Electrochemical CO_(2)reduction has been considered a promising approach to neutralizing the global CO_(2)level.As an intriguing technique,metal-CO_(2)battery devices can not only capture CO_(2)into valuable carbonace...Electrochemical CO_(2)reduction has been considered a promising approach to neutralizing the global CO_(2)level.As an intriguing technique,metal-CO_(2)battery devices can not only capture CO_(2)into valuable carbonaceous chem-icals and reduce the CO_(2)concentration in the atmosphere but enable energy conversion.Among metal-CO_(2)batteries,aqueous Zn–CO_(2)batteries,especially rechargeable systems,exhibit flexible CO_(2)electrochemistry in terms of multi-carbon chemicals,which are gaseous or water-soluble,in favor of rechargeability and cycling durability of aqueous battery systems.Despite the increasing number of publications on Zn–CO_(2)batteries in the past three years,this field is still in its beginning stage and facing many challenges considering the capability of CO_(2)fixation and battery performance.Herein,we present a timely and overall summary of the recent progress in Zn–CO_(2)batteries,including fundamental mechanisms,affecting factors on electrochemical performance,catalyst cathodes,and electrolytes(catholytes and anolytes).Besides,we assess the application potential of Zn–CO_(2)batteries and compare this with those of alkali metal-CO_(2)batteries based on CO_(2)fixation and battery perfor-mance.Finally,we point out some current challenges for the further development of Zn–CO_(2)batteries and put forward perspectives of the research directions for practical applications of Zn–CO_(2)batteries in the future.展开更多
基金supported by the National Key R&D Program of China under Project 2019YFA0705104GRF under Project CityU11212920.
文摘Electrochemical CO_(2)reduction has been considered a promising approach to neutralizing the global CO_(2)level.As an intriguing technique,metal-CO_(2)battery devices can not only capture CO_(2)into valuable carbonaceous chem-icals and reduce the CO_(2)concentration in the atmosphere but enable energy conversion.Among metal-CO_(2)batteries,aqueous Zn–CO_(2)batteries,especially rechargeable systems,exhibit flexible CO_(2)electrochemistry in terms of multi-carbon chemicals,which are gaseous or water-soluble,in favor of rechargeability and cycling durability of aqueous battery systems.Despite the increasing number of publications on Zn–CO_(2)batteries in the past three years,this field is still in its beginning stage and facing many challenges considering the capability of CO_(2)fixation and battery performance.Herein,we present a timely and overall summary of the recent progress in Zn–CO_(2)batteries,including fundamental mechanisms,affecting factors on electrochemical performance,catalyst cathodes,and electrolytes(catholytes and anolytes).Besides,we assess the application potential of Zn–CO_(2)batteries and compare this with those of alkali metal-CO_(2)batteries based on CO_(2)fixation and battery perfor-mance.Finally,we point out some current challenges for the further development of Zn–CO_(2)batteries and put forward perspectives of the research directions for practical applications of Zn–CO_(2)batteries in the future.
