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Comprehensive hydrogen storage performance of Li-Mg-N-H hydrogen storage system co-doped with nano LaNi_(5) and SWCNTs:experimental and theoretical modification study 被引量:1
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作者 Hao-Yuan Zheng Chen Jin +8 位作者 Hang Che Chia-Tse Lee Guang Liu Li Wang Yu-Yuan Zhao Hai-Zhen Liu Xin-Hua Wang Yi-Feng Yu Mi Yan 《Rare Metals》 2025年第10期7317-7331,共15页
The Li-Mg-N-H(Mg(NH_(2))_(2)-2LiH)system,as a high-capacity Mg-based metal hydrogen storage material(5.6 wt%),has broad prospects for in vehicle hydrogen storage applications,but it still has high hydrogen ab/desorpti... The Li-Mg-N-H(Mg(NH_(2))_(2)-2LiH)system,as a high-capacity Mg-based metal hydrogen storage material(5.6 wt%),has broad prospects for in vehicle hydrogen storage applications,but it still has high hydrogen ab/desorption barriers.To improve its hydrogen storage performance,a nanohydrogen storage alloy was innovatively combined with Mg(NH_(2))_(2)-2LiH,AB5 type nanohydrogen storage alloy LaNi_(5)was prepared by co-precipitation method.Nano LaNi_(5)and single-walled carbon nanotubes(SWCNTs)were co-doped into the Mg(NH_(2))_(2)-2LiH system at a ratio of 10 wt%and 2 wt%,significantly enhancing the hydrogen storage performance of Mg(NH_(2))_(2)-2LiH.The initial hydrogen ab/desorption temperatures of the co-doped system decreased from110/130℃to 45/85℃.The release of by-product ammonia is significantly inhibited.4.73 wt% H_(2)can be ab/desorption in 150 min at 180/170℃.Cycle tests show that the co-doped system can still maintain a hydrogen storage capacity of 4.75 wt% after ten hydrogen release cycles.Mechanism and density functional theory study have shown that during the hydrogen release process,partially hydrogenated LaNi_(5)weakens the chemical bonding in Mg(NH_(2))_(2),promoted the dissociation of hydrogen from the Mg(NH_(2))_(2)-2LiH system,while playing a dual role of"hydrogen overflow"and"hydrogen pump".SWCNTs act as auxiliary agents,helping to refine particle size and increase thermal conductivity.The synergistic effect of the two optimizes the comprehensive hydrogen storage performance of Mg(NH_(2))_(2)-2LiH.This study provides a new research method for improving the comprehensive hydrogen storage performance of Mg-based metal hydrogen storage materials using rare earth element catalysts. 展开更多
关键词 Hydrogen storage Mg-based materials Li-Mg-N-H AB5 swcnts
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外翻肠囊法研究Pluronic/SWCNTs对P-糖蛋白底物罗丹明123小肠吸收的影响 被引量:3
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作者 关延彬 韩冰 +2 位作者 周树瑶 田雨冬 贾永艳 《中国医院药学杂志》 CAS 北大核心 2018年第16期1681-1685,共5页
目的:考察3种Pluronic/SWCNTs载体材料对小肠P-糖蛋白(P-gp)药泵的抑制作用。方法:采用外翻肠囊模型进行肠吸收实验,以P-gp特异性底物罗丹明123(R-123)大鼠肠吸收参数为考察指标,研究Pluronic/SWCNTs对R-123肠吸收的影响。结果:Pluronic... 目的:考察3种Pluronic/SWCNTs载体材料对小肠P-糖蛋白(P-gp)药泵的抑制作用。方法:采用外翻肠囊模型进行肠吸收实验,以P-gp特异性底物罗丹明123(R-123)大鼠肠吸收参数为考察指标,研究Pluronic/SWCNTs对R-123肠吸收的影响。结果:Pluronic/SWCNTs可以显著增加R-123在各肠段的累计吸收量与吸收速率常数,特别是在浓度为5μg·mL-1与10μg·mL-1时作用最明显(P<0.05)。结论:Pluronic/SWCNTs可以通过抑制P-gp药泵作用改善P-gp底物药物的小肠吸收,在口服载药系统的应用中具备很大的潜力。 展开更多
