Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in a...Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in alpine mountains with climate change.Hence,94 samples of river water were collected from 2018 to 2020 in the headwaters of the Shule River Basin to assess the nutrients spatiotemporal distribution and combined ap-proach of water quality index to assess water quality and potential sources.The findings depict that high nutrient concentrations were found to coincide with snowmelt and glacial meltwater and rainfall recharge periods,while total flux peaked from June to September due to increased runoff.Notably,total nitrogen(TN)concentrations were significantly higher near the town,primarily attributed to the replenishment of nitrate(NO_(3)^(‒)-N)from live-stock manure.The high total P(TP)was near the glacier,which was attributed to the transportation of glacial sediments into the river,and pH was another critical factor.N was the primary nutrient limiting factor for the growth of phytoplankton in river water.Although the migration and transport of nutrients have altered with climate change,river water quality is good in alpine mountains based on an overall evaluation.These findings contribute to enriching nutrient datasets and highlight the importance of water resource management and water quality assessment in sensitive and fragile alpine mountains.展开更多
39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.Ar...39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.展开更多
Curcuma is a traditional Chinese medicine that has been utilized for centuries in the treatment of various diseases. Terpenoids, particularly monoterpenes and sesquiterpenes, constitute the primary bioactive component...Curcuma is a traditional Chinese medicine that has been utilized for centuries in the treatment of various diseases. Terpenoids, particularly monoterpenes and sesquiterpenes, constitute the primary bioactive components of the essential oil derived from Curcuma species.Among these, curdione—one of the key active constituents—has been identified in 25 Curcuma species, with the highest concentration reported in the rhizome essential oil of Curcuma trichosantha Gagnep. Curdione can also be synthesized through chemical methods,and its regio-and stereo-selectivity can be further optimized via chemo-bio transformations.This compound demonstrates significant therapeutic potential, including anticancer, antithrombotic, anti-inflammatory, anti-viral, anti-fungal, anti-diabetic, and multi-organ protective properties. Despite these promising biological activities, its clinical application is hindered by poor water solubility and potential toxicity. This review summarizes current knowledge on the natural sources, chemical synthesis, chemo-bio transformations, metabolism, pharmacokinetics, pharmacological effects, potential toxicities, and molecular mechanisms of curdione. Furthermore, perspectives on future drug development are discussed with the aim of promoting the clinical translation of this promising natural compound.展开更多
Per-and poly-fluoroalkyl substances(PFAS)have garnered significant global attention due to their widespread presence and potential environmental and health risks.However,research on the occurrence and environmental be...Per-and poly-fluoroalkyl substances(PFAS)have garnered significant global attention due to their widespread presence and potential environmental and health risks.However,research on the occurrence and environmental behavior of PFAS across different media remains limited.We analyzed the occurrence,distribution,sources,and ecological risks of 32 PFAS across multiple media in the Weihe River,China.The concentrations of PFAS ranged from 5.89 to 472.84 ng/L in the pore water and from 9.93 to 459.50 ng/L in surface water,exhibiting significant spatial variability(P<0.05).In contrast,the PFAS concentration range in the sediments was 0.74-1.81 ng/g dry weight,with no pronounced spatial variation in solid-phase PFAS(P>0.05).Vertically,concentrations in 33.00%of pore water samples exceeded those in surface water,showing a heterogeneous vertical distribution with enrichment at depths of 40-60 cm.The physical-chemical characteristics of PFAS and the hydrological and sedimentary processes at the basin scale were responsible for PFAS partitioning between the aquatic environment and sediments.Four major sources were identified through integrated source apportionment:industrial and domestic wastewater(58.25%),aqueous film-forming foam(18.07%),combined input from household pollution and metal plating(8.70%),and stormwater runoff and landfill leachate(14.98%).The ecological risk assessment revealed negligible risks from short-chain PFAS in surface water and pore water,whereas long-chain PFAS posed low to moderate ecological risks.Furthermore,the discharge of PFAS from the Weihe River to the Yellow River was estimated up to 708.20 kg/a.This study provides critical data informing strategies for mitigating PFAS pollution in rivers across typical arid and semi-arid areas of China.展开更多
Accurate identification of sediment sources and erosion hotspots is crucial for implementing targeted soil and water conservation measures.This study analyzed the temporal dynamics of sediment source contributions dur...Accurate identification of sediment sources and erosion hotspots is crucial for implementing targeted soil and water conservation measures.This study analyzed the temporal dynamics of sediment source contributions during seven rainfall events(A_(1)–A_(7))that generated both runoff and suspended sediment at the outlet of the Hantaichuan watershed,located in the wind–water erosion crisscross region of the northern Loess Plateau,China.A total of 82 suspended sediment samples were collected at the Xiangshawan hydrological station during 2021 and 2022.Additionally,145 soil samples were collected from three primary potential sources:sandy soil,loess soil,and Pisha sandstone.Mid-infrared(MIR)spectroscopy and geochemical fingerprinting were used to trace and quantify sediment sources.For MIRbased source apportionment,twelve predictive models were developed using partial least squares regression(PLSR)and support vector machine regression(SVMR)in combination with six spectral preprocessing techniques.The PLSR model with first-derivative Savitzky–Golay(SGD1)preprocessing achieved the best performance.Source apportionment results indicated that Pisha sandstone was the dominant sediment source(44.00%–72.23%),followed by sandy soil(14.23%–37.00%)and loess soil(10.01%–24.00%).Among the analyzed rainfall events,the contribution of Pisha sandstone was lowest in the small flow magnitude event A3(57.53%)and highest in the large flow magnitude event A6(63.48%),suggesting that sediment source composition was strongly controlled by rainfall event magnitude.Both MIR spectroscopic and geochemical fingerprinting methods showed high consistency,confirming MIR spectroscopy as a reliable,non-destructive,and cost-effective alternative for rapid sediment source apportionment and for supporting erosion control prioritization in highly erodible catchments.展开更多
The estimation of the Number of Sources(NoS)is a significant challenge in signal processing,particularly due to the impact of colored noise on the performance of NoS estimation.This paper proposes a Multidimensional F...The estimation of the Number of Sources(NoS)is a significant challenge in signal processing,particularly due to the impact of colored noise on the performance of NoS estimation.This paper proposes a Multidimensional Feature Network(MFNet)which is designed for NoS estimation by extracting features of the sampled received signals and Sampled Covariance Matrix(SCM).The MFNet treats the raw signal and the SCM as two different types of data,and is able to achieve NoS estimation under colored noise and imperfect array.MFNet employs the Gated Recurrent Unit(GRU)to capture sequential information from the original signal data and to construct the Pseudo Covariance Matrix(PCM).Subsequently,various dimensional features,including eigenvalues and the Gerschgorin disk radius,are extracted from both the PCM and SCM,which are then jointly input into the subsequent network.An overall accuracy of 82%can be achieved after network training.The ablation experimental results demonstrate the effectiveness of multiple inputs.And simulation results demonstrate that the proposed MFNet achieves higher estimation accuracy compared to existing algorithms and exhibits greater robustness against colored noise.展开更多
