Development of high performance,flexible piezoelectric nanogenerators(PENGs)is critical for advancing self-powered sensing and microelectronic applications.In this study,a hydrogen-bond substitute strategy was employe...Development of high performance,flexible piezoelectric nanogenerators(PENGs)is critical for advancing self-powered sensing and microelectronic applications.In this study,a hydrogen-bond substitute strategy was employed to fabricate a multi-layer PENG based on a cellulose/polyvinylidene fluoride(PVDF)blend film matrix,incorporating multi-phase BCZT(0.1BaZr_(0.2)Ti_(0.8)O_(3)-0.9Ba_(0.7)Ca_(0.3)TiO_(3))ceramic fillers.Structural characterization via SEM and TEM revealed that an intricate hydrogen-bond network facilitated the uniform dispersion of ceramic fillers within the composite film’s sub-layers.In order to study the effect of filler distribution on piezoelectric performance,the single-and double-layer composite films with varying BCZT configurations were produced and evaluated.The results demonstrated that double-layer PENGs exhibit significantly enhanced electrical output compared to their single-layer counterparts,with the D-L_(3)H_(7) configuration achieving an open circuit voltage(V_(OC))of 23.13 V and a short circuit current(I_(SC))of 8.32μA.This enhancement is attributed to increased inter-layer interfaces,which effectively suppressed charge injection and migration,leading to improved charge density.Additionally,the presence of sharp tipped hexagonal tetragonal phase nanoparticles induced an electric field enhancement effect,further optimizing performance.展开更多
Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2...Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2)O(1)was synthesized as a 2D structure using Coas the metal source,methanol‑water(4∶6,V/V)as the solvent,and specific concentrations of 2,5‑furandicarboxylic acid(H_(2)FDCA)and 1,3,5‑triimidazole benzene(L).Adjusting to pure water and lowering the concentration of L yielded the 1D chain structure of[Co(HL)2(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(2).Using Cu(Ⅱ)as the metal source,methanol/water(9∶1,V/V)as the solvent,and specific concentrations of L and H2FDCA,the 1D chain structure of[Cu(L)(FDCA)(H_(2)O)]·2H_(2)O(3)was synthesized.Upon increasing the concentrations of L and H2FDCA,and switching the solvent to pure water,the 1D chain structure of[Cu(HL)_(2)(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(4)was obtained.This shows that changing the solvent and ligand concentrations can affect the structural changes of CPs.In addition,the solid‑state photoluminescence of CPs 1‑4 at room temperature was studied,and their morphological changes were observed via scanning electron microscopy.Density functional theory calculations revealed that the negative charge concentrates on the O and N atoms of the ligand,facilitating ligand‑metal ion coordination.CCDC:2403934,1;2403935,2;2403936,3;2403938,4.展开更多
The field of neurodegeneration research has long been focused on finding therapeutic strategies to effectively decrease or halt neuronal loss while minimizing side effects.A recent study titled“Inhibiting acute,axona...The field of neurodegeneration research has long been focused on finding therapeutic strategies to effectively decrease or halt neuronal loss while minimizing side effects.A recent study titled“Inhibiting acute,axonal DLK palmitoylation is neuroprotective and avoids deleterious effects of cell-wide DLK inhibition”(Zhang et al.,2025),describes an innovative approach to achieve this goal.The authors target a specific post-translational modification of dual leucine-zipper kinase(DLK),palmitoylation,to selectively inhibit DLK-dependent pro-degenerative signaling and protect neurons,thereby revealing a new way to intervene and block neurodegeneration.This Perspective aims to explore the significance of these findings and propose directions for future research.展开更多
The structural principles of traditional Chinese mortise-and-tenon joints have inspired breakthroughs in supramolecular engineering.Nevertheless,substantial challenges remain in constructing nanoscale supramolecular a...The structural principles of traditional Chinese mortise-and-tenon joints have inspired breakthroughs in supramolecular engineering.Nevertheless,substantial challenges remain in constructing nanoscale supramolecular architectures with precisely controlled giant dimensions.Herein,we report a precision-guided synthetic strategy for constructing giant 2D and 3D supramolecular architectures with rhomboidal motifs,which was achieved through a dovetail joint strategy.Initial assembly of bis-mortise ligand L1 with dovetail tenon ligand L2 in the presence of Cd^(2+)ions yielded the fundamental bis-rhombic supramolecule R1.Subsequent structural elaboration of the dovetail tenon motif enabled the development of multitopic ligands L3 and L4,which facilitated the construction of expanded architectures of the giant bis-propeller supramolecule R2 and tris-propeller supramolecule R3.The synthesized supramolecules R1-R3 were fully characterized multidimensional NMR spectroscopy,electrospray ionization mass spectrometry(ESI-MS),traveling wave ion mobility mass spectrometry(TWIM-MS),transmission electron microscopy(TEM),and atomic force microscopy(AFM).This work develops an innovative dovetail-joint assembly strategy for constructing rigid giant supramolecular architectures,establishing a new paradigm for precision engineering of complex 3D molecular systems.展开更多
Reaction-diffusion systems are widely used to describe pattern formation,and various control strategies have been applied to reaction-diffusion systems to achieve control objectives such as boundary control,output fee...Reaction-diffusion systems are widely used to describe pattern formation,and various control strategies have been applied to reaction-diffusion systems to achieve control objectives such as boundary control,output feedback stabilization,and synchronization.However,controlling pattern dynamics in reaction-diffusion systems with fractional-order diffusion remains an unresolved problem.This paper presents a proportional-derivative(PD)control strategy for the Schnakenberg system with fractional-order diffusion and cross-diffusion.Theoretical analysis explores the amplitude equation near the Turing bifurcation threshold,determining the selection and stability of pattern formations.Numerical simulations demonstrate that the PD controller accomplishes the modification of pattern structures and suppression of Turing instability by adjusting only two control parameters.Additionally,it is found that for smaller fractional diffusion order,the region can accommodate more hexagonal and stripe patterns in space.This work contributes to the control of complex pattern dynamics and offers a new approach to enhancing stability in fractional reaction-diffusion systems.展开更多
Conventional locking/release mechanisms often face challenges in aircraft wing separation processes,such as excessive impact loads and insufficient synchronization.These may cause structural damage to the airframe or ...Conventional locking/release mechanisms often face challenges in aircraft wing separation processes,such as excessive impact loads and insufficient synchronization.These may cause structural damage to the airframe or attitude instability,seriously compromising mission reliability.To address this engineering challenge,this paper proposes a multi-point low-impact locking/release mechanism based on the mobility model and energy conversion strategy.Through establishing a DOF constraint framework system,this paper systematically analyzes the energy transfer and conversion characteristics during the wing separation process,reveals the generation mechanism of impact loads,and conducts research on low-impact design based on energy conversion strategy.Building on this foundation,a single-point locking/release mechanism employing parallel trapezoidal key shaft structure was designed,which increases frictional contact time and reduces the energy release rate,thereby achieving low-impact characteristics.The mechanism's performance was validated through physical prototype development and systematic functional testing(including unlocking force,synchronization,and impact tests).Experimental results demonstrate:(1)Under 14 kN preload condition,the maximum unlocking force was only 92.54 N,showing a linear relationship with preload that satisfies the"strong-connection/weak-unlock"design requirement;(2)Wing separation was completed within 46 ms,with synchronization time difference among three separation mechanisms stably controlled within 12-14 ms,proving rapid and reliable operation;(3)The unlocking impact acceleration ranged between 26 and 73 g,below the 100 g design limit,confirming the effectiveness of the energy conversion strategy.The proposed low-impact locking/release mechanism design method based on energy conversion strategy resolves the traditional challenges of high impact and synchronization deficiencies.The synergistic optimization mechanism of"structural load reduction and performance improvement"provides a highly reliable technical solution for wing separable mechanisms while offering novel design insights for wing connection/separation systems engineering.展开更多
