Numerical simulation technology has been widely used in the foundry industry to analyze and improve casting processes.During the casting filling process,many filling-related defects form easily at the confluences of l...Numerical simulation technology has been widely used in the foundry industry to analyze and improve casting processes.During the casting filling process,many filling-related defects form easily at the confluences of liquid metal streams.The main filling-related defects are cold shut defects.To calculate the positions of casting defects,the characteristics of liquid metal confluences were analyzed.The flow front of liquid metal was captured by the volume-of-fluid algorithm to obtain a time field,which was used to calculate the time derivatives of the liquid front position and the confluences of liquid metal streams.To distinguish small confluences from the main confluences,the concept of confluent scale was developed,which was used to filter the small confluences based on a threshold.The calculation process was demonstrated through the post-processing of numerical simulation.A "W" shaped casting and a steering wheel casting were calculated to validate the accuracy of the method developed in this study.The positions of cold shut defects were predicted by calculating the confluences of liquid metal streams.The method was proved to be practical by comparing the calculation results with the positions of cold shut defects in an end cover casting.The computation of confluences and cold shut defects can improve the analysis efficiency and provide assurance for the optimization of a casting process plan.展开更多
The primary issue for the commercialization of proton exchange membrane fuel cell（PEMFC） is the carbon corrosion of support under start-up/shut-down conditions. In this study, we employ the nanostructured graphitize...The primary issue for the commercialization of proton exchange membrane fuel cell（PEMFC） is the carbon corrosion of support under start-up/shut-down conditions. In this study, we employ the nanostructured graphitized carbon induced by heat-treatment. The degree of graphitization starts to increase between 900 and 1300 ℃ as evidenced by the change of specific surface area, interlayer spacing, and ID/IG value. Pt nanoparticles are deposited on fresh carbon black（Pt/CB） and carbon heat-treated at 1700 ℃（Pt/HCB17） with similar particle size and distribution. Electrochemical characterization demonstrates that the Pt/HCB17 shows higher activity than the Pt/CB due to the inefficient microporous structure of amorphous carbon for the oxygen reduction reaction. An accelerating potential cycle between 1.0 and 1.5 V for the carbon corrosion is applied to examine durability at a single cell under the practical start-up/shutdown conditions. The Pt/HCB17 catalyst shows remarkable durability after 3000 potential cycles. The Pt/HCB17 catalyst exhibits a peak power density gain of 3%, while the Pt/CB catalyst shows 65% loss of the initial peak power density. As well, electrochemical surface area and mass activity of Pt/HCB17 catalyst are even more stable than those of the Pt/CB catalyst. Consequently, the high degree of graphitization is essential for the durability of fuel cells in practical start-up/shut-down conditions due to enhancing the strong interaction of Pt and π-bonds in graphitized carbon.展开更多
Drill string will sustain large uplift force during the shut-in period after gas overflow in an ultra-deep well, and in serious case, it will run out of the wellhead. A calculation model of uplift force was establishe...Drill string will sustain large uplift force during the shut-in period after gas overflow in an ultra-deep well, and in serious case, it will run out of the wellhead. A calculation model of uplift force was established to analyze dynamic change characteristics of the uplift force of drill string during the shut-in period, and then a management procedure for the uplift risk during the shut-in period after gas overflow in the ultra-deep well was formed. Cross section method and pressure area method were used to analyze the force on drill string after shut-in of well, it was found that the source of uplift force was the "fictitious force" caused by the hydrostatic pressure in the well. When the fictitious force is in the opposite direction to the gravity, it is the uplift force. By adopting the theory of annular multiphase flow, considering the effects of wellbore afterflow and gas slippage, the dynamic change of the pressure and fluid in the wellbore and the uplift force of drill string during the shut-in period were analyzed. The magnitude and direction of uplift force are related to the length of drill string in the wellbore and shut-in time, and there is the risk of uplift of drill string when the length of drill string in the wellbore is smaller than the critical drill string length or the shut in time exceeds the critical shut in time. A set of treatment method and process to prevent the uplift of drill string is advanced during the shut-in period after overflow in the ultra-deep well, which makes the risk management of the drill string uplift in the ultra-deep well more rigorous and scientific.展开更多