关键词 P-糖蛋白 外翻肠囊法 Pluronic/swcnts 肠吸收
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黄连总生物碱Pluronic/SWCNTS给药系统的制备及初步评价 被引量:1
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作者 关延彬 韩冰 +2 位作者 田雨冬 贾永艳 刘改枝 《中药材》 CAS 北大核心 2020年第5期1186-1190,共5页
目的:优化黄连总生物碱的提取工艺,构建功能化Pluronic/SWCNTS负载黄连总生物碱的给药系统,并对其进行质量评价。方法:采用星点设计-效应面法优化黄连总生物碱提取工艺;采用超声法制备载药体系,以载药量为指标,通过单因素考察优化处方工... 目的:优化黄连总生物碱的提取工艺,构建功能化Pluronic/SWCNTS负载黄连总生物碱的给药系统,并对其进行质量评价。方法:采用星点设计-效应面法优化黄连总生物碱提取工艺;采用超声法制备载药体系,以载药量为指标,通过单因素考察优化处方工艺,并对给药系统的形态、粒径及稳定性等进行评价。结果:黄连总生物碱Pluronic/SWCNTS给药系统的载药量为9.5%,平均粒径为(220.1±1.5)nm,放置15 d可长期稳定存在。结论:黄连总生物碱Pluronic/SWCNTS给药系统制备成功,具有作为口服纳米给药系统的潜力。 展开更多
关键词 黄连总生物碱 Pluronic/swcnts 口服纳米给药系统
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F127/SWCNTs对P-gp底物在大鼠小肠吸收影响的研究 被引量:1
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作者 关延彬 韩华 +2 位作者 田雨冬 贾永艳 祝侠丽 《中国医院药学杂志》 CAS 北大核心 2021年第15期1502-1506,共5页
目的:考察3种F127/SWCNTs载体系统的稳定性及对小肠P-糖蛋白(P-gp)药泵的抑制作用。方法:将F127/SWCNTs稀释至不同浓度后于4℃放置15 d,检测CNTs含量、粒径、Zeta电位等参数的变化;采用大鼠在体单向灌流模型进行肠吸收试验,以P-gp特异... 目的:考察3种F127/SWCNTs载体系统的稳定性及对小肠P-糖蛋白(P-gp)药泵的抑制作用。方法:将F127/SWCNTs稀释至不同浓度后于4℃放置15 d,检测CNTs含量、粒径、Zeta电位等参数的变化;采用大鼠在体单向灌流模型进行肠吸收试验,以P-gp特异性底物罗丹明123(R-123)大鼠回肠段的吸收速率常数(Ka)和表观渗透系数(Papp)为考察指标,评价F127/SWCNTs对R-123肠吸收的影响。结果:储存稳定性和稀释稳定性均表明其中F127/SWCNT-COOH与F127/SWCNT-OH在15 d内4℃放置稳定性良好,无明显沉淀析出,粒径和含量稳定。3种F127/SWCNTs均可在不同程度增加R-123在回肠段的吸收,且具有浓度依赖性。结论:F127/SWCNTs可能通过抑制P-gp药泵作用改善P-gp底物药物的口服生物利用度,为药物特异性口服应用创造独特机会。 展开更多
关键词 P-糖蛋白 在体单向灌流模型 F127/swcnts 小肠吸收
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PAN/SWCNTs复合纳米纤维纱线的制备及其性能 被引量:6
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作者 张悦 吴韶华 +1 位作者 张弘楠 覃小红 《东华大学学报(自然科学版)》 CAS CSCD 北大核心 2016年第3期313-317,331,共6页
采用改进的静电纺丝装置,分别制备了纯聚丙烯腈(PAN)纳米纤维纱线和不同单壁碳纳米管(SWCNTs)质量分数的PAN/SWCNTs复合纳米纤维纱线.利用扫描电子显微镜、透射电子显微镜、傅里叶红外-拉曼光谱仪和X射线多晶衍射仪分别对复合纳米纤维... 采用改进的静电纺丝装置,分别制备了纯聚丙烯腈(PAN)纳米纤维纱线和不同单壁碳纳米管(SWCNTs)质量分数的PAN/SWCNTs复合纳米纤维纱线.利用扫描电子显微镜、透射电子显微镜、傅里叶红外-拉曼光谱仪和X射线多晶衍射仪分别对复合纳米纤维纱线进行了形貌和直径表征、分子结构分析、结晶结构分析,并测试了不同SWCNTs质量分数对复合纳米纤维纱线力学性能的影响.结果表明:不同SWCNTs质量分数的PAN/SWCNTs复合纳米纤维纱线均具有良好的形态且沿着纱线轴向有序排列;随着SWCNTs质量分数的增加,纱线和纤维的直径均呈现减小的趋势,并且纤维中的串珠增多;碳纳米管沿纤维轴向均匀分布;碳纳米管的加入没有产生新的特征峰,但PAN的峰值有所减弱或增强;碳纳米管的加入改变了PAN的结晶性能;当SWCNTs质量分数为5%时,复合纳米纤维纱线的拉伸强度达到最高值为24.25 MPa. 展开更多
关键词 静电纺 聚丙烯腈/单壁碳纳米管(PAN/swcnts)复合纳米纤维纱线 取向 拉伸强度
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A ternary phased SnO_2-Fe_2O_3/SWCNTs nanocomposite as a high performance anode material for lithium ion batteries 被引量:5
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作者 Wangliang Wu Yi Zhao +2 位作者 Jiaxin Li Chuxin Wu Lunhui Guan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2014年第3期376-382,共7页