Carbon Capture,Utilization,and Storage(CCUS)technology has gained widespread attention in recent years as a critical strategy to combat global climate change,particularly in achieving carbon neutrality goals.The Guang...Carbon Capture,Utilization,and Storage(CCUS)technology has gained widespread attention in recent years as a critical strategy to combat global climate change,particularly in achieving carbon neutrality goals.The Guangdong-Hong Kong-Macao Greater Bay Area(GBA),as one of China's most economically active regions,serves as a key engine for economic growth while also facing considerable carbon emission challenges.This study analyzes the industrial emission volume and geographical distribution of key emitting enterprises in the GBA,summarizes their technological processes and main carbonemitting equipment,and provides scientific support for precise mitigation policies and low-carbon development.Based on data from 176 key emitting enterprises,the study reveals that Guangzhou and Dongguan host the largest number of such enterprises.Carbon emissions are primarily concentrated in the power sector,dominated by coal-and gas-fired power units,characterized by significant spatial dispersion and uneven distribution.Beyond the power sector,the paper industry has a high number of enterprises but lower emissions.Key facilities such as boilers,cogeneration systems,and production lines are predominantly located near tributaries rivers in Dongguan and Jiangmen.The building materials sector,primarily cement production,ranks as the second-largest emitter,with hightemperature kilns and grinding equipment,particularly rotary kilns and glass furnaces,as the main sources.The petrochemical and chemical sectors have fewer enterprises and lower emissions in the GBA,mainly located in suburban industrial clusters.Carbon emissions in the GBA exhibit distinct industry concentration and geographical distribution disparities.This study provides crucial data and theoretical insights for the development of targeted emission reduction strategies,optimization of source-sink matching,and the advancement of CCUS technologies in the region,particularly from the GBA to the northern South China Sea.展开更多
We conducted a field campaign to investigate the chemical composition,sources,and light absorption of submicron aerosols(PM_(1))from early 2022 in Nanjing,China.The average concentration of PM_(1) was 31μg m^(−3),org...We conducted a field campaign to investigate the chemical composition,sources,and light absorption of submicron aerosols(PM_(1))from early 2022 in Nanjing,China.The average concentration of PM_(1) was 31μg m^(−3),organics(33%)constituted the largest fraction,followed by nitrate(30%),sulfate(18%),ammonium(15%),chloride(3%),and rBC(2%).Four organic aerosol(OA)subcomponents were identified,including two primary OA(POA)and two secondary OA(SOA).The less-oxidized SOA(LO-OOA)contributes the most to the total OA mass(59%).LO-OOA is tightly correlated with the tracer ion C_(2)H_(4)O_(2)^(+)from levoglucosan,and another aged biomass-burning derived species,K_(3)SO_(4)^(+),suggesting it was likely influenced by aged biomass-burning OA.Our study also revealed that fireworks during the Spring Festival have a detrimental impact on air quality,contributing to secondary formation and accumulation under static winter meteorological conditions,prolonging the pollution duration.Also,LO-OOA was found to have the strongest light-absorbing ability.Our results highlight that the light absorption of LO-OOA can mainly be attributed to the C_(x)H_(y)N^(+) family,increased with the double-bond equivalent value.The more-oxidized SOA(MO-OOA)exhibited a negligible light absorption and was strongly correlated with daytime photochemical processes,implying a light-bleaching effect.This study enhances our understanding of the regional contribution of biomass combustion and fireworks to PM_(1) pollution in Nanjing,a typical megacity in the Yangtze River Delta region,during winter,aiding in the development of strategies for long-term air quality improvement in the region.展开更多
Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previo...Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previous research,providing a long-term perspective on carbonyl compound variations and their environmental implica-tions.Atmospheric observations were conducted at Beijing(BJ)and Xianghe(XH)during the summer and winter months of 2018,2019,and 2023 to study the sources and impacts of carbonyl compounds in typical urban areas and peri‑urban areas.Notably,concentrations in the summer of 2023 increased compared to 2018 and 2019.The predominant carbonyl compounds—formaldehyde,acetaldehyde,and acetone—accounted for over 60%of the total.The mean values of OFP in BJ ranged from 18.55 to 58.61μg/m3,lower than those in XH(29.82 to 65.48μg/m3),with formaldehyde and acetaldehyde contributing over 80%of the total.SOAP exhibited a similar pattern,with values in XH(69.21 to 508.55μg/m3)significantly exceeding those in BJ(34.47 to 159.78μg/m3).The PMF model highlighted vehicle exhaust,secondary pollution,and biomass combustion as major sources of carbonyl compounds,emphasizing differences in source contributions between the two regions.This study’s com-parative analysis over different years and locations provides new insights into the dynamic changes in carbonyl compounds and their environmental importance.These results not only reinforce the importance of carbonyl compounds regulation but also offer a valuable reference for evaluating and refining emission control strategies during this period.展开更多
The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment....The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment.In this study,terrestrial laser scanning(TLS)and unmanned aerial vehicle(UAV)technologies were integrated to enhance the evaluation methodology for rock mass hazard sources,focusing on the Sichuan Yanjiang Expressway project in China.The findings demonstrate that TLS-UAV technology enhanced both spatial coverage and data density in slope modeling.Through integrated algorithmic analysis,rock discontinuities within heterogeneous datasets were systematically identified,enabling quantitative extraction and statistical analysis of key geometric parameters,including orientation,trace length,spacing,and roughness.Furthermore,quantitative models were developed for cohesion,friction angle and the morphology parameter M of in situ discontinuities,respectively,facilitating efficient mechanical parameter acquisition.A novel rock mass hazard index(RHI)was developed incorporating discontinuity geometric rating(DGR),discontinuity mechanical rating(DMR),and slope mass rating(SMR).Field validation confirmed the methodology's effectiveness in evaluating risk levels and spatial heterogeneity of rock mass hazard sources,revealing the contribution of different discontinuity sets to the rock mass hazard and identifying the primary discontinuity sets controlling instability mechanisms.This study is of great significance for evaluating discontinuity-controlled rock mass hazard sources and preventing rockfall disasters.展开更多
