39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.Ar...39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.展开更多
In wave-equation migration and demigration,the cross-correlation imaging/forwarding step implicitly injects an additional copy of the source wavelet,so that the amplitude spectrum of the wavelet is applied redundantly...In wave-equation migration and demigration,the cross-correlation imaging/forwarding step implicitly injects an additional copy of the source wavelet,so that the amplitude spectrum of the wavelet is applied redundantly(effectively imposing a wavelet-spectrum weighting,often akin to an amplitude-squared bias).This redundancy degrades structural fidelity and amplitude balance yet is frequently overlooked.We(i)formalize the mechanism by which cross-correlation duplicates the source-wavelet amplitude effect in both migration and demigration,and(ii)introduce a source-equalized operator that removes the redundancy by deconvolving(or dividing by)the wavelet amplitude spectrum in the imaging condition and its demigration counterpart,while leaving phase/kinematics intact.Using a band-limited Ricker wavelet on a two-layer model and on Marmousi,we show that,if unmanaged,the redundant wavelet spectrum broadens main lobes,introduces ringing,and suppresses vertical resolution in migrated images,and inflates spectrum mismatches between demigrated and observed data even when peak times agree.With our correction,images recover observed-data-consistent bandwidth and sharpened interfaces,and demigrated data also exhibit improved spectrum conformity and reduced amplitude misfit.The results clarify when source amplitudes matter,why cross-correlation makes them redundantly matter,and how a lightweight spectral correction restores physically meaningful amplitude behavior in wave-equation migration/demigration.展开更多
This study investigated the heterogeneous responses of organic matter(OM)in highly-to over-mature source rocks during thermal maturation.An integrated analysis was conducted on the Raman spectroscopic and geochemical ...This study investigated the heterogeneous responses of organic matter(OM)in highly-to over-mature source rocks during thermal maturation.An integrated analysis was conducted on the Raman spectroscopic and geochemical signatures of shales from the Lower Silurian Longmaxi Formation and the Lower Cambrian Qiongzhusi Formation,as well as anthracites from the Lower Permian Shanxi–Formation and the Upper Carboniferous Taiyuan Formation(collectively referred to as the Shanxi Taiyuan Formations).Additionally,burial and thermal evolution modeling was employed to support the analysis.A systematic assessment of Raman spectral parameters(e.g.,the positions and intensity ratio of the D and G bands)revealed robust correlations between the thermal history patterns of source rocks and molecular structural evolution parameters.The subsequent mechanistic quantification demonstrated that the maturation state of the source rocks was subjected to the hierarchical control of three principal factors:Peak heating temperature,the duration of sustained thermal intensity,and effective maturation duration.In addition,comparative analyses demonstrated that the anthracites attained higher structural ordering under sustained thermal conditions.This contrasts with the disordered carbon matrices observed in the intermittently heated shales.Raman spectroscopy further revealed broader variations in the D and G band intensities of the Longmaxi Formation compared to the Qiongzhusi Formation.This difference is associated with their different thermal histories.The thermal burial histories confirm that shales in the Longmaxi Formation underwent thermal exposure at lower peak temperatures over a shorter duration compared to those in the Qiongzhusi Formation.Finally,this study established a maturity calibration model for over-mature source rocks through a systematic correlation between Raman peak height ratios(R_(D/G))and vitrinite reflectance(R_(o)).展开更多
This study examined a case of ventilator-associated pneumonia caused by Ralstonia mannitolilytica in a neonatal department in order to determine the source of infection and mode of transmission.Symptoms of infection b...This study examined a case of ventilator-associated pneumonia caused by Ralstonia mannitolilytica in a neonatal department in order to determine the source of infection and mode of transmission.Symptoms of infection began to appear on day 16 of admission,and both sputum and catheter tip cultures revealed R.mannitolilytica.The infection control department of the hospital later sampled and identified R.mannitolilytica in the ventilator tube that was used by the patient with the exact gene sequence as the infecting strain.These findings indicate that ventilator tubing is a significant contamination source of this pathogen,and hospitals need to enhance their disinfection methods of ventilator-related devices.展开更多
The Mianhuakeng uranium deposit,characterized by uranium-rich granite,serves as a key site for research into crustal radioactive heating.Based on 45 rock samples,this study reviews that the host granite in the Mianhua...The Mianhuakeng uranium deposit,characterized by uranium-rich granite,serves as a key site for research into crustal radioactive heating.Based on 45 rock samples,this study reviews that the host granite in the Mianhuakeng uranium deposit has a high radioactive heat production rate(avg.5.50μW/m³)and a low Th/U ratio(avg.2.62).Uranium-rich granite and its alteration zone within the upper crust(0-5 km depth)contribute about 45%of the total radioactive heat production,wich is crucial for controlling geothermal resource distribution.For uranium-thermal at tectonic plate margins,a symbiotic geological model was proposed:Firstly,subduction of the Pacific Plate caused upwelling of the asthenosphere,generating a high heat-flow background.Secondly,heat transfer is enhanced by major faults such as the Youdong and Mianhuakeng faults.Subsequently,uranium was mobilized,transported,and enriched within the granite through deep siliceous hydrothermal activity and associated alteration.Ultimately,the uranium enrichment in granite leads to increased radioactive heat production,resulting in local thermal anomalies.This model provides a theoretical support for exploring and developing uranium-thermal symbiotic resources in South China.展开更多
Intervention strategies to control non-point source nitrogen(N)and phosphorus(P)pollution in agriculture are expensive and there is a trade-off between engineering cost and treatment effectiveness.Implementing strateg...Intervention strategies to control non-point source nitrogen(N)and phosphorus(P)pollution in agriculture are expensive and there is a trade-off between engineering cost and treatment effectiveness.Implementing strategies often result in unsatisfactory outcomes and massive engineering costs when managing diffusive pollution in agricultural catchments.To address this issue,this paper proposes a robust,handy,catchment N&P decision support system(CNPDSS),an Android-based smartphone system integrated with a web-based geographic information system(GIS).The CNPDSS aims to provide artificial intelligence-driven decisions that minimize N&P loadings and engineering costs for mitigating pollution in agricultural catchments.It consists of four components:a general user interface(GUI),GIS,N&P pollution modeling(NPPM),and a DSS.The CNPDSS simplifies the GUI and integrates GIS modules to create a user-friendly interface,enabling non-professional users to operate the system easily through intuitive actions.The NPPM uses straightforward empirical models to predict N&P loadings,enhancing efficiency by avoiding excessive parameters.Taking into account the N&P movement pathway in the catchment,the DSS incorporates three control measures:source reduction in farmland(before migration stage),process retention by ecological ditch(midway transport stage),and down-end purification by constructed wetland(waterbody discharge stage),to formulate a comprehensive ternary controlling strategy.To optimize the cost-effectiveness of any proposed N&P control strategies for sub-catchments,a differential evolution algorithm(DEA)is employed in CNPDSS to carry out a dual-objective decision-making optimization computation.In this study,the CNPDSS is applied to a case study in an agricultural catchment in Central China to develop the most cost-effective ternary N&P control strategies that ensure the catchment water quality within Criterion Ⅲ of the Chinese Surface Water Quality Standard GB3838-2002 is met(total N concentration≤1.0 mg L^(-1)and total P concentration≤0.2 mg L^(-1)).Our results demonstrate that the CNPDSS is feasible and also possesses an adaptive design and flexible architecture to enable its generalization and extension to support strong hands-on applications in other catchments.展开更多