A new SnO2-Fe2O3/SWCNTs(single-walled carbon nanotubes) ternary nanocomposite was first synthesized by a facile hydrothermal approach.SnO2 and Fe2O3 nanoparticles(NPs) were homogeneously located on the surface of ... A new SnO2-Fe2O3/SWCNTs(single-walled carbon nanotubes) ternary nanocomposite was first synthesized by a facile hydrothermal approach.SnO2 and Fe2O3 nanoparticles(NPs) were homogeneously located on the surface of SWCNTs,as confirmed by X-ray diffraction(XRD),transmission electron microscope(TEM) and energy dispersive X-ray spectroscopy(EDX).Due to the synergistic effect of different components,the as synthesized SnO2-Fe2O3/SWCNTs composite as an anode material for lithium-ion batteries exhibited excellent electrochemical performance with a high capacity of 692 mAh·g-1 which could be maintained after 50 cycles at 200 mA·g-1.Even at a high rate of2000 mA·g-1,the capacity was still remained at 656 mAh·g-1. 展开更多
关键词 swcnts SnO2 FE2O3 lithium ion batteries anode materials
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Construction of a Bronsted-Lewis solid acid catalyst La-PW-SiO_(2)/SWCNTs based on electron withdrawing effect of La(Ⅲ)onπbond of SWCNTs for biodiesel synthesis from esterification of oleic acid and methanol 被引量:2
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作者 Qing Shu Xinyuan Liu +3 位作者 Yanting Huo Yuhui Tan Caixia Zhang Laixi Zou 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2022年第4期351-362,共12页
A novel solid Bronsted-Lewis acid catalyst La-PW-SiO_(2)/SWCNTs(single-wall carbon nanotubes)was synthesized from the synergistic modification of H_(3)PW_(12)O_(40)(HPW)by single-walled carbon nanotubes functionalized... A novel solid Bronsted-Lewis acid catalyst La-PW-SiO_(2)/SWCNTs(single-wall carbon nanotubes)was synthesized from the synergistic modification of H_(3)PW_(12)O_(40)(HPW)by single-walled carbon nanotubes functionalized with sidewall hydroxyl groups(SWCNTs–OH)and La^(3+) via sol–gel method.The freshly prepared catalyst was characterized by several methods,and the catalytic activity and stability of it were studied from the esterification of oleic acid and methanol.Results showed that the highest conversion of oleic acid was 93.1%(mass)and maintained as high as 88.7%(mass)after six cycles of La-PW-SiO_(2)/SWCNTs.The high catalytic activity and stability of La-PW-SiO_(2)/SWCNTs can be attributed to the strong electron withdrawing effect of La^(3+) on π bond of SWCNTs,because it can facilitate the formation of a large number of strong Lewis acid sites.Therefore,the reduction of catalytic activity of a solid acid catalyst due to the fact that hydration reaction of its Bronsted acid sites can be effectively reduced.La-PW-SiO_(2)/SWCNTs can be an efficient and economical catalyst,because it shows good catalytic activity and stability. 展开更多
关键词 Single-wall carbon nanotubes(swcnts) H_(3)PW_(12)O_(40) La^(3+) Solid Bronsted-Lewis acid catalyst BIODIESEL ESTERIFICATION
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FEM for Blood-Based SWCNTs Flow Through a Circular Cylinder in a Porous Medium with Electromagnetic Radiation 被引量:1