Using photoelectrocatalytic CO_(2) reduction reaction(CO_(2)RR)to produce valuable fuels is a fascinating way to alleviate environmental issues and energy crises.Bismuth-based(Bi-based)catalysts have attracted widespr...Using photoelectrocatalytic CO_(2) reduction reaction(CO_(2)RR)to produce valuable fuels is a fascinating way to alleviate environmental issues and energy crises.Bismuth-based(Bi-based)catalysts have attracted widespread attention for CO_(2)RR due to their high catalytic activity,selectivity,excellent stability,and low cost.However,they still need to be further improved to meet the needs of industrial applications.This review article comprehensively summarizes the recent advances in regulation strategies of Bi-based catalysts and can be divided into six categories:(1)defect engineering,(2)atomic doping engineering,(3)organic framework engineering,(4)inorganic heterojunction engineering,(5)crystal face engineering,and(6)alloying and polarization engineering.Meanwhile,the corresponding catalytic mechanisms of each regulation strategy will also be discussed in detail,aiming to enable researchers to understand the structure-property relationship of the improved Bibased catalysts fundamentally.Finally,the challenges and future opportunities of the Bi-based catalysts in the photoelectrocatalytic CO_(2)RR application field will also be featured from the perspectives of the(1)combination or synergy of multiple regulatory strategies,(2)revealing formation mechanism and realizing controllable synthesis,and(3)in situ multiscale investigation of activation pathways and uncovering the catalytic mechanisms.On the one hand,through the comparative analysis and mechanism explanation of the six major regulatory strategies,a multidimensional knowledge framework of the structure-activity relationship of Bi-based catalysts can be constructed for researchers,which not only deepens the atomic-level understanding of catalytic active sites,charge transport paths,and the adsorption behavior of intermediate products,but also provides theoretical guiding principles for the controllable design of new catalysts;on the other hand,the promising collaborative regulation strategies,controllable synthetic paths,and the in situ multiscale characterization techniques presented in this work provides a paradigm reference for shortening the research and development cycle of high-performance catalysts,conducive to facilitating the transition of photoelectrocatalytic CO_(2)RR technology from the laboratory routes to industrial application.展开更多
The transient behavior of DC-link voltage(DCV)significantly affects the low-voltage ride-through for phase-locked loop(PLL)-based grid-connected doubly-fed induction generator(DFIG)systems.This study investigates the ...The transient behavior of DC-link voltage(DCV)significantly affects the low-voltage ride-through for phase-locked loop(PLL)-based grid-connected doubly-fed induction generator(DFIG)systems.This study investigates the DCV transient behavior of a PLL-based DFIG system under asymmetrical grid faults.First,by considering the coupling characteristics of positive and negative sequence(PNS)components,a nonlinear largesignal model of DCV is developed.Furthermore,the transient characteristics of DCV under varying parameters are analyzed using phase trajectory diagrams.In addition,the transient stability(TS)mechanism of DCV during asymmetrical faults is examined through an en-ergy function approach.The analysis indicates that the transient instability of DCV is primarily associated with the control characteristics of PNS PLLs,while the TS level of DCV is mainly determined by the power coordination control between the rotor side converter and grid side converter.Moreover,a coordinated control strategy is proposed to enhance the TS of DCV under asymmet-rical grid faults.Finally,both simulation and experimental results are presented to validate the theoretical analysis and the effectiveness of the proposed strategy.展开更多
The development of electrocatalysts that both work effectively at industrial current density and resist chloride ion(Cl^(-))corrosion remains a key challenge for hydrogen production from Cl^(-)-rich alkaline water.Her...The development of electrocatalysts that both work effectively at industrial current density and resist chloride ion(Cl^(-))corrosion remains a key challenge for hydrogen production from Cl^(-)-rich alkaline water.Herein,we report a CrO_(x)-engineered nickel-based oxide catalyst(FeCoCrO_(x)/NF)that achieves exceptional activity and stability through a dual-functional interfacial mechanism.Combing in situ Raman spectroscopy,18O isotopic labeling,and electrochemical analysis,we demonstrate that the oxygen evolution reaction follows a lattice oxygen-mediated mechanism.The CrO_(x)layer selectively adsorbs hydroxide ions,forming a dynamic interfacial barrier that electrostatically repels Cl^(-)ingress,thereby mitigating Cl^(-)corrosion.Through enthalpy-based analysis,we demonstrate that electronic redistribution via Cr-O-Fe bonding increases the vacancy formation energy of Fe,thereby suppressing its dissolution.In alkaline electrolyte containing 0.5 M Cl^(-)(1.0 M KOH),the catalyst is operating continuously for 1400 h at an industrial current density of 1000 mA cm^(-2).Furthermore,the catalyst retains 99.5%of its initial activity under fluctuating current density(100-1000 mA cm^(-2)),demonstrating robustness required for industrial electrolyzers.This study establishes a paradigm for designing corrosion-resistant electrocatalysts through the synergistic modulation of interfacial ion selectivity and bulk lattice oxygen activation,advancing the application of green hydrogen production in Cl^(-)-rich alkaline water.展开更多
Improving the optoelectronic behavior and stress-deformation stability of conjugated materials is crucial for the realization of their potential applications in flexible optoelectronics.To tune the emission behavior a...Improving the optoelectronic behavior and stress-deformation stability of conjugated materials is crucial for the realization of their potential applications in flexible optoelectronics.To tune the emission behavior and mechanical property of molecular crystals simultaneously via supramolecular salt strategy is rarely reported,which is very important to improve their photophysical behavior and softness for the fabrication of flexible light-emitting device.Herein,supramolecular salt approach has been successfully applied to synthesize two elastic organic fluorescent crystals(CMOH-Py-Cl and CMOH-Py-Br)derived from non-emissive and brittle pyridine-substituted coumarin derivative(CMOH-Py).Their elastic properties can be attributed to the prevalent presence of numerous weak interactions introduced by halogen atoms,which are beneficial to the absorption and release of mechanical energy.Furthermore,density functional theory(DFT)calculations demonstrated a narrowing of the HOMO-LUMO energy gaps from CMOH-Py to CMOH-Py-Cl/CMOH-Py-Br via supramolecular salt approach.Finally,the application of flexible crystal materials in the field of optical waveguides has been investigated.The transformation of crystals in terms of photophysical and mechanical properties,achieved by the supramolecular salt approach,offers novel insights into the design and construction of flexible crystalline materials,providing a new path for the development of next-generation smart materials.展开更多