The preparation and implementation of raw coke oven gas cut-off, which was the key process involved with shutting down the Baosteel phase I coke ovens, were investigated, and the main technical points and countermeasu...The preparation and implementation of raw coke oven gas cut-off, which was the key process involved with shutting down the Baosteel phase I coke ovens, were investigated, and the main technical points and countermeasures are presented.展开更多
In this paper, the transient behavior of a low specific speed centrifugal pump with straight blades during shutting down is studied through the experimental test, theoretical calculation, and numerical simulation. The...In this paper, the transient behavior of a low specific speed centrifugal pump with straight blades during shutting down is studied through the experimental test, theoretical calculation, and numerical simulation. The variations of the rota- tional speed, flow rate, and head with time are obtained in experiment. Based on the experimental results of the rota- tional speed and flow rate, the additional theoretical heads are quantitatively calculated and analyzed. The experimental results of the rotational speed and flow rate are worked as the boundary conditions to accurately accomplish the nu- merical simulation of the transient flow during shutting down. The experimental results show that the decrease history of the flow rate evidently lags behind that of the rotational speed, while the rotational speed slightly lags behind the head. Theoretical analysis shows that there exists a clear negative head impact phenomenon in the process of stopping. The transient behavior of the centrifugal pump with straight blades mainly comes from the rotation deceleration of im- peller, and has nothing to do with the fluid deceleration. The numerical simulations show that a large area backflow can be seen when the rotational speed decreases to zero due to the flowing inertia. In conclusion, the numerical simulation of the flow field is in good agreement with the internal flow theory of centrifugal pumps.展开更多
During gel treatments for fractures, the leak-off behavior of gelant has a great effect on the water shut-off performance of gel. Experiments were carried out using a polymer/chromium(Cr^(3+)) gel system to explore th...During gel treatments for fractures, the leak-off behavior of gelant has a great effect on the water shut-off performance of gel. Experiments were carried out using a polymer/chromium(Cr^(3+)) gel system to explore the leak-off behavior and the water shut-off performance of gel in fractured media. Results of the gelant leak-off study show that the gelant leak-off from fracture into matrix contributes to the formation of the gelant leak-off layer during the gelant injection. Moreover, because of the gradual formation of the gelant leak-off layer along fracture, the initial leak-off ratio of gelant is relatively high, but it declines and finally levels off with the increase of the injection volume. The polymer concentration of gelant has a great effect on the chromium output in fluids produced from fractures. With the increase of the polymer concentration, the chromium concentration first decreases and then increases, and the leak-off depth of gelant into matrix is gradually reduced. Results of the water shut-off study present that the decrease of the chromium concentration inside the fracture greatly reduces the water shut-off performance after the gel formation. Therefore, because of the relatively high degree of chromium leak-off, enough injection volume of gelant is essential to ensure the sufficient chromium concentration inside the fracture and to further achieve a favorable water shut-off performance. On the premise of gel strength assurance inside the fracture, the water shut-off performance of gel gradually declines with the extension of the distance from the fracture inlet, and different leak-off degrees of gelant along the fracture are responsible for this phenomenon. Therefore, a proper degree of gelant leak-off contributes to enhancing the water shut-off performance of gel for fractures.展开更多
X oilfield is an offshore strong bottom water reservoir with water cut up to 96% at present, and liquid extraction has become one of the main ways to increase oil production. However, the current liquid production of ...X oilfield is an offshore strong bottom water reservoir with water cut up to 96% at present, and liquid extraction has become one of the main ways to increase oil production. However, the current liquid production of the oilfield reaches 60,000 m</span><sup><span style="font-family:Verdana;">3</span></sup><span style="font-family:Verdana;">/d due to the limitation of offshore platform, well trough and equipment, the oilfield is unable to continue liquid extraction. In order to maximize the oil production of the oilfield, it is necessary to study the strategy of shut in and cone pressure. Through numerical simulation, this paper analyzes the influence of different factors, such as crude oil density, viscosity, reservoir thickness, interlayer, permeability and so on, on the drop height of water cone and the effect of precipitation and oil increase after well shut in. At the same time, the weight of each factor is analyzed by combining the actual dynamic data with the fuzzy mathematics method, and the strategy of well shut in and cone pressure is formulated for the offshore strong bottom water reservoir. It provides the basis and guidance for the reasonable use of shut in pressure cone when the reservoir with strong bottom water meets the bottleneck of liquid volume.展开更多
