04%, 1.99% MgO, 2.55%, 3.12%, 2.89%, 2.72% K2O, 0.32%, 0.30%, 0.32%, 0.53% CaO, 5.86%, 6.06%, 7.14%, 6.60% Fe2O3, 207×10-6, 180×10-6, 213×10-6, 200×10-6 Rb, and 56×10-6, 49×10-6, 50×10-6, 32×10-6 Sr for the Setap Shale, Temburong, Belait and Trusmadi samples, respectively. The high Rb/Sr ratios of 3.8, 3.7, 4.2, and 6.1 are attributed to the lowest contents of Sr due to reducing conditions prevailing. The high Rb/K ratio sug- gests either brackish marine or rapid deposition that prevented equilibrium between Rb and K in the shales and ma- rine waters.
文摘The development of unconventional resources in tight shales has stimulated considerable growth of oil and gas production in Northeastern Colorado, but has led to concerns about added demands on the region’s strained water resources. Northeastern Colorado’s semi-arid environment, population growth, competing water demands and uncertainty about drilling and hydraulic fracturing water requirements have resulted in scrutiny and conflict surrounding water use for tight shales. This study collects water use data from wells in Northeastern Colorado to improve water estimates and to better understand important contributing factors. Most water resource studies use estimates for the number of future wells to predict water demands. This study shows that the number of hydraulic fracturing stages is a better measure of the future water demands for horizontal wells. Vertical wells use significantly less water than horizontal wells and will be less prevalent in the future.
文摘水力压裂液回流废水(Flowback Produced Water,FPW)是压裂液混合地层水后伴随油气资源回流至地表的废水,是页岩油气资源开采过程中的副产品之一。与常规油气开采不同,压裂作业经历更广泛的时空变化和地质化学变化,FPW中组分更加复杂,稳定性更强,处理更加复杂。分级处理通过一系列分步处理工艺对采出水进行分层净化,目的是去除不同粒径、成分和浓度的污染物,使其达到再利用或排放标准。综述了水力压裂液回流废水的环境危害及分级处理方法。系统总结了各分步处理工艺、目标污染物及其去除效果,并展望了该领域未来的重点研究方向。