The real-time and accurate calculation of electricity indirect carbon emissions is not only the critical component for quantifying the carbon emission levels of the power system but also an effective mean to guide ele...The real-time and accurate calculation of electricity indirect carbon emissions is not only the critical component for quantifying the carbon emission levels of the power system but also an effective mean to guide electricity users in carbon reduction and promote power industry low-carbon transformation.Fundamentally,calculating indirect carbon emissions involves allocating direct carbon emission data from the power source side,indicating that accurate indirect emission results rely on the precise measurement of power source emissions.However,existing research on indirect carbon emissions in large-scale power systems rarely accounts for variations in carbon emission characteristics under different operating conditions of power sources,such as rated/non-rated operating conditions and ramping up/down conditions,making it difficult to reflect source-side and load-side carbon emission information variation during providing ancillary services.Quadratic and exponential functions are proposed to characterize the energy consumption profiles of coal-fired and gas-fired power generation,respectively,to construct a refined carbon emission model for power sources.By leveraging the theory of power system carbon flow,we analyze how variable operating conditions of power sources impact indirect carbon emissions.Case studies demonstrate that changes in power source emissions under variable conditions have a significant effect on the indirect carbon emissions of power grids.展开更多
Collagen is a class of mammalian extracellular matrix of the main structural proteins,widely present in the skin,bone,muscle and other tissues and it plays a role in supporting,repairing,and protecting tissue cells.Na...Collagen is a class of mammalian extracellular matrix of the main structural proteins,widely present in the skin,bone,muscle and other tissues and it plays a role in supporting,repairing,and protecting tissue cells.Natural source extraction and artificial synthesis provide a rich source of collagen.As a macromolecular material,collagen has good application potential in cosmetics,pharmaceutical,medical and food industries.Collagen has generated a great deal of interest in the cosmetic industry due to its abundance,strength,and direct correlation with skin aging.Collagen is widely used in cosmetics due to its unique structure,good biocompatibility and low antigenicity,as well as rich biological functions.To enhance the youthfulness and health of the user,the cosmetic industry adds collagen to products such as eye creams,face creams,and nutritional supplements,and uses it in medical aesthetic techniques such as tissue fillers,skin replacement,and soft skin enhancement.This paper mainly reviews the sources and types of collagen used in cosmetics industry,then introduces the effects of collagen in cosmetics and prospects the development prospects of collagen in dermatologic and cosmetic fields.展开更多
Heavy metal(loid)(HM)pollution in agricultural soils has become an environmental concern in antimony(Sb)mining areas.However,priority pollution sources identification and deep understanding of environmental risks of H...Heavy metal(loid)(HM)pollution in agricultural soils has become an environmental concern in antimony(Sb)mining areas.However,priority pollution sources identification and deep understanding of environmental risks of HMs face great challenges due to multiple and complex pollution sources coexist.Herein,an integrated approach was conducted to distinguish pollution sources and assess human health risk(HHR)and ecological risk(ER)in a typical Sb mining watershed in Southern China.This approach combines absolute principal component score-multiple linear regression(APCS-MLR)and positivematrix factorization(PMF)models with ER and HHR assessments.Four pollution sources were distinguished for both models,and APCS-MLR model was more accurate and plausible.Predominant HM concentration source was natural source(39.1%),followed by industrial and agricultural activities(23.0%),unknown sources(21.5%)and Sb mining and smelting activities(16.4%).Although natural source contributed the most to HM concentrations,it did not pose a significant ER.Industrial and agricultural activities predominantly contributed to ER,and attention should be paid to Cd and Sb.Sb mining and smelting activities were primary anthropogenic sources of HHR,particularly Sb and As contaminations.Considering ER and HHR assessments,Sb mining and smelting,and industrial and agricultural activities are critical sources,causing serious ecological and health threats.This study showed the advantages of multiple receptor model application in obtaining reliable source identification and providing better source-oriented risk assessments.HM pollution management,such as regulating mining and smelting and implementing soil remediation in polluted agricultural soils,is strongly recommended for protecting ecosystems and humans.展开更多
Precipitation isotopes(δ^(18)O and δ^(2)H)are closely related to meteorological conditions for precipitation generation and the initial state of water vapor source areas,and are essential to the study of the regiona...Precipitation isotopes(δ^(18)O and δ^(2)H)are closely related to meteorological conditions for precipitation generation and the initial state of water vapor source areas,and are essential to the study of the regional hydrological cycle.The deuterium excess(d-excess)indicates deviation in isotope fractionation during evaporation and can trace water vapor sources.This study analyzed 443 precipitation samples collected from the Gannan Plateau,China in 2022 to assess precipitation isotope variations and their driving factors.Water vapor sources were evaluated using the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT),Concentration Weighted Trajectory(CWT),and Potential Source Contribution Factor(PSCF)models.Results showed that precipitation isotope values showed significant spatial and temporal variations on the Gannan Plateau.Temporally,precipitation isotope values peaked in June(when evaporation dominated)and minimized in March(depletion effect of air masses in the westerly wind belt).Spatially,the isotope values showed a distribution pattern of"high in the east and low in the west",which was mainly regulated by the differences in altitude and local meteorological conditions.Compared with the global meteoric water line(GMWL)with equation of δ^(2)H=8.00δ^(18)O+10.00,the slope and intercept of local meteoric water line(LMWL)for precipitation on the Gannan Plateau were smaller(7.49 and 7.63,respectively),reflecting the existence of a stronger secondary evaporation effect under the clouds in the region.The sources of water vapor on the Gannan Plateau showed significant seasonality and spatial heterogeneity.Specifically,the westerly belt and monsoon were the main water vapor transport paths at each sampling point,with Central Asian continental water vapor dominating in spring(53.49%),Indian Ocean water vapor dominating in summer(52.53%),Atlantic Ocean water vapor dominating in autumn(46.74%),and Atlantic Ocean and Mediterranean Sea water vapor dominating in winter(42.30%and 33.68%,respectively).Changes in the intensity of convective activity and Outgoing Longwave Radiation(OLR)affected the enrichment of isotopic values,which exhibited the same change trends as δ^(18)O.During the precipitation process,the δ^(18)O value first decreased and then increased.During the initial and final stages of precipitation process,precipitation was mainly influenced by continental air masses,while during the middle stage,it was controlled by marine air masses.The systematic research on precipitation isotopes and water vapor sources is important for climate change research and extreme precipitation prediction on the Gannan Plateau and other similar areas.展开更多
Infinitely many conservation laws for some （1＋1）-dimension soliton hierarchy with self-consistent sources are constructed from their corresponding Lax pairs directly. Three examples are given. Besides, infinitely m...Infinitely many conservation laws for some （1＋1）-dimension soliton hierarchy with self-consistent sources are constructed from their corresponding Lax pairs directly. Three examples are given. Besides, infinitely many conservation laws for Kadomtsev-Petviashvili （KP） hierarchy with self-consistent sources are obtained from the pseudo-differential operator and the Lax pair.展开更多