The dynamic model of LiBr absorption heat pump in shut-down process is established. The simulation results show good agreement with the experiments. The dynamic performance of high-pressure generator, low-pressure gen...The dynamic model of LiBr absorption heat pump in shut-down process is established. The simulation results show good agreement with the experiments. The dynamic performance of high-pressure generator, low-pressure generator and heat exchanger are analyzed in detail. The proper shut-down mode of the heat pump is presented,which, in consideration of solution parameters, has a great effect on the possibility of crystallization of some components.展开更多
The most important data on the thermal regime of the Earth’s interior come from temperature measurements in deep boreholes. The drilling process greatly alters the temperature field of formations surrounding the well...The most important data on the thermal regime of the Earth’s interior come from temperature measurements in deep boreholes. The drilling process greatly alters the temperature field of formations surrounding the wellbore. In permafrost regions, due to thawing of the formation surrounding the wellbore during drilling, representative data can be obtained only by repeated observations over a long period of time (up to 10 years). Usually a number of temperature logs (3 - 10) are taken after the well’s shut-in. Significant expenses (manpower, transportation) are required to monitor the temperature regime of deep wells. In this paper we show that in most of the cases (when the time of refreezing formations is less than the shut-in time) two temperature logs are sufficient to predict formations temperatures during shut-in, to determine the geothermal gradients, and to evaluate the thickness of the permafrost zone. Thus the cost of monitoring the temperature regime of deep wells after shut-in can be drastically reduced. A simple method to process field data (for the well sections below and above the permafrost base) is presented. Temperature logs conducted in two wells were used to demonstrate utilization of this method.展开更多
China pledges to crack down on counterfeit products to Africa MANY people who have traveled in Africa and visited some of many Chinese retail outlets across the continent have encountered cheap fake items on the shel...China pledges to crack down on counterfeit products to Africa MANY people who have traveled in Africa and visited some of many Chinese retail outlets across the continent have encountered cheap fake items on the shelves,which not only present a bad image of China’s manufacturing abilities but also infringe on the intellectual property rights of others.展开更多
Lithium-sulfur batteries(LSBs)are considered as the promising solution to replace conventional lithium-ion batteries due to satisfactory energy density.In recent times,the LSBs field has been found to face some diffic...Lithium-sulfur batteries(LSBs)are considered as the promising solution to replace conventional lithium-ion batteries due to satisfactory energy density.In recent times,the LSBs field has been found to face some difficulties in exploring practical applications in which cycling stability and cycle life are awful owing to the shuttling effect of lithium polysulfides(LiPSs)and low sulfur utilization.In this work,by synthesizing Co_(3)Se_(4) nanoparticles onto N-doped carbon(NC)polyhedra interconnected with carbon nanotubes(CNTs),NC@Co_(3)Se_(4)/CNTs is proposed as a multifunctional sulfur carrier.The Co_(3)Se_(4) nanoparticles fleetly catalyze the conversion of LiPSs and availably immobilize LiPSs.Meanwhile,the NC polyhedral skeleton enhances the electronic conductivity of active sulfur,while the CNTs facilitate Li+diffusion and supply a mass of conductive channels.Density-functional theory(DFT)calculations demonstrate the relevant mechanisms.That is to say,the NC@Co_(3)Se_(4)/CNTs benefit from the synergistic effect of Co_(3)Se_(4) nanoparticles(highly catalytic ability and strong adsorbability for LiPSs)and the special carbonaceous structure,rapidly converting LiPSs and inhibiting the shuttle of LiPSs.Therefore,lithium-sulfur battery assembled with S/NC@Co_(3)Se_(4)/CNTs cathode as well as nitrogen and sulfur co-doped carbon-coated polypropylene(N,S-C/PP)separator possesses a high initial discharge capacity of 1413 mAh·g-1 at 0.12C and persistently circulates for 1000 cycles at 1C with a capacity attenuation rate per cycle of 0.034%.This work provides a realistic idea for the use of transition metal selenide in the field of high-performance LSBs.展开更多