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作者 Mohamed R.Eid A.F.Al-Hossainy M.Sh.Zoromba 《Communications in Theoretical Physics》 SCIE CAS CSCD 2019年第12期1425-1434,共10页
This work aims to study magnetohydrodynamic flow through a circular cylinder in a horizontal position of SWCNTs in blood as a base fluid in the existence of non-linear thermal radiation and heat source/sink.Three kind... This work aims to study magnetohydrodynamic flow through a circular cylinder in a horizontal position of SWCNTs in blood as a base fluid in the existence of non-linear thermal radiation and heat source/sink.Three kinds of nanoparticles shapes are considered.The study is employed the finite element technique to explore and enhance the influences of essential parameters on temperature profiles and is debated the heat transport within blood injects with SWCNTs and exposes to electromagnetic radiation.The treatment with thermal analysis and heat transfer rate being a better substitute more than surgery and chemotherapy for cancer therapy.Utilizing of nanoparticles thermal features is a mounting area of nanomedicine field because of the probable for purposeful demolition of cancer cells.This remedy is relied on many parameters,including nanofluid thermal conductivity,nanoparticles volume fraction,thermal radiation and power and heat source.The numerical solutions for flow and heat transfer features are assessed for diverse governing parameters values.The obtained results are substantiated against the relevant numerical results in the published researches.Results show that both flow velocity and temperature increase for larger values of thermal radiation,heat source and SWCNTs volume fraction with lamina and cylinder shapes.Also,spherical shape of SWCNTs occurs high disturbances in velocity and temperature distribution in the case of cooled cylinder. 展开更多
关键词 finite element method heat transfer BLOOD swcnts electromagnetic radiation
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基于SWCNTs薄膜的多谐振环太赫兹超表面传感特性
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作者 张向 罗帆 +2 位作者 任铭欣 宋博晨 王玥 《太赫兹科学与电子信息学报》 2024年第4期353-359,372,共8页
基于单壁碳纳米管(SWCNTs)薄膜,构建了一种具有多频窄带共振效应的新型太赫兹(THz)超表面。深入分析了周期性微结构单元参数对超表面的共振特性的影响;通过仿真及理论计算对器件的共振耦合机理进行研究,二者具有较好的一致性。通过在超... 基于单壁碳纳米管(SWCNTs)薄膜,构建了一种具有多频窄带共振效应的新型太赫兹(THz)超表面。深入分析了周期性微结构单元参数对超表面的共振特性的影响;通过仿真及理论计算对器件的共振耦合机理进行研究,二者具有较好的一致性。通过在超表面覆盖不同折射率的介质层,分析这种THz超表面器件的折射率传感特性,灵敏度分析结果显示,该超表面器件可实现最高64 GHz/RIU的折射率传感。 展开更多
关键词 太赫兹 单壁碳纳米管(swcnts) 超表面 传感器
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An Approach to Determination of Phenolic Compounds in Seawater using SPME-GC-MS Based on SWCNTs Coating 被引量:1
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作者 ZHU Jia WANG Ying ZENG Lin 《Journal of Ocean University of China》 SCIE CAS 2016年第4期655-659,共5页
Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of co... Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin^(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L^(-1), and the determination limits ranged between 1.5-10 ngL^(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters. 展开更多
关键词 swcnts nanotubes walled hexagonal SPME ranged simplicity immersed seawater establishing
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SWCNTs的制备及其在生物传感器中的应用前景
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作者 李栋 陈丽华 《山东化工》 CAS 2024年第3期121-123,共3页
SWCNTs独特的电子结构和几何形状赋予了它独特的荧光特性,具有良好的生物相容性和优异的光学性质,还具有高度均匀性以及小孔缺陷,易于处理。因此,它们被广泛应用于生物医学成像、生物传感和药物输送领域。本文对SWCNTs的制备及在荧光生... SWCNTs独特的电子结构和几何形状赋予了它独特的荧光特性,具有良好的生物相容性和优异的光学性质,还具有高度均匀性以及小孔缺陷,易于处理。因此,它们被广泛应用于生物医学成像、生物传感和药物输送领域。本文对SWCNTs的制备及在荧光生物传感器方向的应用研究进展进行了综述,并对其应用前景进行展望。 展开更多
关键词 swcnts 荧光 电化学 生物传感器 检测
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基于SWCNTs的环丙沙星荧光增敏法研究
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作者 胡雅稳 秦铭杉 +2 位作者 刘星妍 杨娇 杨琳燕 《南开大学学报(自然科学版)》 CAS CSCD 北大核心 2020年第4期99-107,共9页
SWCNTs-PEG-NH2,SWCNTs-2,3-NH2和SWCNTs-3,4-NH2纳米微球可经由单壁碳纳米管(SWCNTs)共价修饰制备.SWCNTs-PEG-NH2,SWCNTs-2,3-NH2和SWCNTs-3,4-NH2纳米微球的结构可由X-射线光电子能谱(XPS)确证.结果表明酰胺化反应成功.环丙沙星(CIP... SWCNTs-PEG-NH2,SWCNTs-2,3-NH2和SWCNTs-3,4-NH2纳米微球可经由单壁碳纳米管(SWCNTs)共价修饰制备.SWCNTs-PEG-NH2,SWCNTs-2,3-NH2和SWCNTs-3,4-NH2纳米微球的结构可由X-射线光电子能谱(XPS)确证.结果表明酰胺化反应成功.环丙沙星(CIP)萃取实验表明,对于SWCNTs-PEG-NH2微球,在pH=4和pH=6得到较好吸附效果,而0.1 mol/L NaOH和1%SDS洗脱剂可得到较好的洗脱效果.对于SWCNTs-2,3-NH2和SWCNTs-3,4-NH2微球,pH=6得到最好的吸附效果,而1%SDS洗脱条件可到最好的洗脱效果.Al3+离子的加入可以敏化环丙沙星的荧光. 展开更多
关键词 swcnts 环丙沙星 修饰 萃取
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Spectroscopic Studies of Nanocomposites Based on PEO/PVDF Blend Loaded by SWCNTs
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作者 Hind Mohammed Alhusiki-Alghamdi Naziha Suliman Alghunaim 《Journal of Modern Physics》 2015年第4期414-424,共11页
Novel nanocomposites of PEO/PVDF loaded by different contents of SWCNTs were prepared. From UV-Vis spectra, the estimated values of absorption edge, absorption coefficient, energy of tail and extinction coefficient we... Novel nanocomposites of PEO/PVDF loaded by different contents of SWCNTs were prepared. From UV-Vis spectra, the estimated values of absorption edge, absorption coefficient, energy of tail and extinction coefficient were calculated. The exponential decay tail at low energy is due to the presence of localized states in the energy band gap. The shift of Raman spectra indicates the possibility of SWCNTs to be attached with OH group in the side chain of polymer molecules. The X-ray measurements indicate that the addition of SWCNTs is a rich amorphous region in polymeric matrices and complete complexation between PEO/PVDF blend and SWCNTs. The SEM images show smooth surface of PEO/PVDF and they become rough with single rod with a good distribution within surface region in polymeric matrices after loading SWCNTs. TEM images showed that SWCNTs were dispersed well in polymeric matrices. The broken ends of nanotubes were showing that the SWCNTs were broken apart rather than from at the fracture surface. The films show some defects like rags on the tube walls. There are some black regions in TEM images attributed to amorphous nature carbon. The prepared nanocomposites are very useful in technical application. 展开更多
