The ＂sergeants and soldiers rule＂ occurring in helical copolymer emulsions derived from an achiral monomer （M1） and a chiral monomer （M2） was observed. TEM, GPC, and 1H-NMR techniques in combination demonstrate ...The ＂sergeants and soldiers rule＂ occurring in helical copolymer emulsions derived from an achiral monomer （M1） and a chiral monomer （M2） was observed. TEM, GPC, and 1H-NMR techniques in combination demonstrate the formation of nanoparticles constituted by the copolymers. CD and UV-Vis spectra show the （co）polymer chains in the nanoparticles adopt helical structures of a predominant helicity, and the copolymers follow the ＂sergeants and soldiers rule＂ in forming helical structure.展开更多
基金supported by the National Natural Science Foundation of China (Nos. 21174010, 20974007)the Fundamental Research Funds for the Central Universities (ZZ1117)
文摘The ＂sergeants and soldiers rule＂ occurring in helical copolymer emulsions derived from an achiral monomer （M1） and a chiral monomer （M2） was observed. TEM, GPC, and 1H-NMR techniques in combination demonstrate the formation of nanoparticles constituted by the copolymers. CD and UV-Vis spectra show the （co）polymer chains in the nanoparticles adopt helical structures of a predominant helicity, and the copolymers follow the ＂sergeants and soldiers rule＂ in forming helical structure.