We present the preparation and measurement of the radioactive isotope^(37)Ar,which was produced using thermal neutrons from a reactor,as a calibration source for liquid xenon time projection chambers.^(37)Ar is a low-...We present the preparation and measurement of the radioactive isotope^(37)Ar,which was produced using thermal neutrons from a reactor,as a calibration source for liquid xenon time projection chambers.^(37)Ar is a low-energy calibration source with a half-life of 35.01 days,making it suitable for calibration in the low-energy region of liquid xenon dark-matter experiments.Radioactive isotope^(37)Ar was produced by irradiating ^(36)Ar with thermal neutrons.It was subsequently measured in a gaseous xenon time projection chamber(GXe TPC)to validate its radioactivity.Our results demonstrate that^(37)Ar is an effective and viable calibration source that offers precise calibration capabilities in the low-energy domain of xenon-based detectors.展开更多
We conducted a field campaign to investigate the chemical composition,sources,and light absorption of submicron aerosols(PM_(1))from early 2022 in Nanjing,China.The average concentration of PM_(1) was 31μg m^(−3),org...We conducted a field campaign to investigate the chemical composition,sources,and light absorption of submicron aerosols(PM_(1))from early 2022 in Nanjing,China.The average concentration of PM_(1) was 31μg m^(−3),organics(33%)constituted the largest fraction,followed by nitrate(30%),sulfate(18%),ammonium(15%),chloride(3%),and rBC(2%).Four organic aerosol(OA)subcomponents were identified,including two primary OA(POA)and two secondary OA(SOA).The less-oxidized SOA(LO-OOA)contributes the most to the total OA mass(59%).LO-OOA is tightly correlated with the tracer ion C_(2)H_(4)O_(2)^(+)from levoglucosan,and another aged biomass-burning derived species,K_(3)SO_(4)^(+),suggesting it was likely influenced by aged biomass-burning OA.Our study also revealed that fireworks during the Spring Festival have a detrimental impact on air quality,contributing to secondary formation and accumulation under static winter meteorological conditions,prolonging the pollution duration.Also,LO-OOA was found to have the strongest light-absorbing ability.Our results highlight that the light absorption of LO-OOA can mainly be attributed to the C_(x)H_(y)N^(+) family,increased with the double-bond equivalent value.The more-oxidized SOA(MO-OOA)exhibited a negligible light absorption and was strongly correlated with daytime photochemical processes,implying a light-bleaching effect.This study enhances our understanding of the regional contribution of biomass combustion and fireworks to PM_(1) pollution in Nanjing,a typical megacity in the Yangtze River Delta region,during winter,aiding in the development of strategies for long-term air quality improvement in the region.展开更多
Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previo...Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previous research,providing a long-term perspective on carbonyl compound variations and their environmental implica-tions.Atmospheric observations were conducted at Beijing(BJ)and Xianghe(XH)during the summer and winter months of 2018,2019,and 2023 to study the sources and impacts of carbonyl compounds in typical urban areas and peri‑urban areas.Notably,concentrations in the summer of 2023 increased compared to 2018 and 2019.The predominant carbonyl compounds—formaldehyde,acetaldehyde,and acetone—accounted for over 60%of the total.The mean values of OFP in BJ ranged from 18.55 to 58.61μg/m3,lower than those in XH(29.82 to 65.48μg/m3),with formaldehyde and acetaldehyde contributing over 80%of the total.SOAP exhibited a similar pattern,with values in XH(69.21 to 508.55μg/m3)significantly exceeding those in BJ(34.47 to 159.78μg/m3).The PMF model highlighted vehicle exhaust,secondary pollution,and biomass combustion as major sources of carbonyl compounds,emphasizing differences in source contributions between the two regions.This study’s com-parative analysis over different years and locations provides new insights into the dynamic changes in carbonyl compounds and their environmental importance.These results not only reinforce the importance of carbonyl compounds regulation but also offer a valuable reference for evaluating and refining emission control strategies during this period.展开更多
The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment....The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment.In this study,terrestrial laser scanning(TLS)and unmanned aerial vehicle(UAV)technologies were integrated to enhance the evaluation methodology for rock mass hazard sources,focusing on the Sichuan Yanjiang Expressway project in China.The findings demonstrate that TLS-UAV technology enhanced both spatial coverage and data density in slope modeling.Through integrated algorithmic analysis,rock discontinuities within heterogeneous datasets were systematically identified,enabling quantitative extraction and statistical analysis of key geometric parameters,including orientation,trace length,spacing,and roughness.Furthermore,quantitative models were developed for cohesion,friction angle and the morphology parameter M of in situ discontinuities,respectively,facilitating efficient mechanical parameter acquisition.A novel rock mass hazard index(RHI)was developed incorporating discontinuity geometric rating(DGR),discontinuity mechanical rating(DMR),and slope mass rating(SMR).Field validation confirmed the methodology's effectiveness in evaluating risk levels and spatial heterogeneity of rock mass hazard sources,revealing the contribution of different discontinuity sets to the rock mass hazard and identifying the primary discontinuity sets controlling instability mechanisms.This study is of great significance for evaluating discontinuity-controlled rock mass hazard sources and preventing rockfall disasters.展开更多
The complexity of the seismicity pattern for the subduction zone along the oceanic plate triggered the outer rise events and revealed cyclic tectonic deformation conditions along the plate subduction zones.The outer r...The complexity of the seismicity pattern for the subduction zone along the oceanic plate triggered the outer rise events and revealed cyclic tectonic deformation conditions along the plate subduction zones.The outer rise earthquakes have been observed along the Sunda arc,following the estimated rupture area of the 2005 M_(W)8.6 Nias earthquakes.Here,we used kinematic waveform inversion(KIWI)to obtain the source parameters of the 14 May 2021 M_(W)6.6 event off the west coast of northern Sumatra and to define the fault plane that triggered this outer rise event.The KIWI algorithm allows two types of seismic source to be configured:the moment tensor model to describe the type of shear with six moment tensor components and the Eikonal model for the rupture of pure double-couple sources.This method was chosen for its flexibility to be applied for different sources of seismicity and also for the automated full-moment tensor solution with real-time monitoring.We used full waveform traces from 8 broadband seismic stations within 1000 km epicentral distances sourced from the Incorporated Research Institutions for Seismology(IRIS-IDA)and Geofon GFZ seismic record databases.The initial origin time and hypocenter values are obtained from the IRIS-IDA.The synthetic seismograms used in the inversion process are based on the existing regional green function database model and were accessed from the KIWI Tools Green's Function Database.The obtained scalar seismic moment value is 1.18×10^(19)N·m,equivalent to a moment magnitude M_(W)6.6.The source parameters are 140°,44°,and−99°for the strike,dip,and rake values at a centroid depth of 10.2 km,indicating that this event is a normal fault earthquake that occurred in the outer rise area.The outer rise events with normal faults typically occur at the shallow part of the plate,with nodal-plane dips predominantly in the range of 30°-60°on the weak oceanic lithosphere due to hydrothermal alteration.The stress regime around the plate subduction zone varies both temporally and spatially due to the cyclic influences of megathrust earthquakes.Tensional outer rise earthquakes tend to occur after the megathrust events.The relative timing of these events is not known due to the viscous relaxation of the down going slab and poroelastic response in the trench slope region.The occurrence of the 14 May 2021 earthquake shows the seismicity in the outer rise region in the strongly coupled Sunda arc subduction zone due to elastic bending stress within the duration of the seismic cycle.展开更多
Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in a...Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in alpine mountains with climate change.Hence,94 samples of river water were collected from 2018 to 2020 in the headwaters of the Shule River Basin to assess the nutrients spatiotemporal distribution and combined ap-proach of water quality index to assess water quality and potential sources.The findings depict that high nutrient concentrations were found to coincide with snowmelt and glacial meltwater and rainfall recharge periods,while total flux peaked from June to September due to increased runoff.Notably,total nitrogen(TN)concentrations were significantly higher near the town,primarily attributed to the replenishment of nitrate(NO_(3)^(‒)-N)from live-stock manure.The high total P(TP)was near the glacier,which was attributed to the transportation of glacial sediments into the river,and pH was another critical factor.N was the primary nutrient limiting factor for the growth of phytoplankton in river water.Although the migration and transport of nutrients have altered with climate change,river water quality is good in alpine mountains based on an overall evaluation.These findings contribute to enriching nutrient datasets and highlight the importance of water resource management and water quality assessment in sensitive and fragile alpine mountains.展开更多
In this study,a seismic hazard algorithm was developed,coupled with a multi-source model.The algorithm can calculate the seismic hazard of 2D planar sources and 3D fault sources.A point source model is used to calcula...In this study,a seismic hazard algorithm was developed,coupled with a multi-source model.The algorithm can calculate the seismic hazard of 2D planar sources and 3D fault sources.A point source model is used to calculate the 2D planar potential seismic source by discretizing the potential seismic source into grid points which represent seismic sources.In contrast,a rupture surface model is used to calculate the 3D fault source so as to account for the influence of rupture scale in large earthquakes.The corresponding computational software was developed in Java and was tested on a study area 39.2°N-40.4°N and 116.6°E-118.7°E;the Tangshan and Xiadian faults were used to construct the fault source.Compared with the hazard results obtained using a point source model to calculate a 2D planar potential seismic source,the hazard results will be higher when a rupture surface model is used to calculate a 3D fault source.Moreover,a lower exceedance probability corresponds to a greater contribution rate of the fault source to the hazard and a greater seismic hazard closer to the fault.The algorithm can be used for seismic hazard analysis and can serve as a reference for the development of next-generation methods for zoning areas based on seismic ground motion.展开更多
A new on-chip light source configuration has been proposed,which utilizes the interaction between a microwave or laser and a dielectric nanopillar array to generate a periodic electromagnetic near-field and applies pe...A new on-chip light source configuration has been proposed,which utilizes the interaction between a microwave or laser and a dielectric nanopillar array to generate a periodic electromagnetic near-field and applies periodic transverse acceleration to relativistic electrons to generate high-energy photon radiation.The dielectric nanopillar array interacting with the driving field acts as an electron undulator,in which the near-field drives electrons to oscillate.When an electron beam propagates through this nanopillar array in this light source configuration,it is subjected to a periodic transverse near-field force and will radiate X-ray or evenγ-ray high-energy photons after a relativistic frequency up-conversion.Compared with the undulator which is based on the interaction between strong lasers and nanostructures to generate a plasmonic near-field,this configuration is less prone to damage during operation.展开更多
Along with the proliferating research interest in semantic communication(Sem Com),joint source channel coding(JSCC)has dominated the attention due to the widely assumed existence in efficiently delivering information ...Along with the proliferating research interest in semantic communication(Sem Com),joint source channel coding(JSCC)has dominated the attention due to the widely assumed existence in efficiently delivering information semantics.Nevertheless,this paper challenges the conventional JSCC paradigm and advocates for adopting separate source channel coding(SSCC)to enjoy a more underlying degree of freedom for optimization.We demonstrate that SSCC,after leveraging the strengths of the Large Language Model(LLM)for source coding and Error Correction Code Transformer(ECCT)complemented for channel coding,offers superior performance over JSCC.Our proposed framework also effectively highlights the compatibility challenges between Sem Com approaches and digital communication systems,particularly concerning the resource costs associated with the transmission of high-precision floating point numbers.Through comprehensive evaluations,we establish that assisted by LLM-based compression and ECCT-enhanced error correction,SSCC remains a viable and effective solution for modern communication systems.In other words,separate source channel coding is still what we need.展开更多
The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Pa...The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Paleozoic.However,its hydrocarbon generation and evolution characteristics and resource potential have long been constrained by deeply buried strata and previous research.In this paper,based on the newly obtained ultra-deep well drilling data,the hydrocarbon generation and expulsion model ofЄ_(1)y shale was established by using data-driven Monte Carlo simulation,upon which the hydrocarbon generation,expulsion,and retention amounts were calculated by using the diagenetic method.The research indicates that theЄ_(1)y shale reaches the hydrocarbon generation and expulsion threshold at equivalent vitrinite reflectances of 0.46%and 0.72%,respectively.The cumulative hydrocarbon generation is 68.88×10^(10)t,the cumulative hydrocarbon expulsion is 35.59×10^(10)t,and the cumulative residual hydrocarbon is 33.29×10^(10)t.This paper systematically and quantitatively calculates the hydrocarbon expulsion at various key geological periods for theЄ_(1)y source rocks in the study area for the first time,more precisely confirming that the black shale of theЄ_(1)y is the most significant source rock contributing to the marine oil and gas resources in the Tarim Basin,filling the gap in hydrocarbon expulsion calculation in the study area,and providing an important basis for the formation and distribution of Paleozoic hydrocarbon reservoirs.The prospect of deep ultra-deep oil and gas exploration in the Tarim Basin is promising.Especially,the large area of dolomite reservoirs under the Cambrian salt and source rock interiors are the key breakthrough targets for the next exploration in the Tarim Basin.展开更多
Fine particulatematter(PM_(2.5))samples were collected in two neighboring cities,Beijing and Baoding,China.High-concentration events of PM_(2.5) in which the average mass concentration exceeded 75μg/m^(3) were freque...Fine particulatematter(PM_(2.5))samples were collected in two neighboring cities,Beijing and Baoding,China.High-concentration events of PM_(2.5) in which the average mass concentration exceeded 75μg/m^(3) were frequently observed during the heating season.Dispersion Normalized Positive Matrix Factorization was applied for the source apportionment of PM_(2.5) as minimize the dilution effects of meteorology and better reflect the source strengths in these two cities.Secondary nitrate had the highest contribution for Beijing(37.3%),and residential heating/biomass burning was the largest for Baoding(27.1%).Secondary nitrate,mobile,biomass burning,district heating,oil combustion,aged sea salt sources showed significant differences between the heating and non-heating seasons in Beijing for same period(2019.01.10–2019.08.22)(Mann-Whitney Rank Sum Test P<0.05).In case of Baoding,soil,residential heating/biomass burning,incinerator,coal combustion,oil combustion sources showed significant differences.The results of Pearson correlation analysis for the common sources between the two cities showed that long-range transported sources and some sources with seasonal patterns such as oil combustion and soil had high correlation coefficients.Conditional Bivariate Probability Function(CBPF)was used to identify the inflow directions for the sources,and joint-PSCF(Potential Source Contribution Function)was performed to determine the common potential source areas for sources affecting both cities.These models facilitated a more precise verification of city-specific influences on PM_(2.5) sources.The results of this study will aid in prioritizing air pollution mitigation strategies during the heating season and strengthening air quality management to reduce the impact of downwind neighboring cities.展开更多