English reading proficiency is essential for university students in a globalized academic environment,yet many L2 learners encounter challenges,such as limited vocabulary,complex syntax,and unclear text organization,l...English reading proficiency is essential for university students in a globalized academic environment,yet many L2 learners encounter challenges,such as limited vocabulary,complex syntax,and unclear text organization,leading to cognitive overload.Grounded in the Cognitive Load Theory(CLT),this study examines the role of the Chunking Reading Processing Strategy-which integrates fragmented linguistic information into meaningful units at lexical,syntactic,and discourse levels-in alleviating cognitive load and improving reading comprehension.Through a mixed-methods approach,the research investigates how learners at different proficiency levels perceive and apply the chunking strategy,and how such application relates to cognitive load management.The results indicate that higher-proficiency learners employ chunking more frequently and report greater benefits,whereas lower-proficiency learners depend more on instructional support.The study confirms the theoretical and pedagogical value of chunk-based reading instruction and suggests that differentiated,cognitively informed teaching of the chunking strategy can enhance both reading efficiency and strategic awareness among L2 learners.展开更多
Fires and human casualties caused by single phase-to-ground faults in distribution networks are frequent.However,existing ground fault suppression methods are affected by ground fault resistance.Thus,an adaptive suppr...Fires and human casualties caused by single phase-to-ground faults in distribution networks are frequent.However,existing ground fault suppression methods are affected by ground fault resistance.Thus,an adaptive suppression method that seamlessly combines principles of current and voltage suppression is proposed,which has good adaptability to different ground fault resistance.Meanwhile,a multi-criteria ground fault suppression exit strategy matched to adaptive suppression method is proposed to avoid damage of device caused by power backflow,which provides the possibility for reliable and fast exit of the fault suppression device.Experimental results demonstrate effectiveness and advantages of the adaptive suppression method and its exit strategy.展开更多
Wolfram syndrome(WS)is a rare autosomal rece s s i ve disease characte r i zed by the development of diabetes insipidus,diabetes mellitus,optic atrophy,and deafness(often referred to as DIDMOAD),and overall severe neu...Wolfram syndrome(WS)is a rare autosomal rece s s i ve disease characte r i zed by the development of diabetes insipidus,diabetes mellitus,optic atrophy,and deafness(often referred to as DIDMOAD),and overall severe neurodegenerative fallback.The global prevalence of this disease is estimated at 1 in 770,000(Lee et al.,2023).It is most commonly caused by biallelic(point)mutations in the Wolframin endoplasmic reticulum(ER)transmembrane glycoprotein(WFS1)gene(in case of WS type 1),but mutations in the CDGSH Iron Sulfur Domain 2(CISD2)are also linked to WS(type 2).The latter,however,often present with less severe pathological manifestations(Lee et al.,2023).WFS1 is located on chromosome 4p16.1 and spans over 33 kilobases.Many mutation variants have been identified in WFS1,encompassing missense,nonsense,and frameshift mutations.These mutations are spread across the coding region of WFS1,but certain regions,such as exon 8,the largest exon,appear particularly mutation-prone and associated with the classical WS type 1 phenotype(Lee et al.,2023).展开更多
In this article,a three-dimensional cooperative guidance problem for highly maneuvering targets is investigated under the assumption of perfect information.Inspired by the coverage strategy,the cooperative guidance pr...In this article,a three-dimensional cooperative guidance problem for highly maneuvering targets is investigated under the assumption of perfect information.Inspired by the coverage strategy,the cooperative guidance problem is decomposed into one-on-one guidance problems against predictive interception points.To expand the coverage area of each missile,these one-on-one guidance problems are formulated as flight path angle tracking problems,and the optimal error dynamics is extended to derive the guidance law analytically.In addition,through the introduction of the coverage probability model,the dynamic coverage strategy is proposed.The predictive interception points are updated online by maximizing the coverage probability,which aims to achieve successful interception despite variations in target acceleration.Furthermore,a switching strategy of the guidance command is designed for collision avoidance.Simulation results demonstrate that the missile group can cooperatively intercept a highly maneuvering target under the proposed guidance law.展开更多
It is evident that complex optimization problems are becoming increasingly prominent,metaheuristic algorithms have demonstrated unique advantages in solving high-dimensional,nonlinear problems.However,the traditional ...It is evident that complex optimization problems are becoming increasingly prominent,metaheuristic algorithms have demonstrated unique advantages in solving high-dimensional,nonlinear problems.However,the traditional Sparrow Search Algorithm(SSA)suffers from limited global search capability,insufficient population diversity,and slow convergence,which often leads to premature stagnation in local optima.Despite the proposal of various enhanced versions,the effective balancing of exploration and exploitation remains an unsolved challenge.To address the previously mentioned problems,this study proposes a multi-strategy collaborative improved SSA,which systematically integrates four complementary strategies:(1)the Northern Goshawk Optimization(NGO)mechanism enhances global exploration through guided prey-attacking dynamics;(2)an adaptive t-distribution mutation strategy balances the transition between exploration and exploitation via dynamic adjustment of the degrees of freedom;(3)a dual chaotic initialization method(Bernoulli and Sinusoidal maps)increases population diversity and distribution uniformity;and(4)an elite retention strategy maintains solution quality and prevents degradation during iterations.These strategies cooperate synergistically,forming a tightly coupled optimization framework that significantly improves search efficiency and robustness.Therefore,this paper names it NTSSA:A Novel Multi-Strategy Enhanced Sparrow Search Algorithm with Northern Goshawk Optimization and Adaptive t-Distribution for Global Optimization.Extensive experiments on the CEC2005 benchmark set demonstrate that NTSSA achieves theoretical optimal accuracy on unimodal functions and significantly enhances global optimum discovery for multimodal functions by 2–5 orders of magnitude.Compared with SSA,GWO,ISSA,and CSSOA,NTSSA improves solution accuracy by up to 14.3%(F8)and 99.8%(F12),while accelerating convergence by approximately 1.5–2×.The Wilcoxon rank-sum test(p<0.05)indicates that NTSSA demonstrates a statistically substantial performance advantage.Theoretical analysis demonstrates that the collaborative synergy among adaptive mutation,chaos-based diversification,and elite preservation ensures both high convergence accuracy and global stability.This work bridges a key research gap in SSA by realizing a coordinated optimization mechanism between exploration and exploitation,offering a robust and efficient solution framework for complex high-dimensional problems in intelligent computation and engineering design.展开更多
Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longe...Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,respectively.MATLAB/Simulink was used for simulation test.The optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 yuan.Additionally,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations significantly.The proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.展开更多
