This paper reviewed the trend and development of semi-solid metal technique. The processes and mechanisms for producing slurry of SSM and its industrial applications have been summarized and discussed. Discussions on ...This paper reviewed the trend and development of semi-solid metal technique. The processes and mechanisms for producing slurry of SSM and its industrial applications have been summarized and discussed. Discussions on the basic rheological theory are presented for more applications. Further consideration of the development and application of SSM technique is also proposed.展开更多
The microstructural evolution of AZ91D magnesium alloy prepared by means of the cyclic upsetting-extrusion and partial remelting was investigated. The effects of remelting temperature and holding time on microstructur...The microstructural evolution of AZ91D magnesium alloy prepared by means of the cyclic upsetting-extrusion and partial remelting was investigated. The effects of remelting temperature and holding time on microstructure of semi-solid AZ91D magnesium alloy were studied. Furthermore, tensile properties of thixoextruded AZ91D magnesium alloy components were determined. The results show that the cyclic upsetting-extrusion followed by partial remelting is effective in producing semi-solid AZ91D magnesium alloy for thixofonning. During the partial remelting, with the increase of remelting temperature and holding time, the solid grain size increases and the degree of spheroidization tends to be improved. The tensile mechanical properties of thixoextruded AZ91D magnesium alloy components produced by cyclic upsetting-extrusion and partial remelting are better than those of the same alloy produced by casting.展开更多
A route combining powder metallurgy and subsequent friction stir processing was utilized to fabricate carbon nanotube （CNT） reinforced AI （CNT/AI） and 6061AI （CNT/6061AI） composites. Microstructural observations...A route combining powder metallurgy and subsequent friction stir processing was utilized to fabricate carbon nanotube （CNT） reinforced AI （CNT/AI） and 6061AI （CNT/6061AI） composites. Microstructural observations indicated that CNTs were uniformly dispersed in the matrix in both CNT/AI and CNT/6061AI composites. Mg and Si elements tended to segregate at CNT-AI interfaces in the CNT/6061AI composite during artificial aging treatment. The tensile properties of both the AI and 6061AI were increased by CNT incorporation. The electrical conductivity of CNT/AI was decreased by CNT addition, while CNT/6061AI exhibited an increase in electrical conductivity due to the Mg and Si segregation.展开更多
Owing to its low cost,short process and low energy consumption,semi-solid processing(SSP)of aluminum(Al)and magnesium(Mg)alloys has been considered as a competitive approach to fabricate complicated components with ex...Owing to its low cost,short process and low energy consumption,semi-solid processing(SSP)of aluminum(Al)and magnesium(Mg)alloys has been considered as a competitive approach to fabricate complicated components with excellent performance.Over the past decade,significant progress has been achieved in deeply understanding the SSP process,the microstructure and performance of the fabricated components in China.This paper starts with a retrospective overview of some common slurry preparation methods,followed by presenting the performance and the underlying mechanisms of SSP fabricated alloys.Then,the mainstream opinions on the microstructure evolution and rheological flow behavior of semi-solid slurry are discussed.Subsequently,the general situation and some recent examples of industrial applications of SSP are presented.Finally,special attention is paid to the unresolved issues and the future directions in SSP of Al and Mg alloys in China.展开更多
The feasibility of semi solid processing of hypereutectic A390 alloys using a novel rheoforming process was investigated. A combination of the swirl enthalpy equilibration device （SEED） process, isothermal holding u...The feasibility of semi solid processing of hypereutectic A390 alloys using a novel rheoforming process was investigated. A combination of the swirl enthalpy equilibration device （SEED） process, isothermal holding using insulation and addition of solid alloy during swirling was introduced as a novel method to improve the processability of semi solid slurry. The effects of isothermal holding and the addition of solid alloy on the temperature gradient between the centre and the wall and on the formation of a（Al） particles were examined. In additional tests, phosphorus and strontium were added to the molten metal to refine the primary and eutectic silicon structure to facilitate semi solid processing. The results show that the combination of the SEED process with two additional processing steps can produce semi-solid A390 alloys that can be rheoprocessed. The microstructure reveals an adequate amount of non-dendritic a（Al） globules surrounded by liquid, which greatly improves the processability of semi-solid slurry.展开更多
Structure evolution of an Al-Zn wrought alloy in remelting processing in thestrain induced melt activated (SIMA) serai-solid procedure was observed, and effects of factors, theremelting temperature, the holding time, ...Structure evolution of an Al-Zn wrought alloy in remelting processing in thestrain induced melt activated (SIMA) serai-solid procedure was observed, and effects of factors, theremelting temperature, the holding time, and the compression strain, on structures and grain sizesof the alloy were investigated. The results show that (1) the proper temperature of remelting is inthe range of 610 to 615℃; (2) the grain size in specimen with greater compression strain is smallerthan that with smaller compression strain in condition of the same remelting temperature andholding time, and the grain size in local area with great local equivalent strain is smaller thanthat with small one; (3) liquid occurs in form of cluster in matrix during remelting and itsquantity increases with remelting time increasing; liquid in specimen with great compression strainoccurs earlier than that with small one, and quantity of liquid in the center of specimen withgreater local equivalent strain is greater than that in the two ends of it; (4) distortion energyafter deforming in matrix of the alloy is the significant factor to activate melting of matrix atlocal area with great local equivalent strain.展开更多