Water-soluble organic nitrogen(WSON)affects the formation,hygroscopicity,acidity of organic aerosols,and nitrogen biogeochemical cycles.However,qualitative and quantitative characterizations of WSON remain limited due...Water-soluble organic nitrogen(WSON)affects the formation,hygroscopicity,acidity of organic aerosols,and nitrogen biogeochemical cycles.However,qualitative and quantitative characterizations of WSON remain limited due to its chemical complexity.In the study,1-year field samples of particulate matter 2.5(PM_(2.5))were collected fromJune 2022 to May 2023 to analyze the WSON concentration in PM_(2.5),and correlation analysis,positive matrix factor(PMF),and potential source contribution function(PSCF)modelswere employed to elucidate WSON source apportionment and transport pathways.The results revealed that the mean WSON concentrations reached 1.98±2.64μg/m^(3) with a mean WSON to water-soluble total nitrogen(WSTN)ratio of 21%.Further,WSON concentration exhibited a seasonal variation trend,with higher values in winter and lower in summer.Five sources were identified as contributors to WSON in PM_(2.5) within the reservoir area through a comprehensive analysis including correlation analysis,PSCF and concentration weighted trajectory(CWT),and PMF analyses.These sources were agricultural,dust,combustion,traffic,and industrial sources,of which agricultural source emerged as the primary contributor(76.69%).The atmosphere in the reservoir area were primarily influenced by the transport of northeastern air masses,local agricultural activities,industrial cities along the trajectory,and coastal regions,exerting significant influences on the concentration of WSON in the reservoir area.The findings of this study addressed the research gap concerning organic nitrogen in PM_(2.5) within the reservoir area,thereby offering a theoretical foundation and data support in controlling nitrogen pollution in the Danjiangkou Reservoir area.展开更多
Precipitation isotopes(δ^(18)O and δ^(2)H)are closely related to meteorological conditions for precipitation generation and the initial state of water vapor source areas,and are essential to the study of the regiona...Precipitation isotopes(δ^(18)O and δ^(2)H)are closely related to meteorological conditions for precipitation generation and the initial state of water vapor source areas,and are essential to the study of the regional hydrological cycle.The deuterium excess(d-excess)indicates deviation in isotope fractionation during evaporation and can trace water vapor sources.This study analyzed 443 precipitation samples collected from the Gannan Plateau,China in 2022 to assess precipitation isotope variations and their driving factors.Water vapor sources were evaluated using the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT),Concentration Weighted Trajectory(CWT),and Potential Source Contribution Factor(PSCF)models.Results showed that precipitation isotope values showed significant spatial and temporal variations on the Gannan Plateau.Temporally,precipitation isotope values peaked in June(when evaporation dominated)and minimized in March(depletion effect of air masses in the westerly wind belt).Spatially,the isotope values showed a distribution pattern of"high in the east and low in the west",which was mainly regulated by the differences in altitude and local meteorological conditions.Compared with the global meteoric water line(GMWL)with equation of δ^(2)H=8.00δ^(18)O+10.00,the slope and intercept of local meteoric water line(LMWL)for precipitation on the Gannan Plateau were smaller(7.49 and 7.63,respectively),reflecting the existence of a stronger secondary evaporation effect under the clouds in the region.The sources of water vapor on the Gannan Plateau showed significant seasonality and spatial heterogeneity.Specifically,the westerly belt and monsoon were the main water vapor transport paths at each sampling point,with Central Asian continental water vapor dominating in spring(53.49%),Indian Ocean water vapor dominating in summer(52.53%),Atlantic Ocean water vapor dominating in autumn(46.74%),and Atlantic Ocean and Mediterranean Sea water vapor dominating in winter(42.30%and 33.68%,respectively).Changes in the intensity of convective activity and Outgoing Longwave Radiation(OLR)affected the enrichment of isotopic values,which exhibited the same change trends as δ^(18)O.During the precipitation process,the δ^(18)O value first decreased and then increased.During the initial and final stages of precipitation process,precipitation was mainly influenced by continental air masses,while during the middle stage,it was controlled by marine air masses.The systematic research on precipitation isotopes and water vapor sources is important for climate change research and extreme precipitation prediction on the Gannan Plateau and other similar areas.展开更多
Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan Distr...Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan District,Xilin Gol League,Inner Mongolia,China.It established 12 monitoring sites,conducted one-year monitoring,and collected 144 samples.The concentrations of nitrogen,phosphorus,and water-soluble ions in atmospheric wet sedimentation were measured.This study identified atmospheric precipitation types,revealed seasonal variations in nitrogen and phosphorus concentrations,assessed the contribution of atmosphericwet sedimentation to reservoirwater quality.Utilizing the airmass backward trajectory(HYSPLIT)model and PMF model,themain pollution sources were analyzed.The results were as follows.1)During the observation period,the atmospheric precipitation types were nitric acid rain in spring,sulfuric acid rain in winter,and mixed acid rain in summer and autumn.2)The monthly concentrations of nitrogen and phosphorus of various forms varied significantly,with NH_(4)^(+)-N peaking in spring,NO_(3)^(-)-N and DOP in autumn,and DIP and DON in summer.Annual pollution loads of atmospheric nitrogen and phosphorus precipitation into the reservoir were 35.77 and 4.17 t/a,respectively,severely impacting reservoir water quality.3)Precipitation was negatively correlated with TN concentration,particularly with the NO_(3)^(-)-N/TN ratio,and positively correlated with TP and DIP concen-trations.4)The analysis of pollution sources indicated that the sources of atmospheric nitrogen and phosphorus wet deposition pollution in the study area included agricultural,anthropogenic,dust,and coal sources,with contribution rates of 32.4%,25.6%,21.0%,and 21.0%,respectively.展开更多
文摘39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.
基金supported by the National Natural Science Foundation of China(42430303)Strategy Priority Research Program(Category B)of the Chinese Academy of Sciences(XDB0710000)+2 种基金National Natural Science Foundation of China(42288201)the National Key R&D Program of China(2023YFF0803203)the IGGCAS start-up funding(Grant No.E251510101).
文摘In wave-equation migration and demigration,the cross-correlation imaging/forwarding step implicitly injects an additional copy of the source wavelet,so that the amplitude spectrum of the wavelet is applied redundantly(effectively imposing a wavelet-spectrum weighting,often akin to an amplitude-squared bias).This redundancy degrades structural fidelity and amplitude balance yet is frequently overlooked.We(i)formalize the mechanism by which cross-correlation duplicates the source-wavelet amplitude effect in both migration and demigration,and(ii)introduce a source-equalized operator that removes the redundancy by deconvolving(or dividing by)the wavelet amplitude spectrum in the imaging condition and its demigration counterpart,while leaving phase/kinematics intact.Using a band-limited Ricker wavelet on a two-layer model and on Marmousi,we show that,if unmanaged,the redundant wavelet spectrum broadens main lobes,introduces ringing,and suppresses vertical resolution in migrated images,and inflates spectrum mismatches between demigrated and observed data even when peak times agree.With our correction,images recover observed-data-consistent bandwidth and sharpened interfaces,and demigrated data also exhibit improved spectrum conformity and reduced amplitude misfit.The results clarify when source amplitudes matter,why cross-correlation makes them redundantly matter,and how a lightweight spectral correction restores physically meaningful amplitude behavior in wave-equation migration/demigration.