Excessive concentrations of toxic metals are a global threat to aquatic systems.Taking a typical tributary(Zijiang River,ZR)of the midstream of the Yangtze River as the research area,the concentration distribution and...Excessive concentrations of toxic metals are a global threat to aquatic systems.Taking a typical tributary(Zijiang River,ZR)of the midstream of the Yangtze River as the research area,the concentration distribution and chemical fractions occurrence characteristics of five toxic metals(Cd,Cr,Cu,Pb,and Zn)were analyzed,their potential sources were explored,and their contamination and ecological risk was assessed.In the surface waters and sediments,there were high concentrations of Zn,a low concentration of Cd,and small spatial differences in concentration among the upstream,midstream,and downstream.In terms of speciation,Cd mainly existed in the acid-soluble fraction,Pb mainly existed in the reducible fraction,and Cr,Cu,and Zn mainly existed in the residue fraction.The potential sources in surface waters and sediments were determined to be industrial emissions and agricultural non-point sources through the absolute principal component scores–multiple linear regression model(APCS–MLR).Based on the assessment results of total concentration and speciation,Cd was the typical contamination element in ZR sediments.In addition,the secondary phase enrichment factor(SPEF)based on speciation underestimates the degree of Pb contamination,and the ecological risk of Zn assessed by the ratio of secondary phase and primary phase(RSP)and the risk assessment code(RAC)was higher than that of Cr,which was inconsistent with the results based on total concentrations.SOM and Al/Fe/Mn cycles in sediments influenced the geochemical behavior of toxic metals.展开更多
In this study,different types of small molecular carbon sources such as melamine,dicyandiamine,pyrocatechol,and o-phenylenediamine were used to regulate the surface structures of iron/nitrogen/carbonbased composites(F...In this study,different types of small molecular carbon sources such as melamine,dicyandiamine,pyrocatechol,and o-phenylenediamine were used to regulate the surface structures of iron/nitrogen/carbonbased composites(Fe-N/C),which were used to activate peroxymonosulfate(PMS).The relationship between different small molecular carbon sources and the electronic structure was investigated.The characteristics of metal-carrier interaction in the Fe-N/C were clarified.As a result,there were significant differences in the degradation efficiency of catalysts prepared with different small molecular carbon sources,which was related to the types of active sites.Density functional theory(DFT)and experiments results showed that the catalyst rich in C-O-C and FeN_(x)exhibited better catalytic activity,which may be attributed to the higher adsorption energy for PMS.The main active species for catalytic degradation of ofloxacin were identified as sulfate radical(SO_(4)^(·-))and hydroxyl radical(^(·)OH)by electron paramagnetic resonance(EPR)spectra.The introduction of different small molecular carbon sources can significantly affect the distribution and electronic structure of active sites on the catalyst surface,thereby regulating the generation and migration of radicals.展开更多
With the development of integrated power and gas distribution systems(IPGS)incorporating renewable energy sources(RESs),coordinating the restoration processes of the power distribution system(PS)and the gas distributi...With the development of integrated power and gas distribution systems(IPGS)incorporating renewable energy sources(RESs),coordinating the restoration processes of the power distribution system(PS)and the gas distribution system(GS)by utilizing the benefits of RESs enhances service restoration.In this context,this paper proposes a coordinated service restoration framework that considers the uncertainty in RESs and the bi-directional restoration interactions between the PS and GS.Additionally,a coordinated service restoration model is developed considering the two systems’interdependency and the GS’s dynamic characteristics.The objective is to maximize the system resilience index while adhering to operational,dynamic,restoration logic,and interdependency constraints.A method for managing uncertainties in RES output is employed,and convexification techniques are applied to address the nonlinear constraints arising from the physical laws of the IPGS,thereby reducing solution complexity.As a result,the service restoration optimization problem of the IPGS can be formulated as a computationally tractable mixed-integer second-order cone programming problem.The effectiveness and superiority of the proposed framework are demonstrated through numerical simulations conducted on the interdependent IEEE 13-bus PS and 9-node GS.The comparative results show that the proposed framework improves the system resilience index by at least 65.07%compared to traditional methods.展开更多
Traditional beamforming techniques may not accurately locate sources in scenarios with both stationary and rotating sound sources.The existence of rotating sound sources can cause blurring in the stationary beamformin...Traditional beamforming techniques may not accurately locate sources in scenarios with both stationary and rotating sound sources.The existence of rotating sound sources can cause blurring in the stationary beamforming map.Current algorithms for separating different moving sound sources have limited effectiveness,leading to significant residual noise,especially when the rotating source is strong enough to mask stationary sources completely.To overcome these challenges,a novel solution utilizing a virtual rotating array in the modal domain combined with robust principal component analysis is proposed to separate sound sources with different rotational speeds.This approach,named Robust Principal Component Analysis in the Modal domain(RPCA-M),investigates the performance of convex nuclear norm and non-convex Schatten-p norm to distinguish stationary and rotating sources.By comparing the errors in Cross-Spectral Matrix(CSM)recovery and acoustic imaging across different algorithms,the effectiveness of RPCA-M in separating stationary and moving sound sources is demonstrated.Importantly,this method effectively separates sound sources,even when there are significant variations in their amplitudes at different rotation speeds.展开更多
This study investigates the mercury(Hg)isotope geochemistry of pyrite from the Aketashi volcanic hosted massive sulfide(VMS)deposit in the West Kunlun Orogenic Belt,China,aiming to elucidate the sources of ore-forming...This study investigates the mercury(Hg)isotope geochemistry of pyrite from the Aketashi volcanic hosted massive sulfide(VMS)deposit in the West Kunlun Orogenic Belt,China,aiming to elucidate the sources of ore-forming fluids and the behavior of Hg isotopes during mineralization.The Aketashi deposit is located within a Late Paleozoic back-arc basin,which is characterized by extensive Carboniferous magmatism and hydrothermal activity.Analysis of 19 pyrite ore samples revealed Hg isotope composition with δ^(202)Hg values ranging from−2.48‰to 0.87‰ and Δ^(199)Hg values from−0.02‰ to 0.40‰.The negative δ^(202)Hg values are indicative of isotopic fractionation resulting from hydrothermal processes,whereas the positive Δ^(199)Hg values imply a mixed fluid source comprising both magmatic and seawater-derived components.This study highlights the unique advantage of Hg isotopes in tracing multi-source fluid interactions(e.g.,magmatic vs.seawater-derived)in VMS systems,providing a novel methodology for global metallogenic studies.Our findings not only resolve the longstanding debate on fluid origins at Aketashi but also establish a framework for applying Hg isotopes to other VMS deposits worldwide.展开更多
基金supported by the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(No.2019QZKK0208)the National Natural Science Foundation of China(Nos.42171148 and 42330512)the Key R&D Project from the Science and Technology Department of Tibet(No.XZ202501ZY0030).