In this study, friction stir processing（FSP） was employed to modify cold-sprayed（CSed） AA2024/Al2 O3 metal matrix composites（MMCs）. Three different rotation speeds with a constant traverse speed were used for FS...In this study, friction stir processing（FSP） was employed to modify cold-sprayed（CSed） AA2024/Al2 O3 metal matrix composites（MMCs）. Three different rotation speeds with a constant traverse speed were used for FSP. Microstructural analysis of the FSPed specimens reveals significant Al2 O3 particle refinement and improved particle distribution over the as-sprayed deposits. After FSP, a microstructural and mechanical gradient MMC through the thickness direction was obtained. Therefore, a hybrid technique combining these two solid-state processes, i.e. CS and FSP, was proposed to produce functionally gradient deposits. The Guinier-Preston-Bagaryatskii zone was dissolved during FSP, while the amounts at different rotation speeds were approximately the same, which is possibly due to the excellent thermal conductivity of the used Cu substrate. Mechanical property tests confirm that FSP can effectively improve the tensile performance and Vickers hardness of CSed AA2024/Al2 O3 MMCs. The properties can be further enhanced with a larger rotation speed with a maximum increase of 25.9% in ultimate tensile strength and27.4% in elongation at 1500 rpm. Friction tests show that FSP decreases the wear resistance of CSed MMCs deposits due to the breakup of Al2 O3 particles. The average values and fluctuations of friction coefficients at different rotation speeds vary significantly.展开更多
The mechanical properties of metal yttrium such as strength, plasticity, hardness and elasticity were introduced . The purifying techniques of yttrium were discussed in detail. The processing methods for metal yttrium...The mechanical properties of metal yttrium such as strength, plasticity, hardness and elasticity were introduced . The purifying techniques of yttrium were discussed in detail. The processing methods for metal yttrium including extruding, forging, rolling, wiredrawing and welding were also introduced. Finally, the potential use of yttrium and its alloys were prospected.展开更多
As a new attempt to recycle minute metal scraps, the possibility of manufacturing design materials by semisolid extrusion processing was shown.A design material with an intended shape, such as a character or petal sha...As a new attempt to recycle minute metal scraps, the possibility of manufacturing design materials by semisolid extrusion processing was shown.A design material with an intended shape, such as a character or petal shape, was manufactured using minute metal scraps.Similarly, a design material with an intended color pattern for each metal, such as red copper in a white aluminum matrix, resembling grainlike wood, was manufactured by mixing two or more types of minute metal scrap.In addition, secondary design materials, which have engraved patterns on the surface of the target metal made by an electric discharge machine using the above primary design material as an electrode, were manufactured.展开更多
Rising concerns about climate change drive the demand for lightweight components.Magnesium(Mg)alloys are highly valued for their low weight,making them increasingly important in various industries.Researchers focusing...Rising concerns about climate change drive the demand for lightweight components.Magnesium(Mg)alloys are highly valued for their low weight,making them increasingly important in various industries.Researchers focusing on enhancing the characteristics of Mg alloys and developing their Metal Matrix Composites(MMCs)have gained significant attention worldwide over the past decade,driven by the global shift towards lightweight materials.Friction Stir Processing(FSP)has emerged as a promising technique to enhance the properties of Mg alloys and produce Mg-MMCs.Initially,FSP adapted to refine grain size from the micro to the nano level and accelerated the development of MMCs due to its solid-state nature and the synergistic effects of microstructure refinement and reinforcement,improving strength,hardness,ductility,wear resistance,corrosion resistance,and fatigue strength.However,producing defect-free and sound FSPed Mg and Mg-MMCs requires addressing several variables and their interdependencies,which opens up a broad range of practical applications.Despite existing reviews on individual FSP of Mg,its alloys,and MMCs,an attempt has been made to analyze the latest research on these three aspects collectively to enhance the understanding,application,and effectiveness of FSP for Mg and its derivatives.This review article discusses the literature,classifies the importance of Mg alloys,provides a historical background,and explores developments and potential applications of FSPed Mg alloys.It focuses on novel fabrication methods,reinforcement strategies,machine and tool design parameters,material characterization,and integration with other methods for enhanced properties.The influence of process parameters and the emergence of defects are examined,along with specific applications in mono and hybrid composites and their microstructure evolution.The study identifies promising reinforcement materials and highlights research gaps in FSP for Mg alloys and MMCs production.It concludes with significant recommendations for further exploration,reflecting ongoing advancements in this field.展开更多
It has been more than ten years since the semi-solid processing (SSP) technique was put into commercial applications in the world. A lot of work on semi-solid metals (SSM) including their preparation, reheating and se...It has been more than ten years since the semi-solid processing (SSP) technique was put into commercial applications in the world. A lot of work on semi-solid metals (SSM) including their preparation, reheating and semi-solid forming has been done in China. In order to produce the high quality die-casting, a novel innovation that modifies the present machines based on the SSP technique was proposed. Semi-solid die-casting on modified casting machines can manufacture parts with more excellent quality than those produced by squeeze casting. It was found that the defects such as 'elephant foot' and 'periphery liquid metal loss' during reheating could be avoided through controlling the non-dendritic structure of billets and optimizing the reheating process. The processing parameters and mold designs of semi-solid die-casting are fairly different from those of liquid die-casting.展开更多