“Transformation is not simply about shutting down;it is more about eliminating outdated production capacity while nurturing new driving forces,”according to Wan Qian,a member of the Standing Committee of the Xiangxi...“Transformation is not simply about shutting down;it is more about eliminating outdated production capacity while nurturing new driving forces,”according to Wan Qian,a member of the Standing Committee of the Xiangxiang Municipal Party Committee,referring to an eco-friendly chemical industrial park in Xiangxiang City,central China’s Hunan Province.展开更多
基金supported by the National Key Research and Development Program of China(Nos.2020YFB2008300 and 2020YFB2008302)the Program of Key Research and Development Program of Guangdong Province(No.2019B090921001)。
文摘Numerical simulation technology has been widely used in the foundry industry to analyze and improve casting processes.During the casting filling process,many filling-related defects form easily at the confluences of liquid metal streams.The main filling-related defects are cold shut defects.To calculate the positions of casting defects,the characteristics of liquid metal confluences were analyzed.The flow front of liquid metal was captured by the volume-of-fluid algorithm to obtain a time field,which was used to calculate the time derivatives of the liquid front position and the confluences of liquid metal streams.To distinguish small confluences from the main confluences,the concept of confluent scale was developed,which was used to filter the small confluences based on a threshold.The calculation process was demonstrated through the post-processing of numerical simulation.A "W" shaped casting and a steering wheel casting were calculated to validate the accuracy of the method developed in this study.The positions of cold shut defects were predicted by calculating the confluences of liquid metal streams.The method was proved to be practical by comparing the calculation results with the positions of cold shut defects in an end cover casting.The computation of confluences and cold shut defects can improve the analysis efficiency and provide assurance for the optimization of a casting process plan.
文摘The primary issue for the commercialization of proton exchange membrane fuel cell（PEMFC） is the carbon corrosion of support under start-up/shut-down conditions. In this study, we employ the nanostructured graphitized carbon induced by heat-treatment. The degree of graphitization starts to increase between 900 and 1300 ℃ as evidenced by the change of specific surface area, interlayer spacing, and ID/IG value. Pt nanoparticles are deposited on fresh carbon black（Pt/CB） and carbon heat-treated at 1700 ℃（Pt/HCB17） with similar particle size and distribution. Electrochemical characterization demonstrates that the Pt/HCB17 shows higher activity than the Pt/CB due to the inefficient microporous structure of amorphous carbon for the oxygen reduction reaction. An accelerating potential cycle between 1.0 and 1.5 V for the carbon corrosion is applied to examine durability at a single cell under the practical start-up/shutdown conditions. The Pt/HCB17 catalyst shows remarkable durability after 3000 potential cycles. The Pt/HCB17 catalyst exhibits a peak power density gain of 3%, while the Pt/CB catalyst shows 65% loss of the initial peak power density. As well, electrochemical surface area and mass activity of Pt/HCB17 catalyst are even more stable than those of the Pt/CB catalyst. Consequently, the high degree of graphitization is essential for the durability of fuel cells in practical start-up/shut-down conditions due to enhancing the strong interaction of Pt and π-bonds in graphitized carbon.
基金Supported by China National Science and Technology Major Project(2016ZX05020-006)
文摘Drill string will sustain large uplift force during the shut-in period after gas overflow in an ultra-deep well, and in serious case, it will run out of the wellhead. A calculation model of uplift force was established to analyze dynamic change characteristics of the uplift force of drill string during the shut-in period, and then a management procedure for the uplift risk during the shut-in period after gas overflow in the ultra-deep well was formed. Cross section method and pressure area method were used to analyze the force on drill string after shut-in of well, it was found that the source of uplift force was the "fictitious force" caused by the hydrostatic pressure in the well. When the fictitious force is in the opposite direction to the gravity, it is the uplift force. By adopting the theory of annular multiphase flow, considering the effects of wellbore afterflow and gas slippage, the dynamic change of the pressure and fluid in the wellbore and the uplift force of drill string during the shut-in period were analyzed. The magnitude and direction of uplift force are related to the length of drill string in the wellbore and shut-in time, and there is the risk of uplift of drill string when the length of drill string in the wellbore is smaller than the critical drill string length or the shut in time exceeds the critical shut in time. A set of treatment method and process to prevent the uplift of drill string is advanced during the shut-in period after overflow in the ultra-deep well, which makes the risk management of the drill string uplift in the ultra-deep well more rigorous and scientific.
