This work shows the extraction of cesium (Cs^+) and rubidium (Rb^+) from salt lake brine containing potassium (K^+) and magnesium (Mg^2+). The results show that 4-tert-butyl-2-(α-methylbenzyl) phenol ( t -BAMBP) dilu...This work shows the extraction of cesium (Cs^+) and rubidium (Rb^+) from salt lake brine containing potassium (K^+) and magnesium (Mg^2+). The results show that 4-tert-butyl-2-(α-methylbenzyl) phenol ( t -BAMBP) diluted in sulfonated kerosene (SK) has an excellent extraction effect. Infrared spectroscopic studies indicate that polymerize to form the dimer in the t -BAMBP when Cs^+ or Rb^+ were extracted. The effects of K^+, Mg^2+, t -BAMBP concentration, the volume ratio of organic phase to aqueous phase (O/A) and the alkalinity (pH) of aqueous phase were investigated. The K^+ and Mg^2+ should be eliminated through precipitating before the extraction and separation of Cs^+ and Rb^+.The optimum extraction conditions of the experimental brine were as follows: 0.8 mol/L t -BAMBP diluted in SK, pH≥13, a phase ratio of 1:1, and an extraction contact time of 2 min at room temperature. The optimal extraction yields of Cs^+ and Rb^+ were as high as 100% and 85.8%, in addition, 8.76% of K^+ was co-extracted. Further work would increase the extraction yield and selectivity of Rb^+ and realize the efficient separation of Cs^+ and Rb^+ from brine.展开更多
Over the last 25 years the conservation of 20^(th)-century heritage has developed into a distinct area of practice, catalysed by the efforts of dedicated international and local interest groups and the forward thinkin...Over the last 25 years the conservation of 20^(th)-century heritage has developed into a distinct area of practice, catalysed by the efforts of dedicated international and local interest groups and the forward thinking of a number of government and inter-government organisations who identified, protected and developed approaches to its care. Much has been achieved, but more work is needed to address many of the distinct challenges to conserving the heritage of the 20^(th) century. In 2011, the Getty Conservation Institute (GCI) launched its Conserving Modern Architecture Initiative (CMAI), which seeks to respond to the outstanding current challenges and contribute to advancing practice in this emerging area of conservation. It began with a survey of the field to identify where existing efforts could be best supported and enhanced, or where knowledge gaps could be potentially filled. In response the GCI built a comprehensive program to meet these identified needs and five years later, a number of activities and projects are underway. These include a series of publications, a training program, historical and technical research and two field projects at Louis Kahn’s Salk Biological Institute (1965) and the house of Ray and Charles Eames (1949), both in California. This paper outlines current GCI efforts, reports on initial outcomes and describes forthcoming activities.展开更多
基金Science and Technology Department of Qinghai province(2019-ZJ-7001,2015-ZJ-945Q)“Light of West China”program,CAS
文摘This work shows the extraction of cesium (Cs^+) and rubidium (Rb^+) from salt lake brine containing potassium (K^+) and magnesium (Mg^2+). The results show that 4-tert-butyl-2-(α-methylbenzyl) phenol ( t -BAMBP) diluted in sulfonated kerosene (SK) has an excellent extraction effect. Infrared spectroscopic studies indicate that polymerize to form the dimer in the t -BAMBP when Cs^+ or Rb^+ were extracted. The effects of K^+, Mg^2+, t -BAMBP concentration, the volume ratio of organic phase to aqueous phase (O/A) and the alkalinity (pH) of aqueous phase were investigated. The K^+ and Mg^2+ should be eliminated through precipitating before the extraction and separation of Cs^+ and Rb^+.The optimum extraction conditions of the experimental brine were as follows: 0.8 mol/L t -BAMBP diluted in SK, pH≥13, a phase ratio of 1:1, and an extraction contact time of 2 min at room temperature. The optimal extraction yields of Cs^+ and Rb^+ were as high as 100% and 85.8%, in addition, 8.76% of K^+ was co-extracted. Further work would increase the extraction yield and selectivity of Rb^+ and realize the efficient separation of Cs^+ and Rb^+ from brine.
文摘Over the last 25 years the conservation of 20^(th)-century heritage has developed into a distinct area of practice, catalysed by the efforts of dedicated international and local interest groups and the forward thinking of a number of government and inter-government organisations who identified, protected and developed approaches to its care. Much has been achieved, but more work is needed to address many of the distinct challenges to conserving the heritage of the 20^(th) century. In 2011, the Getty Conservation Institute (GCI) launched its Conserving Modern Architecture Initiative (CMAI), which seeks to respond to the outstanding current challenges and contribute to advancing practice in this emerging area of conservation. It began with a survey of the field to identify where existing efforts could be best supported and enhanced, or where knowledge gaps could be potentially filled. In response the GCI built a comprehensive program to meet these identified needs and five years later, a number of activities and projects are underway. These include a series of publications, a training program, historical and technical research and two field projects at Louis Kahn’s Salk Biological Institute (1965) and the house of Ray and Charles Eames (1949), both in California. This paper outlines current GCI efforts, reports on initial outcomes and describes forthcoming activities.