In order to compare the workability of AZ110 alloy with and without addition of La-rich Mish Metal(MM), hot compression tests were performed on a Gleeble-3500 D thermo-mechanical simulator at the deformation temperatu...In order to compare the workability of AZ110 alloy with and without addition of La-rich Mish Metal(MM), hot compression tests were performed on a Gleeble-3500 D thermo-mechanical simulator at the deformation temperature range of 473-623 K and strain rate range of 0.001-1 s-1. The flow stress, constitutive relation, DRX kinetic model, processing map and microstructure characterization of the alloys were investigated. The results show that the flow stress is very sensitive to deformation temperature and strain rate, and the peak stress of AZ110 LC(LC = La-rich MM) alloy is higher than that of AZ110 alloy.The hot deformation behavior of the alloys can be accurately predicted by the constitutive relations. The derived constitutive equations show that the calculated activation energy Q and stress exponent n for AZ110 alloy are higher than the calculated values of AZ110 LC alloy. The analysis of DRX kinetic models show that the development of DRX in AZ110 LC alloy is earlier than AZ110 alloy at the same deformation condition. The processing maps show that the workability of AZ110 LC alloy is significantly more excellent than AZ110 alloy and the microstructures are in good agreement with the calculated results.The AZ110 LC alloys can obtain complete DRX microstructure at high strain rate due to its higher stored energy and weak basal texture.展开更多
A recrystallization and partial melting(RAP) process was introduced to prepare the semi-solid 7075 aluminum alloy used for thixoforming. In order to obtain an ideal semi-solid microstructure, a series of extrusion exp...A recrystallization and partial melting(RAP) process was introduced to prepare the semi-solid 7075 aluminum alloy used for thixoforming. In order to obtain an ideal semi-solid microstructure, a series of extrusion experiments were conducted to comparatively investigate the optimum extrusion process parameters. Commercial 7075 Al alloy samples were firstly extruded with varying extrusion ratios below the recrystallization temperature followed by homogenization, then these samples were reheated to the semi-solid state and held in the range of 5 to 50 minutes. The experimental results show that varying process cause the difference in the deformation degree and microstructure for as-extruded samples, resulting in various semi-solid microstructure. It is verified that the formation of equiaxed grains in semi-solid microstructure depends on recrystallization behavior of extruded samples during partial melting. Both relative high extrusion temperature and low extrusion ratio lead to high volume fraction of recrystallized area, thus entirely equiaxed solid grains in semi-solid 7075 Al alloy samples can be obtained finally. In addition, Ostwald ripening was determined as the dominate coarsening mechanism of solid grains in semi-solid state for this 7075 Al alloy during the RAP route. The influence of predeformation on recrystallization behavior of this 7075 Al alloy was discussed in detail.展开更多
The influence of geometric configuration on the friction characteristics during incremental sheet forming of AA5052 was analyzed by integrating surface morphology and its characteristic parameters,along with plastic s...The influence of geometric configuration on the friction characteristics during incremental sheet forming of AA5052 was analyzed by integrating surface morphology and its characteristic parameters,along with plastic strain,contact pressure,and area.The interface promotes lubrication and support when wall angles were≤40°,a 0.5 mm-thin sheet was used,and a 10 mm-large tool radius was employed.This mainly results in micro-plowing and plastic extrusion flow,leading to lower friction coefficient.However,when wall angles exceed 40°,significant plastic strain roughening occurs,leading to inadequate lubrication on the newly formed surface.Increased sheet thickness and decreased tool radius elevate contact pressure.These actions trigger micro-cutting and adhesion,potentially leading to localized scuffing and dimple tears,and higher friction coefficient.The friction mechanisms remain unaffected by the part’s plane curve features.As the forming process progresses,abrasive wear intensifies,and surface morphology evolves unfavorably for lubrication and friction reduction.展开更多
The amyloid beta precursor protein (APP) and its pathogenic byproduct β-amyloid peptide (Aβ) play central roles in the pathogenesis of Alzheimer’s disease (AD). Reduction in
The energy dissipation caused by the viscous force has great effects on the flow property of semi-solid metal during rheological processes such as slurry preparing, delivering and cavity filling. Experimental results ...The energy dissipation caused by the viscous force has great effects on the flow property of semi-solid metal during rheological processes such as slurry preparing, delivering and cavity filling. Experimental results in this paper indicate that the viscous friction between semi-solid metal and pipe wall, the collisions among the solid particles, and the liquid flow around particles are the three main types of energy dissipation. On the basis of the hydromechanics, the energy dissipation calculation model is built. It is demonstrated that the micro-structural parameters such as effective solid fraction, particle size and shape, and flow parameters such as the mean velocity, the fluctuant velocity of particles and the relative velocity between the fluid and solid phase, affect the energy dissipation of semi-solid metal.展开更多