文摘Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in alpine mountains with climate change.Hence,94 samples of river water were collected from 2018 to 2020 in the headwaters of the Shule River Basin to assess the nutrients spatiotemporal distribution and combined ap-proach of water quality index to assess water quality and potential sources.The findings depict that high nutrient concentrations were found to coincide with snowmelt and glacial meltwater and rainfall recharge periods,while total flux peaked from June to September due to increased runoff.Notably,total nitrogen(TN)concentrations were significantly higher near the town,primarily attributed to the replenishment of nitrate(NO_(3)^(‒)-N)from live-stock manure.The high total P(TP)was near the glacier,which was attributed to the transportation of glacial sediments into the river,and pH was another critical factor.N was the primary nutrient limiting factor for the growth of phytoplankton in river water.Although the migration and transport of nutrients have altered with climate change,river water quality is good in alpine mountains based on an overall evaluation.These findings contribute to enriching nutrient datasets and highlight the importance of water resource management and water quality assessment in sensitive and fragile alpine mountains.
文摘39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.
基金supported by the National Natural Science Foundation of China (Nos. 82192913 and 82304851)the Scientific and Technological Innovation Project of China Academy of Chinese Medical Sciences (Nos. CI2023E002, CI2021B016, and CI2021A04801)the Fundamental Research Funds for the Central Public Welfare Research Institutes (Nos. ZZ13-YQ-055 and ZXKT22044)。
文摘Curcuma is a traditional Chinese medicine that has been utilized for centuries in the treatment of various diseases. Terpenoids, particularly monoterpenes and sesquiterpenes, constitute the primary bioactive components of the essential oil derived from Curcuma species.Among these, curdione—one of the key active constituents—has been identified in 25 Curcuma species, with the highest concentration reported in the rhizome essential oil of Curcuma trichosantha Gagnep. Curdione can also be synthesized through chemical methods,and its regio-and stereo-selectivity can be further optimized via chemo-bio transformations.This compound demonstrates significant therapeutic potential, including anticancer, antithrombotic, anti-inflammatory, anti-viral, anti-fungal, anti-diabetic, and multi-organ protective properties. Despite these promising biological activities, its clinical application is hindered by poor water solubility and potential toxicity. This review summarizes current knowledge on the natural sources, chemical synthesis, chemo-bio transformations, metabolism, pharmacokinetics, pharmacological effects, potential toxicities, and molecular mechanisms of curdione. Furthermore, perspectives on future drug development are discussed with the aim of promoting the clinical translation of this promising natural compound.
基金supported by the National Natural Science Foundation of China(42230513)the Research Project on Ecological Protection and High-Quality Development in the Yellow River Basin,China(2022-YRUC-01-0101)the Natural Science Basic Research Plan in Shaanxi Province,China(2022JC-LHJJ-11).
文摘Per-and poly-fluoroalkyl substances(PFAS)have garnered significant global attention due to their widespread presence and potential environmental and health risks.However,research on the occurrence and environmental behavior of PFAS across different media remains limited.We analyzed the occurrence,distribution,sources,and ecological risks of 32 PFAS across multiple media in the Weihe River,China.The concentrations of PFAS ranged from 5.89 to 472.84 ng/L in the pore water and from 9.93 to 459.50 ng/L in surface water,exhibiting significant spatial variability(P<0.05).In contrast,the PFAS concentration range in the sediments was 0.74-1.81 ng/g dry weight,with no pronounced spatial variation in solid-phase PFAS(P>0.05).Vertically,concentrations in 33.00%of pore water samples exceeded those in surface water,showing a heterogeneous vertical distribution with enrichment at depths of 40-60 cm.The physical-chemical characteristics of PFAS and the hydrological and sedimentary processes at the basin scale were responsible for PFAS partitioning between the aquatic environment and sediments.Four major sources were identified through integrated source apportionment:industrial and domestic wastewater(58.25%),aqueous film-forming foam(18.07%),combined input from household pollution and metal plating(8.70%),and stormwater runoff and landfill leachate(14.98%).The ecological risk assessment revealed negligible risks from short-chain PFAS in surface water and pore water,whereas long-chain PFAS posed low to moderate ecological risks.Furthermore,the discharge of PFAS from the Weihe River to the Yellow River was estimated up to 708.20 kg/a.This study provides critical data informing strategies for mitigating PFAS pollution in rivers across typical arid and semi-arid areas of China.
基金supported by the National Key Scientific Research Project(Grant No.2023YFC3209303)jointly funded by the National Natural Sciences Foundation of China(Grant Nos.42577406 and 42077076)the National Natural Science Foundation of China and Yellow River Water Science Research Joint Fund(Grant No.U2243211).
文摘Accurate identification of sediment sources and erosion hotspots is crucial for implementing targeted soil and water conservation measures.This study analyzed the temporal dynamics of sediment source contributions during seven rainfall events(A_(1)–A_(7))that generated both runoff and suspended sediment at the outlet of the Hantaichuan watershed,located in the wind–water erosion crisscross region of the northern Loess Plateau,China.A total of 82 suspended sediment samples were collected at the Xiangshawan hydrological station during 2021 and 2022.Additionally,145 soil samples were collected from three primary potential sources:sandy soil,loess soil,and Pisha sandstone.Mid-infrared(MIR)spectroscopy and geochemical fingerprinting were used to trace and quantify sediment sources.For MIRbased source apportionment,twelve predictive models were developed using partial least squares regression(PLSR)and support vector machine regression(SVMR)in combination with six spectral preprocessing techniques.The PLSR model with first-derivative Savitzky–Golay(SGD1)preprocessing achieved the best performance.Source apportionment results indicated that Pisha sandstone was the dominant sediment source(44.00%–72.23%),followed by sandy soil(14.23%–37.00%)and loess soil(10.01%–24.00%).Among the analyzed rainfall events,the contribution of Pisha sandstone was lowest in the small flow magnitude event A3(57.53%)and highest in the large flow magnitude event A6(63.48%),suggesting that sediment source composition was strongly controlled by rainfall event magnitude.Both MIR spectroscopic and geochemical fingerprinting methods showed high consistency,confirming MIR spectroscopy as a reliable,non-destructive,and cost-effective alternative for rapid sediment source apportionment and for supporting erosion control prioritization in highly erodible catchments.
基金supported by the National Natural Science Foundation of China(Nos.62171469,62071029)。
文摘The estimation of the Number of Sources(NoS)is a significant challenge in signal processing,particularly due to the impact of colored noise on the performance of NoS estimation.This paper proposes a Multidimensional Feature Network(MFNet)which is designed for NoS estimation by extracting features of the sampled received signals and Sampled Covariance Matrix(SCM).The MFNet treats the raw signal and the SCM as two different types of data,and is able to achieve NoS estimation under colored noise and imperfect array.MFNet employs the Gated Recurrent Unit(GRU)to capture sequential information from the original signal data and to construct the Pseudo Covariance Matrix(PCM).Subsequently,various dimensional features,including eigenvalues and the Gerschgorin disk radius,are extracted from both the PCM and SCM,which are then jointly input into the subsequent network.An overall accuracy of 82%can be achieved after network training.The ablation experimental results demonstrate the effectiveness of multiple inputs.And simulation results demonstrate that the proposed MFNet achieves higher estimation accuracy compared to existing algorithms and exhibits greater robustness against colored noise.