关键词 swcnts NANOCOMPOSITES UV-VIS Spectroscopy Raman SHIFT TEM
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Single Wall Carbon Nanotubes (SWCNTs) as (i) Type in the Photovoltaic Cell of Nano-Dimensions
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作者 Maen Ishtaiwi Muna Hajjyahya +1 位作者 Khalid Abd-Haqq Mohammed Bashar 《Journal of Applied Mathematics and Physics》 2022年第5期1694-1701,共8页
In this paper, a new modified approach to design the photovoltaic cell has been presented by adding Single Wall Carbon Nanotubes (SWCNTs) as type (i). The main issue is to increase the efficiency of the photovoltaic c... In this paper, a new modified approach to design the photovoltaic cell has been presented by adding Single Wall Carbon Nanotubes (SWCNTs) as type (i). The main issue is to increase the efficiency of the photovoltaic cell, on the other hand, to exploit a larger range of electromagnetic wave frequencies, specifically a range within terahertz (THz) frequency domain, using 3D EM computer simulation technology (CST). It is clear in the normal PV cell start working at frequency of 500 THz, while the frequency at which the PV cell with SWCNTs operates is much less and it is close to zero, on the other hand, the PV cell with SWCNTs needs a larger cross-section area of 2800 nm2 to operate at frequency of 500 THz. This cell can be easily produced industrially, which means increases the efficiency of solar cell. 展开更多
关键词 Single Wall Carbon Nanotubes (swcnts) Photovoltaic Cell (PV) CST Simulation
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Interaction between SWCNTS and the mitochondriai electron transport chain
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作者 YanleiLiu Yingge Zhang 《中国药理通讯》 2012年第3期53-53,共1页
Objective: To investigate the effect of single-wall carbon nanotubes on the mitochondrial electron transport chain (METC) of tumor cells. Methods: Human hepatocarcinoma cell line HepG2 were cultured in DMEM medium... Objective: To investigate the effect of single-wall carbon nanotubes on the mitochondrial electron transport chain (METC) of tumor cells. Methods: Human hepatocarcinoma cell line HepG2 were cultured in DMEM medium (Hyclone) supplemented with 10% fetal calf serum (Gibco) in a atmosphere of 95% oxygen and 5% carbon dioxide under 37C. Cells were exposed by adding SWCNTs in the medium in concentrations of 1.5 - 12btg/ml. HepG2 cells exposed to narmal saline were used as control. The cells were collected after at 24h. The mitochondrial of HepG2 cells were obtained by density gradient centrifugation and were examined under transmis- sion electron microscope (TEM) . Four enzyme activity of the mitochondrial electron transport chain (METC) were determined by enzyme mark instrument. Results: 展开更多