This study investigated the rheological properties of semi-solid metal. An analytical model of apparent viscosity was built up based on analysis of energy dissipation during rheological processes such as slurry prepar...This study investigated the rheological properties of semi-solid metal. An analytical model of apparent viscosity was built up based on analysis of energy dissipation during rheological processes such as slurry preparing, delivering and model filling. The rheological properties of SSM （semi-solid metal） slurry was described by an analytical model in terms of microstructural parameters, which consist of effective solid fraction, particle size and shape, and flow parameters such as mean velocity, fluctuant velocity and relative velocity between liquid and solid phase. The model was verified in the experiment of A356 alloys with a coaxial double-bucket rheometer. And the maximum relative error between the theoretical value and measured one is less than 20%. The results of experiment and theoretical calculation also indicate that the microstructural parameters and flow parameters are two major factors that affect the apparent viscosity of semi-solid alloys, and fluctuant velocity and relative velocity between liquid and solid phase are the key factors to distinguish between steady and transient rheological properties.展开更多
Digital light processing(DLP)is widely used in ceramic additive manufacturing.However,it remains unexplored for metals.In this study,the regulatory mechanisms of the microstructure and mechanical properties of AISI 31...Digital light processing(DLP)is widely used in ceramic additive manufacturing.However,it remains unexplored for metals.In this study,the regulatory mechanisms of the microstructure and mechanical properties of AISI 316L stainless steel were investigated by optimizing a DLP-compatible metal slurry formulation and sintering process.A photosensitive resin system(mass ratio of 5:1:2:2 for U600,LA,ACMO,and HDDA,respectively)with 88 wt%solid content is designed to achieve a slurry with balanced rheology,photocurability,and low pyrolysis residue.Compared to vacuum sintering,which leads to brittle fracture of material,the Ar/H2 mixed gas(5%H2)effectively reduces carbon and oxygen impurities via reduction,mitigating carbide and oxide segregation at grain boundaries and within grains,thereby enhancing strength-ductility.In addition,the prolonged high-temperature sintering inducesδ-ferrite precipitation at grain boundaries,which fills residual pores to improve densification obviously.Under optimized sintering conditions(Ar/H2,1380°C,6 h),the material achieves 96.2%relative density with tensile strength and fracture elongation of 543.5 MPa and 58.7%,respectively,exhibiting uniform dimple-dominated fracture morphology.This synergistic optimization of the slurry formulation and sintering parameters improves the strength-ductility balance in DLP-fabricated metal materials,offering theoretical and technical insights for the additive manufacturing of complex high-performance metal components.展开更多
A new three-dimensional multiphase numerical model was built.The volume of fluid and k-ε turbulence models were used to investigate the hot metal ladle pouring process.During the pouring process,issues such as iron s...A new three-dimensional multiphase numerical model was built.The volume of fluid and k-ε turbulence models were used to investigate the hot metal ladle pouring process.During the pouring process,issues such as iron splashing,overflow,and significant heat loss are prevalent.To realize efficient and stable pouring,the effects of ladle tilting velocity,flow rate,and converter tilting angle on the pouring process were examined.The model was verified by comparing the actual pouring time with the numerical results.It is shown that there is a nonlinear relationship between pouring velocity and hot metal flow rate at the ladle mouth.As the mass flow increased and the converter tilting angle decreased,the impact point of the hot metal into the converter pool shifted from the side wall to the bottom,and the impact force increased accordingly.The pouring velocity curve was optimized by the volume difference of the ladle at different angles,and an empirical formula was derived.After the optimization of pouring speed,the flow rate was stabilized between 4000 and 6000 kg/s,and the pouring time was reduced by approximately 30 s.After applying this model in actual production,the hot metal temperature inside the converter increased by approximately 5℃statistically.This model is potential to enhance the production efficiency,stability,and safety of the pouring process between open containers.展开更多
Even though vacuum induction melting(VIM)is widely employed in the industrial production of bulk metallic glasses(BMGs),the effect and mechanism of the interfacial reaction between the melt and the oxide ceramic cruci...Even though vacuum induction melting(VIM)is widely employed in the industrial production of bulk metallic glasses(BMGs),the effect and mechanism of the interfacial reaction between the melt and the oxide ceramic crucible on BMG formations are not yet fully understood.Here,the influences and mechanisms of the interfacial reaction on a Zr-based BMG(Vit 105)subjected to various melting temperatures and holding times are revealed by employing experiments and theoretical calculations.We find that the degree of interfacial reaction is intriguingly correlated with the process parameters during VIM processing,leading to an increase in the oxygen content of the alloy and the reaction layer thickness.Besides,the increase of oxygen content also induces variations in the ordering and shear transformation zone(STZ)size of the BMGs,thus resulting in the precipitation of a nanoscale fcc phase and affecting the mechanical properties and reliability under deformation of the alloy.Furthermore,thermodynamic and kinetic parameters involved in the interfacial reaction,such as the molar Gibbs free energy of each element,the apparent activation energy,etc.,are obtained,providing a comprehensive understanding of the transport processes at play.Our findings provide new insights into the preparation of BMGs by VIM and may be expanded to other melting techniques to accelerate the commercial application of metallic glasses.展开更多
基金the National Natural Science foundation of China! (59995440)
文摘This paper reviewed the trend and development of semi-solid metal technique. The processes and mechanisms for producing slurry of SSM and its industrial applications have been summarized and discussed. Discussions on the basic rheological theory are presented for more applications. Further consideration of the development and application of SSM technique is also proposed.
