High resolution mode-selective excitation in the mixture of C6H6 （992 cm^-1） and C6D6 （945 cm^-1） is experimentally achieved by adaptive femtosecond pulse shaping based on the genetic algorithm （GA）, and second ...High resolution mode-selective excitation in the mixture of C6H6 （992 cm^-1） and C6D6 （945 cm^-1） is experimentally achieved by adaptive femtosecond pulse shaping based on the genetic algorithm （GA）, and second harmonic generation frequency-resolved optical gating （SHG-FROG） is adopted to characterize the original and optimal laser pulses, and its mechanism is experimentally validated by tailoring the frequency components of the pump pulses at the Fourier plane. It is indicated that two-pulse coherent mode-selective excitation of the Raman scattering mainly depends on the effective frequency components of the pump pulse related to specific molecular vibrational mode. The experimental results have attractive potential applications in the complicated molecular system.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 10574046, the National Basic Research Programme of China under Grant Nos 2006CB806006 and 2006CB921105, the Programme for Changjiang Scholars and Innovative Research Team in University （PCSIRT）, the Programme for New Century Excellent Talents in University （NCET-04-0420）, the Doctoral Programme of High Education of China under Grant No 20050269011, the Phosphor Programme sponsored by Shanghai Science and Technology Committee （06QH14003）.
文摘High resolution mode-selective excitation in the mixture of C6H6 （992 cm^-1） and C6D6 （945 cm^-1） is experimentally achieved by adaptive femtosecond pulse shaping based on the genetic algorithm （GA）, and second harmonic generation frequency-resolved optical gating （SHG-FROG） is adopted to characterize the original and optimal laser pulses, and its mechanism is experimentally validated by tailoring the frequency components of the pump pulses at the Fourier plane. It is indicated that two-pulse coherent mode-selective excitation of the Raman scattering mainly depends on the effective frequency components of the pump pulse related to specific molecular vibrational mode. The experimental results have attractive potential applications in the complicated molecular system.