基金supported by the National Natural Science Foundation of China(52304098,52106092,42376215,52474105)Shenzhen Science and Technology Program(JCYJ20220818095605012,JCYJ20220530113011027)+5 种基金Guangdong Basic and Applied Basic Research Foundation(2022A1515110338,2023A1515012316,2023A1515012761,2025A1515010748)Research Team Cultivation Program of Shenzhen University(2023QNT004)Shenzhen Key Laboratory of Natural Gas Hydrates(ZDSYS20200421111201738)the General Research Fund(No.12616222)Early Career Scheme(No.22611624)of Hong Kong Research Grants CouncilMajor Science and Technology Infrastructure Project of Material Genome Big–science Facilities Platform supported by the Municipal Development and Reform Commission of Shenzhen。
文摘Carbon Capture,Utilization,and Storage(CCUS)technology has gained widespread attention in recent years as a critical strategy to combat global climate change,particularly in achieving carbon neutrality goals.The Guangdong-Hong Kong-Macao Greater Bay Area(GBA),as one of China's most economically active regions,serves as a key engine for economic growth while also facing considerable carbon emission challenges.This study analyzes the industrial emission volume and geographical distribution of key emitting enterprises in the GBA,summarizes their technological processes and main carbonemitting equipment,and provides scientific support for precise mitigation policies and low-carbon development.Based on data from 176 key emitting enterprises,the study reveals that Guangzhou and Dongguan host the largest number of such enterprises.Carbon emissions are primarily concentrated in the power sector,dominated by coal-and gas-fired power units,characterized by significant spatial dispersion and uneven distribution.Beyond the power sector,the paper industry has a high number of enterprises but lower emissions.Key facilities such as boilers,cogeneration systems,and production lines are predominantly located near tributaries rivers in Dongguan and Jiangmen.The building materials sector,primarily cement production,ranks as the second-largest emitter,with hightemperature kilns and grinding equipment,particularly rotary kilns and glass furnaces,as the main sources.The petrochemical and chemical sectors have fewer enterprises and lower emissions in the GBA,mainly located in suburban industrial clusters.Carbon emissions in the GBA exhibit distinct industry concentration and geographical distribution disparities.This study provides crucial data and theoretical insights for the development of targeted emission reduction strategies,optimization of source-sink matching,and the advancement of CCUS technologies in the region,particularly from the GBA to the northern South China Sea.
基金support from the Natural Science Foundation of Jiangsu Province(Grant No.BK20240036)the National Natural Science Foundation of China(Grant Nos.U24A20515,22276099,and 22361162668)Guangxi Key Research and Development Program,China(Grant No.Guike AB24010074)。
文摘We conducted a field campaign to investigate the chemical composition,sources,and light absorption of submicron aerosols(PM_(1))from early 2022 in Nanjing,China.The average concentration of PM_(1) was 31μg m^(−3),organics(33%)constituted the largest fraction,followed by nitrate(30%),sulfate(18%),ammonium(15%),chloride(3%),and rBC(2%).Four organic aerosol(OA)subcomponents were identified,including two primary OA(POA)and two secondary OA(SOA).The less-oxidized SOA(LO-OOA)contributes the most to the total OA mass(59%).LO-OOA is tightly correlated with the tracer ion C_(2)H_(4)O_(2)^(+)from levoglucosan,and another aged biomass-burning derived species,K_(3)SO_(4)^(+),suggesting it was likely influenced by aged biomass-burning OA.Our study also revealed that fireworks during the Spring Festival have a detrimental impact on air quality,contributing to secondary formation and accumulation under static winter meteorological conditions,prolonging the pollution duration.Also,LO-OOA was found to have the strongest light-absorbing ability.Our results highlight that the light absorption of LO-OOA can mainly be attributed to the C_(x)H_(y)N^(+) family,increased with the double-bond equivalent value.The more-oxidized SOA(MO-OOA)exhibited a negligible light absorption and was strongly correlated with daytime photochemical processes,implying a light-bleaching effect.This study enhances our understanding of the regional contribution of biomass combustion and fireworks to PM_(1) pollution in Nanjing,a typical megacity in the Yangtze River Delta region,during winter,aiding in the development of strategies for long-term air quality improvement in the region.
基金supported by the National Natural Science Foundation of China(Nos.41905108 and 42130704).
文摘Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previous research,providing a long-term perspective on carbonyl compound variations and their environmental implica-tions.Atmospheric observations were conducted at Beijing(BJ)and Xianghe(XH)during the summer and winter months of 2018,2019,and 2023 to study the sources and impacts of carbonyl compounds in typical urban areas and peri‑urban areas.Notably,concentrations in the summer of 2023 increased compared to 2018 and 2019.The predominant carbonyl compounds—formaldehyde,acetaldehyde,and acetone—accounted for over 60%of the total.The mean values of OFP in BJ ranged from 18.55 to 58.61μg/m3,lower than those in XH(29.82 to 65.48μg/m3),with formaldehyde and acetaldehyde contributing over 80%of the total.SOAP exhibited a similar pattern,with values in XH(69.21 to 508.55μg/m3)significantly exceeding those in BJ(34.47 to 159.78μg/m3).The PMF model highlighted vehicle exhaust,secondary pollution,and biomass combustion as major sources of carbonyl compounds,emphasizing differences in source contributions between the two regions.This study’s com-parative analysis over different years and locations provides new insights into the dynamic changes in carbonyl compounds and their environmental importance.These results not only reinforce the importance of carbonyl compounds regulation but also offer a valuable reference for evaluating and refining emission control strategies during this period.
基金support from the National Natural Science Foundation of China(Grant Nos.42177142 and 52378477)the Key Research and Development Program of Shaanxi(Grant No.2023-YBSF-486).
文摘The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment.In this study,terrestrial laser scanning(TLS)and unmanned aerial vehicle(UAV)technologies were integrated to enhance the evaluation methodology for rock mass hazard sources,focusing on the Sichuan Yanjiang Expressway project in China.The findings demonstrate that TLS-UAV technology enhanced both spatial coverage and data density in slope modeling.Through integrated algorithmic analysis,rock discontinuities within heterogeneous datasets were systematically identified,enabling quantitative extraction and statistical analysis of key geometric parameters,including orientation,trace length,spacing,and roughness.Furthermore,quantitative models were developed for cohesion,friction angle and the morphology parameter M of in situ discontinuities,respectively,facilitating efficient mechanical parameter acquisition.A novel rock mass hazard index(RHI)was developed incorporating discontinuity geometric rating(DGR),discontinuity mechanical rating(DMR),and slope mass rating(SMR).Field validation confirmed the methodology's effectiveness in evaluating risk levels and spatial heterogeneity of rock mass hazard sources,revealing the contribution of different discontinuity sets to the rock mass hazard and identifying the primary discontinuity sets controlling instability mechanisms.This study is of great significance for evaluating discontinuity-controlled rock mass hazard sources and preventing rockfall disasters.