文摘The microstructural evolution of AZ91D magnesium alloy prepared by means of the cyclic upsetting-extrusion and partial remelting was investigated. The effects of remelting temperature and holding time on microstructure of semi-solid AZ91D magnesium alloy were studied. Furthermore, tensile properties of thixoextruded AZ91D magnesium alloy components were determined. The results show that the cyclic upsetting-extrusion followed by partial remelting is effective in producing semi-solid AZ91D magnesium alloy for thixofonning. During the partial remelting, with the increase of remelting temperature and holding time, the solid grain size increases and the degree of spheroidization tends to be improved. The tensile mechanical properties of thixoextruded AZ91D magnesium alloy components produced by cyclic upsetting-extrusion and partial remelting are better than those of the same alloy produced by casting.
基金the support of the National Basic Research Program,China(Grant Nos.2011CB932603 and 2012CB619600)the National Natural Science Foundation, China(Grant No.51331008)
文摘A route combining powder metallurgy and subsequent friction stir processing was utilized to fabricate carbon nanotube （CNT） reinforced AI （CNT/AI） and 6061AI （CNT/6061AI） composites. Microstructural observations indicated that CNTs were uniformly dispersed in the matrix in both CNT/AI and CNT/6061AI composites. Mg and Si elements tended to segregate at CNT-AI interfaces in the CNT/6061AI composite during artificial aging treatment. The tensile properties of both the AI and 6061AI were increased by CNT incorporation. The electrical conductivity of CNT/AI was decreased by CNT addition, while CNT/6061AI exhibited an increase in electrical conductivity due to the Mg and Si segregation.
基金financial supports from the Shenzhen Science and Technology Innovation Commission, China (Nos. KQTD20170328154443162, JCYJ20180305123432756)。
文摘Owing to its low cost,short process and low energy consumption,semi-solid processing(SSP)of aluminum(Al)and magnesium(Mg)alloys has been considered as a competitive approach to fabricate complicated components with excellent performance.Over the past decade,significant progress has been achieved in deeply understanding the SSP process,the microstructure and performance of the fabricated components in China.This paper starts with a retrospective overview of some common slurry preparation methods,followed by presenting the performance and the underlying mechanisms of SSP fabricated alloys.Then,the mainstream opinions on the microstructure evolution and rheological flow behavior of semi-solid slurry are discussed.Subsequently,the general situation and some recent examples of industrial applications of SSP are presented.Finally,special attention is paid to the unresolved issues and the future directions in SSP of Al and Mg alloys in China.
基金the financial support provided by the Natural Sciences and Engineering Research Council of Canada (NSERC) and Rio Tinto Alcan through the NSERC Industrial Research Chair in Metallurgy of Aluminum Transformation at Université du Québec à Chicoutimi
文摘The feasibility of semi solid processing of hypereutectic A390 alloys using a novel rheoforming process was investigated. A combination of the swirl enthalpy equilibration device （SEED） process, isothermal holding using insulation and addition of solid alloy during swirling was introduced as a novel method to improve the processability of semi solid slurry. The effects of isothermal holding and the addition of solid alloy on the temperature gradient between the centre and the wall and on the formation of a（Al） particles were examined. In additional tests, phosphorus and strontium were added to the molten metal to refine the primary and eutectic silicon structure to facilitate semi solid processing. The results show that the combination of the SEED process with two additional processing steps can produce semi-solid A390 alloys that can be rheoprocessed. The microstructure reveals an adequate amount of non-dendritic a（Al） globules surrounded by liquid, which greatly improves the processability of semi-solid slurry.
