In this paper, a regression method of estimation has been used to derive the mean estimate of the survey variable using simple random sampling without replacement in the presence of observational errors. Two covariate...In this paper, a regression method of estimation has been used to derive the mean estimate of the survey variable using simple random sampling without replacement in the presence of observational errors. Two covariates were used and a case where the observational errors were in both the survey variable and the covariates was considered. The inclusion of observational errors was due to the fact that data collected through surveys are often not free from errors that occur during observation. These errors can occur due to over-reporting, under-reporting, memory failure by the respondents or use of imprecise tools of data collection. The expression of mean squared error (MSE) based on the obtained estimator has been derived to the first degree of approximation. The results of a simulation study show that the derived modified regression mean estimator under observational errors is more efficient than the mean per unit estimator and some other existing estimators. The proposed estimator can therefore be used in estimating a finite population mean, while considering observational errors that may occur during a study.展开更多
An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction.The extraction procedure（including loading,...An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction.The extraction procedure（including loading, washing, and eluting） used a flow rate of1.0 m L/min, and dicyandiamide was eluted with 20 m L of a methanol/acetonitrile mixture（V/V = 2：3）, followed by pre-concentration using nitrogen evaporation and analysis with high performance liquid chromatography–ultraviolet spectroscopy（HPLC–UV）. Sample extraction was carried out using a Waters Sep-Pak AC-2 Cartridge（with activated carbon）.Separation was achieved on a ZIC-Hydrophilic Interaction Liquid Chromatography（ZIC-HILIC）（50 mm × 2.1 mm, 3.5 μm） chromatography column and quantification was accomplished based on UV absorbance. A reliable linear relationship was obtained for the calibration curve using standard solutions（R^2〉 0.999）. Recoveries for dicyandiamide ranged from 84.6% to 96.8%, and the relative standard deviations（RSDs, n = 3） were below 6.1% with a detection limit of 5.0 ng/m L for stream water samples.展开更多
文摘In this paper, a regression method of estimation has been used to derive the mean estimate of the survey variable using simple random sampling without replacement in the presence of observational errors. Two covariates were used and a case where the observational errors were in both the survey variable and the covariates was considered. The inclusion of observational errors was due to the fact that data collected through surveys are often not free from errors that occur during observation. These errors can occur due to over-reporting, under-reporting, memory failure by the respondents or use of imprecise tools of data collection. The expression of mean squared error (MSE) based on the obtained estimator has been derived to the first degree of approximation. The results of a simulation study show that the derived modified regression mean estimator under observational errors is more efficient than the mean per unit estimator and some other existing estimators. The proposed estimator can therefore be used in estimating a finite population mean, while considering observational errors that may occur during a study.
基金Department of Chemistry at Mississippi State University for financial support for this project
文摘An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction.The extraction procedure（including loading, washing, and eluting） used a flow rate of1.0 m L/min, and dicyandiamide was eluted with 20 m L of a methanol/acetonitrile mixture（V/V = 2：3）, followed by pre-concentration using nitrogen evaporation and analysis with high performance liquid chromatography–ultraviolet spectroscopy（HPLC–UV）. Sample extraction was carried out using a Waters Sep-Pak AC-2 Cartridge（with activated carbon）.Separation was achieved on a ZIC-Hydrophilic Interaction Liquid Chromatography（ZIC-HILIC）（50 mm × 2.1 mm, 3.5 μm） chromatography column and quantification was accomplished based on UV absorbance. A reliable linear relationship was obtained for the calibration curve using standard solutions（R^2〉 0.999）. Recoveries for dicyandiamide ranged from 84.6% to 96.8%, and the relative standard deviations（RSDs, n = 3） were below 6.1% with a detection limit of 5.0 ng/m L for stream water samples.