基金supported by the Science and Technology Project of China Southern Power Grid Co.,Ltd.(ZBKTM20232244)the Project of National Natural of Science Foundation of China(52477103).
文摘The real-time and accurate calculation of electricity indirect carbon emissions is not only the critical component for quantifying the carbon emission levels of the power system but also an effective mean to guide electricity users in carbon reduction and promote power industry low-carbon transformation.Fundamentally,calculating indirect carbon emissions involves allocating direct carbon emission data from the power source side,indicating that accurate indirect emission results rely on the precise measurement of power source emissions.However,existing research on indirect carbon emissions in large-scale power systems rarely accounts for variations in carbon emission characteristics under different operating conditions of power sources,such as rated/non-rated operating conditions and ramping up/down conditions,making it difficult to reflect source-side and load-side carbon emission information variation during providing ancillary services.Quadratic and exponential functions are proposed to characterize the energy consumption profiles of coal-fired and gas-fired power generation,respectively,to construct a refined carbon emission model for power sources.By leveraging the theory of power system carbon flow,we analyze how variable operating conditions of power sources impact indirect carbon emissions.Case studies demonstrate that changes in power source emissions under variable conditions have a significant effect on the indirect carbon emissions of power grids.
文摘Collagen is a class of mammalian extracellular matrix of the main structural proteins,widely present in the skin,bone,muscle and other tissues and it plays a role in supporting,repairing,and protecting tissue cells.Natural source extraction and artificial synthesis provide a rich source of collagen.As a macromolecular material,collagen has good application potential in cosmetics,pharmaceutical,medical and food industries.Collagen has generated a great deal of interest in the cosmetic industry due to its abundance,strength,and direct correlation with skin aging.Collagen is widely used in cosmetics due to its unique structure,good biocompatibility and low antigenicity,as well as rich biological functions.To enhance the youthfulness and health of the user,the cosmetic industry adds collagen to products such as eye creams,face creams,and nutritional supplements,and uses it in medical aesthetic techniques such as tissue fillers,skin replacement,and soft skin enhancement.This paper mainly reviews the sources and types of collagen used in cosmetics industry,then introduces the effects of collagen in cosmetics and prospects the development prospects of collagen in dermatologic and cosmetic fields.
基金supported by the National Natural Science Foundation of China(No.42107394)the Major Project of the National Natural Science Foundation of China(No.71991483)the Central Public-interest Scientific Institution Basal Research Fund(No.BSRF202309).
文摘Heavy metal(loid)(HM)pollution in agricultural soils has become an environmental concern in antimony(Sb)mining areas.However,priority pollution sources identification and deep understanding of environmental risks of HMs face great challenges due to multiple and complex pollution sources coexist.Herein,an integrated approach was conducted to distinguish pollution sources and assess human health risk(HHR)and ecological risk(ER)in a typical Sb mining watershed in Southern China.This approach combines absolute principal component score-multiple linear regression(APCS-MLR)and positivematrix factorization(PMF)models with ER and HHR assessments.Four pollution sources were distinguished for both models,and APCS-MLR model was more accurate and plausible.Predominant HM concentration source was natural source(39.1%),followed by industrial and agricultural activities(23.0%),unknown sources(21.5%)and Sb mining and smelting activities(16.4%).Although natural source contributed the most to HM concentrations,it did not pose a significant ER.Industrial and agricultural activities predominantly contributed to ER,and attention should be paid to Cd and Sb.Sb mining and smelting activities were primary anthropogenic sources of HHR,particularly Sb and As contaminations.Considering ER and HHR assessments,Sb mining and smelting,and industrial and agricultural activities are critical sources,causing serious ecological and health threats.This study showed the advantages of multiple receptor model application in obtaining reliable source identification and providing better source-oriented risk assessments.HM pollution management,such as regulating mining and smelting and implementing soil remediation in polluted agricultural soils,is strongly recommended for protecting ecosystems and humans.
基金supported by the National Natural Science Foundation of China(42161007)the Innovation Foundation of Higher Education Institutions of Gansu Province(2021B-081)the Foundation for Distinguished Young Scholars of Gansu Province(20JR10RA112).
文摘Precipitation isotopes(δ^(18)O and δ^(2)H)are closely related to meteorological conditions for precipitation generation and the initial state of water vapor source areas,and are essential to the study of the regional hydrological cycle.The deuterium excess(d-excess)indicates deviation in isotope fractionation during evaporation and can trace water vapor sources.This study analyzed 443 precipitation samples collected from the Gannan Plateau,China in 2022 to assess precipitation isotope variations and their driving factors.Water vapor sources were evaluated using the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT),Concentration Weighted Trajectory(CWT),and Potential Source Contribution Factor(PSCF)models.Results showed that precipitation isotope values showed significant spatial and temporal variations on the Gannan Plateau.Temporally,precipitation isotope values peaked in June(when evaporation dominated)and minimized in March(depletion effect of air masses in the westerly wind belt).Spatially,the isotope values showed a distribution pattern of"high in the east and low in the west",which was mainly regulated by the differences in altitude and local meteorological conditions.Compared with the global meteoric water line(GMWL)with equation of δ^(2)H=8.00δ^(18)O+10.00,the slope and intercept of local meteoric water line(LMWL)for precipitation on the Gannan Plateau were smaller(7.49 and 7.63,respectively),reflecting the existence of a stronger secondary evaporation effect under the clouds in the region.The sources of water vapor on the Gannan Plateau showed significant seasonality and spatial heterogeneity.Specifically,the westerly belt and monsoon were the main water vapor transport paths at each sampling point,with Central Asian continental water vapor dominating in spring(53.49%),Indian Ocean water vapor dominating in summer(52.53%),Atlantic Ocean water vapor dominating in autumn(46.74%),and Atlantic Ocean and Mediterranean Sea water vapor dominating in winter(42.30%and 33.68%,respectively).Changes in the intensity of convective activity and Outgoing Longwave Radiation(OLR)affected the enrichment of isotopic values,which exhibited the same change trends as δ^(18)O.During the precipitation process,the δ^(18)O value first decreased and then increased.During the initial and final stages of precipitation process,precipitation was mainly influenced by continental air masses,while during the middle stage,it was controlled by marine air masses.The systematic research on precipitation isotopes and water vapor sources is important for climate change research and extreme precipitation prediction on the Gannan Plateau and other similar areas.