文摘Structure evolution of an Al-Zn wrought alloy in remelting processing in thestrain induced melt activated (SIMA) serai-solid procedure was observed, and effects of factors, theremelting temperature, the holding time, and the compression strain, on structures and grain sizesof the alloy were investigated. The results show that (1) the proper temperature of remelting is inthe range of 610 to 615℃; (2) the grain size in specimen with greater compression strain is smallerthan that with smaller compression strain in condition of the same remelting temperature andholding time, and the grain size in local area with great local equivalent strain is smaller thanthat with small one; (3) liquid occurs in form of cluster in matrix during remelting and itsquantity increases with remelting time increasing; liquid in specimen with great compression strainoccurs earlier than that with small one, and quantity of liquid in the center of specimen withgreater local equivalent strain is greater than that in the two ends of it; (4) distortion energyafter deforming in matrix of the alloy is the significant factor to activate melting of matrix atlocal area with great local equivalent strain.
基金financially by the National Key Research and Development Program of China (No. 2016YFB1100104)the Fund of SAST (No. SAST2016043)the 111 Project (No. B08040)
文摘In this study, friction stir processing（FSP） was employed to modify cold-sprayed（CSed） AA2024/Al2 O3 metal matrix composites（MMCs）. Three different rotation speeds with a constant traverse speed were used for FSP. Microstructural analysis of the FSPed specimens reveals significant Al2 O3 particle refinement and improved particle distribution over the as-sprayed deposits. After FSP, a microstructural and mechanical gradient MMC through the thickness direction was obtained. Therefore, a hybrid technique combining these two solid-state processes, i.e. CS and FSP, was proposed to produce functionally gradient deposits. The Guinier-Preston-Bagaryatskii zone was dissolved during FSP, while the amounts at different rotation speeds were approximately the same, which is possibly due to the excellent thermal conductivity of the used Cu substrate. Mechanical property tests confirm that FSP can effectively improve the tensile performance and Vickers hardness of CSed AA2024/Al2 O3 MMCs. The properties can be further enhanced with a larger rotation speed with a maximum increase of 25.9% in ultimate tensile strength and27.4% in elongation at 1500 rpm. Friction tests show that FSP decreases the wear resistance of CSed MMCs deposits due to the breakup of Al2 O3 particles. The average values and fluctuations of friction coefficients at different rotation speeds vary significantly.
文摘The mechanical properties of metal yttrium such as strength, plasticity, hardness and elasticity were introduced . The purifying techniques of yttrium were discussed in detail. The processing methods for metal yttrium including extruding, forging, rolling, wiredrawing and welding were also introduced. Finally, the potential use of yttrium and its alloys were prospected.
文摘As a new attempt to recycle minute metal scraps, the possibility of manufacturing design materials by semisolid extrusion processing was shown.A design material with an intended shape, such as a character or petal shape, was manufactured using minute metal scraps.Similarly, a design material with an intended color pattern for each metal, such as red copper in a white aluminum matrix, resembling grainlike wood, was manufactured by mixing two or more types of minute metal scrap.In addition, secondary design materials, which have engraved patterns on the surface of the target metal made by an electric discharge machine using the above primary design material as an electrode, were manufactured.
文摘Rising concerns about climate change drive the demand for lightweight components.Magnesium(Mg)alloys are highly valued for their low weight,making them increasingly important in various industries.Researchers focusing on enhancing the characteristics of Mg alloys and developing their Metal Matrix Composites(MMCs)have gained significant attention worldwide over the past decade,driven by the global shift towards lightweight materials.Friction Stir Processing(FSP)has emerged as a promising technique to enhance the properties of Mg alloys and produce Mg-MMCs.Initially,FSP adapted to refine grain size from the micro to the nano level and accelerated the development of MMCs due to its solid-state nature and the synergistic effects of microstructure refinement and reinforcement,improving strength,hardness,ductility,wear resistance,corrosion resistance,and fatigue strength.However,producing defect-free and sound FSPed Mg and Mg-MMCs requires addressing several variables and their interdependencies,which opens up a broad range of practical applications.Despite existing reviews on individual FSP of Mg,its alloys,and MMCs,an attempt has been made to analyze the latest research on these three aspects collectively to enhance the understanding,application,and effectiveness of FSP for Mg and its derivatives.This review article discusses the literature,classifies the importance of Mg alloys,provides a historical background,and explores developments and potential applications of FSPed Mg alloys.It focuses on novel fabrication methods,reinforcement strategies,machine and tool design parameters,material characterization,and integration with other methods for enhanced properties.The influence of process parameters and the emergence of defects are examined,along with specific applications in mono and hybrid composites and their microstructure evolution.The study identifies promising reinforcement materials and highlights research gaps in FSP for Mg alloys and MMCs production.It concludes with significant recommendations for further exploration,reflecting ongoing advancements in this field.
基金This Work financially supported by the China National Advanced Materials Committee
文摘It has been more than ten years since the semi-solid processing (SSP) technique was put into commercial applications in the world. A lot of work on semi-solid metals (SSM) including their preparation, reheating and semi-solid forming has been done in China. In order to produce the high quality die-casting, a novel innovation that modifies the present machines based on the SSP technique was proposed. Semi-solid die-casting on modified casting machines can manufacture parts with more excellent quality than those produced by squeeze casting. It was found that the defects such as 'elephant foot' and 'periphery liquid metal loss' during reheating could be avoided through controlling the non-dendritic structure of billets and optimizing the reheating process. The processing parameters and mold designs of semi-solid die-casting are fairly different from those of liquid die-casting.