文摘The preparation and implementation of raw coke oven gas cut-off, which was the key process involved with shutting down the Baosteel phase I coke ovens, were investigated, and the main technical points and countermeasures are presented.
文摘In this paper, the transient behavior of a low specific speed centrifugal pump with straight blades during shutting down is studied through the experimental test, theoretical calculation, and numerical simulation. The variations of the rota- tional speed, flow rate, and head with time are obtained in experiment. Based on the experimental results of the rota- tional speed and flow rate, the additional theoretical heads are quantitatively calculated and analyzed. The experimental results of the rotational speed and flow rate are worked as the boundary conditions to accurately accomplish the nu- merical simulation of the transient flow during shutting down. The experimental results show that the decrease history of the flow rate evidently lags behind that of the rotational speed, while the rotational speed slightly lags behind the head. Theoretical analysis shows that there exists a clear negative head impact phenomenon in the process of stopping. The transient behavior of the centrifugal pump with straight blades mainly comes from the rotation deceleration of im- peller, and has nothing to do with the fluid deceleration. The numerical simulations show that a large area backflow can be seen when the rotational speed decreases to zero due to the flowing inertia. In conclusion, the numerical simulation of the flow field is in good agreement with the internal flow theory of centrifugal pumps.
基金Project(51404280)supported by the National Natural Science Foundation of ChinaProject(2014D-5006-0203)supported by the Petro China Innovation Foundation,China
文摘During gel treatments for fractures, the leak-off behavior of gelant has a great effect on the water shut-off performance of gel. Experiments were carried out using a polymer/chromium(Cr^(3+)) gel system to explore the leak-off behavior and the water shut-off performance of gel in fractured media. Results of the gelant leak-off study show that the gelant leak-off from fracture into matrix contributes to the formation of the gelant leak-off layer during the gelant injection. Moreover, because of the gradual formation of the gelant leak-off layer along fracture, the initial leak-off ratio of gelant is relatively high, but it declines and finally levels off with the increase of the injection volume. The polymer concentration of gelant has a great effect on the chromium output in fluids produced from fractures. With the increase of the polymer concentration, the chromium concentration first decreases and then increases, and the leak-off depth of gelant into matrix is gradually reduced. Results of the water shut-off study present that the decrease of the chromium concentration inside the fracture greatly reduces the water shut-off performance after the gel formation. Therefore, because of the relatively high degree of chromium leak-off, enough injection volume of gelant is essential to ensure the sufficient chromium concentration inside the fracture and to further achieve a favorable water shut-off performance. On the premise of gel strength assurance inside the fracture, the water shut-off performance of gel gradually declines with the extension of the distance from the fracture inlet, and different leak-off degrees of gelant along the fracture are responsible for this phenomenon. Therefore, a proper degree of gelant leak-off contributes to enhancing the water shut-off performance of gel for fractures.
文摘X oilfield is an offshore strong bottom water reservoir with water cut up to 96% at present, and liquid extraction has become one of the main ways to increase oil production. However, the current liquid production of the oilfield reaches 60,000 m</span><sup><span style="font-family:Verdana;">3</span></sup><span style="font-family:Verdana;">/d due to the limitation of offshore platform, well trough and equipment, the oilfield is unable to continue liquid extraction. In order to maximize the oil production of the oilfield, it is necessary to study the strategy of shut in and cone pressure. Through numerical simulation, this paper analyzes the influence of different factors, such as crude oil density, viscosity, reservoir thickness, interlayer, permeability and so on, on the drop height of water cone and the effect of precipitation and oil increase after well shut in. At the same time, the weight of each factor is analyzed by combining the actual dynamic data with the fuzzy mathematics method, and the strategy of well shut in and cone pressure is formulated for the offshore strong bottom water reservoir. It provides the basis and guidance for the reasonable use of shut in pressure cone when the reservoir with strong bottom water meets the bottleneck of liquid volume.