BACKGROUND Hepatocellular carcinoma ranks among the most prevalent malignant neoplasms.Surgical intervention constitutes a critical therapeutic approach for this condition.Nonetheless,postoperative recovery is frequen...BACKGROUND Hepatocellular carcinoma ranks among the most prevalent malignant neoplasms.Surgical intervention constitutes a critical therapeutic approach for this condition.Nonetheless,postoperative recovery is frequently influenced by the patient's nutritional status and the quality of nursing care provided.AIM To examine the comprehensive impact of personalized nutritional support and nursing strategies on the postoperative rehabilitation of patients with liver cancer.METHODS In this study,a retrospective comparative analysis was conducted involving 60 post-operative liver cancer patients.The subjects were selected as subjects and divided into two groups based on differing nursing interventions,with each group comprising 30 patients.The control group received standard nutritional support and care,whereas the experimental group received individualized nutritional support and nursing strategies.The study aimed to evaluate the impact of individualized nutrition by comparing the rehabilitation indices,nutritional status,quality of life(QoL),and complication rates between the two groups.RESULTS The results showed that the recovery index of the experimental group was significantly better than that of the control group 2 weeks after surgery,and the average liver function recovery index of the experimental group was 85.significantly higher than that of the control group(73.67±7.19).In terms of nutritional status,the serum albumin level and body weight stabilization rate of the experimental group were also significantly higher than those of the control group,which were 42.33±2.4 g/L and 93.3%,respectively,compared with 36.01±3.85 g/L and 76.7%of the control group.In addition,the average QoL score of the experimental group was 84.66±3.7 points,which was significantly higher than that of the control group(70.92±4.28 points).At the psychological level,the average anxiety score of the experimental group was 1.17±0.29,and the average depression score was 1.47±0.4,which were significantly lower than the 2.26±0.42 and 2.57±0.45 of the control group.This showed that patients in the experimental group were better relieved of anxiety and depression under the individualized nutrition support and nursing strategy.More importantly,the complication rate in the experimental group was only 10%,much lower than the 33.3%in the control group.CONCLUSION Personalized nutritional support and tailored nursing strategies significantly enhance the postoperative rehabilitation of liver cancer patients.Consequently,it is recommended to implement and advocate for these individualized approaches to improve both the recovery outcomes and QoL for these patients.展开更多
Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improv...Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improving the sodium storage performance and initial coulombic efficiency(ICE).However,the preparation of such HC materials with specific pore structures still faces great challenges.Herein,a simple pre-oxidation strategy is employed to construct abundant closed ultra-microporous structures in soy protein powder-derived HC material,achieving a significant improvement in its ICE and platform capacity.The pre-oxidation process promotes the cross-linking degree of the soy protein,thereby hindering the directional growth of graphite domains during the carbonization process.The optimized HC exhibits ultra-high platform capacity(329 mAh g^(-1))and considerable energy density(148.5 Wh kg^(-1)).Based on the ex-situ Raman and X-ray photoelectron spectroscopy characterization results,the excellent sodium storage capacity of the HC material is attributed to the synergistic effect of adsorption-intercalation/filling.The presented work provides novel insights into the synthesis of other biomass-derived HC materials with abundant closed ultra-micro pores.展开更多
Zeolite-loaded noble metal catalysts have demonstrated excellent performance in addressing cold-start automotive exhaust NOx emissions and catalytic oxidation of VOCs applications.Pd and Pt are the most commonly used ...Zeolite-loaded noble metal catalysts have demonstrated excellent performance in addressing cold-start automotive exhaust NOx emissions and catalytic oxidation of VOCs applications.Pd and Pt are the most commonly used active metals in PNA and VOC catalysts,respectively.However,despite the same metal/zeolite composition,the efficient active sites for PNA and VOC catalysts have been viewed as mainly Pd^(2+) and Pt^(0),respectively,both of which are different from each other.As a result,various methods need to be applied to dope Pd and Pt in zeolitic support respectively for different usages.No matter which type of metal species is needed,the common requirement for both PNA and VOC catalysts is that the metal species should be highly dispersed in zeolite support and stay stable.The purpose of this paper is to review the progress of synthetic means of zeolite-coated noble metals(Pd,Pt,etc.)as effective PNA or VOC catalysts.To give a better understanding of the relationship between efficient metal species and the introduced methods,the species that contributed to the NOx adsorption(PNA)and VOCs deep catalytic oxidation were first summarized and compared.Then,based on the above discussion,the detailed construction strategies for different active sites in PNA and VOC catalysts,respectively,were elaborated in terms of synthetic routes,precursor selection,and zeolite carrier requirements.It is hoped that this will contribute to a better understanding of noble metal adsorption/catalysis in zeolites and provide promising strategies for the design of adsorption/catalysts with high activity,selectivity and stability.展开更多
To achieve an unmanned rice farm,in this study,a cotransporter system was developed using a tracked rice harvester and transporter for autonomous harvesting,unloading,and transportation.Additionally,two unloading and ...To achieve an unmanned rice farm,in this study,a cotransporter system was developed using a tracked rice harvester and transporter for autonomous harvesting,unloading,and transportation.Additionally,two unloading and transportation modes—harvester waiting for unloading(HWU)and transporter fol-lowing for unloading(TFU)—were proposed,and a harvesting-unloading-transportation(HUT)strategy was defined.By breaking down the main stages of the collaborative operation,designing module-state machines(MSMs),and constructing state-transition chains,a HUT collaborative operation logic frame-work suitable for the embedded navigation controller was designed using the concept and method of the finite-state machine(FSM).This method addresses the multiple-stage,nonsequential,and complex processes in HUT collaborative operations.Simulations and field-harvesting experiments were performed to evaluate the applicability of this proposed strategy and system.The experimental results showed that the HUT collaborative operation strategy effectively integrated path planning,path-tracking control,inter-vehicle communication,collaborative operation control,and implementation control.The cotrans-porter system completed the entire process of harvesting,unloading,and transportation.The field-harvesting experiment revealed that a harvest efficiency of 0.42 hm^(2)·h^(−1) was achieved.This study can provide insight into collaborative harvesting and solutions for the harvesting process of unmanned farms.展开更多
基金National Natural Science Foundation of China(52472132)Opening Project of Engineering Research Center of Eco-friendly Polymeric Materials,Ministry of Education(EFP-KF2403)Innovation Service Capability Support Plan of Xianyang(Science and Technology Innovation Talents)。
文摘Development of high performance,flexible piezoelectric nanogenerators(PENGs)is critical for advancing self-powered sensing and microelectronic applications.In this study,a hydrogen-bond substitute strategy was employed to fabricate a multi-layer PENG based on a cellulose/polyvinylidene fluoride(PVDF)blend film matrix,incorporating multi-phase BCZT(0.1BaZr_(0.2)Ti_(0.8)O_(3)-0.9Ba_(0.7)Ca_(0.3)TiO_(3))ceramic fillers.Structural characterization via SEM and TEM revealed that an intricate hydrogen-bond network facilitated the uniform dispersion of ceramic fillers within the composite film’s sub-layers.In order to study the effect of filler distribution on piezoelectric performance,the single-and double-layer composite films with varying BCZT configurations were produced and evaluated.The results demonstrated that double-layer PENGs exhibit significantly enhanced electrical output compared to their single-layer counterparts,with the D-L_(3)H_(7) configuration achieving an open circuit voltage(V_(OC))of 23.13 V and a short circuit current(I_(SC))of 8.32μA.This enhancement is attributed to increased inter-layer interfaces,which effectively suppressed charge injection and migration,leading to improved charge density.Additionally,the presence of sharp tipped hexagonal tetragonal phase nanoparticles induced an electric field enhancement effect,further optimizing performance.