基金financially supported by the National Key Research and Development Program of China(No.2016YFB0301104)the National Natural Science Foundation of China(No.51771043)support by State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization。
文摘In order to compare the workability of AZ110 alloy with and without addition of La-rich Mish Metal(MM), hot compression tests were performed on a Gleeble-3500 D thermo-mechanical simulator at the deformation temperature range of 473-623 K and strain rate range of 0.001-1 s-1. The flow stress, constitutive relation, DRX kinetic model, processing map and microstructure characterization of the alloys were investigated. The results show that the flow stress is very sensitive to deformation temperature and strain rate, and the peak stress of AZ110 LC(LC = La-rich MM) alloy is higher than that of AZ110 alloy.The hot deformation behavior of the alloys can be accurately predicted by the constitutive relations. The derived constitutive equations show that the calculated activation energy Q and stress exponent n for AZ110 alloy are higher than the calculated values of AZ110 LC alloy. The analysis of DRX kinetic models show that the development of DRX in AZ110 LC alloy is earlier than AZ110 alloy at the same deformation condition. The processing maps show that the workability of AZ110 LC alloy is significantly more excellent than AZ110 alloy and the microstructures are in good agreement with the calculated results.The AZ110 LC alloys can obtain complete DRX microstructure at high strain rate due to its higher stored energy and weak basal texture.
基金Funded by the National Natural Science Foundation of China(Nos.51774054 and 51974050)
文摘A recrystallization and partial melting(RAP) process was introduced to prepare the semi-solid 7075 aluminum alloy used for thixoforming. In order to obtain an ideal semi-solid microstructure, a series of extrusion experiments were conducted to comparatively investigate the optimum extrusion process parameters. Commercial 7075 Al alloy samples were firstly extruded with varying extrusion ratios below the recrystallization temperature followed by homogenization, then these samples were reheated to the semi-solid state and held in the range of 5 to 50 minutes. The experimental results show that varying process cause the difference in the deformation degree and microstructure for as-extruded samples, resulting in various semi-solid microstructure. It is verified that the formation of equiaxed grains in semi-solid microstructure depends on recrystallization behavior of extruded samples during partial melting. Both relative high extrusion temperature and low extrusion ratio lead to high volume fraction of recrystallized area, thus entirely equiaxed solid grains in semi-solid 7075 Al alloy samples can be obtained finally. In addition, Ostwald ripening was determined as the dominate coarsening mechanism of solid grains in semi-solid state for this 7075 Al alloy during the RAP route. The influence of predeformation on recrystallization behavior of this 7075 Al alloy was discussed in detail.
基金the support of the Key Research and Development Program of Shaanxi Province,China(No.2021GXLH-Z-049)。
文摘The influence of geometric configuration on the friction characteristics during incremental sheet forming of AA5052 was analyzed by integrating surface morphology and its characteristic parameters,along with plastic strain,contact pressure,and area.The interface promotes lubrication and support when wall angles were≤40°,a 0.5 mm-thin sheet was used,and a 10 mm-large tool radius was employed.This mainly results in micro-plowing and plastic extrusion flow,leading to lower friction coefficient.However,when wall angles exceed 40°,significant plastic strain roughening occurs,leading to inadequate lubrication on the newly formed surface.Increased sheet thickness and decreased tool radius elevate contact pressure.These actions trigger micro-cutting and adhesion,potentially leading to localized scuffing and dimple tears,and higher friction coefficient.The friction mechanisms remain unaffected by the part’s plane curve features.As the forming process progresses,abrasive wear intensifies,and surface morphology evolves unfavorably for lubrication and friction reduction.
文摘The amyloid beta precursor protein (APP) and its pathogenic byproduct β-amyloid peptide (Aβ) play central roles in the pathogenesis of Alzheimer’s disease (AD). Reduction in
文摘The energy dissipation caused by the viscous force has great effects on the flow property of semi-solid metal during rheological processes such as slurry preparing, delivering and cavity filling. Experimental results in this paper indicate that the viscous friction between semi-solid metal and pipe wall, the collisions among the solid particles, and the liquid flow around particles are the three main types of energy dissipation. On the basis of the hydromechanics, the energy dissipation calculation model is built. It is demonstrated that the micro-structural parameters such as effective solid fraction, particle size and shape, and flow parameters such as the mean velocity, the fluctuant velocity of particles and the relative velocity between the fluid and solid phase, affect the energy dissipation of semi-solid metal.