关键词 TTP HSC SOD 药理学 swcnts
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First principles study on magnetic and electronic properties with rare-earth atoms doped SWCNTs 被引量:3
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作者 Shun-li Yue Hong Zhang 《Frontiers of physics》 SCIE CSCD 2012年第3期353-359,共7页
The adsorptions of rare-earth (RE) atoms on (6, 0) and (8, 0) single-walled carbon nanotubes (SWCNTs) have been investigated by using the first-principles pseudopotential plane wave method within density funct... The adsorptions of rare-earth (RE) atoms on (6, 0) and (8, 0) single-walled carbon nanotubes (SWCNTs) have been investigated by using the first-principles pseudopotential plane wave method within density functional theory (DFT). The binding energy, Mulliken charge, magnetic properties, band structure and DOS were calculated and analyzed. Most of RE atoms including Nd, Sm and Eu have a magnetic ground state with a significant magnetic moment. Some electrons transfer between RE-5d, 6s and C-2p orbitals. Owing to the curvature effect, the values of binding energy for RE atoms doped (6, 0) SWCNT are lower than those of the same atoms on (8, 0) SWCNT. The pictures of DOS show that hybridizations between RE-5d, 6s states and C-2p orbitals and between RE-4f and C-2p orbitals appear near the Fermi level. Results indicate that the properties of SWCNTs can be modified by the adsorptions of RE atoms. 展开更多
关键词 DFT RE atoms single-walled carbon nanotubes swcnts DOPING
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Free-standingβ-Ta_(2)O_(5)/SWCNTs composite film for high-rate Li-ion storage
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作者 WU ZhiMin LIU JiaJia +4 位作者 HE XingYu BIAN Jing ZHU XianJun CHEN JianMei LI JianMin 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2024年第2期616-626,共11页
The rapid development of portable and wearable electronic devices is responding to the urgent demand for high-efficiency flexible energy storage devices.Flexible supercapacitors,showing long cycle life,high power dens... The rapid development of portable and wearable electronic devices is responding to the urgent demand for high-efficiency flexible energy storage devices.Flexible supercapacitors,showing long cycle life,high power density,and good safety,are considered ideal candidates.Nevertheless,the relatively low energy density restricts their practical applications.With a large dielectric constant of 18-46,Ta_(2)O_(5)-based materials typically exhibit excellent electron-binding ability,which is critical for enhancing the energy density of supercapacitors.In this work,the free-standingβ-Ta_(2)O_(5)/single-walled carbon nanotubes(SWCNTs)composite film was prepared,with a highβ-Ta_(2)O_(5)loading of over 70%.By anchoringβ-Ta_(2)O_(5)nanoparticles onto