文摘Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2)O(1)was synthesized as a 2D structure using Coas the metal source,methanol‑water(4∶6,V/V)as the solvent,and specific concentrations of 2,5‑furandicarboxylic acid(H_(2)FDCA)and 1,3,5‑triimidazole benzene(L).Adjusting to pure water and lowering the concentration of L yielded the 1D chain structure of[Co(HL)2(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(2).Using Cu(Ⅱ)as the metal source,methanol/water(9∶1,V/V)as the solvent,and specific concentrations of L and H2FDCA,the 1D chain structure of[Cu(L)(FDCA)(H_(2)O)]·2H_(2)O(3)was synthesized.Upon increasing the concentrations of L and H2FDCA,and switching the solvent to pure water,the 1D chain structure of[Cu(HL)_(2)(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(4)was obtained.This shows that changing the solvent and ligand concentrations can affect the structural changes of CPs.In addition,the solid‑state photoluminescence of CPs 1‑4 at room temperature was studied,and their morphological changes were observed via scanning electron microscopy.Density functional theory calculations revealed that the negative charge concentrates on the O and N atoms of the ligand,facilitating ligand‑metal ion coordination.CCDC:2403934,1;2403935,2;2403936,3;2403938,4.
基金supported by NIH(R01 NS094402 and R21 EY029386)Shriners Children’s(#85190 PHI and#87400 PHI)by BrightFocus Foundation(G2019267)(to GMT).
文摘The field of neurodegeneration research has long been focused on finding therapeutic strategies to effectively decrease or halt neuronal loss while minimizing side effects.A recent study titled“Inhibiting acute,axonal DLK palmitoylation is neuroprotective and avoids deleterious effects of cell-wide DLK inhibition”(Zhang et al.,2025),describes an innovative approach to achieve this goal.The authors target a specific post-translational modification of dual leucine-zipper kinase(DLK),palmitoylation,to selectively inhibit DLK-dependent pro-degenerative signaling and protect neurons,thereby revealing a new way to intervene and block neurodegeneration.This Perspective aims to explore the significance of these findings and propose directions for future research.
基金supported by the Hunan Science and Technology Innovation Plan(No.2024RC3015)the National Natural Science Foundation of China(No.22501053)+1 种基金National Key Research and Development Program(Nos.2022YFC3900902 and 2024YFC3907900)Major Science and Technology Projects of Yunnan Province(No.202302AB080016).
文摘The structural principles of traditional Chinese mortise-and-tenon joints have inspired breakthroughs in supramolecular engineering.Nevertheless,substantial challenges remain in constructing nanoscale supramolecular architectures with precisely controlled giant dimensions.Herein,we report a precision-guided synthetic strategy for constructing giant 2D and 3D supramolecular architectures with rhomboidal motifs,which was achieved through a dovetail joint strategy.Initial assembly of bis-mortise ligand L1 with dovetail tenon ligand L2 in the presence of Cd^(2+)ions yielded the fundamental bis-rhombic supramolecule R1.Subsequent structural elaboration of the dovetail tenon motif enabled the development of multitopic ligands L3 and L4,which facilitated the construction of expanded architectures of the giant bis-propeller supramolecule R2 and tris-propeller supramolecule R3.The synthesized supramolecules R1-R3 were fully characterized multidimensional NMR spectroscopy,electrospray ionization mass spectrometry(ESI-MS),traveling wave ion mobility mass spectrometry(TWIM-MS),transmission electron microscopy(TEM),and atomic force microscopy(AFM).This work develops an innovative dovetail-joint assembly strategy for constructing rigid giant supramolecular architectures,establishing a new paradigm for precision engineering of complex 3D molecular systems.
基金supported by the National Natural Science Foundation of China(62073172)the Natural Science Foundation of Jiangsu Province of China(BK20221329)。
文摘Reaction-diffusion systems are widely used to describe pattern formation,and various control strategies have been applied to reaction-diffusion systems to achieve control objectives such as boundary control,output feedback stabilization,and synchronization.However,controlling pattern dynamics in reaction-diffusion systems with fractional-order diffusion remains an unresolved problem.This paper presents a proportional-derivative(PD)control strategy for the Schnakenberg system with fractional-order diffusion and cross-diffusion.Theoretical analysis explores the amplitude equation near the Turing bifurcation threshold,determining the selection and stability of pattern formations.Numerical simulations demonstrate that the PD controller accomplishes the modification of pattern structures and suppression of Turing instability by adjusting only two control parameters.Additionally,it is found that for smaller fractional diffusion order,the region can accommodate more hexagonal and stripe patterns in space.This work contributes to the control of complex pattern dynamics and offers a new approach to enhancing stability in fractional reaction-diffusion systems.
文摘Conventional locking/release mechanisms often face challenges in aircraft wing separation processes,such as excessive impact loads and insufficient synchronization.These may cause structural damage to the airframe or attitude instability,seriously compromising mission reliability.To address this engineering challenge,this paper proposes a multi-point low-impact locking/release mechanism based on the mobility model and energy conversion strategy.Through establishing a DOF constraint framework system,this paper systematically analyzes the energy transfer and conversion characteristics during the wing separation process,reveals the generation mechanism of impact loads,and conducts research on low-impact design based on energy conversion strategy.Building on this foundation,a single-point locking/release mechanism employing parallel trapezoidal key shaft structure was designed,which increases frictional contact time and reduces the energy release rate,thereby achieving low-impact characteristics.The mechanism's performance was validated through physical prototype development and systematic functional testing(including unlocking force,synchronization,and impact tests).Experimental results demonstrate:(1)Under 14 kN preload condition,the maximum unlocking force was only 92.54 N,showing a linear relationship with preload that satisfies the"strong-connection/weak-unlock"design requirement;(2)Wing separation was completed within 46 ms,with synchronization time difference among three separation mechanisms stably controlled within 12-14 ms,proving rapid and reliable operation;(3)The unlocking impact acceleration ranged between 26 and 73 g,below the 100 g design limit,confirming the effectiveness of the energy conversion strategy.The proposed low-impact locking/release mechanism design method based on energy conversion strategy resolves the traditional challenges of high impact and synchronization deficiencies.The synergistic optimization mechanism of"structural load reduction and performance improvement"provides a highly reliable technical solution for wing separable mechanisms while offering novel design insights for wing connection/separation systems engineering.