基金supported by the National Natural Science Foundation of China(42362022)the Open Fund of the Shaanxi Key Laboratory of Petroleum Accumulation Geology(PAG-202406)the Open Fund of the Mine Geology and Environment Academician and Expert Workstation(2024OITYSZJGZZ-005)。
文摘This study investigated the heterogeneous responses of organic matter(OM)in highly-to over-mature source rocks during thermal maturation.An integrated analysis was conducted on the Raman spectroscopic and geochemical signatures of shales from the Lower Silurian Longmaxi Formation and the Lower Cambrian Qiongzhusi Formation,as well as anthracites from the Lower Permian Shanxi–Formation and the Upper Carboniferous Taiyuan Formation(collectively referred to as the Shanxi Taiyuan Formations).Additionally,burial and thermal evolution modeling was employed to support the analysis.A systematic assessment of Raman spectral parameters(e.g.,the positions and intensity ratio of the D and G bands)revealed robust correlations between the thermal history patterns of source rocks and molecular structural evolution parameters.The subsequent mechanistic quantification demonstrated that the maturation state of the source rocks was subjected to the hierarchical control of three principal factors:Peak heating temperature,the duration of sustained thermal intensity,and effective maturation duration.In addition,comparative analyses demonstrated that the anthracites attained higher structural ordering under sustained thermal conditions.This contrasts with the disordered carbon matrices observed in the intermittently heated shales.Raman spectroscopy further revealed broader variations in the D and G band intensities of the Longmaxi Formation compared to the Qiongzhusi Formation.This difference is associated with their different thermal histories.The thermal burial histories confirm that shales in the Longmaxi Formation underwent thermal exposure at lower peak temperatures over a shorter duration compared to those in the Qiongzhusi Formation.Finally,this study established a maturity calibration model for over-mature source rocks through a systematic correlation between Raman peak height ratios(R_(D/G))and vitrinite reflectance(R_(o)).
文摘This study examined a case of ventilator-associated pneumonia caused by Ralstonia mannitolilytica in a neonatal department in order to determine the source of infection and mode of transmission.Symptoms of infection began to appear on day 16 of admission,and both sputum and catheter tip cultures revealed R.mannitolilytica.The infection control department of the hospital later sampled and identified R.mannitolilytica in the ventilator tube that was used by the patient with the exact gene sequence as the infecting strain.These findings indicate that ventilator tubing is a significant contamination source of this pathogen,and hospitals need to enhance their disinfection methods of ventilator-related devices.
基金supported by the National Natural Science Foundation of China(41902310,42372348,42372286)Deep Earth Probe and Mineral Resources Exploration-National Science and Technology Major Project(2024ZD1003607)+2 种基金China Geological Survey Projects(DD20230700802,DD20221819)the Basic Research Fund of the Chinese Academy of Geological Sciences(JKYQN202306)Key Research and Development Program of Shanxi Province,China(202102090301009).
文摘The Mianhuakeng uranium deposit,characterized by uranium-rich granite,serves as a key site for research into crustal radioactive heating.Based on 45 rock samples,this study reviews that the host granite in the Mianhuakeng uranium deposit has a high radioactive heat production rate(avg.5.50μW/m³)and a low Th/U ratio(avg.2.62).Uranium-rich granite and its alteration zone within the upper crust(0-5 km depth)contribute about 45%of the total radioactive heat production,wich is crucial for controlling geothermal resource distribution.For uranium-thermal at tectonic plate margins,a symbiotic geological model was proposed:Firstly,subduction of the Pacific Plate caused upwelling of the asthenosphere,generating a high heat-flow background.Secondly,heat transfer is enhanced by major faults such as the Youdong and Mianhuakeng faults.Subsequently,uranium was mobilized,transported,and enriched within the granite through deep siliceous hydrothermal activity and associated alteration.Ultimately,the uranium enrichment in granite leads to increased radioactive heat production,resulting in local thermal anomalies.This model provides a theoretical support for exploring and developing uranium-thermal symbiotic resources in South China.
基金financially supported by the National Key Research and Development Program of China(2024YFD1700104 and 2022YFE0209200-03)the National Natural Science Foundation of China(42161144002 and 41977156)+3 种基金the Guangxi Natural Science Foundation,China(2022GXNSFBA035625)the Guangxi Technology Base and Talent Subject,China(Guike AD22035927)the Shandong Key Research and Development Project,China(2022TZXD0045)the State Key Laboratory of Earth System Numerical Modeling and Application,Institute of Atmospheric Physics,Chinese Academy of Sciences。
文摘Intervention strategies to control non-point source nitrogen(N)and phosphorus(P)pollution in agriculture are expensive and there is a trade-off between engineering cost and treatment effectiveness.Implementing strategies often result in unsatisfactory outcomes and massive engineering costs when managing diffusive pollution in agricultural catchments.To address this issue,this paper proposes a robust,handy,catchment N&P decision support system(CNPDSS),an Android-based smartphone system integrated with a web-based geographic information system(GIS).The CNPDSS aims to provide artificial intelligence-driven decisions that minimize N&P loadings and engineering costs for mitigating pollution in agricultural catchments.It consists of four components:a general user interface(GUI),GIS,N&P pollution modeling(NPPM),and a DSS.The CNPDSS simplifies the GUI and integrates GIS modules to create a user-friendly interface,enabling non-professional users to operate the system easily through intuitive actions.The NPPM uses straightforward empirical models to predict N&P loadings,enhancing efficiency by avoiding excessive parameters.Taking into account the N&P movement pathway in the catchment,the DSS incorporates three control measures:source reduction in farmland(before migration stage),process retention by ecological ditch(midway transport stage),and down-end purification by constructed wetland(waterbody discharge stage),to formulate a comprehensive ternary controlling strategy.To optimize the cost-effectiveness of any proposed N&P control strategies for sub-catchments,a differential evolution algorithm(DEA)is employed in CNPDSS to carry out a dual-objective decision-making optimization computation.In this study,the CNPDSS is applied to a case study in an agricultural catchment in Central China to develop the most cost-effective ternary N&P control strategies that ensure the catchment water quality within Criterion Ⅲ of the Chinese Surface Water Quality Standard GB3838-2002 is met(total N concentration≤1.0 mg L^(-1)and total P concentration≤0.2 mg L^(-1)).Our results demonstrate that the CNPDSS is feasible and also possesses an adaptive design and flexible architecture to enable its generalization and extension to support strong hands-on applications in other catchments.
基金supported by National Key R&D grant from the Ministry of Science and Technology of China(Nos.2021YFA1601600,2023YFA1606200)National Science Foundation of China(Nos.12090062,12105008)the Major State Basic Research Development Program of China.