基金supported by the National Natural Science Foundation of China (Grant Nos.10371070, 10671121)the Shanghai Leading Academic Discipline Project (Grant No.J50101)the President Foundation of East China Institute of Technology (Grant No.DHXK0810)
文摘Infinitely many conservation laws for some （1＋1）-dimension soliton hierarchy with self-consistent sources are constructed from their corresponding Lax pairs directly. Three examples are given. Besides, infinitely many conservation laws for Kadomtsev-Petviashvili （KP） hierarchy with self-consistent sources are obtained from the pseudo-differential operator and the Lax pair.
基金supported by the National Natural Science Foundation of China(No.42030706).
文摘Excessive concentrations of toxic metals are a global threat to aquatic systems.Taking a typical tributary(Zijiang River,ZR)of the midstream of the Yangtze River as the research area,the concentration distribution and chemical fractions occurrence characteristics of five toxic metals(Cd,Cr,Cu,Pb,and Zn)were analyzed,their potential sources were explored,and their contamination and ecological risk was assessed.In the surface waters and sediments,there were high concentrations of Zn,a low concentration of Cd,and small spatial differences in concentration among the upstream,midstream,and downstream.In terms of speciation,Cd mainly existed in the acid-soluble fraction,Pb mainly existed in the reducible fraction,and Cr,Cu,and Zn mainly existed in the residue fraction.The potential sources in surface waters and sediments were determined to be industrial emissions and agricultural non-point sources through the absolute principal component scores–multiple linear regression model(APCS–MLR).Based on the assessment results of total concentration and speciation,Cd was the typical contamination element in ZR sediments.In addition,the secondary phase enrichment factor(SPEF)based on speciation underestimates the degree of Pb contamination,and the ecological risk of Zn assessed by the ratio of secondary phase and primary phase(RSP)and the risk assessment code(RAC)was higher than that of Cr,which was inconsistent with the results based on total concentrations.SOM and Al/Fe/Mn cycles in sediments influenced the geochemical behavior of toxic metals.
基金supported by National Natural Science Foundation of China(Nos.52170086,52300056)Natural Science Foundation of Shandong Province(Nos.ZR2021ME013,ZR202211280298)。
文摘In this study,different types of small molecular carbon sources such as melamine,dicyandiamine,pyrocatechol,and o-phenylenediamine were used to regulate the surface structures of iron/nitrogen/carbonbased composites(Fe-N/C),which were used to activate peroxymonosulfate(PMS).The relationship between different small molecular carbon sources and the electronic structure was investigated.The characteristics of metal-carrier interaction in the Fe-N/C were clarified.As a result,there were significant differences in the degradation efficiency of catalysts prepared with different small molecular carbon sources,which was related to the types of active sites.Density functional theory(DFT)and experiments results showed that the catalyst rich in C-O-C and FeN_(x)exhibited better catalytic activity,which may be attributed to the higher adsorption energy for PMS.The main active species for catalytic degradation of ofloxacin were identified as sulfate radical(SO_(4)^(·-))and hydroxyl radical(^(·)OH)by electron paramagnetic resonance(EPR)spectra.The introduction of different small molecular carbon sources can significantly affect the distribution and electronic structure of active sites on the catalyst surface,thereby regulating the generation and migration of radicals.
基金funded by the Science and Technology Project of State Grid Shanxi Electric Power Company(5205E0230001).
文摘With the development of integrated power and gas distribution systems(IPGS)incorporating renewable energy sources(RESs),coordinating the restoration processes of the power distribution system(PS)and the gas distribution system(GS)by utilizing the benefits of RESs enhances service restoration.In this context,this paper proposes a coordinated service restoration framework that considers the uncertainty in RESs and the bi-directional restoration interactions between the PS and GS.Additionally,a coordinated service restoration model is developed considering the two systems’interdependency and the GS’s dynamic characteristics.The objective is to maximize the system resilience index while adhering to operational,dynamic,restoration logic,and interdependency constraints.A method for managing uncertainties in RES output is employed,and convexification techniques are applied to address the nonlinear constraints arising from the physical laws of the IPGS,thereby reducing solution complexity.As a result,the service restoration optimization problem of the IPGS can be formulated as a computationally tractable mixed-integer second-order cone programming problem.The effectiveness and superiority of the proposed framework are demonstrated through numerical simulations conducted on the interdependent IEEE 13-bus PS and 9-node GS.The comparative results show that the proposed framework improves the system resilience index by at least 65.07%compared to traditional methods.
基金supported by the National Key Research and Development Plan of China(No.2023YFB3406500)the National Natural Science Foundation of China(No.52475132)+2 种基金the Aeronautical Science Foundation of China(No.20200015053001)the Shaanxi Key Research Program Project,China(No.2024GX-ZDCYL-01–16)the Xi’an Key Industrial Chain Technology Research Project,China(No.2023JH-RGZNGG-0033)。
文摘Traditional beamforming techniques may not accurately locate sources in scenarios with both stationary and rotating sound sources.The existence of rotating sound sources can cause blurring in the stationary beamforming map.Current algorithms for separating different moving sound sources have limited effectiveness,leading to significant residual noise,especially when the rotating source is strong enough to mask stationary sources completely.To overcome these challenges,a novel solution utilizing a virtual rotating array in the modal domain combined with robust principal component analysis is proposed to separate sound sources with different rotational speeds.This approach,named Robust Principal Component Analysis in the Modal domain(RPCA-M),investigates the performance of convex nuclear norm and non-convex Schatten-p norm to distinguish stationary and rotating sources.By comparing the errors in Cross-Spectral Matrix(CSM)recovery and acoustic imaging across different algorithms,the effectiveness of RPCA-M in separating stationary and moving sound sources is demonstrated.Importantly,this method effectively separates sound sources,even when there are significant variations in their amplitudes at different rotation speeds.
基金Innovative Research Group Project of the National Natural Science Foundation of China(NSFC Nos.U1603245,U1703242,U1812402).
文摘This study investigates the mercury(Hg)isotope geochemistry of pyrite from the Aketashi volcanic hosted massive sulfide(VMS)deposit in the West Kunlun Orogenic Belt,China,aiming to elucidate the sources of ore-forming fluids and the behavior of Hg isotopes during mineralization.The Aketashi deposit is located within a Late Paleozoic back-arc basin,which is characterized by extensive Carboniferous magmatism and hydrothermal activity.Analysis of 19 pyrite ore samples revealed Hg isotope composition with δ^(202)Hg values ranging from−2.48‰to 0.87‰ and Δ^(199)Hg values from−0.02‰ to 0.40‰.The negative δ^(202)Hg values are indicative of isotopic fractionation resulting from hydrothermal processes,whereas the positive Δ^(199)Hg values imply a mixed fluid source comprising both magmatic and seawater-derived components.This study highlights the unique advantage of Hg isotopes in tracing multi-source fluid interactions(e.g.,magmatic vs.seawater-derived)in VMS systems,providing a novel methodology for global metallogenic studies.Our findings not only resolve the longstanding debate on fluid origins at Aketashi but also establish a framework for applying Hg isotopes to other VMS deposits worldwide.