文摘This study investigated the rheological properties of semi-solid metal. An analytical model of apparent viscosity was built up based on analysis of energy dissipation during rheological processes such as slurry preparing, delivering and model filling. The rheological properties of SSM （semi-solid metal） slurry was described by an analytical model in terms of microstructural parameters, which consist of effective solid fraction, particle size and shape, and flow parameters such as mean velocity, fluctuant velocity and relative velocity between liquid and solid phase. The model was verified in the experiment of A356 alloys with a coaxial double-bucket rheometer. And the maximum relative error between the theoretical value and measured one is less than 20%. The results of experiment and theoretical calculation also indicate that the microstructural parameters and flow parameters are two major factors that affect the apparent viscosity of semi-solid alloys, and fluctuant velocity and relative velocity between liquid and solid phase are the key factors to distinguish between steady and transient rheological properties.
基金supported by National Natural Science Foundation of China(Grant Nos.52205231,52205196)Taishan Scholars Program,and Research Project of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai(Grant Nos.AMGM0613,AMGM0620).
文摘Digital light processing(DLP)is widely used in ceramic additive manufacturing.However,it remains unexplored for metals.In this study,the regulatory mechanisms of the microstructure and mechanical properties of AISI 316L stainless steel were investigated by optimizing a DLP-compatible metal slurry formulation and sintering process.A photosensitive resin system(mass ratio of 5:1:2:2 for U600,LA,ACMO,and HDDA,respectively)with 88 wt%solid content is designed to achieve a slurry with balanced rheology,photocurability,and low pyrolysis residue.Compared to vacuum sintering,which leads to brittle fracture of material,the Ar/H2 mixed gas(5%H2)effectively reduces carbon and oxygen impurities via reduction,mitigating carbide and oxide segregation at grain boundaries and within grains,thereby enhancing strength-ductility.In addition,the prolonged high-temperature sintering inducesδ-ferrite precipitation at grain boundaries,which fills residual pores to improve densification obviously.Under optimized sintering conditions(Ar/H2,1380°C,6 h),the material achieves 96.2%relative density with tensile strength and fracture elongation of 543.5 MPa and 58.7%,respectively,exhibiting uniform dimple-dominated fracture morphology.This synergistic optimization of the slurry formulation and sintering parameters improves the strength-ductility balance in DLP-fabricated metal materials,offering theoretical and technical insights for the additive manufacturing of complex high-performance metal components.
基金supported by the National Natural Science Foundation of China(Grant Nos.52104318 and 52374322).
文摘A new three-dimensional multiphase numerical model was built.The volume of fluid and k-ε turbulence models were used to investigate the hot metal ladle pouring process.During the pouring process,issues such as iron splashing,overflow,and significant heat loss are prevalent.To realize efficient and stable pouring,the effects of ladle tilting velocity,flow rate,and converter tilting angle on the pouring process were examined.The model was verified by comparing the actual pouring time with the numerical results.It is shown that there is a nonlinear relationship between pouring velocity and hot metal flow rate at the ladle mouth.As the mass flow increased and the converter tilting angle decreased,the impact point of the hot metal into the converter pool shifted from the side wall to the bottom,and the impact force increased accordingly.The pouring velocity curve was optimized by the volume difference of the ladle at different angles,and an empirical formula was derived.After the optimization of pouring speed,the flow rate was stabilized between 4000 and 6000 kg/s,and the pouring time was reduced by approximately 30 s.After applying this model in actual production,the hot metal temperature inside the converter increased by approximately 5℃statistically.This model is potential to enhance the production efficiency,stability,and safety of the pouring process between open containers.
基金financially supported by the National Natural Science Foundation of China(Nos.51827801 and 52371152)the National Key Research and Development Program of China(Nos.2023YFB3710801,2023YFB3710802,and 2021YFB3704002)+1 种基金the Fundamental Research Funds for the Central Universities(No.FRFCU5710001320)the fellowship from the China Scholarship Council(CSC,No.202406120125)for the Visiting PhD Student Program.
文摘Even though vacuum induction melting(VIM)is widely employed in the industrial production of bulk metallic glasses(BMGs),the effect and mechanism of the interfacial reaction between the melt and the oxide ceramic crucible on BMG formations are not yet fully understood.Here,the influences and mechanisms of the interfacial reaction on a Zr-based BMG(Vit 105)subjected to various melting temperatures and holding times are revealed by employing experiments and theoretical calculations.We find that the degree of interfacial reaction is intriguingly correlated with the process parameters during VIM processing,leading to an increase in the oxygen content of the alloy and the reaction layer thickness.Besides,the increase of oxygen content also induces variations in the ordering and shear transformation zone(STZ)size of the BMGs,thus resulting in the precipitation of a nanoscale fcc phase and affecting the mechanical properties and reliability under deformation of the alloy.Furthermore,thermodynamic and kinetic parameters involved in the interfacial reaction,such as the molar Gibbs free energy of each element,the apparent activation energy,etc.,are obtained,providing a comprehensive understanding of the transport processes at play.Our findings provide new insights into the preparation of BMGs by VIM and may be expanded to other melting techniques to accelerate the commercial application of metallic glasses.