文摘We present the preparation and measurement of the radioactive isotope^(37)Ar,which was produced using thermal neutrons from a reactor,as a calibration source for liquid xenon time projection chambers.^(37)Ar is a low-energy calibration source with a half-life of 35.01 days,making it suitable for calibration in the low-energy region of liquid xenon dark-matter experiments.Radioactive isotope^(37)Ar was produced by irradiating ^(36)Ar with thermal neutrons.It was subsequently measured in a gaseous xenon time projection chamber(GXe TPC)to validate its radioactivity.Our results demonstrate that^(37)Ar is an effective and viable calibration source that offers precise calibration capabilities in the low-energy domain of xenon-based detectors.
基金support from the Natural Science Foundation of Jiangsu Province(Grant No.BK20240036)the National Natural Science Foundation of China(Grant Nos.U24A20515,22276099,and 22361162668)Guangxi Key Research and Development Program,China(Grant No.Guike AB24010074)。
文摘We conducted a field campaign to investigate the chemical composition,sources,and light absorption of submicron aerosols(PM_(1))from early 2022 in Nanjing,China.The average concentration of PM_(1) was 31μg m^(−3),organics(33%)constituted the largest fraction,followed by nitrate(30%),sulfate(18%),ammonium(15%),chloride(3%),and rBC(2%).Four organic aerosol(OA)subcomponents were identified,including two primary OA(POA)and two secondary OA(SOA).The less-oxidized SOA(LO-OOA)contributes the most to the total OA mass(59%).LO-OOA is tightly correlated with the tracer ion C_(2)H_(4)O_(2)^(+)from levoglucosan,and another aged biomass-burning derived species,K_(3)SO_(4)^(+),suggesting it was likely influenced by aged biomass-burning OA.Our study also revealed that fireworks during the Spring Festival have a detrimental impact on air quality,contributing to secondary formation and accumulation under static winter meteorological conditions,prolonging the pollution duration.Also,LO-OOA was found to have the strongest light-absorbing ability.Our results highlight that the light absorption of LO-OOA can mainly be attributed to the C_(x)H_(y)N^(+) family,increased with the double-bond equivalent value.The more-oxidized SOA(MO-OOA)exhibited a negligible light absorption and was strongly correlated with daytime photochemical processes,implying a light-bleaching effect.This study enhances our understanding of the regional contribution of biomass combustion and fireworks to PM_(1) pollution in Nanjing,a typical megacity in the Yangtze River Delta region,during winter,aiding in the development of strategies for long-term air quality improvement in the region.
基金supported by the National Natural Science Foundation of China(Nos.41905108 and 42130704).
文摘Carbonyl compounds play a pivotal role in the formation of secondary pollutants such as O_(3) and SOA,signifi-cantly impacting air quality and human health.This study extended the observation period compared to previous research,providing a long-term perspective on carbonyl compound variations and their environmental implica-tions.Atmospheric observations were conducted at Beijing(BJ)and Xianghe(XH)during the summer and winter months of 2018,2019,and 2023 to study the sources and impacts of carbonyl compounds in typical urban areas and peri‑urban areas.Notably,concentrations in the summer of 2023 increased compared to 2018 and 2019.The predominant carbonyl compounds—formaldehyde,acetaldehyde,and acetone—accounted for over 60%of the total.The mean values of OFP in BJ ranged from 18.55 to 58.61μg/m3,lower than those in XH(29.82 to 65.48μg/m3),with formaldehyde and acetaldehyde contributing over 80%of the total.SOAP exhibited a similar pattern,with values in XH(69.21 to 508.55μg/m3)significantly exceeding those in BJ(34.47 to 159.78μg/m3).The PMF model highlighted vehicle exhaust,secondary pollution,and biomass combustion as major sources of carbonyl compounds,emphasizing differences in source contributions between the two regions.This study’s com-parative analysis over different years and locations provides new insights into the dynamic changes in carbonyl compounds and their environmental importance.These results not only reinforce the importance of carbonyl compounds regulation but also offer a valuable reference for evaluating and refining emission control strategies during this period.
基金support from the National Natural Science Foundation of China(Grant Nos.42177142 and 52378477)the Key Research and Development Program of Shaanxi(Grant No.2023-YBSF-486).
文摘The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment.In this study,terrestrial laser scanning(TLS)and unmanned aerial vehicle(UAV)technologies were integrated to enhance the evaluation methodology for rock mass hazard sources,focusing on the Sichuan Yanjiang Expressway project in China.The findings demonstrate that TLS-UAV technology enhanced both spatial coverage and data density in slope modeling.Through integrated algorithmic analysis,rock discontinuities within heterogeneous datasets were systematically identified,enabling quantitative extraction and statistical analysis of key geometric parameters,including orientation,trace length,spacing,and roughness.Furthermore,quantitative models were developed for cohesion,friction angle and the morphology parameter M of in situ discontinuities,respectively,facilitating efficient mechanical parameter acquisition.A novel rock mass hazard index(RHI)was developed incorporating discontinuity geometric rating(DGR),discontinuity mechanical rating(DMR),and slope mass rating(SMR).Field validation confirmed the methodology's effectiveness in evaluating risk levels and spatial heterogeneity of rock mass hazard sources,revealing the contribution of different discontinuity sets to the rock mass hazard and identifying the primary discontinuity sets controlling instability mechanisms.This study is of great significance for evaluating discontinuity-controlled rock mass hazard sources and preventing rockfall disasters.
基金supported by the National Natural Science Foundation of China(Grant No.42130312)。
文摘The complexity of the seismicity pattern for the subduction zone along the oceanic plate triggered the outer rise events and revealed cyclic tectonic deformation conditions along the plate subduction zones.The outer rise earthquakes have been observed along the Sunda arc,following the estimated rupture area of the 2005 M_(W)8.6 Nias earthquakes.Here,we used kinematic waveform inversion(KIWI)to obtain the source parameters of the 14 May 2021 M_(W)6.6 event off the west coast of northern Sumatra and to define the fault plane that triggered this outer rise event.The KIWI algorithm allows two types of seismic source to be configured:the moment tensor model to describe the type of shear with six moment tensor components and the Eikonal model for the rupture of pure double-couple sources.This method was chosen for its flexibility to be applied for different sources of seismicity and also for the automated full-moment tensor solution with real-time monitoring.We used full waveform traces from 8 broadband seismic stations within 1000 km epicentral distances sourced from the Incorporated Research Institutions for Seismology(IRIS-IDA)and Geofon GFZ seismic record databases.The initial origin time and hypocenter values are obtained from the IRIS-IDA.The synthetic seismograms used in the inversion process are based on the existing regional green function database model and were accessed from the KIWI Tools Green's Function Database.The obtained scalar seismic moment value is 1.18×10^(19)N·m,equivalent to a moment magnitude M_(W)6.6.The source parameters are 140°,44°,and−99°for the strike,dip,and rake values at a centroid depth of 10.2 km,indicating that this event is a normal fault earthquake that occurred in the outer rise area.The outer rise events with normal faults typically occur at the shallow part of the plate,with nodal-plane dips predominantly in the range of 30°-60°on the weak oceanic lithosphere due to hydrothermal alteration.The stress regime around the plate subduction zone varies both temporally and spatially due to the cyclic influences of megathrust earthquakes.Tensional outer rise earthquakes tend to occur after the megathrust events.The relative timing of these events is not known due to the viscous relaxation of the down going slab and poroelastic response in the trench slope region.The occurrence of the 14 May 2021 earthquake shows the seismicity in the outer rise region in the strongly coupled Sunda arc subduction zone due to elastic bending stress within the duration of the seismic cycle.