基金supports from the National Natural Science Foundation of China(Grant Nos.12305372 and 22376217)the National Key Research&Development Program of China(Grant Nos.2022YFA1603802 and 2022YFB3504100)+1 种基金the projects of the key laboratory of advanced energy materials chemistry,ministry of education(Nankai University)key laboratory of Jiangxi Province for persistent pollutants prevention control and resource reuse(2023SSY02061)are gratefully acknowledged.
文摘Using photoelectrocatalytic CO_(2) reduction reaction(CO_(2)RR)to produce valuable fuels is a fascinating way to alleviate environmental issues and energy crises.Bismuth-based(Bi-based)catalysts have attracted widespread attention for CO_(2)RR due to their high catalytic activity,selectivity,excellent stability,and low cost.However,they still need to be further improved to meet the needs of industrial applications.This review article comprehensively summarizes the recent advances in regulation strategies of Bi-based catalysts and can be divided into six categories:(1)defect engineering,(2)atomic doping engineering,(3)organic framework engineering,(4)inorganic heterojunction engineering,(5)crystal face engineering,and(6)alloying and polarization engineering.Meanwhile,the corresponding catalytic mechanisms of each regulation strategy will also be discussed in detail,aiming to enable researchers to understand the structure-property relationship of the improved Bibased catalysts fundamentally.Finally,the challenges and future opportunities of the Bi-based catalysts in the photoelectrocatalytic CO_(2)RR application field will also be featured from the perspectives of the(1)combination or synergy of multiple regulatory strategies,(2)revealing formation mechanism and realizing controllable synthesis,and(3)in situ multiscale investigation of activation pathways and uncovering the catalytic mechanisms.On the one hand,through the comparative analysis and mechanism explanation of the six major regulatory strategies,a multidimensional knowledge framework of the structure-activity relationship of Bi-based catalysts can be constructed for researchers,which not only deepens the atomic-level understanding of catalytic active sites,charge transport paths,and the adsorption behavior of intermediate products,but also provides theoretical guiding principles for the controllable design of new catalysts;on the other hand,the promising collaborative regulation strategies,controllable synthetic paths,and the in situ multiscale characterization techniques presented in this work provides a paradigm reference for shortening the research and development cycle of high-performance catalysts,conducive to facilitating the transition of photoelectrocatalytic CO_(2)RR technology from the laboratory routes to industrial application.
基金supported in part by Smart Grid-National Science and Technology Major Project(No.2024ZD0801400)Science and technology projects of State Grid Corporation of China(No.52272224000V).
文摘The transient behavior of DC-link voltage(DCV)significantly affects the low-voltage ride-through for phase-locked loop(PLL)-based grid-connected doubly-fed induction generator(DFIG)systems.This study investigates the DCV transient behavior of a PLL-based DFIG system under asymmetrical grid faults.First,by considering the coupling characteristics of positive and negative sequence(PNS)components,a nonlinear largesignal model of DCV is developed.Furthermore,the transient characteristics of DCV under varying parameters are analyzed using phase trajectory diagrams.In addition,the transient stability(TS)mechanism of DCV during asymmetrical faults is examined through an en-ergy function approach.The analysis indicates that the transient instability of DCV is primarily associated with the control characteristics of PNS PLLs,while the TS level of DCV is mainly determined by the power coordination control between the rotor side converter and grid side converter.Moreover,a coordinated control strategy is proposed to enhance the TS of DCV under asymmet-rical grid faults.Finally,both simulation and experimental results are presented to validate the theoretical analysis and the effectiveness of the proposed strategy.
基金supported by the National Nature Science Foundation of China under Grant No.22269021the Tianshan Talent Project of Xinjiang Uygur Autonomous Region:2023TSYCQNTJ0039the Open project of Key Laboratory in Xinjiang Uygur Autonomous Region of China:2023D04027。
文摘The development of electrocatalysts that both work effectively at industrial current density and resist chloride ion(Cl^(-))corrosion remains a key challenge for hydrogen production from Cl^(-)-rich alkaline water.Herein,we report a CrO_(x)-engineered nickel-based oxide catalyst(FeCoCrO_(x)/NF)that achieves exceptional activity and stability through a dual-functional interfacial mechanism.Combing in situ Raman spectroscopy,18O isotopic labeling,and electrochemical analysis,we demonstrate that the oxygen evolution reaction follows a lattice oxygen-mediated mechanism.The CrO_(x)layer selectively adsorbs hydroxide ions,forming a dynamic interfacial barrier that electrostatically repels Cl^(-)ingress,thereby mitigating Cl^(-)corrosion.Through enthalpy-based analysis,we demonstrate that electronic redistribution via Cr-O-Fe bonding increases the vacancy formation energy of Fe,thereby suppressing its dissolution.In alkaline electrolyte containing 0.5 M Cl^(-)(1.0 M KOH),the catalyst is operating continuously for 1400 h at an industrial current density of 1000 mA cm^(-2).Furthermore,the catalyst retains 99.5%of its initial activity under fluctuating current density(100-1000 mA cm^(-2)),demonstrating robustness required for industrial electrolyzers.This study establishes a paradigm for designing corrosion-resistant electrocatalysts through the synergistic modulation of interfacial ion selectivity and bulk lattice oxygen activation,advancing the application of green hydrogen production in Cl^(-)-rich alkaline water.
基金supported by the National Natural Science Foundation of China(Nos.22205105,61874053,22075136)National Key Basic Research Program of China(No.2020YFA0709900)Jiangsu Provincial Postgraduate Scientific Research Innovation Program(No.KYCX24_1649).
