采用CALPHAD(CALculation of PHAse Diagrams)方法重新对Mg-Al-Gd三元系进行评估,获得一套自洽的热力学参数。用Mg_(x)(TM,Mg)_(6)(RE,Mg)_(8)热力学模型(TM=过渡金属,RE=稀土金属)描述长周期堆积有序相14H和18R。计算代表性的等温截面...采用CALPHAD(CALculation of PHAse Diagrams)方法重新对Mg-Al-Gd三元系进行评估,获得一套自洽的热力学参数。用Mg_(x)(TM,Mg)_(6)(RE,Mg)_(8)热力学模型(TM=过渡金属,RE=稀土金属)描述长周期堆积有序相14H和18R。计算代表性的等温截面、垂直截面、液相线投影图和相关的零变量反应,与实验数据进行比较,表明所得热力学参数的可靠性。绘制了整个三元体系的反应图,并对几种Mg-Al-Gd合金的Scheil凝固路径和相分数进行计算和分析,清楚地描述了凝固过程中各相的形成以及γ和LPSO相的相分数随Gd成分的变化,这些是影响Mg-Al-Gd合金的显微硬度、极限抗拉强度和屈服强度的重要因素。展开更多
Based on the modified Scheil model of solute redistribution,the effects of solidification rate,molten steel flow,and alloy composition on solute macrosegregation during the solidification of carbon steel continuous ca...Based on the modified Scheil model of solute redistribution,the effects of solidification rate,molten steel flow,and alloy composition on solute macrosegregation during the solidification of carbon steel continuous casting billet are calculated and analyzed. The formation mechanism of "white band "segregation under the condition of electromagnetic stirring is also involved,and some practical countermeasures to restrain the central segregation are suggested. The results show that the modified Scheil model can be applied to predict and analyze the macrosegregation of casting slab effectively. The ratio vx/R of the flow velocity of molten steel to solidification rate has decisive formations of segregation such as linear,V,and "white band"types. It is an effective way to select sufficient terminal cooling and reasonable electromagnetic stirring in order to decrease macrosegregation in the slab. The concept of the characteristic distance of solute enrichment layer can drastically simplify the calculation of solute redistribution at the solid/liquid interface of various elements in carbon steel.展开更多
基金The financial supports from the National Key Laboratory of Science and Technology on High-strength Structural Materialsthe National Natural Science Foundation of China(No.51771235)。
文摘采用CALPHAD(CALculation of PHAse Diagrams)方法重新对Mg-Al-Gd三元系进行评估,获得一套自洽的热力学参数。用Mg_(x)(TM,Mg)_(6)(RE,Mg)_(8)热力学模型(TM=过渡金属,RE=稀土金属)描述长周期堆积有序相14H和18R。计算代表性的等温截面、垂直截面、液相线投影图和相关的零变量反应,与实验数据进行比较,表明所得热力学参数的可靠性。绘制了整个三元体系的反应图,并对几种Mg-Al-Gd合金的Scheil凝固路径和相分数进行计算和分析,清楚地描述了凝固过程中各相的形成以及γ和LPSO相的相分数随Gd成分的变化,这些是影响Mg-Al-Gd合金的显微硬度、极限抗拉强度和屈服强度的重要因素。
文摘Based on the modified Scheil model of solute redistribution,the effects of solidification rate,molten steel flow,and alloy composition on solute macrosegregation during the solidification of carbon steel continuous casting billet are calculated and analyzed. The formation mechanism of "white band "segregation under the condition of electromagnetic stirring is also involved,and some practical countermeasures to restrain the central segregation are suggested. The results show that the modified Scheil model can be applied to predict and analyze the macrosegregation of casting slab effectively. The ratio vx/R of the flow velocity of molten steel to solidification rate has decisive formations of segregation such as linear,V,and "white band"types. It is an effective way to select sufficient terminal cooling and reasonable electromagnetic stirring in order to decrease macrosegregation in the slab. The concept of the characteristic distance of solute enrichment layer can drastically simplify the calculation of solute redistribution at the solid/liquid interface of various elements in carbon steel.