基金supported by the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(No.2019QZKK0208)the National Natural Science Foundation of China(Nos.42171148 and 42330512)the Key R&D Project from the Science and Technology Department of Tibet(No.XZ202501ZY0030).
文摘Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in alpine mountains with climate change.Hence,94 samples of river water were collected from 2018 to 2020 in the headwaters of the Shule River Basin to assess the nutrients spatiotemporal distribution and combined ap-proach of water quality index to assess water quality and potential sources.The findings depict that high nutrient concentrations were found to coincide with snowmelt and glacial meltwater and rainfall recharge periods,while total flux peaked from June to September due to increased runoff.Notably,total nitrogen(TN)concentrations were significantly higher near the town,primarily attributed to the replenishment of nitrate(NO_(3)^(‒)-N)from live-stock manure.The high total P(TP)was near the glacier,which was attributed to the transportation of glacial sediments into the river,and pH was another critical factor.N was the primary nutrient limiting factor for the growth of phytoplankton in river water.Although the migration and transport of nutrients have altered with climate change,river water quality is good in alpine mountains based on an overall evaluation.These findings contribute to enriching nutrient datasets and highlight the importance of water resource management and water quality assessment in sensitive and fragile alpine mountains.
基金supported by the National Key R&D Program of China(No.2022YFC3003502)。
文摘In this study,a seismic hazard algorithm was developed,coupled with a multi-source model.The algorithm can calculate the seismic hazard of 2D planar sources and 3D fault sources.A point source model is used to calculate the 2D planar potential seismic source by discretizing the potential seismic source into grid points which represent seismic sources.In contrast,a rupture surface model is used to calculate the 3D fault source so as to account for the influence of rupture scale in large earthquakes.The corresponding computational software was developed in Java and was tested on a study area 39.2°N-40.4°N and 116.6°E-118.7°E;the Tangshan and Xiadian faults were used to construct the fault source.Compared with the hazard results obtained using a point source model to calculate a 2D planar potential seismic source,the hazard results will be higher when a rupture surface model is used to calculate a 3D fault source.Moreover,a lower exceedance probability corresponds to a greater contribution rate of the fault source to the hazard and a greater seismic hazard closer to the fault.The algorithm can be used for seismic hazard analysis and can serve as a reference for the development of next-generation methods for zoning areas based on seismic ground motion.
基金pported by the National Natural Science Foundation of China(Grant Nos.12325409,12388102,12074398,and U2267204)the CAS Project for Young Scientists in Basic Research(Grant No.YSBR-060)the Shanghai Pilot Program for Basic Research,Chinese Academy of Sciences Shanghai Branch。
文摘A new on-chip light source configuration has been proposed,which utilizes the interaction between a microwave or laser and a dielectric nanopillar array to generate a periodic electromagnetic near-field and applies periodic transverse acceleration to relativistic electrons to generate high-energy photon radiation.The dielectric nanopillar array interacting with the driving field acts as an electron undulator,in which the near-field drives electrons to oscillate.When an electron beam propagates through this nanopillar array in this light source configuration,it is subjected to a periodic transverse near-field force and will radiate X-ray or evenγ-ray high-energy photons after a relativistic frequency up-conversion.Compared with the undulator which is based on the interaction between strong lasers and nanostructures to generate a plasmonic near-field,this configuration is less prone to damage during operation.
基金supported in part by the National Key Research and Development Program of China under Grant No.2024YFE0200600the Zhejiang Provincial Natural Science Foundation of China under Grant No.LR23F010005the Huawei Cooperation Project under Grant No.TC20240829036。
文摘Along with the proliferating research interest in semantic communication(Sem Com),joint source channel coding(JSCC)has dominated the attention due to the widely assumed existence in efficiently delivering information semantics.Nevertheless,this paper challenges the conventional JSCC paradigm and advocates for adopting separate source channel coding(SSCC)to enjoy a more underlying degree of freedom for optimization.We demonstrate that SSCC,after leveraging the strengths of the Large Language Model(LLM)for source coding and Error Correction Code Transformer(ECCT)complemented for channel coding,offers superior performance over JSCC.Our proposed framework also effectively highlights the compatibility challenges between Sem Com approaches and digital communication systems,particularly concerning the resource costs associated with the transmission of high-precision floating point numbers.Through comprehensive evaluations,we establish that assisted by LLM-based compression and ECCT-enhanced error correction,SSCC remains a viable and effective solution for modern communication systems.In other words,separate source channel coding is still what we need.
基金supported by the CNPC Science and Technology Major Project of the Fourteenth Five-Year Plan(2021DJ0101)the National Natural Science Foundation of China(U19B600302,41872148)。
文摘The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Paleozoic.However,its hydrocarbon generation and evolution characteristics and resource potential have long been constrained by deeply buried strata and previous research.In this paper,based on the newly obtained ultra-deep well drilling data,the hydrocarbon generation and expulsion model ofЄ_(1)y shale was established by using data-driven Monte Carlo simulation,upon which the hydrocarbon generation,expulsion,and retention amounts were calculated by using the diagenetic method.The research indicates that theЄ_(1)y shale reaches the hydrocarbon generation and expulsion threshold at equivalent vitrinite reflectances of 0.46%and 0.72%,respectively.The cumulative hydrocarbon generation is 68.88×10^(10)t,the cumulative hydrocarbon expulsion is 35.59×10^(10)t,and the cumulative residual hydrocarbon is 33.29×10^(10)t.This paper systematically and quantitatively calculates the hydrocarbon expulsion at various key geological periods for theЄ_(1)y source rocks in the study area for the first time,more precisely confirming that the black shale of theЄ_(1)y is the most significant source rock contributing to the marine oil and gas resources in the Tarim Basin,filling the gap in hydrocarbon expulsion calculation in the study area,and providing an important basis for the formation and distribution of Paleozoic hydrocarbon reservoirs.The prospect of deep ultra-deep oil and gas exploration in the Tarim Basin is promising.Especially,the large area of dolomite reservoirs under the Cambrian salt and source rock interiors are the key breakthrough targets for the next exploration in the Tarim Basin.
基金supported by the National Institute of Environmental Research(NIER)funded by the Ministry of Environment(No.NIER-2019-04-02-039)supported by Particulate Matter Management Specialized Graduate Program through the Korea Environmental Industry&Technology Institute(KEITI)funded by the Ministry of Environment(MOE).