文摘Improving the optoelectronic behavior and stress-deformation stability of conjugated materials is crucial for the realization of their potential applications in flexible optoelectronics.To tune the emission behavior and mechanical property of molecular crystals simultaneously via supramolecular salt strategy is rarely reported,which is very important to improve their photophysical behavior and softness for the fabrication of flexible light-emitting device.Herein,supramolecular salt approach has been successfully applied to synthesize two elastic organic fluorescent crystals(CMOH-Py-Cl and CMOH-Py-Br)derived from non-emissive and brittle pyridine-substituted coumarin derivative(CMOH-Py).Their elastic properties can be attributed to the prevalent presence of numerous weak interactions introduced by halogen atoms,which are beneficial to the absorption and release of mechanical energy.Furthermore,density functional theory(DFT)calculations demonstrated a narrowing of the HOMO-LUMO energy gaps from CMOH-Py to CMOH-Py-Cl/CMOH-Py-Br via supramolecular salt approach.Finally,the application of flexible crystal materials in the field of optical waveguides has been investigated.The transformation of crystals in terms of photophysical and mechanical properties,achieved by the supramolecular salt approach,offers novel insights into the design and construction of flexible crystalline materials,providing a new path for the development of next-generation smart materials.
基金funded by the 2024 Shanghai Social Science Planning Annual Project titled“A Study on the Chunk Processing Mechanisms and Cognitive Motivations of ESL Reading”(Fund No.2024BYY012).
文摘English reading proficiency is essential for university students in a globalized academic environment,yet many L2 learners encounter challenges,such as limited vocabulary,complex syntax,and unclear text organization,leading to cognitive overload.Grounded in the Cognitive Load Theory(CLT),this study examines the role of the Chunking Reading Processing Strategy-which integrates fragmented linguistic information into meaningful units at lexical,syntactic,and discourse levels-in alleviating cognitive load and improving reading comprehension.Through a mixed-methods approach,the research investigates how learners at different proficiency levels perceive and apply the chunking strategy,and how such application relates to cognitive load management.The results indicate that higher-proficiency learners employ chunking more frequently and report greater benefits,whereas lower-proficiency learners depend more on instructional support.The study confirms the theoretical and pedagogical value of chunk-based reading instruction and suggests that differentiated,cognitively informed teaching of the chunking strategy can enhance both reading efficiency and strategic awareness among L2 learners.
基金supported by the National Natural Science Foundation of China(51677030).
文摘Fires and human casualties caused by single phase-to-ground faults in distribution networks are frequent.However,existing ground fault suppression methods are affected by ground fault resistance.Thus,an adaptive suppression method that seamlessly combines principles of current and voltage suppression is proposed,which has good adaptability to different ground fault resistance.Meanwhile,a multi-criteria ground fault suppression exit strategy matched to adaptive suppression method is proposed to avoid damage of device caused by power backflow,which provides the possibility for reliable and fast exit of the fault suppression device.Experimental results demonstrate effectiveness and advantages of the adaptive suppression method and its exit strategy.
基金Research into Wolfram syndrome in the De Groef team has been supported by the Eye Hope Foundation(Belgium),Wolfram UK(UK)and The Snow Foundation(USA).
文摘Wolfram syndrome(WS)is a rare autosomal rece s s i ve disease characte r i zed by the development of diabetes insipidus,diabetes mellitus,optic atrophy,and deafness(often referred to as DIDMOAD),and overall severe neurodegenerative fallback.The global prevalence of this disease is estimated at 1 in 770,000(Lee et al.,2023).It is most commonly caused by biallelic(point)mutations in the Wolframin endoplasmic reticulum(ER)transmembrane glycoprotein(WFS1)gene(in case of WS type 1),but mutations in the CDGSH Iron Sulfur Domain 2(CISD2)are also linked to WS(type 2).The latter,however,often present with less severe pathological manifestations(Lee et al.,2023).WFS1 is located on chromosome 4p16.1 and spans over 33 kilobases.Many mutation variants have been identified in WFS1,encompassing missense,nonsense,and frameshift mutations.These mutations are spread across the coding region of WFS1,but certain regions,such as exon 8,the largest exon,appear particularly mutation-prone and associated with the classical WS type 1 phenotype(Lee et al.,2023).
基金supported by the National Natural Science Foundation of China(Nos.61773142,62303136)China Postdoctoral Science Foundation(No.2023M740912)Postdoctoral Fellowship Program of CPSF,China(No.GZC20233447).
文摘In this article,a three-dimensional cooperative guidance problem for highly maneuvering targets is investigated under the assumption of perfect information.Inspired by the coverage strategy,the cooperative guidance problem is decomposed into one-on-one guidance problems against predictive interception points.To expand the coverage area of each missile,these one-on-one guidance problems are formulated as flight path angle tracking problems,and the optimal error dynamics is extended to derive the guidance law analytically.In addition,through the introduction of the coverage probability model,the dynamic coverage strategy is proposed.The predictive interception points are updated online by maximizing the coverage probability,which aims to achieve successful interception despite variations in target acceleration.Furthermore,a switching strategy of the guidance command is designed for collision avoidance.Simulation results demonstrate that the missile group can cooperatively intercept a highly maneuvering target under the proposed guidance law.
文摘It is evident that complex optimization problems are becoming increasingly prominent,metaheuristic algorithms have demonstrated unique advantages in solving high-dimensional,nonlinear problems.However,the traditional Sparrow Search Algorithm(SSA)suffers from limited global search capability,insufficient population diversity,and slow convergence,which often leads to premature stagnation in local optima.Despite the proposal of various enhanced versions,the effective balancing of exploration and exploitation remains an unsolved challenge.To address the previously mentioned problems,this study proposes a multi-strategy collaborative improved SSA,which systematically integrates four complementary strategies:(1)the Northern Goshawk Optimization(NGO)mechanism enhances global exploration through guided prey-attacking dynamics;(2)an adaptive t-distribution mutation strategy balances the transition between exploration and exploitation via dynamic adjustment of the degrees of freedom;(3)a dual chaotic initialization method(Bernoulli and Sinusoidal maps)increases population diversity and distribution uniformity;and(4)an elite retention strategy maintains solution quality and prevents degradation during iterations.These strategies cooperate synergistically,forming a tightly coupled optimization framework that significantly improves search efficiency and robustness.Therefore,this paper names it NTSSA:A Novel Multi-Strategy Enhanced Sparrow Search Algorithm with Northern Goshawk Optimization and Adaptive t-Distribution for Global Optimization.Extensive experiments on the CEC2005 benchmark set demonstrate that NTSSA achieves theoretical optimal accuracy on unimodal functions and significantly enhances global optimum discovery for multimodal functions by 2–5 orders of magnitude.Compared with SSA,GWO,ISSA,and CSSOA,NTSSA improves solution accuracy by up to 14.3%(F8)and 99.8%(F12),while accelerating convergence by approximately 1.5–2×.The Wilcoxon rank-sum test(p<0.05)indicates that NTSSA demonstrates a statistically substantial performance advantage.Theoretical analysis demonstrates that the collaborative synergy among adaptive mutation,chaos-based diversification,and elite preservation ensures both high convergence accuracy and global stability.This work bridges a key research gap in SSA by realizing a coordinated optimization mechanism between exploration and exploitation,offering a robust and efficient solution framework for complex high-dimensional problems in intelligent computation and engineering design.
