Laser-ablation laser-induced breakdown spectroscopy (LA-LIBS) based on single Nd:YAG laser is used to analyze copper impurity in silver jewellery with enhanced sensitivity and minimal sample ablation. 6-30 folds si...Laser-ablation laser-induced breakdown spectroscopy (LA-LIBS) based on single Nd:YAG laser is used to analyze copper impurity in silver jewellery with enhanced sensitivity and minimal sample ablation. 6-30 folds signal enhancement can be achieved under the re-excitation of the breakdown laser and the spatial resolution is only determined by the ablation laser. 50 ppm limit of detection of copper is achieved when the crater diameter is 17.2 μm under current experimental condition. This technique gives higher analysis sensitivity under the same sample ablation in comparison with single pulse (SP) LIBS. It is useful for high sensitive element mieroanalvsis of precious samples.展开更多
Deep neural networks(DNNs)are widely used in real-world applications,thanks to their exceptional performance in image recognition.However,their vulnerability to attacks,such as Trojan and data poison,can compromise th...Deep neural networks(DNNs)are widely used in real-world applications,thanks to their exceptional performance in image recognition.However,their vulnerability to attacks,such as Trojan and data poison,can compromise the integrity and stability of DNN applications.Therefore,it is crucial to verify the integrity of DNN models to ensure their security.Previous research on model watermarking for integrity detection has encountered the issue of overexposure of model parameters during embedding and extraction of the watermark.To address this problem,we propose a novel score-based black-box DNN fragile watermarking framework called fragile trigger generation(FTG).The FTG framework only requires the prediction probability distribution of the final output of the classifier during the watermarking process.It generates different fragile samples as the trigger,based on the classification prediction probability of the target classifier and a specified prediction probability mask to watermark it.Different prediction probability masks can promote the generation of fragile samples in corresponding distribution types.The whole watermarking process does not affect the performance of the target classifier.When verifying the watermarking information,the FTG only needs to compare the prediction results of the model on the samples with the previous label.As a result,the required model parameter information is reduced,and the FTG only needs a few samples to detect slight modifications in the model.Experimental results demonstrate the effectiveness of our proposed method and show its superiority over related work.The FTG framework provides a robust solution for verifying the integrity of DNN models,and its effectiveness in detecting slight modifications makes it a valuable tool for ensuring the security and stability of DNN applications.展开更多
基金the National"973"Program of China(No.2012CB921900)the National Natural Science Foundation of China(Nos.11274123 and 11304100)the Basic Scientific Research Program of South China University of Technology(No.2014ZZ0066)
文摘Laser-ablation laser-induced breakdown spectroscopy (LA-LIBS) based on single Nd:YAG laser is used to analyze copper impurity in silver jewellery with enhanced sensitivity and minimal sample ablation. 6-30 folds signal enhancement can be achieved under the re-excitation of the breakdown laser and the spatial resolution is only determined by the ablation laser. 50 ppm limit of detection of copper is achieved when the crater diameter is 17.2 μm under current experimental condition. This technique gives higher analysis sensitivity under the same sample ablation in comparison with single pulse (SP) LIBS. It is useful for high sensitive element mieroanalvsis of precious samples.
基金supported by Research Funders National Natural Science Foundation of China(62172001,U22B2047,62076147).
文摘Deep neural networks(DNNs)are widely used in real-world applications,thanks to their exceptional performance in image recognition.However,their vulnerability to attacks,such as Trojan and data poison,can compromise the integrity and stability of DNN applications.Therefore,it is crucial to verify the integrity of DNN models to ensure their security.Previous research on model watermarking for integrity detection has encountered the issue of overexposure of model parameters during embedding and extraction of the watermark.To address this problem,we propose a novel score-based black-box DNN fragile watermarking framework called fragile trigger generation(FTG).The FTG framework only requires the prediction probability distribution of the final output of the classifier during the watermarking process.It generates different fragile samples as the trigger,based on the classification prediction probability of the target classifier and a specified prediction probability mask to watermark it.Different prediction probability masks can promote the generation of fragile samples in corresponding distribution types.The whole watermarking process does not affect the performance of the target classifier.When verifying the watermarking information,the FTG only needs to compare the prediction results of the model on the samples with the previous label.As a result,the required model parameter information is reduced,and the FTG only needs a few samples to detect slight modifications in the model.Experimental results demonstrate the effectiveness of our proposed method and show its superiority over related work.The FTG framework provides a robust solution for verifying the integrity of DNN models,and its effectiveness in detecting slight modifications makes it a valuable tool for ensuring the security and stability of DNN applications.