文摘Fine particulatematter(PM_(2.5))samples were collected in two neighboring cities,Beijing and Baoding,China.High-concentration events of PM_(2.5) in which the average mass concentration exceeded 75μg/m^(3) were frequently observed during the heating season.Dispersion Normalized Positive Matrix Factorization was applied for the source apportionment of PM_(2.5) as minimize the dilution effects of meteorology and better reflect the source strengths in these two cities.Secondary nitrate had the highest contribution for Beijing(37.3%),and residential heating/biomass burning was the largest for Baoding(27.1%).Secondary nitrate,mobile,biomass burning,district heating,oil combustion,aged sea salt sources showed significant differences between the heating and non-heating seasons in Beijing for same period(2019.01.10–2019.08.22)(Mann-Whitney Rank Sum Test P<0.05).In case of Baoding,soil,residential heating/biomass burning,incinerator,coal combustion,oil combustion sources showed significant differences.The results of Pearson correlation analysis for the common sources between the two cities showed that long-range transported sources and some sources with seasonal patterns such as oil combustion and soil had high correlation coefficients.Conditional Bivariate Probability Function(CBPF)was used to identify the inflow directions for the sources,and joint-PSCF(Potential Source Contribution Function)was performed to determine the common potential source areas for sources affecting both cities.These models facilitated a more precise verification of city-specific influences on PM_(2.5) sources.The results of this study will aid in prioritizing air pollution mitigation strategies during the heating season and strengthening air quality management to reduce the impact of downwind neighboring cities.
基金supported by the National Natural Science Foundation of China(Nos.U23A2016,U1704241,and 42007175).
文摘Water-soluble organic nitrogen(WSON)affects the formation,hygroscopicity,acidity of organic aerosols,and nitrogen biogeochemical cycles.However,qualitative and quantitative characterizations of WSON remain limited due to its chemical complexity.In the study,1-year field samples of particulate matter 2.5(PM_(2.5))were collected fromJune 2022 to May 2023 to analyze the WSON concentration in PM_(2.5),and correlation analysis,positive matrix factor(PMF),and potential source contribution function(PSCF)modelswere employed to elucidate WSON source apportionment and transport pathways.The results revealed that the mean WSON concentrations reached 1.98±2.64μg/m^(3) with a mean WSON to water-soluble total nitrogen(WSTN)ratio of 21%.Further,WSON concentration exhibited a seasonal variation trend,with higher values in winter and lower in summer.Five sources were identified as contributors to WSON in PM_(2.5) within the reservoir area through a comprehensive analysis including correlation analysis,PSCF and concentration weighted trajectory(CWT),and PMF analyses.These sources were agricultural,dust,combustion,traffic,and industrial sources,of which agricultural source emerged as the primary contributor(76.69%).The atmosphere in the reservoir area were primarily influenced by the transport of northeastern air masses,local agricultural activities,industrial cities along the trajectory,and coastal regions,exerting significant influences on the concentration of WSON in the reservoir area.The findings of this study addressed the research gap concerning organic nitrogen in PM_(2.5) within the reservoir area,thereby offering a theoretical foundation and data support in controlling nitrogen pollution in the Danjiangkou Reservoir area.
基金supported by the National Natural Science Foundation of China(42161007)the Innovation Foundation of Higher Education Institutions of Gansu Province(2021B-081)the Foundation for Distinguished Young Scholars of Gansu Province(20JR10RA112).
文摘Precipitation isotopes(δ^(18)O and δ^(2)H)are closely related to meteorological conditions for precipitation generation and the initial state of water vapor source areas,and are essential to the study of the regional hydrological cycle.The deuterium excess(d-excess)indicates deviation in isotope fractionation during evaporation and can trace water vapor sources.This study analyzed 443 precipitation samples collected from the Gannan Plateau,China in 2022 to assess precipitation isotope variations and their driving factors.Water vapor sources were evaluated using the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT),Concentration Weighted Trajectory(CWT),and Potential Source Contribution Factor(PSCF)models.Results showed that precipitation isotope values showed significant spatial and temporal variations on the Gannan Plateau.Temporally,precipitation isotope values peaked in June(when evaporation dominated)and minimized in March(depletion effect of air masses in the westerly wind belt).Spatially,the isotope values showed a distribution pattern of"high in the east and low in the west",which was mainly regulated by the differences in altitude and local meteorological conditions.Compared with the global meteoric water line(GMWL)with equation of δ^(2)H=8.00δ^(18)O+10.00,the slope and intercept of local meteoric water line(LMWL)for precipitation on the Gannan Plateau were smaller(7.49 and 7.63,respectively),reflecting the existence of a stronger secondary evaporation effect under the clouds in the region.The sources of water vapor on the Gannan Plateau showed significant seasonality and spatial heterogeneity.Specifically,the westerly belt and monsoon were the main water vapor transport paths at each sampling point,with Central Asian continental water vapor dominating in spring(53.49%),Indian Ocean water vapor dominating in summer(52.53%),Atlantic Ocean water vapor dominating in autumn(46.74%),and Atlantic Ocean and Mediterranean Sea water vapor dominating in winter(42.30%and 33.68%,respectively).Changes in the intensity of convective activity and Outgoing Longwave Radiation(OLR)affected the enrichment of isotopic values,which exhibited the same change trends as δ^(18)O.During the precipitation process,the δ^(18)O value first decreased and then increased.During the initial and final stages of precipitation process,precipitation was mainly influenced by continental air masses,while during the middle stage,it was controlled by marine air masses.The systematic research on precipitation isotopes and water vapor sources is important for climate change research and extreme precipitation prediction on the Gannan Plateau and other similar areas.
基金supported by Inner Mongolia Autonomous Region Department of Education Science and Technology Talent Project(No.NJYT22040)Inner Mongolia Agricultural University Young Teachers'Scientific Research Ability Promotion Project(No.BR220102)+4 种基金the National Natural Science Foundation of China(No.52260029)the National Key R&D Program(No.2019YFC0409204)Inner Mongolia Natural Science Foundation(No.2021MS04013)the Science and Technology Project of Inner Mongolia Autonomous Region(No.2023YFHH0060)Inner Mongolia AutonomousRegion Science and Technology Leading TalentTeam(No.2022LJRC0007).
文摘Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan District,Xilin Gol League,Inner Mongolia,China.It established 12 monitoring sites,conducted one-year monitoring,and collected 144 samples.The concentrations of nitrogen,phosphorus,and water-soluble ions in atmospheric wet sedimentation were measured.This study identified atmospheric precipitation types,revealed seasonal variations in nitrogen and phosphorus concentrations,assessed the contribution of atmosphericwet sedimentation to reservoirwater quality.Utilizing the airmass backward trajectory(HYSPLIT)model and PMF model,themain pollution sources were analyzed.The results were as follows.1)During the observation period,the atmospheric precipitation types were nitric acid rain in spring,sulfuric acid rain in winter,and mixed acid rain in summer and autumn.2)The monthly concentrations of nitrogen and phosphorus of various forms varied significantly,with NH_(4)^(+)-N peaking in spring,NO_(3)^(-)-N and DOP in autumn,and DIP and DON in summer.Annual pollution loads of atmospheric nitrogen and phosphorus precipitation into the reservoir were 35.77 and 4.17 t/a,respectively,severely impacting reservoir water quality.3)Precipitation was negatively correlated with TN concentration,particularly with the NO_(3)^(-)-N/TN ratio,and positively correlated with TP and DIP concen-trations.4)The analysis of pollution sources indicated that the sources of atmospheric nitrogen and phosphorus wet deposition pollution in the study area included agricultural,anthropogenic,dust,and coal sources,with contribution rates of 32.4%,25.6%,21.0%,and 21.0%,respectively.