基金This paper is supported by thy UTC RongHong foundation
文摘The dynamic model of LiBr absorption heat pump in shut-down process is established. The simulation results show good agreement with the experiments. The dynamic performance of high-pressure generator, low-pressure generator and heat exchanger are analyzed in detail. The proper shut-down mode of the heat pump is presented,which, in consideration of solution parameters, has a great effect on the possibility of crystallization of some components.
文摘The most important data on the thermal regime of the Earth’s interior come from temperature measurements in deep boreholes. The drilling process greatly alters the temperature field of formations surrounding the wellbore. In permafrost regions, due to thawing of the formation surrounding the wellbore during drilling, representative data can be obtained only by repeated observations over a long period of time (up to 10 years). Usually a number of temperature logs (3 - 10) are taken after the well’s shut-in. Significant expenses (manpower, transportation) are required to monitor the temperature regime of deep wells. In this paper we show that in most of the cases (when the time of refreezing formations is less than the shut-in time) two temperature logs are sufficient to predict formations temperatures during shut-in, to determine the geothermal gradients, and to evaluate the thickness of the permafrost zone. Thus the cost of monitoring the temperature regime of deep wells after shut-in can be drastically reduced. A simple method to process field data (for the well sections below and above the permafrost base) is presented. Temperature logs conducted in two wells were used to demonstrate utilization of this method.
文摘China pledges to crack down on counterfeit products to Africa MANY people who have traveled in Africa and visited some of many Chinese retail outlets across the continent have encountered cheap fake items on the shelves,which not only present a bad image of China’s manufacturing abilities but also infringe on the intellectual property rights of others.
基金supported by the National Natural Science Foundation of China(Nos.52130101 and 52271217)the Project of Science and Technology Development Plan of Jilin Province in China(Nos.20210402058GH,20220201114GX).
文摘Lithium-sulfur batteries(LSBs)are considered as the promising solution to replace conventional lithium-ion batteries due to satisfactory energy density.In recent times,the LSBs field has been found to face some difficulties in exploring practical applications in which cycling stability and cycle life are awful owing to the shuttling effect of lithium polysulfides(LiPSs)and low sulfur utilization.In this work,by synthesizing Co_(3)Se_(4) nanoparticles onto N-doped carbon(NC)polyhedra interconnected with carbon nanotubes(CNTs),NC@Co_(3)Se_(4)/CNTs is proposed as a multifunctional sulfur carrier.The Co_(3)Se_(4) nanoparticles fleetly catalyze the conversion of LiPSs and availably immobilize LiPSs.Meanwhile,the NC polyhedral skeleton enhances the electronic conductivity of active sulfur,while the CNTs facilitate Li+diffusion and supply a mass of conductive channels.Density-functional theory(DFT)calculations demonstrate the relevant mechanisms.That is to say,the NC@Co_(3)Se_(4)/CNTs benefit from the synergistic effect of Co_(3)Se_(4) nanoparticles(highly catalytic ability and strong adsorbability for LiPSs)and the special carbonaceous structure,rapidly converting LiPSs and inhibiting the shuttle of LiPSs.Therefore,lithium-sulfur battery assembled with S/NC@Co_(3)Se_(4)/CNTs cathode as well as nitrogen and sulfur co-doped carbon-coated polypropylene(N,S-C/PP)separator possesses a high initial discharge capacity of 1413 mAh·g-1 at 0.12C and persistently circulates for 1000 cycles at 1C with a capacity attenuation rate per cycle of 0.034%.This work provides a realistic idea for the use of transition metal selenide in the field of high-performance LSBs.
文摘“Transformation is not simply about shutting down;it is more about eliminating outdated production capacity while nurturing new driving forces,”according to Wan Qian,a member of the Standing Committee of the Xiangxiang Municipal Party Committee,referring to an eco-friendly chemical industrial park in Xiangxiang City,central China’s Hunan Province.