the surface of SWCNTs,the system’s flexibility and conductivity were significantly enhanced,which also facilitated the intercalation electrodynamics of metal cations.As a result,the flexibleβ-Ta_(2)O_(5)/SWCNTs film exhibits excellent Li-ion storage performance,with a high volumetric specific capacitance of 392.3 F cm^(-3)at the scan rate of 10 mV s^(-1)and 198.9 F cm^(-3)at 500 mV s^(-1).In addition,the asymmetric device,assembled by theβ-Ta_(2)O_(5)/SWCNTs and activated carbon films,shows a high energy density of 45.5 Wh kg^(-1)at the power density of 10.8 kW kg^(-1).This technique opens up a new avenue for improving the energy density and rate performance of flexible supercapacitors. 展开更多
关键词 PSEUDOCAPACITOR Li-ion storage β-Ta_(2)O_(5)/swcnts film flexible device high-rate capability
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单壁碳纳米管材料对水稻幼苗的毒性效应 被引量:18
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作者 袁刚强 龚继来 曾光明 《环境科学学报》 CAS CSCD 北大核心 2015年第12期4143-4149,共7页
随着碳纳米管材料(CNTs)被广泛地应用于工业和商业等多个领域,其将不可避免地进入到大气、水和土壤环境中,从而对生态系统结构和功能产生一些负面影响.为明确进入水环境中的碳纳米管材料对农业生产的潜在危险,本实验采用水培法,研究了... 随着碳纳米管材料(CNTs)被广泛地应用于工业和商业等多个领域,其将不可避免地进入到大气、水和土壤环境中,从而对生态系统结构和功能产生一些负面影响.为明确进入水环境中的碳纳米管材料对农业生产的潜在危险,本实验采用水培法,研究了不同浓度(10、20、40mg·L^(-1))的单壁碳纳米管材料(SWCNTs)对萌发期内水稻的发芽率、根长耐性指数和幼苗生长期内水稻的鲜重、叶绿素和可溶性蛋白的影响,以及单壁碳纳米管材料在水稻根部的累积.结果表明,在萌发期,胁迫处理4 d后,与对照相比,10、20、40 mg·L-1SWCNTs处理组对水稻发芽率没有任何抑制作用,但会延迟种子的发芽时间;水稻根长耐性指数随着单壁碳纳米管材料浓度的增加而下降.在幼苗生长期,胁迫处理30 d后,与对照相比,水稻鲜重随着单壁碳纳米管材料浓度的增加而分别下降14.2%、21.0%和38.8%;与此相类似,水稻叶绿素和可溶性蛋白质含量随着单壁碳纳米管材料浓度的增加而下降;另外,通过透射电镜观察(TEM)发现,SWCNTs颗粒分布在水稻幼苗根尖表皮细胞的细胞壁中.SWCNTs对水稻生长起抑制作用,且随着浓度的增加抑制作用逐渐增强. 展开更多
关键词 单壁碳纳米管(swcnts) 水稻 鲜重 叶绿素 可溶性蛋白 抑制
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单壁碳纳米管对小鼠肝和肾氧化损伤的诱导 被引量:4
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作者 王红蕾 柯砚 +2 位作者 赵明明 吴凯 杨旭 《环境科学学报》 CAS CSCD 北大核心 2009年第7期1491-1495,共5页
为了评价单壁碳纳米管(SWCNTs)对生物体的毒性效应,以昆明小鼠为受试动物,采用腹腔注射的染毒方法,研究了SWCNTs和标准碳黑(CB)对其肝和肾组织氧化损伤的诱导.实验结果表明:与对照组相比,SWCNTs和CB暴露显著的降低了小鼠肝和肾中还原性... 为了评价单壁碳纳米管(SWCNTs)对生物体的毒性效应,以昆明小鼠为受试动物,采用腹腔注射的染毒方法,研究了SWCNTs和标准碳黑(CB)对其肝和肾组织氧化损伤的诱导.实验结果表明:与对照组相比,SWCNTs和CB暴露显著的降低了小鼠肝和肾中还原性谷胱甘肽(GSH)的含量、抑制了超氧化物歧化酶(SOD)的活力、诱导了脂质过氧化终产物丙二醛(MDA)的产生、提高了DNA-蛋白质交联率(DNA-protein crosslinks,DPC),但在最高浓度(0.08mg.d-1)暴露下,SWCNTs暴露组的影响程度要高于标准碳黑组.说明了SWCNTs暴露可以抑制小鼠肝和肾组织抗氧化系统,从而导致了器官的氧化损伤.并且这种氧化损伤的诱导部分是由于SWCNTs的特殊结构和金属元素的参与. 展开更多
关键词 单壁碳纳米管(swcnts) 碳黑(CB) 小鼠 氧化损伤
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竖立在晶态金表面上的短单壁碳纳米管 被引量:2
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作者 薛增泉 刘惟敏 +4 位作者 侯士敏 施祖进 顾镇南 刘虹雯 张兆祥 《电子科学学刊》 CSCD 1999年第5期692-697,共6页
合成和提纯了单壁碳纳米管(SWCNTs),用胶体将其竖直地组装在金薄膜表面上。用此组装技术制造了扫描隧道显微镜(STM)的针尖,成功地观测到了金晶粒的形貌像和高定向石墨的原子像。SWCNTs竖立在金表面上对于电学特性测量,制造场发射电子源... 合成和提纯了单壁碳纳米管(SWCNTs),用胶体将其竖直地组装在金薄膜表面上。用此组装技术制造了扫描隧道显微镜(STM)的针尖,成功地观测到了金晶粒的形貌像和高定向石墨的原子像。SWCNTs竖立在金表面上对于电学特性测量,制造场发射电子源,组装纳米电子器件,制作扫描探针显微镜(SPM)针尖等有重要意义。 展开更多
关键词 碳纳米管 组装技术 原子像 纳米材料 swcnts STM
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