基金supported by a Horizontal Project on the Development of a Hybrid Energy Storage Simulation Model for Wind Power Based on an RT-LAB Simulation System(PH2023000190)the Inner Mongolia Natural Science Foundation Project and the Optimization of Exergy Efficiency of a Hybrid Energy Storage System with Crossover Control for Wind Power(2023JQ04).
文摘Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,respectively.MATLAB/Simulink was used for simulation test.The optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 yuan.Additionally,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations significantly.The proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.
文摘BACKGROUND Hepatocellular carcinoma ranks among the most prevalent malignant neoplasms.Surgical intervention constitutes a critical therapeutic approach for this condition.Nonetheless,postoperative recovery is frequently influenced by the patient's nutritional status and the quality of nursing care provided.AIM To examine the comprehensive impact of personalized nutritional support and nursing strategies on the postoperative rehabilitation of patients with liver cancer.METHODS In this study,a retrospective comparative analysis was conducted involving 60 post-operative liver cancer patients.The subjects were selected as subjects and divided into two groups based on differing nursing interventions,with each group comprising 30 patients.The control group received standard nutritional support and care,whereas the experimental group received individualized nutritional support and nursing strategies.The study aimed to evaluate the impact of individualized nutrition by comparing the rehabilitation indices,nutritional status,quality of life(QoL),and complication rates between the two groups.RESULTS The results showed that the recovery index of the experimental group was significantly better than that of the control group 2 weeks after surgery,and the average liver function recovery index of the experimental group was 85.significantly higher than that of the control group(73.67±7.19).In terms of nutritional status,the serum albumin level and body weight stabilization rate of the experimental group were also significantly higher than those of the control group,which were 42.33±2.4 g/L and 93.3%,respectively,compared with 36.01±3.85 g/L and 76.7%of the control group.In addition,the average QoL score of the experimental group was 84.66±3.7 points,which was significantly higher than that of the control group(70.92±4.28 points).At the psychological level,the average anxiety score of the experimental group was 1.17±0.29,and the average depression score was 1.47±0.4,which were significantly lower than the 2.26±0.42 and 2.57±0.45 of the control group.This showed that patients in the experimental group were better relieved of anxiety and depression under the individualized nutrition support and nursing strategy.More importantly,the complication rate in the experimental group was only 10%,much lower than the 33.3%in the control group.CONCLUSION Personalized nutritional support and tailored nursing strategies significantly enhance the postoperative rehabilitation of liver cancer patients.Consequently,it is recommended to implement and advocate for these individualized approaches to improve both the recovery outcomes and QoL for these patients.
基金supported by the National Natural Science Foundation of China(42167068,22269020)the Gansu Province Higher Education Industry Support Plan Project(2023CYZC-68)the Central Guidance for Local Science and Technology Development Funds Project(YDZX20216200001007)。
文摘Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improving the sodium storage performance and initial coulombic efficiency(ICE).However,the preparation of such HC materials with specific pore structures still faces great challenges.Herein,a simple pre-oxidation strategy is employed to construct abundant closed ultra-microporous structures in soy protein powder-derived HC material,achieving a significant improvement in its ICE and platform capacity.The pre-oxidation process promotes the cross-linking degree of the soy protein,thereby hindering the directional growth of graphite domains during the carbonization process.The optimized HC exhibits ultra-high platform capacity(329 mAh g^(-1))and considerable energy density(148.5 Wh kg^(-1)).Based on the ex-situ Raman and X-ray photoelectron spectroscopy characterization results,the excellent sodium storage capacity of the HC material is attributed to the synergistic effect of adsorption-intercalation/filling.The presented work provides novel insights into the synthesis of other biomass-derived HC materials with abundant closed ultra-micro pores.
基金supported by Zhongtian Iron and Steel-University of Science and Technology Beijing Youth Science and Technology Innovation Fund(No.FZTNTC2024050005)National Engineering Laboratory for Mobile Source Emission Control Technology,China(No.NELMS2020A07)The Fundamental Research Funds for the Central Universities,China(No.FRF-AT-20-12)。
文摘Zeolite-loaded noble metal catalysts have demonstrated excellent performance in addressing cold-start automotive exhaust NOx emissions and catalytic oxidation of VOCs applications.Pd and Pt are the most commonly used active metals in PNA and VOC catalysts,respectively.However,despite the same metal/zeolite composition,the efficient active sites for PNA and VOC catalysts have been viewed as mainly Pd^(2+) and Pt^(0),respectively,both of which are different from each other.As a result,various methods need to be applied to dope Pd and Pt in zeolitic support respectively for different usages.No matter which type of metal species is needed,the common requirement for both PNA and VOC catalysts is that the metal species should be highly dispersed in zeolite support and stay stable.The purpose of this paper is to review the progress of synthetic means of zeolite-coated noble metals(Pd,Pt,etc.)as effective PNA or VOC catalysts.To give a better understanding of the relationship between efficient metal species and the introduced methods,the species that contributed to the NOx adsorption(PNA)and VOCs deep catalytic oxidation were first summarized and compared.Then,based on the above discussion,the detailed construction strategies for different active sites in PNA and VOC catalysts,respectively,were elaborated in terms of synthetic routes,precursor selection,and zeolite carrier requirements.It is hoped that this will contribute to a better understanding of noble metal adsorption/catalysis in zeolites and provide promising strategies for the design of adsorption/catalysts with high activity,selectivity and stability.
基金the National Key Research and Development Program of China(2021YFD2000600)the National Natural Science Foundation of China(32071914)+1 种基金the Modern Agricultural Industry Technology System of China(CARS-170405)the Key Research and Development Program(Science and Technology Demonstration Project)project of Shandong Province(2022SFGC0202).
文摘To achieve an unmanned rice farm,in this study,a cotransporter system was developed using a tracked rice harvester and transporter for autonomous harvesting,unloading,and transportation.Additionally,two unloading and transportation modes—harvester waiting for unloading(HWU)and transporter fol-lowing for unloading(TFU)—were proposed,and a harvesting-unloading-transportation(HUT)strategy was defined.By breaking down the main stages of the collaborative operation,designing module-state machines(MSMs),and constructing state-transition chains,a HUT collaborative operation logic frame-work suitable for the embedded navigation controller was designed using the concept and method of the finite-state machine(FSM).This method addresses the multiple-stage,nonsequential,and complex processes in HUT collaborative operations.Simulations and field-harvesting experiments were performed to evaluate the applicability of this proposed strategy and system.The experimental results showed that the HUT collaborative operation strategy effectively integrated path planning,path-tracking control,inter-vehicle communication,collaborative operation control,and implementation control.The cotrans-porter system completed the entire process of harvesting,unloading,and transportation.The field-harvesting experiment revealed that a harvest efficiency of 0.42 hm^(2)·h^(−1) was achieved.This study can provide insight into collaborative harvesting and solutions for the harvesting process of unmanned farms.
